CN102978570B - 金属蒸镀薄膜及其制作中间体和相关制作方法 - Google Patents

金属蒸镀薄膜及其制作中间体和相关制作方法 Download PDF

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CN102978570B
CN102978570B CN201210487140.7A CN201210487140A CN102978570B CN 102978570 B CN102978570 B CN 102978570B CN 201210487140 A CN201210487140 A CN 201210487140A CN 102978570 B CN102978570 B CN 102978570B
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蔡莳铨
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Kunshan Renquan Laser Technology Co., Ltd.
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Priority to PCT/CN2012/085701 priority patent/WO2014079097A1/zh
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Abstract

本发明涉及一种金属蒸镀薄膜，由从下而上依次形成或贴合的第一高分子材料层、金属蒸镀层、第二高分子材料层和可水解高分子材料层组成，金属蒸镀层、第一和第二高分子材料层的X轴与Y轴皆为波浪形，可水解高分子材料层的下表面的X轴与Y轴皆为波浪形。较佳地，第二高分子材料层涂布在金属蒸镀层上。可水解高分子材料层涂布在第二高分子材料层上。还涉及金属蒸镀薄膜制作中间体和相关制作方法，其采用载体膜来制作。本发明的金属蒸镀薄膜设计巧妙，结构简洁，其金属蒸镀层能更均匀地扩张或拉伸，具有相当强的弹性，不开裂，并能更容易地转移附着于物件的立体曲面上，且制作巧妙简便，适于大规模推广应用。

