CN104262028B - A kind of medicine fertilizer composition comprising MTI-446 and/or phoxim - Google Patents
A kind of medicine fertilizer composition comprising MTI-446 and/or phoxim Download PDFInfo
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- CN104262028B CN104262028B CN201410559845.4A CN201410559845A CN104262028B CN 104262028 B CN104262028 B CN 104262028B CN 201410559845 A CN201410559845 A CN 201410559845A CN 104262028 B CN104262028 B CN 104262028B
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B1/00—Superphosphates, i.e. fertilisers produced by reacting rock or bone phosphates with sulfuric or phosphoric acid in such amounts and concentrations as to yield solid products directly
- C05B1/02—Superphosphates
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B17/00—Other phosphatic fertilisers, e.g. soft rock phosphates, bone meal
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/60—Biocides or preservatives, e.g. disinfectants, pesticides or herbicides; Pest repellants or attractants
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/80—Soil conditioners
Abstract
The present invention relates to a kind of medicine fertilizer composition, it comprises following components and weight percentage thereof: fertilizer component 70 95%, farm chemical ingredients 1 20%, auxiliary agent 1 10%.Wherein, one or more during described fertilizer includes organic fertilizer, inorganic fertilizer, complex fertilizer, organic-inorganic compound fertilizer, trace-element fertilizer.Described pesticide is selected from anabasine insecticide and/or organophosphorus insecticides.Described auxiliary agent includes one or more in solvent, surfactant, binding agent.
Description
Technical field
The present invention relates to agriculture field, be specifically related to a kind of comprise MTI-446 and or the medicine fertilizer composition of phoxim and
Its purposes.
Background technology
Rhizoma Solani tuber osi is a kind of Multifunctional crop, and it is possible not only to grain, dish dual-purpose, is again food processing industry, medical industry, spins
Raw material required for weaver's industry.Owing to its purposes is wide, market potential is big, so its economic benefit is much larger than other grains, economy
Crop.But, Rhizoma Solani tuber osi is from being seeded into results, during whole fertility, is endangered by many insects, especially by many undergrounds evil
The harm of worm, main subterranean pest-insect has Gryllotalpa, Holotrichia diomphalia Bates, cutworm etc., and this has had a strong impact on the yield of Rhizoma Solani tuber osi.Current preventing and treating
Method mainly includes field management (such as deep ploughing in autumn, cleaning rural area etc.), physical control (as adult is trapped and killed) and chemical prevention
Deng.The medicament wherein used in chemical prevention mainly includes metrifonate, phoxim, chlopyrifos etc., the life-time service of these medicaments,
Making insect create Drug resistance, prevention effect has declined.
Medicine fertilizer is to be mixed mutually with fertilizer formula according to a certain percentage by pesticide, and by certain Technology by fertilizer and
Pesticide is stable in specific compound system the novel ecological compound fertilizer formed, typically with the carrier of fertilizer used as pesticides.Medicine
Fertile two operating procedures in field can be made to unite two into one, this not only saves labour force, and decreases disappearing of time and the energy
Consumption.
Anabasine insecticide model of action is novel, select strong toxicity, efficiently, wide spectrum and good to Environmental compatibility.It is made
Mainly control insect nerve system nicotinic acetylcholine esterase receptor by selectivity by mechanism, block insecticide heatstroke neural
The normal conduction of system, thus cause insect that paralysis and then death occur.Owing to this insecticides has the mechanism of action of uniqueness,
Not having cross resistance with common insecticides, it not only has efficiently, absorption in wide spectrum and good root, tag and stomach toxicity is made
With, and low to mammalian toxicity, can effectively prevent and treat the insects such as Homoptera, coleoptera, Diptera and Lepidoptera, to by tradition
The insect that insecticide control develops immunity to drugs also has good activity.Anabasine insecticide can be not only used for stem and leaf and processes, also may be used
For soil, seed treatment.MTI-446 (dinotefuran) is the nicotinic insecticide of Mitsui company research and development, and it has
The widest insecticidal spectrum, and the most fool proof to crop, people and animals and environment.
