CN104788799B - 环保型无卤电动汽车传导充电系统用电缆护套料及其制备方法 - Google Patents
环保型无卤电动汽车传导充电系统用电缆护套料及其制备方法 Download PDFInfo
- Publication number
- CN104788799B CN104788799B CN201510190651.6A CN201510190651A CN104788799B CN 104788799 B CN104788799 B CN 104788799B CN 201510190651 A CN201510190651 A CN 201510190651A CN 104788799 B CN104788799 B CN 104788799B
- Authority
- CN
- China
- Prior art keywords
- parts
- antioxidant
- cable jacket
- jacket material
- environment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000463 material Substances 0.000 title claims abstract description 42
- 238000002360 preparation method Methods 0.000 title claims abstract description 22
- 239000004594 Masterbatch (MB) Substances 0.000 claims abstract description 36
- 239000000203 mixture Substances 0.000 claims abstract description 35
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 34
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 34
- 239000002994 raw material Substances 0.000 claims abstract description 28
- 239000003063 flame retardant Substances 0.000 claims abstract description 25
- 229920000092 linear low density polyethylene Polymers 0.000 claims abstract description 14
- 239000004707 linear low-density polyethylene Substances 0.000 claims abstract description 14
- 229920000459 Nitrile rubber Polymers 0.000 claims abstract description 13
- 239000000843 powder Substances 0.000 claims abstract description 13
- 238000004132 cross linking Methods 0.000 claims abstract description 12
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 12
- 229920006124 polyolefin elastomer Polymers 0.000 claims abstract description 12
- 229920003225 polyurethane elastomer Polymers 0.000 claims abstract description 10
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 16
- 229910000077 silane Inorganic materials 0.000 claims description 16
- 238000013329 compounding Methods 0.000 claims description 15
- 238000003756 stirring Methods 0.000 claims description 14
- 239000003795 chemical substances by application Substances 0.000 claims description 13
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 12
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 12
- 239000000779 smoke Substances 0.000 claims description 12
- 239000000314 lubricant Substances 0.000 claims description 11
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 8
- 229920001577 copolymer Polymers 0.000 claims description 8
- 229920006245 ethylene-butyl acrylate Polymers 0.000 claims description 8
