CN102701878A - Pomacea canaliculata molluscicide fertilizer mixture and production method thereof - Google Patents
Pomacea canaliculata molluscicide fertilizer mixture and production method thereof Download PDFInfo
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Abstract
The invention relates to a pomacea canaliculata molluscicide fertilizer mixture and a production method thereof. The pomacea canaliculata molluscicide fertilizer mixture is produced by avermectin added with an appropriate amount of additive and carrier fertilizer, wherein the weight content of the avermectin is 0.01% to 0.2%, the weight content of the additive is 1% to 30%, and the balance is the carrier fertilizer. With the pomacea canaliculata molluscicide fertilizer mixture, the effect of preventing and controlling pomacea canaliculata harmful to crops is good, the duration is long, the mixture is safe to the crops, toxicity and residues are low, the use is simple and convenient, and the impact on the environment is small.
Description
Technical field
The present invention relates to a kind of spiral shell medicament, particularly Fushou spiral shell of harming the crops killed and kill spiral shell medicament-fertilizer mixture and working method thereof, be mainly used in the spiral shell evil of preventing and kill off farm crop.
Background technology
Fushou spiral shell Pomacea canaliculata, (Golden Apple snail) is a kind of exotic invasive mollusk of serious harm China Rice Production.It originates in South America Amazon River basin, after having a mind to introduce Guangdong in 1981, grows surely in a plurality of provinces and regions of China, and becomes the important harmful organism of farm crop such as paddy rice.In recent years, in Guangdong, provinces and regions such as Guangxi, Fujian, Yunnan, Zhejiang, Shanghai, Jiangsu, Fushou spiral shell causing harm on paddy rice, be on the rise; Its zone of causing harm also is the gesture of continuous expansion, and national paddy rice injured area surpassed 4,500,000 mu in 2006, and wherein Guangxi serious injured area of late rice in 2006 reaches 2,500,000 mu; The paddy rice strain rate of being injured is generally 7%～15%; High reaches 64%, and the part reaches more than 90%, forms major disaster.Particularly along with the continuous expansion of rice seedling throwing and live area, Fushou spiral shell is more outstanding to causing harm of paddy rice.Fushou spiral shell except that the paddy rice of causing harm, also seriously cause harm various waterplant, Lu Shengcao class and gourd, fruit and vegetable etc.; Fushou spiral shell also is the important intermediate host who causes human eosinophilic meningoencephalitis's angiostrongylus cantonensis, and the incident of group infection angiostrongyliasis cantonensis constantly appearred causing because of edible Fushou spiral shell in China in recent years.Therefore, Fushou spiral shell is to the Rice Production and the grain security of China, constituted serious threat to people ' s health, and present stage, Fushou spiral shell is listed in one of 16 kinds " alien species that harm is maximum " by State Environmental Protection Administration.
During traditional agriculture was produced, the control of rice field Fushou spiral shell was to be main with chemical prevention, mainly contains niclosamide ethanolamine salt, the methaldehyde, Witophen N and triphen vinegar tin granula (TPTA) etc.But its effect respectively has deficiency: niclosamide ethanolamine salt (Niclosamide ethanolamine); It is a kind of invertebrate poison with stomach poison function; Spiral shell ovum, schistosomicide etc. there are stronger killing action, low to the person poultry toxicity, but that it is degraded in water is very fast; Be prone to by the adsorption by soil solid failure, hold and imitate short deficiency; The methaldehyde is main with food calling, mostly be applied on the vegetable crop, as it is higher to recommend to the rice terrace cost; Though Witophen N has good molluscicidal effect to the rice field Fushou spiral shell, it has restraining effect to the rice seedling seedling, and environment is had bigger influence and by national Ministry of Agriculture forbidding.
So, how the Fushou spiral shell that harms the crops is killed, can not destroy ecotope again, remain a difficult problem that needs solution in the present agricultural sciences.
Summary of the invention
The purpose of this invention is to provide a kind of safety, efficient that has, low toxicity, low residue, that can prevent and treat the Fushou spiral shell that harms the crops kills spiral shell medicament-fertilizer mixture product.
The inventor is in secular agriculture prodn, and finding that some low toxicity sterilant and agricultural chemicals have Fushou spiral shell suppresses and killing action, so, through screening relatively, found the molluscacide of effective Fushou spiral shell, Here it is Avrmectin.
Avrmectin (Abamectin), molecular formula C48H72O14 (B1a) C47H70O14 (B1b).