Organophosphorus pesticide, is for preventing and treating phytopathy, worm, the organic compound containing organophosphorus pesticide of evil, this class agriculture
Medicine is wide in variety, drug effect is high, and purposes is wide, easily decomposes, does not typically accumulate in people, animal body, is a particularly important class in pesticide
Compound.Among these, phoxim insecticidal spectrum is wide, and power of knocking down is strong, becomes the important kind of organic phosphates.
It is fertile that CN101906001A discloses a kind of medicine comprising avilamycin, phoxim and/or chlopyrifos, including Ah
Dimension rhzomorph, phoxim and/or chlopyrifos, macroelement fertilizer, trace-element fertilizer and carrier, and disclose described medicine fertilizer energy
Enough prevent and treat corn field subterranean pest-insect and increase corn yield.
CN102204563A discloses a kind of insecticides containing MTI-446, and described insecticides is moisture
Shot agent, suspending agent or wettable powder, described insecticides comprises active component, composite assistant and filler, wherein
Described active component is 1 by mass ratio: the MTI-446 of (0.2～50) and another kind of insecticide form；Described another kind kills
Worm agent is Malathion, dichlorvos, phoxim or ethiprole, and specifically discloses the effect of described composition for preventing and controlling brown paddy plant hopper.
It is currently, there are the demand of the new drug fertilizer being effective between potato fields, and not for Ma Ling in prior art
The medicine of potato is fertile, and therefore, exploitation is applicable to the medicine fertilizer composition of Rhizoma Solani tuber osi and becomes current urgent problem.
Summary of the invention
In order to solve the problems referred to above, the present inventor through studying for a long period of time, finds to comprise anabasine pesticide and/or organic
Phosphorus pesticide, preferably comprise the medicine fertilizer composition of MTI-446 and phoxim when potato fields, it is possible to effectively ground, preventing and treating field
Lower insect, especially produces synergistic function to Holotrichia diomphalia Bates；The present inventor is the most also found surprisingly that the described medicine fertilizer composition of use
After, potato leaf chlorophyll content increased, and yield increases substantially.In view of above-mentioned discovery, the present inventor completes
The present invention.
One aspect of the present invention relates to a kind of medicine fertilizer composition, and it comprises following components and weight percentage thereof:
Fertilizer component 70-95%
Farm chemical ingredients 1-20%
Auxiliary agent 1-10%；
Wherein, described fertilizer includes organic fertilizer, inorganic fertilizer, complex fertilizer, organic-inorganic complex fertilizer, trace unit
One or more in fertilizer；
Described pesticide is selected from anabasine insecticide and/or organophosphorus insecticides；
Described auxiliary agent includes one or more in solvent, surfactant, binding agent.
The weight percentage of each component is preferably:
Fertilizer component 80-90%
Farm chemical ingredients 2-10%
Auxiliary agent 2-10%.
The weight percentage of each component is more preferably:
Fertilizer component 82%
Farm chemical ingredients 8%
Auxiliary agent 10%.
In above-mentioned medicine fertilizer composition, preferably:
Described organic fertilizer includes one or more in humic acids, rapeseed cake, bog moss, cottonseed cake, tea seed cake；
Described inorganic fertilizer includes carbamide, ammonium nitrate, MAP, Diammonium phosphate (DAP), potassium dihydrogen phosphate, calcium superphosphate, weight
One or more in persulfuric acid calcium, ammonium chloride, potassium chloride, potassium nitrate；
Described complex fertilizer includes the mixed fertilizer of two or more described inorganic fertilizer；
Described organic-inorganic compound mixed fertilizer includes that fertilizer described in any one or more is multiple with described in any one or more
The mixed fertilizer of complex fertilizer material；
Described trace-element fertilizer includes zinc chloride, zinc sulfate, ferric citrate, copper sulfate, manganese sulfate, cobaltous chloride, molybdic acid
One or more in ammonium, sodium molybdate.
In above-mentioned medicine fertilizer composition, preferably:
Described pesticide is the mixture of MTI-446 and phoxim, the weight ratio of the two be 1: 20 to 20: 1, preferably 1: 10 to
10: 1, more preferably 1: 5 to 5: 1, particularly preferred 3: 2.