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 7
- QYMGIIIPAFAFRX-UHFFFAOYSA-N butyl prop-2-enoate;ethene Chemical compound C=C.CCCCOC(=O)C=C QYMGIIIPAFAFRX-UHFFFAOYSA-N 0.000 claims description 7
- 238000005469 granulation Methods 0.000 claims description 7
- 230000003179 granulation Effects 0.000 claims description 7
- 238000005453 pelletization Methods 0.000 claims description 7
- 239000007921 spray Substances 0.000 claims description 7
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 6
- 239000000347 magnesium hydroxide Substances 0.000 claims description 6
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 6
- OKKRPWIIYQTPQF-UHFFFAOYSA-N Trimethylolpropane trimethacrylate Chemical compound CC(=C)C(=O)OCC(CC)(COC(=O)C(C)=C)COC(=O)C(C)=C OKKRPWIIYQTPQF-UHFFFAOYSA-N 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 5
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 5
- HCILJBJJZALOAL-UHFFFAOYSA-N 3-(3,5-ditert-butyl-4-hydroxyphenyl)-n'-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyl]propanehydrazide Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)NNC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 HCILJBJJZALOAL-UHFFFAOYSA-N 0.000 claims description 4
- KWUZCAVKPCRJPO-UHFFFAOYSA-N n-ethyl-4-(6-methyl-1,3-benzothiazol-2-yl)aniline Chemical compound C1=CC(NCC)=CC=C1C1=NC2=CC=C(C)C=C2S1 KWUZCAVKPCRJPO-UHFFFAOYSA-N 0.000 claims description 4
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 4
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 3
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 3
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 claims description 3
- -1 isocyanuric acid ester Chemical class 0.000 claims description 3
- 229910052749 magnesium Inorganic materials 0.000 claims description 3
- 239000011777 magnesium Substances 0.000 claims description 3
- 229910052750 molybdenum Inorganic materials 0.000 claims description 3
- 239000011733 molybdenum Substances 0.000 claims description 3
- 150000002978 peroxides Chemical class 0.000 claims description 3
- 150000002989 phenols Chemical class 0.000 claims description 3
- 239000011701 zinc Substances 0.000 claims description 3
- 229910052725 zinc Inorganic materials 0.000 claims description 3
- 238000002485 combustion reaction Methods 0.000 claims description 2
- 229920000098 polyolefin Polymers 0.000 claims description 2
