CN102977585B - 一种聚氨酯阻燃环保电缆料及其制备方法 - Google Patents
一种聚氨酯阻燃环保电缆料及其制备方法 Download PDFInfo
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- CN102977585B CN102977585B CN201210435482.4A CN201210435482A CN102977585B CN 102977585 B CN102977585 B CN 102977585B CN 201210435482 A CN201210435482 A CN 201210435482A CN 102977585 B CN102977585 B CN 102977585B
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- clay
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- 239000000463 material Substances 0.000 title claims abstract description 23
- 229920002635 polyurethane Polymers 0.000 title claims abstract description 19
- 239000004814 polyurethane Substances 0.000 title claims abstract description 19
- 238000002360 preparation method Methods 0.000 title claims description 7
- 239000004927 clay Substances 0.000 claims abstract description 20
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 19
- 229920001971 elastomer Polymers 0.000 claims abstract description 11
- 238000012986 modification Methods 0.000 claims abstract description 11
- 230000004048 modification Effects 0.000 claims abstract description 11
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229920013649 Paracril Polymers 0.000 claims abstract description 8
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000000806 elastomer Substances 0.000 claims abstract description 8
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims abstract description 8
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229920001084 poly(chloroprene) Polymers 0.000 claims abstract description 8
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 8
- 235000021355 Stearic acid Nutrition 0.000 claims abstract description 5
- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 claims abstract description 5
- 239000011609 ammonium molybdate Substances 0.000 claims abstract description 5
- 229940010552 ammonium molybdate Drugs 0.000 claims abstract description 5
- 235000018660 ammonium molybdate Nutrition 0.000 claims abstract description 5
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 5
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 5
- AGXUVMPSUKZYDT-UHFFFAOYSA-L barium(2+);octadecanoate Chemical compound [Ba+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O AGXUVMPSUKZYDT-UHFFFAOYSA-L 0.000 claims abstract description 5
- YKPUWZUDDOIDPM-SOFGYWHQSA-N capsaicin Chemical compound COC1=CC(CNC(=O)CCCC\C=C\C(C)C)=CC=C1O YKPUWZUDDOIDPM-SOFGYWHQSA-N 0.000 claims abstract description 5
- 229960002504 capsaicin Drugs 0.000 claims abstract description 5
- 230000036571 hydration Effects 0.000 claims abstract description 5
- 238000006703 hydration reaction Methods 0.000 claims abstract description 5
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims abstract description 5
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000002994 raw material Substances 0.000 claims abstract description 5
- 239000008117 stearic acid Substances 0.000 claims abstract description 5
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 5
- 239000011593 sulfur Substances 0.000 claims abstract description 5
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 claims abstract description 5
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 claims abstract description 5
- 238000004073 vulcanization Methods 0.000 claims abstract description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- 238000002156 mixing Methods 0.000 claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 6
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 6
- 239000008367 deionised water Substances 0.000 claims description 6
- 229910021641 deionized water Inorganic materials 0.000 claims description 6
- 239000006185 dispersion Substances 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 5
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 3
- 239000005864 Sulphur Substances 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 3
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 3
- 230000003712 anti-aging effect Effects 0.000 claims description 3
- 239000000945 filler Substances 0.000 claims description 3
- 238000002386 leaching Methods 0.000 claims description 3
- 230000007935 neutral effect Effects 0.000 claims description 3
- 238000005453 pelletization Methods 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- 239000011787 zinc oxide Substances 0.000 claims description 3
- 230000007613 environmental effect Effects 0.000 abstract description 5
- 239000003063 flame retardant Substances 0.000 abstract description 5
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 abstract description 4
- 241000256602 Isoptera Species 0.000 abstract description 4
- 235000019504 cigarettes Nutrition 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 4
- 239000007789 gas Substances 0.000 abstract description 2
- 239000002341 toxic gas Substances 0.000 abstract description 2
- 230000032683 aging Effects 0.000 description 3
- 239000000779 smoke Substances 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
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- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
项目 | 结果 |
抗张强度 MPa | 15.5 |
断裂伸长率 % | 370 |
体积电阻率 Ω.cm | 8.9×1012 |
氧指数% | 41 |
135℃×168h热老化后拉伸强度≥ | 25.7MPa |
单位质量烟密度 | 10.3g |
热老化质量损失 ≤ | 21.8g/m2 |
Claims (2)
Priority Applications (1)
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CN201210435482.4A CN102977585B (zh) | 2012-11-05 | 2012-11-05 | 一种聚氨酯阻燃环保电缆料及其制备方法 |
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CN201210435482.4A CN102977585B (zh) | 2012-11-05 | 2012-11-05 | 一种聚氨酯阻燃环保电缆料及其制备方法 |
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CN102977585A CN102977585A (zh) | 2013-03-20 |
CN102977585B true CN102977585B (zh) | 2016-03-30 |
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Cited By (1)
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EP4206773A1 (en) * | 2021-12-28 | 2023-07-05 | Sterlite Technologies Limited | Fire retardant strength member for optical fiber cables and manufacturing method thereof |
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NO346554B1 (en) | 2019-08-09 | 2022-10-03 | Klingelberg Products As | Flame retardant, method for its manufacture and article comprising such flame retardant |
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CN114716807A (zh) * | 2022-03-07 | 2022-07-08 | 东莞市益恒特新材料科技有限公司 | 特种柔性线缆专用护套材料及其制备方法 |
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CN102757582B (zh) * | 2012-07-28 | 2014-04-09 | 江西联创电缆科技有限公司 | 无线电装置用橡皮电缆环保抗菌护套组合物 |
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WO2007068596A1 (de) * | 2005-12-14 | 2007-06-21 | Tesa Ag | Wickelband aus einer tpu-folie |
CN102336946A (zh) * | 2010-07-22 | 2012-02-01 | 浙江万马电缆股份有限公司 | 轨道交通用橡皮电缆护套材料及其制备方法和应用 |
CN102492191A (zh) * | 2011-12-01 | 2012-06-13 | 江苏德威新材料股份有限公司 | 环保型耐高低温耐油耐磨阻燃橡塑组合物 |
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EP4206773A1 (en) * | 2021-12-28 | 2023-07-05 | Sterlite Technologies Limited | Fire retardant strength member for optical fiber cables and manufacturing method thereof |
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