Description

金属蒸镀薄膜及其制作中间体和相关制作方法
技术领域
本发明涉及薄膜技术领域，特别涉及金属蒸镀薄膜技术领域，具体是指一种金属蒸镀薄膜及其制作中间体和相关制作方法。
背景技术
目前市场上使用的金属蒸镀薄膜上的金属蒸镀层不够均匀，易开裂，并且不是很容易地转移附着于物件的立体曲面上。
因此，需要提供一种金属蒸镀薄膜，其金属蒸镀层能更均匀地扩张或拉伸，具有相当强的弹性，不开裂，并能更容易地转移附着于物件的立体曲面上。
发明内容
本发明的目的是克服了上述现有技术中的缺点，提供一种金属蒸镀薄膜及其制作中间体和相关制作方法，该金属蒸镀薄膜设计巧妙，结构简洁，其金属蒸镀层能更均匀地扩张或拉伸，具有相当强的弹性，不开裂，并能更容易地转移附着于物件的立体曲面上，且制作巧妙简便，适于大规模推广应用。
为了实现上述目的，在本发明的第一方面，提供了一种金属蒸镀薄膜，其特点是，由从下而上依次形成或贴合的第一高分子材料层、金属蒸镀层、第二高分子材料层和可水解高分子材料层组成，所述第一高分子材料层、所述金属蒸镀层和所述第二高分子材料层的X轴与Y轴皆为波浪形，所述可水解高分子材料层的下表面的X轴与Y轴皆为波浪形。
较佳地，所述第二高分子材料层涂布在所述金属蒸镀层上。
较佳地，所述可水解高分子材料层涂布在所述第二高分子材料层上。
在本发明的第二方面，提供了一种金属蒸镀薄膜制作中间体，其特点是，包括从下而上依次形成或贴合的载体膜、第一高分子材料层、金属蒸镀层、第二高分子材料层和可水解高分子材料层，所述第一高分子材料层、所述金属蒸镀层和所述第二高分子材料层的X轴与Y轴皆为波浪形，所述可水解高分子材料层的下表面的X轴与Y轴皆为波浪形，所述载体膜的上表面的X轴与Y轴皆为波浪形。
较佳地，所述第二高分子材料层涂布在所述金属蒸镀层上。
较佳地，所述可水解高分子材料层涂布在所述第二高分子材料层上。
较佳地，所述第一高分子材料层涂布在所述载体膜上。
在本发明的第三方面，提供了上述的金属蒸镀薄膜的制作方法，其特点是，包括以下步骤：
（1）对载体膜的上表面进行加工使其X轴与Y轴皆为波浪形，从而得到波浪形凹凸面；
（2）在载体膜的波浪形凹凸面上形成或贴合一波浪形凹凸高分子材料层即第一高分子材料层；
（3）在第一高分子材料层上蒸镀波浪形凹凸金属层即金属蒸镀层；
（4）在金属蒸镀层上形成或贴合一波浪形凹凸高分子材料层即第二高分子材料层；
（5）在第二高分子材料层上形成或贴合一水解的高分子材料薄膜即可水解高分子材料层；
（6）将载体膜与第一高分子材料层分离得到所述金属蒸镀薄膜。
较佳地，在所述步骤（5）中，所述可水解高分子材料层涂布在所述第二高分子材料层上；或者在所述步骤（4）中，所述第二高分子材料层涂布在所述金属蒸镀层上；或者在所述步骤（2）中，所述第一高分子材料层涂布在所述载体膜上。
本发明的有益效果具体在于：
1、本发明的金属蒸镀薄膜由从下而上依次形成或贴合的第一高分子材料层、金属蒸镀层、第二高分子材料层和可水解高分子材料层组成，所述第一高分子材料层、所述金属蒸镀层和所述第二高分子材料层的X轴与Y轴皆为波浪形，所述可水解高分子材料层的下表面的X轴与Y轴皆为波浪形，设计巧妙，结构简洁，其金属蒸镀层能更均匀地扩张或拉伸，具有相当强的弹性，不开裂，并能更容易地转移附着于物件的立体曲面上，适于大规模推广应用。
2、本发明的金属蒸镀薄膜制作中间体包括从下而上依次形成或贴合的载体膜、第一高分子材料层、金属蒸镀层、第二高分子材料层和可水解高分子材料层，所述第一高分子材料层、所述金属蒸镀层和所述第二高分子材料层的X轴与Y轴皆为波浪形，所述可水解高分子材料层的下表面的X轴与Y轴皆为波浪形，所述载体膜的上表面的X轴与Y轴皆为波浪形，设计巧妙，结构简洁，其金属蒸镀层能更均匀地扩张或拉伸，具有相当强的弹性，不开裂，并能更容易地转移附着于物件的立体曲面上，适于大规模推广应用。
3、本发明的金属蒸镀薄膜的制作方法采用单面波浪形载体膜来制造双面结构（高分子涂层）波浪形金属蒸镀薄膜，制作巧妙简便，适于大规模推广应用。
附图说明
图1是本发明的金属蒸镀薄膜制作中间体的一具体实施例的局部主视示意图。
具体实施方式
为了能够更清楚地理解本发明的技术内容，特举以下实施例详细说明。其中相同的部件采用相同的附图标记。
请参见图1所示，本发明的金属蒸镀薄膜制作中间体包括从下而上依次形成或贴合的载体膜1、第一高分子材料层2、金属蒸镀层3、第二高分子材料层4和可水解高分子材料层5，所述第一高分子材料层2、所述金属蒸镀层3和所述第二高分子材料层4的X轴与Y轴皆为波浪形，所述可水解高分子材料层5的下表面的X轴与Y轴皆为波浪形，所述载体膜1的上表面的X轴与Y轴皆为波浪形。
所述载体膜1可以采用OPP（定向聚丙烯）薄膜或PET（聚酯）薄膜等（广东德冠薄膜新材料股份有限公司）。
所述第一高分子材料层2可以采用聚氨酯（高鼎精细化工（昆山）有限公司）。
所述金属蒸镀层3可以是任何合适的金属蒸镀层，例如铝蒸镀层、铜蒸镀层、金蒸镀层、银蒸镀层等。
所述第二高分子材料层4可以采用聚氨酯（高鼎精细化工（昆山）有限公司）。
所述可水解高分子材料层5可以采用聚乙烯醇（北京有机化工厂）。
所述可水解高分子材料层5形成或贴合在所述第二高分子材料层4上可以采用任何合适的结构，在本发明的具体实施例中，所述可水解高分子材料层5涂布在所述第二高分子材料层4上。显然也可以采用例如粘接方式。
所述第二高分子材料层4形成或贴合在所述金属蒸镀层3上可以采用任何合适的结构，在本发明的具体实施例中，所述第二高分子材料层4涂布在所述金属蒸镀层3上。同样也可以采用例如粘接方式。
所述第一高分子材料层2形成或贴合在所述载体膜1上可以采用任何合适的结构，在本发明的具体实施例中，所述第一高分子材料层2涂布在所述载体膜1上。同样也可以采用例如粘接方式。
将所述载体膜1与所述第一高分子材料层2分离即得到本发明的金属蒸镀薄膜。
上述金属蒸镀薄膜的制作方法简述如下：
1、对载体膜1的上表面进行加工使其X轴与Y轴皆为波浪形，从而得到波浪形凹凸面；
2、在载体膜1的波浪形凹凸面上形成或贴合一波浪形凹凸高分子材料层即第一高分子材料层2；
3、在第一高分子材料层2上蒸镀波浪形凹凸金属层即金属蒸镀层3；
4、在金属蒸镀层3上形成或贴合一波浪形凹凸高分子材料层即第二高分子材料层4；此时，第一高分子材料层2、金属蒸镀层3和第二高分子材料层4形成一完整的高弹性、可伸缩、可形变的金属镀层。
5、在第二高分子材料层4上形成或贴合一水解的高分子材料薄膜即可水解高分子材料层5，因此，所述可水解高分子材料层5的下表面的X轴与Y轴皆为波浪形；高弹性的可水解高分子材料层5辅助上述三层形成的金属镀层均匀地扩张或拉伸，能容易地转移附着于物件的立体表面上。
6、将载体膜1与第一高分子材料层2分离得到所述金属蒸镀薄膜。
如果不进行步骤6，得到的就是上述的金属蒸镀薄膜制作中间体。
真空蒸镀是在一定的真空条件下加热被蒸镀材料，使其熔化（或升华）并形成原子、分子或原子团组成的蒸气，凝结在基底表面成膜，金属真空蒸镀层本身是由微小颗粒致密排布形成的，上述制作方法是利用载体膜1来制作新型金属蒸镀薄膜的新工艺，制作巧妙简便，符合专利技术（中国发明专利ZL200510111618.6）的工艺,能使金属蒸镀薄膜上的金属真空蒸镀层（Matal Vaccum Deposited Layer）即上述金属蒸镀层3更均匀地扩张或拉伸，具有相当强的弹性，不开裂，并能更容易地转移附着于物件的立体曲面上。
综上，本发明的金属蒸镀薄膜设计巧妙，结构简洁，其金属蒸镀层能更均匀地扩张或拉伸，具有相当强的弹性，不开裂，并能更容易地转移附着于物件的立体曲面上，且制作巧妙简便，适于大规模推广应用。
在此说明书中，本发明已参照其特定的实施例作了描述。但是，很显然仍可以作出各种修改和变换而不背离本发明的精神和范围。因此，说明书和附图应被认为是说明性的而非限制性的。