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Natural products OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 claims 1
- 229910052736 halogen Inorganic materials 0.000 abstract description 8
- 150000002367 halogens Chemical class 0.000 abstract description 8
- 239000002341 toxic gas Substances 0.000 abstract description 3
- 238000009472 formulation Methods 0.000 description 8
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 description 7
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 5
- 229920001971 elastomer Polymers 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- 238000002844 melting Methods 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- 238000004381 surface treatment Methods 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 3
- 239000000806 elastomer Substances 0.000 description 3
- 238000002955 isolation Methods 0.000 description 3
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 description 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 3
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 235000019359 magnesium stearate Nutrition 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000005060 rubber Substances 0.000 description 2
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 2
- FEXBEKLLSUWSIM-UHFFFAOYSA-N 2-Butyl-4-methylphenol Chemical class CCCCC1=CC(C)=CC=C1O FEXBEKLLSUWSIM-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- KVNRLNFWIYMESJ-UHFFFAOYSA-N butyronitrile Chemical compound CCCC#N KVNRLNFWIYMESJ-UHFFFAOYSA-N 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 229920006226 ethylene-acrylic acid Polymers 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 230000001404 mediated effect Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical class OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 230000000505 pernicious effect Effects 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920001084 poly(chloroprene) Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000003908 quality control method Methods 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C08L23/0869—Acids or derivatives thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B9/00—Making granules
- B29B9/02—Making granules by dividing preformed material
- B29B9/06—Making granules by dividing preformed material in the form of filamentary material, e.g. combined with extrusion
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
- C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
