CN103011968A - Leaf fertilizer composition comprising sodium alginate oligosaccharide and application of leaf fertilizer composition - Google Patents
Leaf fertilizer composition comprising sodium alginate oligosaccharide and application of leaf fertilizer composition Download PDFInfo
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- CN103011968A CN103011968A CN2012105626544A CN201210562654A CN103011968A CN 103011968 A CN103011968 A CN 103011968A CN 2012105626544 A CN2012105626544 A CN 2012105626544A CN 201210562654 A CN201210562654 A CN 201210562654A CN 103011968 A CN103011968 A CN 103011968A
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F11/00—Other organic fertilisers
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D9/00—Other inorganic fertilisers
- C05D9/02—Other inorganic fertilisers containing trace elements
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F11/00—Other organic fertilisers
- C05F11/10—Fertilisers containing plant vitamins or hormones
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/20—Liquid fertilisers
- C05G5/27—Dispersions, e.g. suspensions or emulsions
Abstract
The invention discloses a leaf fertilizer composition comprising sodium alginate oligosaccharide, which is characterized in that the composition comprises sodium alginate oligosaccharide, amino acid and microelements that can promote plant growth significantly, wherein sodium alginate oligosaccharide is also known as sodium alginate, sea-tangle glue and algin, is natural polysaccharide carbohydrate extracted from sea tangle, and is a copolymer comprising a-L-mannuronic acid (M), b-D-guluronic acid (G) connected with a-L-mannuronic acid (M) by 1,4-glycosidic bond, and different GGGMMM fragments; a molecular formula is (C6H7O6Na)n; the degree of polymerization is 2-10; the uronic acid constitution M/G is equal to 7:3; the uronic acid content is greater than 90%, and is 2-3% of the total content; the content of a microelement leaf fertilizer is 2-20%; and the microelement leaf fertilizer comprises at least two of sulfur, boron, ferrum, manganese, copper, zinc and molybdenum. The composition is mainly applicable to industrial crops, fruit and vegetable crops, grain crops, economic trees, flowers, lawns and the like.
Description
Technical field
The present invention relates to the physiological metabolism of plant, specifically a kind ofly use in Plant growth-promoting effect take amino acid, sodium alginate oligosaccharides and trace element as main active substances.
Background technology
Traditional chemical fertilizer fertilizer efficiency is single, seriously polluted, life-time service spoiled soil structure, and the synthetic plant-growth regulator then easily causes pollution of dining table, causes quality of agricultural product to descend.After the China joined WTO, food safety has become impact agricultural and foodstuffs industry in the key factor of competitiveness in the international market, and the development and application of non-polluted farm product safety production technique is extremely urgent.Amino acid and marine oligosaccharide belong to natural extract, can remedy the deficiency of China's conventional fertilizers and synthetic plant-growth regulator, as the new foliar fertilizer exploitation, help to improve agricultural products in China safety, protection of the environment.
Some oligosaccharide kind materials such as oligochitosan are applied to plant field from the seventies in last century, have the functions such as inducing plant resistance, Promoting plant growth, and this class oligosaccharides material is by special called after oligosaccharide.The sodium alginate oligosaccharides is one of important molecule of oligosaccharide, be by the enzymolysis sodium alginate obtain by а-L-mannuronic acid (mannuronic acid, M) with b-D-guluronic acid (guluronic acid, G) rely on 1, the 4-glycosidic link connects and by the oligose that different GGGMMM fragments form, the advantage such as have that relative molecular mass is little, toxicity is low, good water solubility, absorptivity are strong.The amino-acid trace element fertilizer that contains take the sodium alginate oligosaccharides as active ingredient has no document and patent report.
Summary of the invention
The object of the present invention is to provide a kind of amino-acid trace element fertilizer that the sodium alginate oligosaccharides is activeconstituents that contains.
For achieving the above object, the technical solution used in the present invention is:
A kind of amino-acid trace element foliage fertilizer, the main active ingredient of described foliage fertilizer are amino acid, trace element and sodium alginate oligosaccharides, and all the other compositions are solvent, auxiliary agent or carrier.This foliage fertilizer composition can be used for cash crop, food crop, vegetables, fruit tree, commodity trees, flowers and lawn etc.The class of yielding positive results plant flower and fruit protecting rate reaches 50-99%, the various enzymes that resistance is relevant under the increase plant drought condition and the synthetic 70%-90% of secondary metabolite.