Claims (7)

1.一种金属蒸镀薄膜，其特征在于，由从下而上依次形成或贴合的第一高分子材料层、金属蒸镀层、第二高分子材料层和可水解高分子材料层组成，所述第一高分子材料层、所述金属蒸镀层和所述第二高分子材料层的X轴与Y轴皆为波浪形，所述金属蒸镀层可扩张或拉伸，所述可水解高分子材料层的下表面的X轴与Y轴皆为波浪形；
所述可水解高分子材料层涂布在所述第二高分子材料层上，所述可水解高分子材料层为高弹性材料；
所述第二高分子材料层涂布在所述金属蒸镀层上。
2.一种金属蒸镀薄膜制作中间体，其特征在于，包括从下而上依次形成或贴合的载体膜、第一高分子材料层、金属蒸镀层、第二高分子材料层和可水解高分子材料层，所述第一高分子材料层、所述金属蒸镀层和所述第二高分子材料层的X轴与Y轴皆为波浪形，所述可水解高分子材料层的下表面的X轴与Y轴皆为波浪形，所述载体膜的上表面的X轴与Y轴皆为波浪形。
3.根据权利要求2所述的金属蒸镀薄膜制作中间体，其特征在于，所述可水解高分子材料层涂布在所述第二高分子材料层上。
4.根据权利要求2所述的金属蒸镀薄膜制作中间体，其特征在于，所述第二高分子材料层涂布在所述金属蒸镀层上。
5.根据权利要求2所述的金属蒸镀薄膜制作中间体，其特征在于，所述第一高分子材料层涂布在所述载体膜上。
6.一种根据权利要求1所述的金属蒸镀薄膜的制作方法，其特征在于，包括以下步骤：
(1)对载体膜的上表面进行加工使其X轴与Y轴皆为波浪形，从而得到波浪形凹凸面；
(2)在载体膜的波浪形凹凸面上形成或贴合一波浪形凹凸高分子材料层即第一高分子材料层；
(3)在第一高分子材料层上蒸镀波浪形凹凸金属层即金属蒸镀层；
(4)在金属蒸镀层上形成或贴合一波浪形凹凸高分子材料层即第二高分子材料层；
(5)在第二高分子材料层上形成或贴合一水解的高分子材料薄膜即可水解高分子材料层；
(6)将载体膜与第一高分子材料层分离得到所述金属蒸镀薄膜。
7.根据权利要求6所述的制作方法，其特征在于，在所述步骤(5)中，所述可水解高分子材料层涂布在所述第二高分子材料层上；或者在所述步骤(4)中，所述第二高分子材料层涂布在所述金属蒸镀层上；或者在所述步骤(2)中，所述第一高分子材料层涂布在所述载体膜上。
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