- H01B3/441—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from alkenes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B7/00—Insulated conductors or cables characterised by their form
- H01B7/17—Protection against damage caused by external factors, e.g. sheaths or armouring
- H01B7/18—Protection against damage caused by wear, mechanical force or pressure; Sheaths; Armouring
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B7/00—Insulated conductors or cables characterised by their form
- H01B7/17—Protection against damage caused by external factors, e.g. sheaths or armouring
- H01B7/29—Protection against damage caused by extremes of temperature or by flame
- H01B7/295—Protection against damage caused by extremes of temperature or by flame using material resistant to flame
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92704—Temperature
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
- C08J2323/08—Copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2423/04—Homopolymers or copolymers of ethene
- C08J2423/08—Copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/22—Halogen free composition
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Mechanical Engineering (AREA)
- Insulated Conductors (AREA)
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Insulating Materials (AREA)
Abstract
本发明涉及一种环保型无卤电动汽车传导充电系统用电缆护套料及其制备方法,以重量份计，它的原料配方如下：弹性体组合物25~80份；丁腈橡胶粉10~25份；预交联母料5~10份；阻燃剂120~180份；交联敏化剂1.5~6份；所述弹性体组合物包括聚氨酯弹性体和聚烯烃弹性体；所述预交联母料的原料配方包括以下质量分数的组份：线性低密度聚乙烯94~98%、交联剂1~5%、第一抗氧剂0.1~1%。一方面使用线性低密度聚乙烯、交联剂、第一抗氧剂形成的预交联母料，使得该电缆护套料具有良好的耐热性和交联度，增加产品的物理机械性能和耐油性能；采用的原料均环保无卤，不含有PVC等在高温时释放有毒气体的成分，是环境友好型材料。
Description
技术领域
本发明涉及一种电缆护套料,具体涉及一种环保型无卤电动汽车传导充电系统用电缆护套料及其制备方法。
背景技术
面对日益严峻的能源、环境、气候变化，发展新能源动力汽车已经逐步成为全球共识。电动汽车作为解决方案之一，其普及将对新能源应用以及交通系统产生积极而又深远的影响，也将为电动汽车相关传导充电系统产品行业带来良好的发展机遇。
电动汽车传导充电系统用电缆用于电动汽车与电源的充电连接，是电动汽车传导充电系统的关键设备之一，该类产品性能的优劣对电动汽车的安全可靠运行将产生直接的影响。
电动汽车传导充电系统用电缆是随着电动汽车而出现的一种新型的电缆形式，国际上先进国家也正在积极进行该产品的研发，我国自2010年以来也逐步进行该类产品的研制，由于该类产品目前尚无相应的IEC标准、也无国家标准，各方对于产品质量的控制和评估存在一定的差异。目前，电动汽车传导充电系统用电缆护套料可使用乙丙橡胶、氯丁橡胶、PVC、低烟无卤聚烯烃、TPU、TPE等材料，其中PVC材料以其优异的物理性能和加工工艺性能、低廉的价格，获得普遍关注；但是PVC含有卤素，燃烧后会产生二噁英等有害气体。因此，有必要从配方着手开发出一种新的环保无卤的电动汽车传导充电系统用电缆护套料。
发明内容
本发明所要解决的技术问题是提供一种环保型无卤电动汽车传导充电系统用电缆护套料。
为达到上述目的，本发明采用的技术方案是：一种环保型无卤电动汽车传导充电系统用电缆护套料，以重量份计，它的原料配方如下：
弹性体组合物25～80份；
丁腈橡胶粉10～25份；
预交联母料5～10份；
阻燃剂120～180份；
交联敏化剂1.5～6份；
所述弹性体组合物包括聚氨酯弹性体和聚烯烃弹性体；所述预交联母料的原料配方包括以下质量分数的组份：线性低密度聚乙烯94～98％、交联剂1～5％、第一抗氧剂0.1～1％。