Described active ingredient: described amino acid comprises several in glycine, L-Ala, Isoleucine, Gelucystine, halfcystine, methionine(Met), Threonine, Serine, phenylalanine, tyrosine, tryptophane, proline(Pro), oxyproline, L-glutamic acid, the aspartic acid etc.; Described trace element fertilizer is for providing the fertilizer of minimum plant element, such as boron fertilizer, molydbenum fertilizer, manganese fertilizer, copper fertilizer, iron fertilizer, zinc fertilizer etc.; Described sodium alginate oligosaccharides is the natural polysaccharide carbohydrate that extracts in the sea-tangle, by а-L-mannuronic acid (mannuronic acid, M) with b-D-guluronic acid (guluronic acid, G) rely on 1, the connection of 4-glycosidic link and the multipolymer that is comprised of different GGGMMM fragments, molecular formula is (C
6H
7O
6Na) n, polymerization degree 2-10, uronic acid consists of M/G=7:3, glucuronic acid content〉90%.500 times of liquid of described foliage fertilizer composition dilution in crop bud stage foliage-spray, sprayed 1 time, and sprayed 3-4 time continuously in 7-10 days.
Described active ingredient adds solvent, dispersion agent and auxiliary agent and is made into aqua, missible oil, soluble liquid, aqueous emulsion, microemulsion, suspension agent.Described solvent including, but not limited to: a kind of or said mixture of water, ethanol, acetone, dimethylbenzene, toluene, chlorobenzene, hexanaphthene, methyl alcohol, dimethyl formamide, pyrrolidone, pimelinketone, butanols, amylalcohol, ethers, ester class, dimethyl sulfoxide (DMSO), lauryl alcohol, methylene dichloride, petroleum distillate, solvent quality ratio are 10-99%; Described auxiliary agent has non-ionic type and ionic, including, but not limited to: a kind of or mixture of Glacial acetic acid, hydrochloric acid, sulfuric acid, sodium hydroxide, potassium hydroxide, ammoniacal liquor, fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene, polyoxyethylene fatty acid ester, alkylaryl polyglycol ether, alkylsulfonate, arylsulphonate, fatty acid polyglycol di-alcohol, dodecylbenzene sulfonate, alkylphenol polyoxyethylene phosphoric acid ester, polyoxyethylene alkylphenol formaldehyde condensation products etc.The auxiliary agent mass ratio is 10-99%.Described dispersion agent comprises a kind of or said mixture of sulfonated lignin, methylcellulose gum, alkylsulfonate, sulfonated alkyl naphathalene, fatty alcohol-polyoxyethylene ether etc., and mass ratio is 0.05-50%;
Described foliage fertilizer composition can add a kind of or mixture of zinc sulfate, zinc nitrate, zinc chloride, zinc phosphate, copper sulfate, cupric nitrate, cupric chloride, cupric phosphate, manganous nitrate, manganous sulfate, Manganous chloride tetrahydrate, manganous phosphate, vitriolate of tartar, saltpetre, potassiumphosphate, potassium dihydrogen sulfate, dipotassium hydrogen phosphate, Repone K, sal epsom, magnesium nitrate, magnesium chloride, ferrous sulfate, ferric sulfate, Iron nitrate, iron nitrate, iron protochloride, iron(ic) chloride, ferrous phosphate and tertiary iron phosphate, and mass ratio is 0.005-20%.
Described cash crop comprise tobacco, cotton, oil tea, rape, beet, sugarcane, soybean, tea tree, peanut etc.; Described food crop comprise wheat, paddy rice, corn, Chinese sorghum etc.; Described vegetables comprise Chinese cabbage, balsam pear, sponge gourd, celery, eggplant, tomato, wax gourd, spinach, garlic, green onion, capsicum, cucumber, spinach, black salted turnip, potato, sweet potato, radish, Radix Dauci Sativae, pea, Kidney bean, string bean, green soy bean etc.; Comprise mango, watermelon, apple, pears, banana, pawpaw, oranges and tangerines, orange, grape, cherry, lichee, peach, Lee, apricot, strawberry, pineapple, blueberry, Kiwifruit, Zao, persimmon, hami melon etc. with described fruit, three leaves, coronilia varia etc., the Herba Dichodrae of crawling, dwarf lilyturf, Thymus vulgaris, tormentic etc. crawls.Described commodity trees comprise: rubber, coconut, walnut, Chinese chestnut, fibert etc., and described flowers include: one, biennial herb flowers: money, perennial pholx, Primula