CN102977610B - 一种机车车辆用交联低烟无卤阻燃电缆料及其制备方法 - Google Patents
一种机车车辆用交联低烟无卤阻燃电缆料及其制备方法 Download PDFInfo
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- CN102977610B CN102977610B CN201210435498.5A CN201210435498A CN102977610B CN 102977610 B CN102977610 B CN 102977610B CN 201210435498 A CN201210435498 A CN 201210435498A CN 102977610 B CN102977610 B CN 102977610B
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- 238000004132 cross linking Methods 0.000 title claims abstract description 15
- 239000000779 smoke Substances 0.000 title claims abstract description 14
- 238000005096 rolling process Methods 0.000 title claims abstract description 12
- DXZMANYCMVCPIM-UHFFFAOYSA-L zinc;diethylphosphinate Chemical compound [Zn+2].CCP([O-])(=O)CC.CCP([O-])(=O)CC DXZMANYCMVCPIM-UHFFFAOYSA-L 0.000 title claims abstract description 12
- 238000002360 preparation method Methods 0.000 title claims description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 15
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 12
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 claims abstract description 12
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims abstract description 10
- 238000012986 modification Methods 0.000 claims abstract description 9
- 230000004048 modification Effects 0.000 claims abstract description 9
- 239000002994 raw material Substances 0.000 claims abstract description 9
- 239000000347 magnesium hydroxide Substances 0.000 claims abstract description 8
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims abstract description 8
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 claims abstract description 6
- OUBMGJOQLXMSNT-UHFFFAOYSA-N N-isopropyl-N'-phenyl-p-phenylenediamine Chemical compound C1=CC(NC(C)C)=CC=C1NC1=CC=CC=C1 OUBMGJOQLXMSNT-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000006096 absorbing agent Substances 0.000 claims abstract description 6
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 6
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 6
- 239000006229 carbon black Substances 0.000 claims abstract description 6
- 229920001971 elastomer Polymers 0.000 claims abstract description 6
- HIHIPCDUFKZOSL-UHFFFAOYSA-N ethenyl(methyl)silicon Chemical compound C[Si]C=C HIHIPCDUFKZOSL-UHFFFAOYSA-N 0.000 claims abstract description 6
- 230000036571 hydration Effects 0.000 claims abstract description 6
- 238000006703 hydration reaction Methods 0.000 claims abstract description 6
- 229920000092 linear low density polyethylene Polymers 0.000 claims abstract description 6
- 239000004707 linear low-density polyethylene Substances 0.000 claims abstract description 6
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229920001195 polyisoprene Polymers 0.000 claims abstract description 6
- 239000011347 resin Substances 0.000 claims abstract description 6
- 229920005989 resin Polymers 0.000 claims abstract description 6
- 229920002379 silicone rubber Polymers 0.000 claims abstract description 6
- 239000004945 silicone rubber Substances 0.000 claims abstract description 6
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 claims abstract description 6
- 125000003011 styrenyl group Chemical class [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 claims abstract description 6
- 229920002725 thermoplastic elastomer Polymers 0.000 claims abstract description 6
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 claims abstract description 6
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000011787 zinc oxide Substances 0.000 claims abstract description 6
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- 230000005855 radiation Effects 0.000 claims description 6
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 3
- 239000011609 ammonium molybdate Substances 0.000 claims description 3
- 235000018660 ammonium molybdate Nutrition 0.000 claims description 3
- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 claims description 3
- 229940010552 ammonium molybdate Drugs 0.000 claims description 3
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- 239000008367 deionised water Substances 0.000 claims description 3
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- 238000010894 electron beam technology Methods 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
