CN102977465A - 一种辐照交联阻燃电缆料及其制备方法 - Google Patents
一种辐照交联阻燃电缆料及其制备方法 Download PDFInfo
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- CN102977465A CN102977465A CN2012104353802A CN201210435380A CN102977465A CN 102977465 A CN102977465 A CN 102977465A CN 2012104353802 A CN2012104353802 A CN 2012104353802A CN 201210435380 A CN201210435380 A CN 201210435380A CN 102977465 A CN102977465 A CN 102977465A
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- 239000000463 material Substances 0.000 title claims abstract description 28
- 239000003063 flame retardant Substances 0.000 title claims abstract description 17
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 16
- 238000004132 cross linking Methods 0.000 title claims abstract description 16
- 238000002360 preparation method Methods 0.000 title claims description 7
- 239000002994 raw material Substances 0.000 claims abstract description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 12
- ZFOZVQLOBQUTQQ-UHFFFAOYSA-N Tributyl citrate Chemical compound CCCCOC(=O)CC(O)(C(=O)OCCCC)CC(=O)OCCCC ZFOZVQLOBQUTQQ-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229920001577 copolymer Polymers 0.000 claims abstract description 8
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims abstract description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000006087 Silane Coupling Agent Substances 0.000 claims abstract description 6
- 235000021355 Stearic acid Nutrition 0.000 claims abstract description 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000000395 magnesium oxide Substances 0.000 claims abstract description 6
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract description 6
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims abstract description 6
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims abstract description 6
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000008117 stearic acid Substances 0.000 claims abstract description 6
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 6
- 239000011593 sulfur Substances 0.000 claims abstract description 6
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 claims abstract description 6
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Inorganic materials O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000004709 Chlorinated polyethylene Substances 0.000 claims abstract description 3
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000004927 clay Substances 0.000 claims description 17
- 238000012986 modification Methods 0.000 claims description 8
- 230000004048 modification Effects 0.000 claims description 8
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 6
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 6
- 239000008367 deionised water Substances 0.000 claims description 6
- 229910021641 deionized water Inorganic materials 0.000 claims description 6
- 239000006185 dispersion Substances 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- 230000005855 radiation Effects 0.000 claims description 6
- 239000006242 Semi-Reinforcing Furnace Substances 0.000 claims description 5
- 239000011609 ammonium molybdate Substances 0.000 claims description 5
- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 claims description 5
- 229940010552 ammonium molybdate Drugs 0.000 claims description 5
- 235000018660 ammonium molybdate Nutrition 0.000 claims description 5
- 230000003712 anti-aging effect Effects 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 229920001971 elastomer Polymers 0.000 claims description 5
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 claims description 5
- 239000005060 rubber Substances 0.000 claims description 5
- 229920001897 terpolymer Polymers 0.000 claims description 5
- 238000004073 vulcanization Methods 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 3
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 3
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 3
- 238000010894 electron beam technology Methods 0.000 claims description 3
- 238000002386 leaching Methods 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 230000007935 neutral effect Effects 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- 238000005303 weighing Methods 0.000 claims description 3
- 239000011787 zinc oxide Substances 0.000 claims description 3
- 239000000779 smoke Substances 0.000 abstract description 4
- 230000032683 aging Effects 0.000 abstract description 3
- 239000007789 gas Substances 0.000 abstract description 2