优化地，它的原料配方还包括抑烟剂2～4份、润滑剂1～4份和第二抗氧剂1～3份。
优化地，所述聚烯烃弹性体由乙烯-辛烯共聚物或/和乙烯-丙烯酸丁酯共聚物复配而成，其硬度为80～90A；所述弹性体组合物包括5～35份聚氨酯弹性体和20～70份聚烯烃弹性体。
优化地，所述引发剂为二烷基过氧化物，所述第一抗氧剂为受阻酚类抗氧剂。
优化地，所述丁腈橡胶粉中丙烯腈的质量含量为30～33％，它还包括超细氢氧化铝隔离剂；所述阻燃剂为经过表面处理的氢氧化铝、氢氧化镁中的一种或两种，所述交联敏化剂为三烯丙基异氰脲酸酯、三羟甲基丙烷三甲基丙烯酸酯中的一种。
进一步地，所述抑烟剂为含锌、钼、镁元素的复合抑烟剂；所述润滑剂采用0.3～2份硬脂酸盐和0.5～2份丙烯酸接枝聚乙烯蜡复配而成；所述第二抗氧剂为抗氧剂300与硫代二丙酸双月桂酯、抗氧剂1010、抗氧剂1024中的一种或多种复配而成。
本发明的又一目的是提供一种环保型无卤电动汽车传导充电系统用电缆护套料的制备方法，它包括以下步骤：
(a)在400～500转/分钟的转速下对阻燃剂进行搅拌，随后向其中喷入占阻燃剂质量1～2％的硅烷，继续搅拌30～60秒；
(b)将各种原料按配方称量好，加入捏合机中进行搅拌，随后经密炼机、双螺杆挤出机挤出造粒；所述密炼机温度为140～160℃，所述双螺杆挤出机温度分别为：进料段120～140℃，熔融段130～150℃，模头145～155℃。
优化地，所述步骤(b)中，在将原料加入捏合机前先将线性低密度聚乙烯加热熔融，随后加入配方量的交联剂和第一抗氧剂，搅拌均匀后造粒挤出形成预交联母料。
由于上述技术方案运用，本发明与现有技术相比具有下列优点：本发明环保型无卤电动汽车传导充电系统用电缆护套料，一方面使用线性低密度聚乙烯、交联剂、第一抗氧剂形成的预交联母料，使得该电缆护套料具有良好的耐热性和交联度，增加产品的物理机械性能和耐油性能；其次，氢氧化铝隔离丁腈橡胶粉，用以增加产品的最终耐油性能，与传统的碳酸钙或者PVC隔离剂相比较，具有环保无卤和阻燃性好的特点；而且本发明采用的原料均环保无卤，不含有PVC等在高温时释放有毒气体的成分，是环境友好型材料。
具体实施方式
本发明环保型无卤电动汽车传导充电系统用电缆护套料，以重量份计，它的原料配方如下：弹性体组合物25～80份；丁腈橡胶粉10～25份；预交联母料5～10份；阻燃剂120～180份；交联敏化剂1.5～6份；所述弹性体组合物包括聚氨酯弹性体和聚烯烃弹性体；所述预交联母料的原料配方包括以下质量分数的组份：线性低密度聚乙烯94～98％、交联剂1～5％、第一抗氧剂0.1～1％。一方面使用线性低密度聚乙烯、交联剂、第一抗氧剂形成的预交联母料，使得该电缆护套料具有良好的耐热性和交联度，增加产品的物理机械性能和耐油性能；其次，氢氧化铝隔离丁腈橡胶粉，用以增加产品的最终耐油性能，与传统的碳酸钙或者PVC隔离剂相比较，具有环保无卤和阻燃性好的特点；而且本发明采用的原料均环保无卤，不含有PVC等在高温时释放有毒气体的成分，是环境友好型材料。
它的原料配方还优选包括抑烟剂2～4份、润滑剂1～4份和第二抗氧剂1～3份，抑烟剂能够同阻燃剂产生协同作用，从而抑制电缆护套料在高温时产生浓烟，对使用者产生不利影响；润滑剂主要使产品具有优异的加工性能和光滑的表面；第二抗氧剂主要用于提高电缆护套料的使用寿命。弹性体组合物优选包括5～35份聚氨酯弹性体和20～70份聚烯烃弹性体，聚烯烃弹性体优选由乙烯-辛烯共聚物或/和乙烯-丙烯酸丁酯共聚物复配而成，其硬度优选为80～90A，这样能够使聚烯烃弹性体的聚合物主链上形成较长的支链，避免聚烯烃弹性体规整度太高而刚度太强，其中乙烯-辛烯共聚物的质量分数(占聚烯烃弹性体的质量分数)约为0～45％，乙烯-丙烯酸丁酯共聚物的质量分数约为55～100％。
交联剂优选为常规的二烷基过氧化物，例如过氧化二异丙苯、过氧化二叔丁基等；第一抗氧剂优选为常规的受阻酚类抗氧剂，例如2,6-三级丁基-4-甲基苯酚、双(3,5-三级丁基-4-羟基苯基)硫醚、四(β-(3,5-三级丁基-4-羟基苯基)丙酸)季戊四醇酯等；所述丁腈橡胶粉中丙烯腈的质量含量优选为30～33％，它还包括超细氢氧化铝作为隔离剂，所述阻燃剂优选为经过表面处理的氢氧化铝、氢氧化镁中的一种或两种，所述交联敏化剂优选为三烯丙基异氰脲酸酯(TAIC)和三羟甲基丙烷三甲基丙烯酸酯(TMPTMA)中的一种。
所述抑烟剂优选为含锌、钼、镁元素的复合抑烟剂，例如进口的Charmax LS-SEP等；所述润滑剂优选为采用0.3～2份硬脂酸盐和0.5～2份丙烯酸接枝聚乙烯蜡复配而成，添加丙烯酸接枝聚乙烯蜡后能够同时提高其与高分子材料、硬脂酸盐的相容性，从而提高最终电缆护套料的性能。所述第二抗氧剂优选为抗氧剂300与硫代二丙酸双月桂酯、抗氧剂1010、抗氧剂1024中的一种或多种复配而成。
上述环保型无卤电动汽车传导充电系统用电缆护套料的制备方法，它包括以下步骤：
(a)在400～500转/分钟的转速下对阻燃剂进行高速捏合，随后向其中喷入占阻燃剂质量1～2％的硅烷，继续搅拌30～60秒至硅烷被阻燃剂吸收；
(b)将各种原料按配方称量好，加入捏合机中进行搅拌，随后经密炼机、双螺杆挤出机挤出造粒；所述密炼机温度为140～160℃，所述双螺杆挤出机温度分别为：进料段120～140℃，熔融段130～150℃，模头155～165℃。
步骤(b)中，在将原料加入捏合机前优选先将线性低密度聚乙烯加热熔融，随后加入配方量的交联剂和第一抗氧剂，搅拌均匀后造粒挤出形成预交联母料。
下面将对本发明优选实施方案进行详细说明：
实施例1
本实施例提供一种环保型无卤电动汽车传导充电系统用电缆护套料，以重量份计，它的原料配方如下：
聚氨酯弹性体15份；
聚烯烃弹性体50份，硬度为80A，其中乙烯-辛烯共聚物9份，乙烯-丙烯酸丁酯共聚物11份；