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- 230000007935 neutral effect Effects 0.000 claims description 3
- 239000012286 potassium permanganate Substances 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 239000011701 zinc Substances 0.000 claims description 3
- 229910052725 zinc Inorganic materials 0.000 claims description 3
- 239000007789 gas Substances 0.000 abstract description 2
- 239000002341 toxic gas Substances 0.000 abstract description 2
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 abstract 1
- 229920001935 styrene-ethylene-butadiene-styrene Polymers 0.000 abstract 1
- 235000012254 magnesium hydroxide Nutrition 0.000 description 7
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
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- 230000015572 biosynthetic process Effects 0.000 description 1
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- 238000005516 engineering process Methods 0.000 description 1
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- 229910010272 inorganic material Inorganic materials 0.000 description 1
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- 229920000098 polyolefin Polymers 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
Abstract
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CN201210435498.5A CN102977610B (zh) | 2012-11-05 | 2012-11-05 | 一种机车车辆用交联低烟无卤阻燃电缆料及其制备方法 |
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CN102977610A CN102977610A (zh) | 2013-03-20 |
CN102977610B true CN102977610B (zh) | 2016-03-30 |
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Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
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CN103333504B (zh) * | 2013-07-03 | 2015-08-19 | 贵州天虹志远电线电缆有限公司 | 硅橡胶电力电缆绝缘层及护套材料 |
CN103524820B (zh) * | 2013-09-30 | 2016-04-13 | 芜湖航天特种电缆厂 | 一种柔软型无卤阻燃电缆料及其制备方法 |
CN103525096B (zh) * | 2013-09-30 | 2016-01-20 | 安徽明都电力线缆有限公司 | 一种改性纳米碳的甲基乙烯基硅橡胶电缆护套料及其制备方法 |
CN103554922A (zh) * | 2013-10-25 | 2014-02-05 | 安徽文峰电子科技集团有限公司 | 一种耐温防潮绝缘甲基乙烯基硅橡胶电缆料 |
CN103756108A (zh) * | 2013-12-10 | 2014-04-30 | 芜湖佳诚电子科技有限公司 | 一种防开裂韧性聚乙烯电缆料及其制备方法 |
CN104072999A (zh) * | 2014-07-15 | 2014-10-01 | 安徽国电电缆集团有限公司 | 一种抗电磁干扰型控制电缆料及其制备方法 |
CN104086997B (zh) * | 2014-07-25 | 2016-11-02 | 广西众昌树脂有限公司 | 阻燃导电橡胶 |
CN104277461A (zh) * | 2014-10-27 | 2015-01-14 | 安徽锐视光电技术有限公司 | 一种色选机用抗龟裂合成橡胶及其制备方法 |
CN104371155A (zh) * | 2014-10-30 | 2015-02-25 | 安徽电信器材贸易工业有限责任公司 | 一种抗热抗老化电缆料及其制备方法 |
CN105037840A (zh) * | 2015-06-23 | 2015-11-11 | 中山市鸿程科研技术服务有限公司 | 一种抗热耐水电缆料及其制备方法 |
CN106280477A (zh) * | 2016-09-20 | 2017-01-04 | 苏州直角新材料有限公司 | 一种阻燃高强度纳米硅橡胶及其制备方法 |
WO2018119617A1 (zh) * | 2016-12-27 | 2018-07-05 | 辛范范 | 电器用屏蔽材料 |
CN110491594A (zh) * | 2019-08-30 | 2019-11-22 | 安徽电缆股份有限公司 | 一种交联聚乙烯绝缘阻燃防水防紫外线电力电缆 |
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CN102746546A (zh) * | 2012-06-15 | 2012-10-24 | 安徽华通电缆集团有限公司 | 一种无卤环保型风力发电用电力电缆料及其制备方法 |
CN102746671A (zh) * | 2012-06-15 | 2012-10-24 | 安徽华通电缆集团有限公司 | 一种耐环境开裂低温补偿电缆料及其制备方法 |
CN102746672A (zh) * | 2012-06-15 | 2012-10-24 | 安徽华通电缆集团有限公司 | 一种硅橡胶绝缘电缆料及其制备方法 |
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CN102746546A (zh) * | 2012-06-15 | 2012-10-24 | 安徽华通电缆集团有限公司 | 一种无卤环保型风力发电用电力电缆料及其制备方法 |
CN102746671A (zh) * | 2012-06-15 | 2012-10-24 | 安徽华通电缆集团有限公司 | 一种耐环境开裂低温补偿电缆料及其制备方法 |
CN102746672A (zh) * | 2012-06-15 | 2012-10-24 | 安徽华通电缆集团有限公司 | 一种硅橡胶绝缘电缆料及其制备方法 |
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Inventor after: Li Kui Inventor after: Zhang Yingqian Inventor before: Jiang Rui |
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Address after: 210 000 10 buildings, 103 Mufu West Road, Gulou District, Nanjing City, Jiangsu Province Co-patentee after: Zhang Yingqian Patentee after: Li Kui Address before: 232200 Qin Yung Team of Mayong Village, Zhangli Township, Shouxian County, Lu'an City, Anhui Province Co-patentee before: Zhang Yingqian Patentee before: Li Kui |
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Effective date of registration: 20190918 Address after: 233090 No. 10, 32 blocks, Guangcai Dachang 8 District, Bengbu City, Anhui Province Patentee after: Bengbu Shangwei Intellectual Property Operations Co., Ltd. Address before: 210 000 10 blocks, 103 Mufu West Road, Gulou District, Nanjing City, Jiangsu Province Co-patentee before: Zhang Ying Qian Patentee before: Li Kui |
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