CN102827473A - 原位法制备超韧尼龙6合金及其方法 - Google Patents
原位法制备超韧尼龙6合金及其方法 Download PDFInfo
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- CN102827473A CN102827473A CN2012102831481A CN201210283148A CN102827473A CN 102827473 A CN102827473 A CN 102827473A CN 2012102831481 A CN2012102831481 A CN 2012102831481A CN 201210283148 A CN201210283148 A CN 201210283148A CN 102827473 A CN102827473 A CN 102827473A
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- nylon
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- 229920002292 Nylon 6 Polymers 0.000 title claims abstract description 76
- 239000000956 alloy Substances 0.000 title claims abstract description 49
- 229910045601 alloy Inorganic materials 0.000 title claims abstract description 49
- 238000000034 method Methods 0.000 title claims abstract description 24
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- 238000011065 in-situ storage Methods 0.000 title claims abstract description 11
- 230000008569 process Effects 0.000 title abstract description 4
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 claims abstract description 26
- 239000003999 initiator Substances 0.000 claims abstract description 21
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 20
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims abstract description 20
- 229920001577 copolymer Polymers 0.000 claims abstract description 19
- 239000002994 raw material Substances 0.000 claims abstract description 13
- 238000004519 manufacturing process Methods 0.000 claims abstract description 7
- 239000004677 Nylon Substances 0.000 claims description 21
- 229920001778 nylon Polymers 0.000 claims description 21
- 206010013786 Dry skin Diseases 0.000 claims description 12
- 238000001035 drying Methods 0.000 claims description 12
- 238000012545 processing Methods 0.000 claims description 9
- 238000005469 granulation Methods 0.000 claims description 6
- 230000003179 granulation Effects 0.000 claims description 6
- 125000003003 spiro group Chemical group 0.000 claims description 6
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 4
- 239000000178 monomer Substances 0.000 claims description 4
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 2
- 125000002252 acyl group Chemical group 0.000 claims description 2
- -1 peroxy dicarbonates compound Chemical class 0.000 claims description 2
- 238000010521 absorption reaction Methods 0.000 abstract description 6
- 230000008901 benefit Effects 0.000 abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 4
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 abstract description 3
- 239000004566 building material Substances 0.000 abstract description 2
- 230000005611 electricity Effects 0.000 abstract 1
- 238000004806 packaging method and process Methods 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 230000007797 corrosion Effects 0.000 description 4
- 238000005260 corrosion Methods 0.000 description 4
- 238000010586 diagram Methods 0.000 description 4
- 229920006351 engineering plastic Polymers 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 229920000098 polyolefin Polymers 0.000 description 4
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 4
- 238000001291 vacuum drying Methods 0.000 description 4
- 229920002302 Nylon 6,6 Polymers 0.000 description 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 230000007246 mechanism Effects 0.000 description 3
- 230000004224 protection Effects 0.000 description 3
- YEECOJZAMZEUBB-UHFFFAOYSA-N 2,2,3,3,6,6,7,7-octamethyloctane Chemical compound CC(C)(C)C(C)(C)CCC(C)(C)C(C)(C)C YEECOJZAMZEUBB-UHFFFAOYSA-N 0.000 description 2
- 238000004364 calculation method Methods 0.000 description 2
- 125000005518 carboxamido group Chemical group 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- LVHBHZANLOWSRM-UHFFFAOYSA-N itaconic acid Chemical compound OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 150000002924 oxiranes Chemical group 0.000 description 2
- 239000002574 poison Substances 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- 229920006124 polyolefin elastomer Polymers 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 238000005303 weighing Methods 0.000 description 2
- 206010015946 Eye irritation Diseases 0.000 description 1
- 229920000305 Nylon 6,10 Polymers 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- OUUQCZGPVNCOIJ-UHFFFAOYSA-M Superoxide Chemical compound [O-][O] OUUQCZGPVNCOIJ-UHFFFAOYSA-M 0.000 description 1
- 230000006750 UV protection Effects 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000008064 anhydrides Chemical group 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 238000011066 ex-situ storage Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 231100000013 eye irritation Toxicity 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 230000005501 phase interface Effects 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 238000010094 polymer processing Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 238000002910 structure generation Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 229920002725 thermoplastic elastomer Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 238000004073 vulcanization Methods 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/50—Details of extruders