obconica fall at China pink, Flower of Aztec Marigold, Potmarigold Calendula, nasturtium, wild pansy, Flower of Garden Balsam, Mirabilis jalapa, Flos Papaveris rhoeadis, Eschscholtzia californica, red sage, violet, morning glory, Touch-me-notAction Plant, Flos Celosiae Cristatae, Globeamaranth Flower, night; Perennial herb flowers: asparagus fern, phoenix celestial being, bracketplant, kafir lily, vanilla, violet, He Wanglan, Bulbus et Radix Crini Sinici, Longitudinally-striped Hippeastrum, evergreen, Radix Asparagi, common calla, Agipanthus, Herba Passiflorae Caeruleae, Cyclamen persicum, gloxinia, African chrysanthemum, heronsbill, Flower of Evans Begonia, tassel pineapple; Fallen leaves perennial root and the napiform root class showy flowers of herbaceous plants: lily, tawny daylily, tree peony, chrysanthemum, Chinese herbaceous peony, iris, narcissus, hollyhock, Garden Dahlia, gladiolus, freesia, Tuberose, turmeric, jacinthe, Canna generalis Bailey; Flowering marsh plants: lotus, water lily, Herba Eichhorniae, Rhizome of Grass leaf Sweelflag;
Fern flowers: tuber fern, venushair fern, Platycerium bifurcatum; The orchid family flowers: Chunlan, orchid, sword-leaved cymbidium, Chinese cymbidium, blue, the cold orchid of platform, the stem of noble dendrobium, Cymbidium lancifolium, Bowring cattleya, Hong Kong pocket orchid; The evergreen shrubs class: Milan, cape jasmine, with a smile, jasmine, Japan, spy spring, the bamboo palm, poinsettia, Leaf of Common Lantana, cestrum nocturnum, Serissa japonica, Winter Jasmine, Largeflower Jasmine Flower, Folium seu Cortex Nerii, Nandina domestica, rhododendron, Euonymus japonicus; The machaka class: Chinese rose, rose, rose, wintersweet, pomegranate, winter jasmine, the rose of Sharon, Chinese bush cherry, yellow rose, Cortex Sorbariae Arboreae, flowering plum, Syringa oblata Lindl., Hibisci Mutabilis, Fructus Fici, chaenomeles lagenaria, woody ivory red; The aiphyllium class: sago cycas, mountain palm fibre, Chinese fan palm, banyan, Chinese ilex, sweet osmanthus,, camellia, Buddha's hand, fragrant circle, kumquat, Chinese incense cedar, cypress, rubber tree, southern magnolia, five-leaved pine, golden larch, Podocarpus macrophyllus, cdear, Flower of Bailan; Deciduous tree class: peach blossom, plum blossom, oriental cherry, yulan, cercis, Chinese flowering crabapple, Hall Crabapple; Evergreen liana class: dragon tells pearl, Monstera deliciosa, Flower of Lesser Bougainvillea, ivy, ten thousand word jasmines, African Ling Xiao; Fallen leaves liana class: Ling Xiao, liana, the banksia rose, Japanese Honeysuckle, parthenocissus; Root and stem of Cholla and succulent: broad-leaved epiphyllum, aloe, red-spotted stonecrop, Zygopetalum truncatns (Haw). Schum., Folium Agaves variegatae, tiger fur orchid, euphorbia milii, rattle stick dance, celestial being are ball, nopalxochia, take root, wooden leaf Root and stem of Cholla.The Chinese medicinal materials class comprises: ginseng, pseudo-ginseng, rheum officinale, Ligusticum wallichii, rhizoma Gastrodiae, auricularia auriculajudae, the banksia rose, the tuber of dwarf lilyturf, radix bupleuri, Radix Codonopsis, the Radix Astragali, the coptis, betel nut, peppermint, nux vomica, shizandra berry, Turkey-galls, Great Burdock Achene, Cordyceps, Semen Myristicae, st-yrax, Yanhusuo, Shinyleaf Pricklyash Root, Tuber Fleeceflower Root, Root of Indigowoad, Radix Et Caulis Acanthopanacis Senticosi, Grosvenor Momordica, Mahonia fortunei; The kind of turfgrass: thin and delicate bent grass, velvet bent grass, the bent grass of crawling, white bent, tough leaf red fescue, the red fescue that crawls, fescue grass, spire thatch and Festuca Arundinacea etc., English grass, rough stalked blue grass, forest land annual bluegrass and annual bluegrass, English ryegrass, crested dogstail, thimothy grass, jielu grass, Zoysia macrostachya, Zoysia sinica, Manila jielu grass, Zoysia tenuifolia, Carex rigescens, spire tongue, different fringe tongue and Carex duriuscula etc.; Bai Sanye, red clover, coronilia varia etc., the Herba Dichodrae of crawling, dwarf lilyturf, Thymus vulgaris, tormentic etc. crawls.