丁腈橡胶粉25份(丙烯腈的质量含量为30％)，包含1份超细氢氧化铝隔离剂；
预交联母料10份；
经过硅烷表面处理的氢氧化铝160份；
TAIC 2份；
抑烟剂(Charmax LS-SEP)2份；
润滑剂1.5份，采用0.3份硬脂酸镁和0.7份丙烯酸接枝聚乙烯蜡复配而成；
第二抗氧剂1.5份，它为抗氧剂300与硫代二丙酸双月桂酯复配而成，它们的质量比为1:0.5；
它的制备方法包括以下步骤：
(a)在400转/分钟的转速下对阻燃剂进行搅拌，随后向其中喷入占阻燃剂质量1％的硅烷，继续搅拌30秒至硅烷被阻燃剂吸收；
(b)预交联母料的制备：将线性低密度聚乙烯(占预交联母料配方质量总量的94％)加热熔融，随后加入过氧化二异丙苯(占预交联母料配方质量总量的2％)，搅拌均匀后造粒挤出形成预交联母料；电缆护套料的制备：将各种原料按上述配方称量好，加入捏合机中进行搅拌，随后经密炼机、双螺杆挤出机挤出造粒；所述密炼机温度为140℃，所述双螺杆挤出机温度分别为：进料段120℃，熔融段130℃，模头155℃。
实施例2
本实施例提供一种环保型无卤电动汽车传导充电系统用电缆护套料，以重量份计，它的原料配方如下：
聚氨酯弹性体35份；
聚烯烃弹性体40份，它全部是乙烯-丙烯酸丁酯共聚物，即40份乙烯-丙烯酸丁酯共聚物，硬度为90A；
丁腈橡胶粉20份(丙烯腈的质量含量为33％，)，包含0.5份超细氢氧化铝隔离剂；
预交联母料5份；
经过硅烷表面处理的氢氧化镁120份；
TAIC 2.5份；
Charmax LS-SEP 3份；
润滑剂1份，采用0.5份硬脂酸锌和0.5份丙烯酸接枝聚乙烯蜡复配而成；
第二抗氧剂1份，它为抗氧剂300；
它的制备方法包括以下步骤：
(a)在500转/分钟的转速下对阻燃剂进行搅拌，随后向其中喷入占阻燃剂质量2％的硅烷，继续搅拌30秒至硅烷被阻燃剂吸收；
(b)预交联母料的制备：将线性低密度聚乙烯(占预交联母料配方质量总量的98％)加热熔融，随后加入过氧化二异丙苯(占预交联母料配方质量总量的3％)，搅拌均匀后造粒挤出形成预交联母料；电缆护套料的制备：将各种原料按配方称量好，加入捏合机中进行搅拌，随后经密炼机、双螺杆挤出机挤出造粒；所述密炼机温度为160℃，所述双螺杆挤出机温度分别为：进料段140℃，熔融段150℃，模头165℃。
实施例3
本实施例提供一种环保型无卤电动汽车传导充电系统用电缆护套料，以重量份计，它的原料配方如下：
聚氨酯弹性体20份；
聚烯烃弹性体52份，硬度为85A左右，其中，乙烯-辛烯共聚物10份、乙烯-丙烯酸丁酯共聚物40份；
丁腈橡胶粉20份(丙烯腈的质量含量为30％)，包含2份超细氢氧化铝作为隔离剂；
预交联母料8份；
经过硅烷表面处理的氢氧化镁150份；
TMPTMA 2份；
Charmax LS-SEP 2.5份；
润滑剂1.5份，采用2份硬脂酸镁和2份丙烯酸接枝聚乙烯蜡复配而成；
第二抗氧剂1.5份，它为抗氧剂300与硫代二丙酸双月桂酯、抗氧剂1010复配而成，它们的质量比为0.8：0.3：0.4；
它的制备方法包括以下步骤：
(a)在450转/分钟的转速下对阻燃剂进行搅拌，随后向其中喷入占阻燃剂质量1.5％的硅烷，继续搅拌60秒至硅烷被阻燃剂吸收；
(b)预交联母料的制备：将线性低密度聚乙烯(占预交联母料配方质量总量的96％)加热熔融，随后加入过氧化二异丙苯等(占预交联母料配方质量总量的2.5％)，搅拌均匀后造粒挤出形成预交联母料；
(c)电缆护套料的制备：将各种原料按配方称量好，加入捏合机中进行搅拌，随后经密炼机、双螺杆挤出机挤出造粒；所述密炼机温度为150℃，所述双螺杆挤出机温度分别为：进料段135℃，熔融段145℃，模头160℃。
实施例4
本实施例提供一种环保型无卤电动汽车传导充电系统用电缆护套料，以重量份计，它的原料配方如下：
聚氨酯弹性体5份；
聚烯烃弹性体65份，硬度为88A，其中，乙烯-辛烯共聚物15份、乙烯-丙烯酸丁酯共聚物40份；
丁腈橡胶粉25份(丙烯腈的质量含量为32％，)，包含1份超细氢氧化铝作为隔离剂；
预交联母料5份；
经过硅烷表面处理的氢氧化镁180份；
三烯丙基异氰脲酸酯(TAIC)1.5份；
Charmax LS-SEP 2份；
润滑剂3份，采用1份硬脂酸锌和1份丙烯酸接枝聚乙烯蜡，1份硅酮母粒复配而成；
第二抗氧剂2.5份，它为抗氧剂300与抗氧剂1024复配而成，它们的质量比为1.5：1；
它的制备方法包括以下步骤：
(a)在500转/分钟的转速下对阻燃剂进行搅拌，随后向其中喷入占阻燃剂质量1.5％的硅烷，继续搅拌60秒至硅烷被阻燃剂吸收；
(b)预交联母料的制备：将线性低密度聚乙烯(占预交联母料配方质量总量的95％)加热熔融，随后加入过氧化二异丙苯(占预交联母料配方质量总量的2％)，搅拌均匀后造粒挤出形成预交联母料；
(c)电缆护套料的制备：将各种原料按配方称量好，加入捏合机中进行搅拌，随后经密炼机、双螺杆挤出机挤出造粒；所述密炼机温度为150℃，所述双螺杆挤出机温度分别为：进料段135℃，熔融段145℃，模头150℃。
对比例1
本实施例提供一种电动汽车传导充电系统用电缆护套料，它的原料配方及制备方法与实施例3中的基本相同，不同的是它不含有预交联母料。
对比例2
本实施例提供一种电动汽车传导充电系统用电缆护套料，它的原料配方及制备方法与实施例3中的基本相同，不同的是它不含有丁腈橡胶。
表1 实施例1至4、对比例1至2中制备的电缆护套料的性能测试
上述实施例只为说明本发明的技术构思及特点，其目的在于让熟悉此项技术的人士能够了解本发明的内容并据以实施，并不能以此限制本发明的保护范围，凡根据本发明精神实质所作的等效变化或修饰，都应涵盖在本发明的保护范围之内。
Claims (6)