- B29C48/505—Screws
- B29C48/625—Screws characterised by the ratio of the threaded length of the screw to its outside diameter [L/D ratio]
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/395—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
- B29C48/40—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using two or more parallel screws or at least two parallel non-intermeshing screws, e.g. twin screw extruders
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/9258—Velocity
- B29C2948/9259—Angular velocity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92704—Temperature
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92819—Location or phase of control
- B29C2948/92857—Extrusion unit
- B29C2948/92876—Feeding, melting, plasticising or pumping zones, e.g. the melt itself
- B29C2948/92885—Screw or gear
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92819—Location or phase of control
- B29C2948/92857—Extrusion unit
- B29C2948/92876—Feeding, melting, plasticising or pumping zones, e.g. the melt itself
- B29C2948/92895—Barrel or housing
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
Claims (7)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201210283148.1A CN102827473B (zh) | 2012-08-09 | 2012-08-09 | 原位法制备超韧尼龙6合金及其方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201210283148.1A CN102827473B (zh) | 2012-08-09 | 2012-08-09 | 原位法制备超韧尼龙6合金及其方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN102827473A true CN102827473A (zh) | 2012-12-19 |
CN102827473B CN102827473B (zh) | 2014-01-15 |
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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CN201210283148.1A Active CN102827473B (zh) | 2012-08-09 | 2012-08-09 | 原位法制备超韧尼龙6合金及其方法 |
Country Status (1)
Country | Link |
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CN (1) | CN102827473B (zh) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103073880A (zh) * | 2012-12-25 | 2013-05-01 | 广州鹿山新材料股份有限公司 | 一种增韧尼龙复合物及其制备方法 |
CN105017523A (zh) * | 2015-07-29 | 2015-11-04 | 苏州荣昌复合材料有限公司 | 一种磁性吸附尼龙材料 |
CN109265720A (zh) * | 2018-09-11 | 2019-01-25 | 浙江奔富新能源股份有限公司 | 耐氢氟酸尼龙膜及其制备方法 |
CN117050513A (zh) * | 2022-06-20 | 2023-11-14 | 台州俪盛塑料有限公司 | 一种可吹塑专用超韧尼龙 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1286717A (zh) * | 1997-11-19 | 2001-03-07 | 波里阿利斯有限公司 | 基于聚烯烃和聚酰胺树脂的聚合物共混物 |
CN1935900A (zh) * | 2006-10-20 | 2007-03-28 | 邓凯桓 | 一种铝合金型材隔热条专用增强增韧尼龙66复合材料及其制备方法 |
CN102108205A (zh) * | 2009-12-25 | 2011-06-29 | 上海普利特复合材料股份有限公司 | 低气味增韧pa6材料及其制备方法 |
-
2012
- 2012-08-09 CN CN201210283148.1A patent/CN102827473B/zh active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1286717A (zh) * | 1997-11-19 | 2001-03-07 | 波里阿利斯有限公司 | 基于聚烯烃和聚酰胺树脂的聚合物共混物 |
CN1935900A (zh) * | 2006-10-20 | 2007-03-28 | 邓凯桓 | 一种铝合金型材隔热条专用增强增韧尼龙66复合材料及其制备方法 |
CN102108205A (zh) * | 2009-12-25 | 2011-06-29 | 上海普利特复合材料股份有限公司 | 低气味增韧pa6材料及其制备方法 |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103073880A (zh) * | 2012-12-25 | 2013-05-01 | 广州鹿山新材料股份有限公司 | 一种增韧尼龙复合物及其制备方法 |
CN105017523A (zh) * | 2015-07-29 | 2015-11-04 | 苏州荣昌复合材料有限公司 | 一种磁性吸附尼龙材料 |
CN109265720A (zh) * | 2018-09-11 | 2019-01-25 | 浙江奔富新能源股份有限公司 | 耐氢氟酸尼龙膜及其制备方法 |
CN117050513A (zh) * | 2022-06-20 | 2023-11-14 | 台州俪盛塑料有限公司 | 一种可吹塑专用超韧尼龙 |
Also Published As
Publication number | Publication date |
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CN102827473B (zh) | 2014-01-15 |
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C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Super-tough nylon 6 alloy prepared by using in-situ process and preparation method thereof Effective date of registration: 20140924 Granted publication date: 20140115 Pledgee: Guangdong Development Bank Limited by Share Ltd. Dongguan Humen branch Pledgor: DONGGUAN SINOPLAST INDUSTRIAL Ltd. Registration number: 2014990000803 |
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Date of cancellation: 20151130 Granted publication date: 20140115 Pledgee: Guangdong Development Bank Limited by Share Ltd. Dongguan Humen branch Pledgor: DONGGUAN SINOPLAST INDUSTRIAL Ltd. Registration number: 2014990000803 |
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Address after: 355 No. 523850 Guangdong city in Dongguan Province town of Changan Wusha Cun BBK Avenue Patentee after: GUANGDONG SINOPLAST ADVANCED MATERIAL CO.,LTD. Address before: 355 No. 523850 Guangdong city in Dongguan Province town of Changan Wusha Cun BBK Avenue Patentee before: DONGGUAN SINOPLAST INDUSTRIAL Ltd. |
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Address after: 523850 Baibugao Avenue, Wushajiang, Chang'an Town, Dongguan City, Guangdong Province, 355 Patentee after: Guangdong Sinoplast New Materials Co.,Ltd. Address before: 523850 Baibugao Avenue, Wushajiang, Chang'an Town, Dongguan City, Guangdong Province, 355 Patentee before: GUANGDONG SINOPLAST ADVANCED MATERIAL CO.,LTD. |
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