- 239000002341 toxic gas Substances 0.000 abstract description 2
- BZQKBFHEWDPQHD-UHFFFAOYSA-N 1,2,3,4,5-pentabromo-6-[2-(2,3,4,5,6-pentabromophenyl)ethyl]benzene Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1CCC1=C(Br)C(Br)=C(Br)C(Br)=C1Br BZQKBFHEWDPQHD-UHFFFAOYSA-N 0.000 abstract 1
- SSZWWUDQMAHNAQ-UHFFFAOYSA-N 3-chloropropane-1,2-diol Chemical compound OCC(O)CCl SSZWWUDQMAHNAQ-UHFFFAOYSA-N 0.000 abstract 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 1
- 229920002943 EPDM rubber Polymers 0.000 abstract 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 abstract 1
- XUGISPSHIFXEHZ-GPJXBBLFSA-N [(3r,8s,9s,10r,13r,14s,17r)-10,13-dimethyl-17-[(2r)-6-methylheptan-2-yl]-2,3,4,7,8,9,11,12,14,15,16,17-dodecahydro-1h-cyclopenta[a]phenanthren-3-yl] acetate Chemical compound C1C=C2C[C@H](OC(C)=O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 XUGISPSHIFXEHZ-GPJXBBLFSA-N 0.000 abstract 1
- 238000005299 abrasion Methods 0.000 abstract 1
- 239000003963 antioxidant agent Substances 0.000 abstract 1
- 230000003078 antioxidant effect Effects 0.000 abstract 1
- 238000002485 combustion reaction Methods 0.000 abstract 1
- 239000006232 furnace black Substances 0.000 abstract 1
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 241000256602 Isoptera Species 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Organic Insulating Materials (AREA)
- Insulated Conductors (AREA)
Abstract
Description
Claims (3)
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CN102977465A true CN102977465A (zh) | 2013-03-20 |
CN102977465B CN102977465B (zh) | 2016-05-18 |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103351535A (zh) * | 2013-06-25 | 2013-10-16 | 绿宝电缆(集团)有限公司 | 一种增韧耐寒橡胶电缆料 |
CN106543578A (zh) * | 2016-11-25 | 2017-03-29 | 佛山慧创正元新材料科技有限公司 | 一种阻燃高强度的聚苯乙烯材料及其制造方法 |
CN109456542A (zh) * | 2018-09-29 | 2019-03-12 | 重庆鹏博电器有限公司 | 一种橡胶绝缘材料 |
CN112341722A (zh) * | 2020-11-26 | 2021-02-09 | 江苏达胜高聚物股份有限公司 | 一种高阻燃辐照交联材料及其制备方法和应用 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101386693A (zh) * | 2008-10-22 | 2009-03-18 | 深圳长园电子材料有限公司 | 一种辐射交联阻燃聚烯烃热收缩材料及其制备方法 |
CN102516675A (zh) * | 2011-11-21 | 2012-06-27 | 安徽蓝德集团股份有限公司 | 一种矿用电缆橡皮护套胶 |
CN102746585A (zh) * | 2012-06-12 | 2012-10-24 | 安徽华海特种电缆集团有限公司 | 一种聚丙烯绝缘电缆料及其制备方法 |
-
2012
- 2012-11-05 CN CN201210435380.2A patent/CN102977465B/zh active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101386693A (zh) * | 2008-10-22 | 2009-03-18 | 深圳长园电子材料有限公司 | 一种辐射交联阻燃聚烯烃热收缩材料及其制备方法 |
CN102516675A (zh) * | 2011-11-21 | 2012-06-27 | 安徽蓝德集团股份有限公司 | 一种矿用电缆橡皮护套胶 |
CN102746585A (zh) * | 2012-06-12 | 2012-10-24 | 安徽华海特种电缆集团有限公司 | 一种聚丙烯绝缘电缆料及其制备方法 |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103351535A (zh) * | 2013-06-25 | 2013-10-16 | 绿宝电缆(集团)有限公司 | 一种增韧耐寒橡胶电缆料 |
CN103351535B (zh) * | 2013-06-25 | 2016-03-02 | 绿宝电缆(集团)有限公司 | 一种增韧耐寒橡胶电缆料 |
CN106543578A (zh) * | 2016-11-25 | 2017-03-29 | 佛山慧创正元新材料科技有限公司 | 一种阻燃高强度的聚苯乙烯材料及其制造方法 |
CN109456542A (zh) * | 2018-09-29 | 2019-03-12 | 重庆鹏博电器有限公司 | 一种橡胶绝缘材料 |
CN112341722A (zh) * | 2020-11-26 | 2021-02-09 | 江苏达胜高聚物股份有限公司 | 一种高阻燃辐照交联材料及其制备方法和应用 |
CN112341722B (zh) * | 2020-11-26 | 2023-01-17 | 江苏达胜高聚物股份有限公司 | 一种高阻燃辐照交联材料及其制备方法和应用 |
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CN102977465B (zh) | 2016-05-18 |
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Inventor after: Yu He Inventor before: Jiang Rui |
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Effective date of registration: 20170930 Address after: 221127 Jiangsu province Xuzhou city Copper Mt. District Copper Mt. County single town government office dormitory 285 Patentee after: Yu He Address before: 244121 Tongling Jinqiao Industrial Park, Tongling, Anhui Patentee before: ANHUI JINQIAO CABLE Co.,Ltd. |
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Address after: 210 000 No. 88 Mufu West Road, Gulou District, Nanjing, Jiangsu Province Patentee after: Yu He Address before: 221127 No. 285 Dormitory of Shanji Town, Tongshan County, Xuzhou City, Jiangsu Province Patentee before: Yu He |
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Effective date of registration: 20221205 Address after: 523795 Zone 1, No. 8, Changhe Road, Songmushan Village, Dalang Town, Dongguan City, Guangdong Province Patentee after: Dongguan Yuelai Photoelectric Technology Co.,Ltd. Address before: 233090 No.10, building 32, District 8, Guangcai market, Bengbu City, Anhui Province Patentee before: Bengbu Shangwei Intellectual Property Operations Co.,Ltd. |
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