In above-mentioned medicine fertilizer composition, preferably:
Described solvent includes in toluene, dimethylbenzene, acetone, hexamethylene, Ketohexamethylene, N-Methyl pyrrolidone, petroleum ether
One or more；
Described surfactant includes fatty alcohol-polyoxyethylene ether, sorbitan monostearate polyoxyethylene ether, benzene
Ethenylphenyl polyoxyethylene ether, sodium lauryl sulphate, dodecylbenzene sodium sulfonate, calcium dodecyl benzene sulfonate, isooctanol
One or more in Disodium sulfosuccinate, sodium lignin sulfonate.
Described binding agent includes in starch, xanthan gum, arabic gum, polyvinylpyrrolidone, carboxymethyl cellulose
Plant or multiple；
In a specific embodiment of the present invention, described medicine fertilizer composition includes that following component and weight percent thereof contain
Amount:
Wherein:
Described organic fertilizer is one or more in humic acids, bog moss, cottonseed cake；
Described inorganic fertilizer is one or more in carbamide, potassium dihydrogen phosphate, calcium superphosphate, potassium nitrate；
Described trace-element fertilizer is one or more in manganese sulfate, cobaltous chloride, sodium molybdate；
Described MTI-446 is 1: 5 to 5: 1 with the weight ratio of phoxim, preferably 3: 2.
Described solvent is one or more in dimethylbenzene, acetone, Ketohexamethylene, N-Methyl pyrrolidone；
Described surfactant be fatty alcohol-polyoxyethylene ether, sorbitan monostearate polyoxyethylene ether, 12
One or more in alkyl sodium sulfate, sodium lignin sulfonate；
Described binding agent is one or more in xanthan gum, arabic gum, carboxymethyl cellulose.
Wherein, each component and weight content thereof are preferred:
Wherein:
Described organic fertilizer is humic acids and bog moss, and the weight ratio of the two is 1: 1；
Described inorganic fertilizer is carbamide, calcium superphosphate and potassium nitrate, and the weight ratio of three is 1: 2: 1；
Described trace-element fertilizer is manganese sulfate and cobaltous chloride, and the weight ratio of the two is 1: 4；
Described solvent is dimethylbenzene；
Described surfactant is fatty alcohol-polyoxyethylene ether and sodium lignin sulfonate, and the weight ratio of the two is 1: 1；
Described binding agent is carboxymethyl cellulose.
In the another embodiment of the present invention, described medicine fertilizer composition includes following component and weight percent thereof
Content:
Wherein:
Described organic fertilizer is one or more in humic acids, bog moss, cottonseed cake；
Described inorganic fertilizer is one or more in carbamide, potassium dihydrogen phosphate, calcium superphosphate, potassium nitrate；
Described MTI-446 is 1: 5 to 5: 1 with the weight ratio of phoxim, preferably 4: 1.
Described solvent is one or more in dimethylbenzene, acetone, Ketohexamethylene, N-Methyl pyrrolidone；
Described surfactant be fatty alcohol-polyoxyethylene ether, sorbitan monostearate polyoxyethylene ether, 12
One or more in alkyl sodium sulfate, sodium lignin sulfonate；
Described binding agent is one or more in xanthan gum, arabic gum, carboxymethyl cellulose.
Wherein, each component and weight content thereof are preferred:
Wherein:
Described organic fertilizer is humic acids and cottonseed cake, and the weight ratio of the two is 2: 1；
Described inorganic fertilizer is carbamide and potassium dihydrogen phosphate, and the weight ratio of three is 1: 2；
Described solvent is Ketohexamethylene；
Described surfactant is sorbitan monostearate polyoxyethylene ether and sodium lauryl sulphate, the two
Weight ratio is 1: 1；
Described binding agent is arabic gum.
The above-mentioned medicine fertilizer composition of the present invention is when potato fields, it is possible to effectively preventing and treating field subterranean pest-insect, the most right
Holotrichia diomphalia Bates produce synergistic function, and also can increase love potato leaf chlorophyll content increased and improve Ma Ling
The yield of potato.