The present invention has following advantage:
1. the present invention is used for amino-acid trace element fertilizer, green, environmental protection, nuisanceless, pollution-free, nuisanceless with the sodium alginate oligosaccharides of biogenetic derivation.
2. main active ingredient amino acid, trace element and the sodium alginate oligosaccharides among the present invention, wide material sources, cheap, be suitable for large-scale promotion.
3. the foliage fertilizer composition usage quantity among the present invention is few, and efficiency time is long, and can not produce poisoning.
4. the double effects of the plant nutrition of providing and promotion plant strain growth is provided the foliage fertilizer composition among the present invention, but the use of part instead of chemical plant-growth regulator reduces chemical residual, solves food-safety problem.
Description of drawings
Fig. 1. the EFI thing MALDI-MS collection of illustrative plates of sodium alginate oligosaccharides
Embodiment
The present invention will be further described below in conjunction with embodiment.
The preparation of this foliage fertilizer composition that embodiment 1 commonly uses
This foliage fertilizer composition adds solvent, auxiliary agent is made into aqua, missible oil, soluble liquid, aqueous emulsion, microemulsion, suspension agent; Add known carrier, auxiliary agent is made into pulvis, soluble powder, wettable powder, granule, water-dispersible granules, microcapsule, tablet.Present embodiment has been introduced a kind of aqua proportioning commonly used, but content of the present invention is not limited to this:
25g sodium alginate oligosaccharides is dissolved in the 1L water, then add simultaneously the boric acid of whole mass concentration 16%, the borax of whole mass concentration 12%, add at last the ammonium molybdate of whole mass concentration 0.4% and the amino acid of 106g content 95% (mainly comprising Threonine, aspartic acid, Serine, L-glutamic acid, proline(Pro), arginine, glycine etc.), regulate pH6.5 with KOH, it is dissolved fully, thereby prepare this foliage fertilizer composition.
Wherein aminoacids content detects with automatic analyzer for amino acids; The method that trace element fertilizer is pressed in the NY1428 annex is measured.Wherein the quality of sodium alginate oligosaccharides is measured by being furnished with electric spray ion source (ESI) liquid chromatograph-mass spectrometer.The chromatographic determination condition is: the mass spectrum pattern is positive ion mode; Electric spray ion source (ESI); Spray voltage 4.5kV; 350 ℃ of transfer capillary temperature; Sheath gas (Sheathgas, N2) pressure is that 30au(1au is about 1psi), assisted gas (Aux gas, N2) pressure is 5au, ion sweep gas (Ion sweep gas, N2) pressure is 0au; Sweep limit: 150～2000.Content adopts colorimetric method for determining.Its EFI thing MALDI-MS collection of illustrative plates is seen Fig. 1.
Embodiment 2 uses this foliage fertilizer composition to improve yield of rape
Test designs two processing altogether: process 1, with 500 times of embodiment 1 foliage fertilizer composition dilutions, in each spray of rape peduncle-growing period for rapeseed+full-bloom stage once, mu is executed 30kg; Process 2 and do not spray medicine (contrast).Every processing triplicate, random alignment, zone leader 13.52m, wide 7.4m, the row cave is apart from 0.74m * 0.26m, and every residential quarter plants 11 row, 583 caves, two strains are planted, and mu is planted 7226 strains.Spray date was carried out on March 7th, 2012 and March 25, used workers and peasants' 16 type hand sprayers, did not drip as degree so that leaf is wet.Test was investigated each processing in the rape ripening stage.50 strains are investigated at every by 4 some samplings in every residential quarter, and investigation index has child's hair twisted in a knot-childhood fruit tree, every angle fruit grain tree, thousand seed weight and actual output.Experimental result shows, uses this foliage fertilizer composition and can significantly improve rape boron content, yield and its components.Shown in table 1 specific as follows and the table 2.
Table 1. uses this foliage fertilizer composition on the impact of rape peduncle-growing period for rapeseed dry matter and B utilising efficiency
Table 2. uses this foliage fertilizer composition on the impact of yield of rape and Components thereof
Embodiment 3 uses this foliage fertilizer composition to improve cherry output
Utilize the cherry of red light, pioneer, three kinds of different varietiess of dragon hat to carry out the output experiment, with 500 times of embodiment 1 foliage fertilizer composition dilutions, spray before the snow on April 12nd, 2012, mu is executed the 200kg liquid, investigate 3 cherry variety output, the result shows that this foliage fertilizer composition has preferably effect of increasing production to cherry, and concrete outcome is as shown in table 3 below.