1.一种环保型无卤电动汽车传导充电系统用电缆护套料，其特征在于，以重量份计，它的原料配方如下：
弹性体组合物 25~80份；
丁腈橡胶粉 10~25份；
预交联母料5~10份；
阻燃剂120~180份；
交联敏化剂1.5~6份；
抑烟剂2~4份；
润滑剂1~4份；
第二抗氧剂1~3份；
所述弹性体组合物包括5~35份聚氨酯弹性体和20~70份聚烯烃弹性体；所述聚烯烃弹性体由乙烯-辛烯共聚物或/和乙烯-丙烯酸丁酯共聚物复配而成，其硬度为80~90A；所述预交联母料的原料配方包括以下质量分数的组份：线性低密度聚乙烯94~98%、交联剂1~5%、第一抗氧剂0.1~1%。
2.根据权利要求1所述的环保型无卤电动汽车传导充电系统用电缆护套料，其特征在于：所述交联剂为二烷基过氧化物，所述第一抗氧剂为受阻酚类抗氧剂。
3.根据权利要求1所述的环保型无卤电动汽车传导充电系统用电缆护套料，其特征在于：所述丁腈橡胶粉中丙烯腈的质量含量为30~33%，它还包括超细氢氧化铝隔离剂；所述阻燃剂为经过表面处理的氢氧化铝、氢氧化镁中的一种或两种，所述交联敏化剂为三烯丙基异氰脲酸酯、三羟甲基丙烷三甲基丙烯酸酯中的一种。
4.根据权利要求1所述的环保型无卤电动汽车传导充电系统用电缆护套料，其特征在于：所述抑烟剂为含锌、钼、镁元素的复合抑烟剂；所述润滑剂采用0.3~2份硬脂酸盐和0.5~2份丙烯酸接枝聚乙烯蜡复配而成；所述第二抗氧剂为抗氧剂300与硫代二丙酸双月桂酯、抗氧剂1010、抗氧剂1024中的一种或多种复配而成。
5.权利要求1所述环保型无卤电动汽车传导充电系统用电缆护套料的制备方法，其特征在于，它包括以下步骤：
（a）在400～500转/分钟的转速下对阻燃剂进行搅拌，随后向其中喷入占阻燃剂质量1~2%的硅烷，继续搅拌30~60秒；
（b）将各种原料按配方称量好，加入捏合机中进行搅拌，随后经密炼机、双螺杆挤出机挤出造粒；所述密炼机温度为140~160℃，所述双螺杆挤出机温度分别为：进料段120~140℃，熔融段130~150℃，模头145~155℃。
6.根据权利要求5所述环保型无卤电动汽车传导充电系统用电缆护套料的制备方法，其特征在于：所述步骤（b）中，在将原料加入捏合机前先将线性低密度聚乙烯加热熔融，随后加入配方量的交联剂和第一抗氧剂，搅拌均匀后造粒挤出形成预交联母料。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510190651.6A CN104788799B (zh) | 2015-04-21 | 2015-04-21 | 环保型无卤电动汽车传导充电系统用电缆护套料及其制备方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510190651.6A CN104788799B (zh) | 2015-04-21 | 2015-04-21 | 环保型无卤电动汽车传导充电系统用电缆护套料及其制备方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104788799A CN104788799A (zh) | 2015-07-22 |
| CN104788799B true CN104788799B (zh) | 2017-06-16 |
Family
ID=53554012
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510190651.6A Active CN104788799B (zh) | 2015-04-21 | 2015-04-21 | 环保型无卤电动汽车传导充电系统用电缆护套料及其制备方法 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104788799B (zh) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105038088B (zh) * | 2015-08-21 | 2017-10-13 | 中广核三角洲（苏州）高聚物有限公司 | 一种耐油耐寒耐高温电动汽车充电桩用弹性体电缆料及其制备方法 |
| CN105315887A (zh) * | 2015-11-25 | 2016-02-10 | 国网辽宁省电力有限公司阜新供电公司 | 电力变压器绝缘层的制备方法 |
| CN105602071B (zh) * | 2016-03-21 | 2018-06-15 | 江苏德威新材料股份有限公司 | 耐高温辐照无卤阻燃汽车线料及其制备方法 |
| CN106366635A (zh) * | 2016-08-31 | 2017-02-01 | 苏州亨利通信材料有限公司 | 一种易加工无卤阻燃tpu弹性体及其制备方法 |
| CN110079073A (zh) * | 2019-05-09 | 2019-08-02 | 安徽省通信产业服务有限公司 | 高阻燃性能的电缆料及其制备方法 |
| CN110903589B (zh) * | 2019-11-14 | 2021-08-31 | 苏州铂玛新材料有限公司 | 一种新能源汽车用高压软质聚烯烃电线料及其制备方法 |
| CN112233843B (zh) * | 2020-12-17 | 2021-02-26 | 特变电工(德阳)电缆股份有限公司 | 一种环保阻燃耐寒耐磨电缆及其制造方法和应用 |
| CN112708255A (zh) * | 2020-12-24 | 2021-04-27 | 广州机械科学研究院有限公司 | 一种耐低温弹性体橡胶组合物及其应用 |