Another aspect of the present invention relates to the preparation method of medicine fertilizer composition of the present invention.Medicine fertilizer of the present invention combines
Thing its can be prepared by any means well known in the art, but be preferably prepared via a method which:
1) raw agent of being lived in the pesticide activity component of formula ratio, solvent and surface mixes, and is configured to mother solution；
2) fertilizer component of formula ratio is mixed, and pulverize, obtain powder；
3) binder making of formula ratio is become adhesive solution；
4) mother solution above-mentioned steps 1 obtained adds in the powder that step 2 obtains, mix homogeneously；The most while stirring
Spray the adhesive solution that step 3 obtains wherein, then through pelletize, be dried, obtain the graininess medicine fertilizer combination of the present invention
Thing.
Another aspect of the present invention relates to medicine fertilizer composition of the present invention for preventing and treating the purposes of potato fields Holotrichia diomphalia Bates.Wherein
Described medicine fertilizer composition can produce synergistic function to the preventing and treating of Holotrichia diomphalia Bates.Wherein, the amount of application of medicine fertilizer composition of the present invention
Can be such as 20-100kg/ mu, preferred 30-80kg/ mu, more preferably 35-60kg/ mu.
Another aspect of the present invention relates to medicine fertilizer composition of the present invention for improving the purposes of potato yield.Wherein,
The amount of application of medicine fertilizer composition of the present invention can be such as 20-100kg/ mu, preferred 30-80kg/ mu, more preferably 35-60kg/
Mu.The medicine fertilizer composition of the present invention such as can make Rhizoma Solani tuber osi volume increase 10%, preferably 15%, more preferably 20%.
Another aspect of the present invention relates to medicine fertilizer composition of the present invention for increasing potato leaf chlorophyll content
Purposes.Wherein, the amount of application of medicine fertilizer composition of the present invention can be such as 20-100kg/ mu, preferred 30-80kg/ mu, more preferably
35-60kg/ mu.The medicine fertilizer composition of the present invention such as can make potato leaf chlorophyll content increase by 5%, preferably 8%, more
Preferably 10%.
Another aspect of the present invention relates to medicine fertilizer composition of the present invention for preventing and treating potato fields Holotrichia diomphalia Bates and improving Ma Ling
Potato yield and the purposes of increase potato leaf chlorophyll content.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is further described, but does not limit the invention to these tools
Body embodiment.One skilled in the art would recognize that present invention encompasses and potentially included in Claims scope
All alternatives, improvement project and equivalents.
(1) embodiment is prepared
Embodiment 1 4.8% MTI-446+3.2% phoxim medicine fertilizer composition
Its preparation method is: 1) by the MTI-446 of formula ratio, phoxim, dimethylbenzene, fatty alcohol-polyoxyethylene ether and wood
Quality sodium sulfonate mixes, and is configured to mother solution；2) by the humic acids of formula ratio, bog moss, carbamide, calcium superphosphate, potassium nitrate, sulphuric acid
Manganese, cobaltous chloride mix, and pulverize, and obtain powder；3) carboxymethyl cellulose of formula ratio is configured to adhesive solution；4) will
The mother solution that above-mentioned steps 1 obtains adds in the powder that step 2 obtains, mix homogeneously；Spray step the most wherein
Rapid 3 adhesive solutions obtained, then through pelletize, are dried, obtain graininess medicine fertilizer composition.
Embodiment 2 8% MTI-446+2% phoxim medicine fertilizer composition
Its preparation method states respective components in component alternative embodiment 1 with embodiment 1, different the most only using.
Embodiment 3 3% MTI-446+3% phoxim medicine fertilizer composition
Its preparation method states respective components in component alternative embodiment 1 with embodiment 1, different the most only using.
Embodiment 4 2% MTI-446+6% phoxim medicine fertilizer composition
Its preparation method states respective components in component alternative embodiment 1 with embodiment 1, different the most only using.
Comparative example 1 organic-inorganic complex fertilizer
Said components is mixed, pulverizes, pelletize, obtain granular organic-inorganic complex fertilizer.
Comparative example 2 inorganic complex fertilizer
Said components is mixed, pulverizes, pelletize, obtain granular organic-inorganic complex fertilizer.