Table 3. uses this foliage fertilizer composition on the impact of cherry output
Embodiment 4 uses this foliage fertilizer composition to improve apple production
On April 10th, 2012, carry out the output experiment in Fu County, Luochuan, Shaanxi for apple, with 500 times of this foliage fertilizer composition dilutions, spray apple tree, mu is executed the liquid of 200kg.Investigation output and exterior quality, concrete outcome is as shown in table 4 below.
Table 4. uses this foliage fertilizer composition on the impact of apple production and exterior quality
Embodiment 5 uses this foliage fertilizer composition can improve the Nanguo Pear yield and its components
Used aqua 200kg for every mu with 500 times of liquid of embodiment 1 foliage fertilizer composition dilution, and early spring pear tree was carried out the output experiment in the Pucheng in 2012.Before pear tree is blooming (inflorescence separation period) and thank and spend rear young fruit period to spray this foliage fertilizer composition, spray altogether twice.Investigation output, concrete outcome is as shown in table 5 below:
Table 5. uses this foliage fertilizer composition on the impact of Nanguo Pear yield and yield components
| The treatment agent combination | Single fruit weight (g) | Single plant yield (kg/ strain) |
| Contrast | 42．6 | 12．4 |
| Foliage fertilizer composition | 57.8 | 21.6 |
Embodiment 6 uses this foliage fertilizer composition can improve southern orange yield and Components thereof
500 times of liquid of embodiment 1 foliage fertilizer composition dilution were used aqua 200kg for every mu, in the Yichang oranges and tangerines have been carried out the output experiment in 2012.Before the oranges and tangerines flower is being bloomed (inflorescence separation period) and thank and spend rear young fruit period to spray this foliage fertilizer composition, spray altogether twice.Concrete outcome is as shown in table 6 below:
Table 6 uses this foliage fertilizer composition can improve the Nanguo Pear yield and its components
Embodiment 7 uses this foliage fertilizer composition can promote the paddy rice root of hair and improves drought resistance
Utilize embodiment 1 foliage fertilizer composition that rice seedling is carried out drought resistance experiment, rice seedling is grown to two leaves and processes wholeheartedly the time, and drought condition is with the PEG6000 simulation of adding 20%.Each group is processed quantity and is 100 strains; 500 times of liquid of this foliage fertilizer dilution use, and spray weekly three times altogether 1 time.The result shows: the rice seedling of this foliage fertilizer composition improves than untreated fish group surviving rate and root of hair digital display work.Shown in the table 7 specific as follows.
Table 7. uses this foliage fertilizer composition on the impact of rice seedling surviving rate and root of hair number
| Process | Survive number | Surviving rate (%) | The root of hair number |
| The foliage fertilizer composition group | 77 | 77 | 23 |
| The arid treatment group | 49 | 49 | 15 |
| The blank group | 98 | 98 | 24 |
Use embodiment 1 foliage fertilizer composition that wheat is carried out root irrigation or foliage-spray is processed, every mu is used 3g, seven days afterwards sampling utilize each drought resistant index of spectrophotometry.Concrete outcome is as shown in table 8 below:
Use this foliage fertilizer composition of 500 times of liquid of dilution to the Drought-resistance in Wheat index under table 8. drought condition
Impact
| Process | Root irrigation | Spray processing | Blank |
| POD(mmol?min -1mg -1pro) | 1.149 | 1.139 | 1.066 |
| CAT(mmol?min -1mg -1pro) | 0.139 | 0.142 | 0.128 |
| Mda (μ mol/ (g FW)) | 0.361 | 0.355 | 0.498 |
| Proline(Pro) (μ g/ (g FW)) | 0.138 | 0.146 | 0.128 |
| Soluble sugar (μ mol/L) | 0.149 | 0.123 | 0.105 |
Embodiment 9 uses this foliage fertilizer composition to the raising of flowers drought resistance
Butterfly orchid, Cyclamen persicum carried out the drought resistance experiment in 2012.Drought condition is with the PEG6000 simulation of adding 20%, chooses butterfly orchid, each 100 strain of Cyclamen persicum and carries out 500 times of liquid of foliage-spray embodiment 1 foliage fertilizer composition dilution and process, and sprays weekly 1 time, and three times altogether, concrete outcome is as shown in table 9 below.