| CN114763424A (zh) * | 2021-01-15 | 2022-07-19 | 深圳市沃尔核材股份有限公司 | 交联聚烯烃胶料及制备方法、以及使用该胶料的汽车线缆 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101618594B (zh) * | 2009-07-22 | 2012-05-30 | 湖北拓普聚合体科技有限公司 | 一种新型高耐油耐热阻燃环保热塑性弹性体的制备方法 |
| CN102863686B (zh) * | 2012-10-11 | 2014-12-17 | 江苏德威新材料股份有限公司 | 一种半导电低烟无卤阻燃聚烯烃护套料及其制备方法 |
| CN102977585B (zh) * | 2012-11-05 | 2016-03-30 | 安徽金桥电缆有限公司 | 一种聚氨酯阻燃环保电缆料及其制备方法 |
| US9062193B2 (en) * | 2012-12-04 | 2015-06-23 | E. I. Du Pont De Nemours And Company | Heat aging resistant ethylene vinyl acetate copolymer composition and process for its production |
-
2015
- 2015-04-21 CN CN201510190651.6A patent/CN104788799B/zh active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN104788799A (zh) | 2015-07-22 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104788799B (zh) | 环保型无卤电动汽车传导充电系统用电缆护套料及其制备方法 | |
| CN102070821B (zh) | 辐照交联耐油型柔软低烟无卤阻燃电缆材料 | |
| CN103012946B (zh) | 一种150℃辐照交联低烟无卤阻燃电缆料 | |
| CN105419072A (zh) | 一种柔性低烟无卤阻燃型电线电缆料及其制备方法 | |
| CN102532674A (zh) | 辐照交联耐油无卤阻燃电线及其制备方法 | |
| CN106633420A (zh) | 一种无卤阻燃热塑性动态硫化三元乙丙橡胶/聚丙烯组合物及其制备方法 | |
| CN102757588B (zh) | 一种聚氯乙烯阻燃耐火电力电缆料及其制备方法 | |
| CN106432886A (zh) | 环保型抗粘连聚烯烃电缆料 | |
| CN101942141A (zh) | 低烟无卤阻燃电缆料及其制备方法 | |
| CN106398003A (zh) | 一种阻燃导电热塑性硫化橡胶材料 | |
| CN104387713B (zh) | 一种再生hips环保改性材料及其制备方法 | |
| CN104312038A (zh) | 超耐热耐油型聚氯乙烯电缆料及其制备方法、电缆 | |
| CN102352066A (zh) | 一种低烟无卤环保阻燃材料及其制备方法 | |
| CN106674768A (zh) | 一种三元乙丙橡胶低烟无卤阻燃软胶料 | |
| CN105199329A (zh) | 辐照交联热塑性聚酯弹性体电缆料及电缆生产方法 | |
| CN105034186B (zh) | 光伏线缆护套层材料的制备方法 | |
| CN102746636A (zh) | 一种煤矿用聚乙烯绝缘电力电缆料及其制备方法 | |
| CN104194170B (zh) | 一种cpe/pvc组份型低气味电线电缆护套胶料及其制备方法 | |
| CN105086108A (zh) | 一种含回收料的防鼠低烟无卤聚烯烃电缆料的制备方法 | |
| CN102585343A (zh) | 一种黑色105℃辐照交联低烟无卤阻燃聚烯烃电缆护套料及其制备方法 | |
| CN102977612B (zh) | 一种丙烯酸酯阻燃环保橡胶电缆料及其制备方法 | |
| CN102585344A (zh) | 一种黑色125℃辐照交联低烟无卤阻燃聚烯烃电缆护套料及其制备方法 | |
| CN105017662A (zh) | Cpe/eva组分型耐高温超耐磨电线电缆护套胶料 | |
| CN105419073A (zh) | 一种低烟无卤阻燃型电线电缆护套料及其制备方法 | |
| CN104829827A (zh) | 一种改性聚亚芳醚树脂及其复合无卤阻燃材料、制备方法及用途 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| EXSB | Decision made by sipo to initiate substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| PP01 | Preservation of patent right |
Effective date of registration: 20210122 Granted publication date: 20170616 |
|
| PP01 | Preservation of patent right | ||
| PD01 | Discharge of preservation of patent |
Date of cancellation: 20240122 Granted publication date: 20170616 |
|
| PD01 | Discharge of preservation of patent |