(2) biological Examples
1, grub control test
There will be three kinds of situations: antagonism, addition and potentiation, generally when activity after active compound
When acting on effect summation when each reactive compound is administered alone of compound composition, i.e. it is believed that active compound is deposited
At synergistic function.The predictive role of reactive compound is calculated by Colby formula:
X=is when using killing rate during active component A with the amount of application of m ppm, being expressed as the hundred of untreated control group
Proportion by subtraction；
Y=is when using killing rate during active component B with the amount of application of n ppm, being expressed as the hundred of untreated control group
Proportion by subtraction；
E=is when using killing rate when active component A and B with the amount of application of m and n ppm, being expressed as untreated control
The percentage ratio of group.
If the killing rate of reality is higher than value of calculation, then the eradicative rate of conjugate has superadditivity, i.e. there is synergy.
Thus, if it is observed that activity more than expected from Colby formula activity, then there is synergy.
Material to be tested: Holotrichia diomphalia Bates
Medicament is prepared: by MTI-446, phoxim respectively with acetone solution, be made into mother solution, standby.During use, with containing 5%
Above-mentioned mother solution is diluted to concentration by the deionized water of tween 80.
Test method: often process 50 examination worms, use infusion process by examination worm in the medicinal liquid of concentration for the treatment of each described in table 1 on
Lower dipping 10 seconds, lucifuge raises, one week " Invest, Then Investigate " result, the results are shown in Table 1, and wherein " observation killing rate " is actual killing of observing
Going out rate, " theoretical killing rate " is for using the calculated killing rate of Colby formula.
Table 1 present composition effect test to Holotrichia diomphalia Bates
| Reactive compound | Concentration (ppm) | Observe killing rate (%) | Theoretical killing rate (%) |
| MTI-446 | 60 | 35 | - |
| Phoxim | 40 | 28 | - |
| MTI-446+phoxim | 60+40 | 65.4 | 53.2 |
| MTI-446 | 80 | 39.5 | - |
| Phoxim | 20 | 21 | - |
| MTI-446+phoxim | 80+20 | 60.4 | 52.2 |
| MTI-446 | 50 | 32 | - |
| Phoxim | 50 | 36 | - |
| MTI-446+phoxim | 50+50 | 63.8 | 56.5 |
| MTI-446 | 25 | 22.4 | - |
| Phoxim | 75 | 40.6 | - |
| MTI-446+phoxim | 25+75 | 59.8 | 53.9 |
It is not difficult to find out by the data of table 1, in the present invention, by MTI-446 and phoxim compound, Holotrichia diomphalia Bates is produced and significantly increases
Effect effect.
2, potato yield measures
Choose smooth plot, be averagely divided into 20 communities.
Test sets 7 process (as shown in table 2) altogether, often processes 3 times and repeats (its empty sets 2 repetitions), between each repetition
Arrange immediately, Gong20Ge community.Each process is applied fertilizer respectively described in table 2, plants Rhizoma Solani tuber osi afterwards.After results,
Respectively process Rhizoma Solani tuber osi per mu yield
Table 2 respectively processes potato yield situation
| Process numbering | Fertilising situation | Fertilizer mu consumption (kg) | Per mu yield (kg) |
| 1 | Embodiment 1 medicine fertilizer composition | 50 | 3590 |
| 2 | Embodiment 2 medicine fertilizer composition | 50 | 3520 |
| 3 | Embodiment 3 medicine fertilizer composition | 50 | 3490 |
| 4 | Embodiment 4 medicine fertilizer composition | 50 | 3510 |
| 5 | Comparative example 1 fertilizer | 50 | 3150 |
| 6 | Comparative example 2 fertilizer | 50 | 3080 |
| 7 | Blank (not applying fertilizer) | - | 2500 |
Above-mentioned data are not difficult to find out, under the same conditions, medicine fertilizer composition of the present invention is relative to comparison fertilizer, it is possible to notable
Improve potato yield.
3, measuring chlorophyll content
For respectively processing in (2), forming the phase at potato tubers, application multi-point sampling method gathers 5 horses respectively to each process
Bell potato chips leaf, main collection plant middle and upper part healthy leaves.Then according to Chen Jianxun chief editor, the publication of publishing house of South China Science & Engineering University
" plant physiology experiment instruct (second edition) " described in method measure, respectively 663nm and 645nm measure chlorophyll a,
The content of b, and then calculate the total content of blade Determination of Chlorophyll, its result is as shown in table 3 below.