Table 9. uses this foliage fertilizer composition on the impact of flowers drought resistance
Embodiment 10 uses this foliage fertilizer composition to the raising of yellow bluestem drought resistance
With embodiment 1 foliage fertilizer composition yellow bluestem was carried out the drought resistance experiment in 2012.Arid is processed with the PEG6000 simulation of adding 20%, and 500 times of liquid of this foliage fertilizer composition of foliage-spray dilution are processed, and sprays weekly five times altogether 1 time.Concrete outcome is as shown in table 10 below:
Table 10. uses this foliage fertilizer composition on the impact of yellow bluestem drought resistance
Embodiment 11 contains the collocation method of the foliage fertilizer composition of sodium alginate oligosaccharides
The activeconstituents of this foliage fertilizer is amino acid, sodium alginate oligosaccharides and trace element, and wherein amino acid is including, but not limited to glycine, L-Ala, Isoleucine, Gelucystine, halfcystine, methionine(Met), Threonine, Serine, phenylalanine, tyrosine, tryptophane, proline(Pro), oxyproline, L-glutamic acid, aspartic acid etc.; Described trace element fertilizer is for providing the fertilizer of minimum plant element, such as boron fertilizer, molydbenum fertilizer, manganese fertilizer, copper fertilizer, iron fertilizer, zinc fertilizer etc.The antifreeze cold-resistance agent of this plant adds solvent, auxiliary agent is made into aqua, missible oil, soluble liquid, aqueous emulsion, microemulsion, suspension agent; Add known carrier, auxiliary agent is made into pulvis, soluble powder, wettable powder, granule, water-dispersible granules, microcapsule, tablet.Present embodiment has been introduced a kind of aqua proportioning commonly used, but content of the present invention is not limited to this: the amino acid of 100-200g is dissolved in the 1L water, then add needed trace element and sodium alginate oligosaccharides, then regulate pH with alkali, add auxiliary agent, it is dissolved fully, thereby prepare this foliage fertilizer composition.
Claims (9)
1. contain the foliage fertilizer composition of sodium alginate oligosaccharides, it is characterized in that: the main active ingredient of described foliage fertilizer is amino acid, trace element and sodium alginate oligosaccharides, and all the other compositions are solvent, auxiliary agent or carrier.
2. the foliage fertilizer composition that contains the sodium alginate oligosaccharides according to claim 1, it is characterized in that: described amino acid comprises one or two or more kinds in glycine, L-Ala, Isoleucine, Gelucystine, halfcystine, methionine(Met), Threonine, Serine, phenylalanine, tyrosine, tryptophane, proline(Pro), oxyproline, L-glutamic acid, the aspartic acid;
Described trace element fertilizer be for can providing the fertilizer of minimum plant element, such as in boron fertilizer, molydbenum fertilizer, manganese fertilizer, copper fertilizer, iron fertilizer, the zinc fertilizer one or two or more kinds;
Described sodium alginate oligosaccharides is the natural polysaccharide carbohydrate that extracts in the sea-tangle, by а-L-mannuronic acid (mannuronic acid, M) with b-D-guluronic acid (guluronic acid, G) rely on 1, the connection of 4-glycosidic link and the multipolymer that is comprised of different GGGMMM fragments, molecular formula is (C
6H
7O
6Na) n, polymerization degree 2-10, uronic acid consists of M/G=7:3, glucuronic acid content〉90%.
3. the foliage fertilizer composition that contains the sodium alginate oligosaccharides according to claim 1, it is characterized in that: described main active ingredient amino acid, trace element and sodium alginate oligosaccharides mass content are respectively 10-400g/L, 0.2-50g/L and 0.1-30g/L, and the ratio between them is 20:4:5.
4. the foliage fertilizer composition that contains the sodium alginate oligosaccharides according to claim 1 is characterized in that:
Described solvent is including, but not limited to one or two or more kinds mixture of: water, ethanol, acetone, dimethylbenzene, toluene, chlorobenzene, hexanaphthene, methyl alcohol, dimethyl formamide, pyrrolidone, pimelinketone, butanols, amylalcohol, ethers, ester class, dimethyl sulfoxide (DMSO), lauryl alcohol, methylene dichloride, petroleum distillate, and the solvent quality ratio is 50-99% in the foliage fertilizer composition;
Described auxiliary agent is non-ionic type auxiliary agent and ionic auxiliary agent, including, but not limited to: the aqueous solution of one or two or more kinds mixing of hydrochloric acid, sulfuric acid, Glacial acetic acid, sodium hydroxide, potassium hydroxide, ammoniacal liquor, fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene, polyoxyethylene fatty acid ester, alkylaryl polyglycol ether, alkylsulfonate, arylsulphonate, fatty acid polyglycol di-alcohol, dodecylbenzene sulfonate, alkylphenol polyoxyethylene phosphoric acid ester, polyoxyethylene alkylphenol formaldehyde condensation products, auxiliary agent mass concentration 0.1-2% in the aqueous solution; The mass ratio of adjuvant water solution is 50-99% in the foliage fertilizer composition;
Described carrier comprises a kind of of sulfonated lignin, methylcellulose gum, alkylsulfonate, sulfonated alkyl naphathalene, fatty alcohol-polyoxyethylene ether etc. or mixture more than two kinds, and the carrier mass ratio is 0.05-50% in the foliage fertilizer composition.
5. the foliage fertilizer composition that contains the sodium alginate oligosaccharides according to claim 1, it is characterized in that: described trace element fertilizer is zinc sulfate, zinc nitrate, zinc chloride, zinc phosphate, copper sulfate, cupric nitrate, cupric chloride, cupric phosphate, manganous nitrate, manganous sulfate, Manganous chloride tetrahydrate, manganous phosphate, vitriolate of tartar, saltpetre, potassiumphosphate, potassium dihydrogen sulfate, dipotassium hydrogen phosphate, Repone K, sal epsom, magnesium nitrate, magnesium chloride, ferrous sulfate, ferric sulfate, Iron nitrate, iron nitrate, iron protochloride, iron(ic) chloride, a kind of in ferrous phosphate and the tertiary iron phosphate or mixture more than two kinds, its mass ratio in foliage fertilizer composition is 0.005-20%.
6. described application in crop yield and drought resisting that contains the foliage fertilizer composition of sodium alginate oligosaccharides of claim 1.
7. application according to claim 6 is characterized in that:
This foliage fertilizer composition can be used for cash crop, food crop, vegetables, fruit tree, commodity trees, flowers or lawn; The class of yielding positive results plant flower and fruit protecting rate reaches 50-99%, the various enzymes that resistance is relevant under the increase plant drought condition and the synthetic 70%-90% of secondary metabolite.
8. application according to claim 6 is characterized in that:
Described cash crop comprise a kind of in tobacco, cotton, oil tea, rape, beet, sugarcane, soybean, tea tree, the peanut or more than two kinds;
Described food crop comprise a kind of in wheat, paddy rice, corn, the Chinese sorghum or more than two kinds;
Described vegetables comprise a kind of in Chinese cabbage, balsam pear, sponge gourd, celery, eggplant, tomato, wax gourd, spinach, garlic, green onion, capsicum, cucumber, spinach, black salted turnip, potato, sweet potato, radish, Radix Dauci Sativae, pea, Kidney bean, string bean, the green soy bean or more than two kinds;
Described fruit comprises mango, watermelon, apple, pears, banana, pawpaw, oranges and tangerines, orange, grape, cherry, lichee, peach, Lee, apricot, strawberry, pineapple, blueberry, Kiwifruit, Zao, persimmon, hami melon etc., a kind of in three leaves, coronilia varia etc., the Herba Dichodrae of crawling, dwarf lilyturf, Thymus vulgaris, the tormentic that crawls or more than two kinds;
Described commodity trees comprise: a kind of in rubber, coconut, walnut, Chinese chestnut, the fibert or more than two kinds;
Described flowers comprise a kind of in following or more than two kinds: one, biennial herb flowers: money, perennial pholx, Primula obconica fall at China pink, Flower of Aztec Marigold, Potmarigold Calendula, nasturtium, wild pansy, Flower of Garden Balsam, Mirabilis jalapa, Flos Papaveris rhoeadis, Eschscholtzia californica, red sage, violet, morning glory, Touch-me-notAction Plant, Flos Celosiae Cristatae, Globeamaranth Flower, night; Perennial herb flowers: asparagus fern, phoenix celestial being, bracketplant, kafir lily, vanilla, violet, He Wanglan, Bulbus et Radix Crini Sinici, Longitudinally-striped Hippeastrum, evergreen, Radix Asparagi, common calla, Agipanthus, Herba Passiflorae Caeruleae, Cyclamen persicum, gloxinia, African chrysanthemum, heronsbill, Flower of Evans Begonia, tassel pineapple; Fallen leaves perennial root and the napiform root class showy flowers of herbaceous plants: lily, tawny daylily, tree peony, chrysanthemum, Chinese herbaceous peony, iris, narcissus, hollyhock, Garden Dahlia, gladiolus, freesia, Tuberose, turmeric, jacinthe, Canna generalis Bailey; Flowering marsh plants: lotus, water lily, Herba Eichhorniae, Rhizome of Grass leaf Sweelflag; Fern flowers: tuber fern, venushair fern, Platycerium bifurcatum; The orchid family flowers: Chunlan, orchid, sword-leaved cymbidium, Chinese cymbidium, blue, the cold orchid of platform, the stem of noble dendrobium, Cymbidium lancifolium, Bowring cattleya, Hong Kong pocket orchid; The evergreen shrubs class: Milan, cape jasmine, with a smile, jasmine, Japan, spy spring, the bamboo palm, poinsettia, Leaf of Common Lantana, cestrum nocturnum, Serissa japonica, Winter