Table 3 respectively processes chlorophyll content and compares
| Process numbering | Fertilising situation | Chlorophyll content (mg/g FW) |
| 1 | Embodiment 1 medicine fertilizer composition | 4.16 |
| 2 | Embodiment 2 medicine fertilizer composition | 4.05 |
| 3 | Embodiment 3 medicine fertilizer composition | 3.92 |
| 4 | Embodiment 4 medicine fertilizer composition | 3.94 |
| 5 | Comparative example 1 fertilizer | 3.22 |
| 6 | Comparative example 2 fertilizer | 3.15 |
| 7 | Blank (not applying fertilizer) | 3.12 |
Above-mentioned data are not difficult to find out, under the same conditions, medicine fertilizer composition of the present invention is relative to comparison fertilizer, it is possible to notable
Increase potato leaf chlorophyll content.
The present invention is described by specific embodiment.But examples detailed above is only further to the present invention
Explain, be not limitation of the invention, by scheme such scheme simply adjusted and then obtain, without departing from
The spirit of the present invention, is regarded as being included within the scope of the present invention.
Claims (3)
1. a medicine fertilizer composition, it is characterised in that described medicine fertilizer composition is made up of following component and weight percentage thereof:
Wherein:
Described organic fertilizer is one or more in humic acids, bog moss, cottonseed cake；
Described inorganic fertilizer is one or more in carbamide, potassium dihydrogen phosphate, calcium superphosphate, potassium nitrate；
Described trace-element fertilizer is one or more in manganese sulfate, cobaltous chloride, sodium molybdate；
Described MTI-446 is 3: 2 with the weight ratio of phoxim；
Described solvent is one or more in dimethylbenzene, acetone, Ketohexamethylene, N-Methyl pyrrolidone；
Described surfactant is fatty alcohol-polyoxyethylene ether, sorbitan monostearate polyoxyethylene ether, dodecyl
One or more in sodium sulfate, sodium lignin sulfonate；
Described binding agent is one or more in xanthan gum, arabic gum, carboxymethyl cellulose.
Medicine fertilizer composition the most according to claim 1, it is characterised in that described medicine fertilizer composition is by following component and weight thereof
Amount percentage composition composition:
3. the medicine fertilizer composition described in claim 1-2 is for increasing the purposes of potato leaf chlorophyll content.
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104672029A (en) * | 2015-01-14 | 2015-06-03 | 广西欧维生物技术有限公司 | Pesticide fertilizer containing lythidathion |
| CN105638649A (en) * | 2016-01-12 | 2016-06-08 | 山东锦鸿源生态农业有限责任公司 | Spring striking root herbicide-containing fertilizer for wheat as well as preparation method and application thereof |
| CN105601447A (en) * | 2016-02-04 | 2016-05-25 | 锦州硕丰农药集团有限公司 | Dinotefuran slow release pesticide-fertilizer mixture and production method thereof |
| CN109020711A (en) * | 2018-09-21 | 2018-12-18 | 广东省生物工程研究所（广州甘蔗糖业研究所） | A kind of charcoal base medicine fertilizer and its preparation method and application containing dinotefuran |
| CN110583683B (en) * | 2019-08-28 | 2021-04-16 | 广东省农业科学院植物保护研究所 | Insecticidal composition containing dinotefuran and trichlorfon |
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| CN103030473A (en) * | 2013-01-15 | 2013-04-10 | 广西汇丰生物科技有限公司 | Sugarcane pesticide fertilizer granule with chlorantraniliprole and preparation method thereof |
| CN103030475A (en) * | 2013-01-15 | 2013-04-10 | 广西汇丰生物科技有限公司 | Sugarcane pesticide fertilizer granule containing thiamethoxam and preparation method thereof |
| CN103242095A (en) * | 2013-05-16 | 2013-08-14 | 山东亿丰源生物科技股份有限公司 | Abamectin-containing drug fertilizer preparation |
| CN103242108A (en) * | 2013-05-16 | 2013-08-14 | 山东亿丰源生物科技股份有限公司 | Drug fertilizer preparation containing chlorpyrifos and organic fertilizer |
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