Jasmine, Largeflower Jasmine Flower, Folium seu Cortex Nerii, Nandina domestica, rhododendron, Euonymus japonicus; The machaka class: Chinese rose, rose, rose, wintersweet, pomegranate, winter jasmine, the rose of Sharon, Chinese bush cherry, yellow rose, Cortex Sorbariae Arboreae, flowering plum, Syringa oblata Lindl., Hibisci Mutabilis, Fructus Fici, chaenomeles lagenaria, woody ivory red; The aiphyllium class: sago cycas, mountain palm fibre, Chinese fan palm, banyan, Chinese ilex, sweet osmanthus,, camellia, Buddha's hand, fragrant circle, kumquat, Chinese incense cedar, cypress, rubber tree, southern magnolia, five-leaved pine, golden larch, Podocarpus macrophyllus, cdear, Flower of Bailan; Deciduous tree class: peach blossom, plum blossom, oriental cherry, yulan, cercis, Chinese flowering crabapple, Hall Crabapple; Evergreen liana class: dragon tells pearl, Monstera deliciosa, Flower of Lesser Bougainvillea, ivy, ten thousand word jasmines, African Ling Xiao; Fallen leaves liana class: Ling Xiao, liana, the banksia rose, Japanese Honeysuckle, parthenocissus; Root and stem of Cholla and succulent: broad-leaved epiphyllum, aloe, red-spotted stonecrop, Zygopetalum truncatns (Haw). Schum., Folium Agaves variegatae, tiger fur orchid, euphorbia milii, rattle stick dance, celestial being are ball, nopalxochia, take root, wooden leaf Root and stem of Cholla; The Chinese medicinal materials class comprises: ginseng, pseudo-ginseng, rheum officinale, Ligusticum wallichii, rhizoma Gastrodiae, auricularia auriculajudae, the banksia rose, the tuber of dwarf lilyturf, radix bupleuri, Radix Codonopsis, the Radix Astragali, the coptis, betel nut, peppermint, nux vomica, shizandra berry, Turkey-galls, Great Burdock Achene, Cordyceps, Semen Myristicae, st-yrax, Yanhusuo, Shinyleaf Pricklyash Root, Tuber Fleeceflower Root, Root of Indigowoad, Radix Et Caulis Acanthopanacis Senticosi, Grosvenor Momordica, Mahonia fortunei; The kind of turfgrass: thin and delicate bent grass, velvet bent grass, the bent grass of crawling, white bent, tough leaf red fescue, the red fescue that crawls, fescue grass, spire thatch and Festuca Arundinacea etc., English grass, rough stalked blue grass, forest land annual bluegrass and annual bluegrass, English ryegrass, crested dogstail, thimothy grass, jielu grass, Zoysia macrostachya, Zoysia sinica, Manila jielu grass, Zoysia tenuifolia, Carex rigescens, spire tongue, different fringe tongue and Carex duriuscula etc.; Bai Sanye, red clover, coronilia varia etc., the Herba Dichodrae of crawling, dwarf lilyturf, Thymus vulgaris, tormentic crawls.
9. application according to claim 6 is characterized in that:
10-2000 times of liquid of described foliage fertilizer composition dilution till crop bud stage foliage-spray to blade drenches fully, sprayed 1-3 time, and sprayed 3-4 time continuously in 7-10 days.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210562654.4A CN103011968B (en) | 2012-12-21 | 2012-12-21 | Leaf fertilizer composition comprising sodium alginate oligosaccharide and application of leaf fertilizer composition |
| PCT/CN2013/076894 WO2014094412A1 (en) | 2012-12-21 | 2013-06-07 | Foliar fertilizer composition containing sodium alginate oligosaccharide and use thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210562654.4A CN103011968B (en) | 2012-12-21 | 2012-12-21 | Leaf fertilizer composition comprising sodium alginate oligosaccharide and application of leaf fertilizer composition |
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| Publication Number | Publication Date |
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| CN103011968A true CN103011968A (en) | 2013-04-03 |
| CN103011968B CN103011968B (en) | 2014-11-26 |
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| CN201210562654.4A Active CN103011968B (en) | 2012-12-21 | 2012-12-21 | Leaf fertilizer composition comprising sodium alginate oligosaccharide and application of leaf fertilizer composition |
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|---|---|
| CN (1) | CN103011968B (en) |
| WO (1) | WO2014094412A1 (en) |
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| CN103011968B (en) | 2014-11-26 |
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