Avrmectin is a kind of antibiotics insecticidal/acaricidal agent of efficient, wide spectrum, is a kind of macrolide disaccharide compounds.It is an isolating natural product from soil microorganisms, insect and mite class is had tag with stomach poison function and faint fumigation action is arranged, no systemic action.But it has very strong osmosis to blade, can kill subepidermal insect, and the lasting period is long.What its mechanism of action was different with general sterilant is that it disturbs nervous physiology movable; Stimulate and discharge the r-propalanine; And the r-propalanine has restraining effect to arthropodan nerve conduction; The mite class becomes, if mite and insect and larva with paralysis symptom promptly appears after medicament contacts, outage is not got food, death after 2-4 days.Because of not causing that insect dewaters rapidly, so its lethal effect is slower, though predatism and parasite there are direct killing effect, but because of plant surface is residual few, therefore little to the damage of beneficial insect.Its stability: usually these article are stablized under the storage requirement, and its aqueous solution hydrolysis can not take place when PH5-9 and 25 ℃.Its toxicity: rat oral LD50 is 1470mg/kg.No teratogenesis, carcinogenic, mutagenesis.
At present, do not see the medicine of Avrmectin is processed extremely spiral shell medicine preparation and killed the fertile preparation of spiral shell medicine, be applied to the report of the technology that farm crop control Fushou spiral shell causes harm.
Technical solution of the present invention is:
Of the present invention to kill the fertile mixed preparation of spiral shell medicine be to be effective constituent with the Avrmectin, with carrier fertilizer, processes the fertile mixed preparation of spiral shell medicine extremely after other carrier mixes, and is used for farm crop and prevents and kill off Fushou spiral shell and cause harm, and fertilization effect is arranged simultaneously, has the effect of saving of work and time.
Described carrier fertilizer is the required fertilizer of farm crop, comprises mineral manure, organic fertilizer and their mixture;
The fertile mixed preparation of spiral shell medicine that kills of the present invention, its effective constituent is to make after the former medicine of Avrmectin perhaps adds an amount of auxiliary agent and carrier fertilizer, its parts by weight are:
Avrmectin 0.01%-0.2%;
Auxiliary agent 1%-30%;
Carrier fertilizer surplus;
The said effective constituent Avrmectin that kills in the fertile mixed preparation of spiral shell medicine can be the former medicine of Avrmectin (or ointment), or abamectin fermented thing;
Described carrier fertilizer is organic fertilizer or mineral manure, or the mixture of organic fertilizer, mineral manure;
Described auxiliary agent is dispersion agent and stopping composition.
Above-described dispersion agent and stopping composition are dispersion agent and solid dispersion; Comprise sodium lauryl sulphate; X 2073, calcium lignin sulphonate; Bitter edible plant sulfonic acid and formaldehyde (NN0), alkyl polyoxyethylene ether, draw back powder, lime carbonate, dry powder, kaolin powder, clay powder, zeyssatite and potter's clay, perhaps wherein one or more the mixture of above-mentioned substance at castor oil polyoxyethylene ether, alkylphenol polyethylene oxide ether, water, farming breast.
Above-described mineral manure is to comprise the chemical fertilizer that contains nitrogenous fertilizer, phosphate fertilizer and potash fertilizer; Comprise vitriol commonly used, nitrate salt, carbonate, chlorate and phosphate fertilizer; For example ammonium sulfate, vitriolate of tartar, bicarbonate of ammonia, salt of wormwood, an ammonium nitrate, saltpetre, ammonium chloride, Repone K, ammonium phosphate, potassium primary phosphate, fused(calcium magnesium)phosphate etc., perhaps wherein one or more the mixture of above-mentioned substance.
Also comprise water miscible trace elements such as containing copper, iron, zinc, manganese, boron in the above-described fertilizer, for example copper sulfate, ferrous sulfate, zinc sulfate, zinc nitrate, manganous sulfate, potassium tetraborate, borax etc.
Above-described organic fertilizer is the fertilizer that can directly supply with the necessary nutritive element of crop growth and be rich in organic substance, the farm manure that comprise urea, green manure, tea young slag, peanut press pulp, husk, manioc waste, filter mud of sugar refinery, weathered coal, fish meal, bone meal, plant straw powder, livestock and poultry manure, barnyard manure, compost, make compost, biogas manure and waste forms through microbiological degradation or fermentation.
Above-described Fushou spiral shell kills spiral shell medicament-fertilizer mixture working method:
1) with water is solvent, the former medicine of Avrmectin or ointment, fermented product and auxiliary agent are prepared into the agricultural-chemical suspension mixture;
2) the agricultural-chemical suspension mixture is sprayed coating in carrier fertilizer, mix, process particulate state or powdery.
The method of use that above-described Fushou spiral shell kills spiral shell medicament-fertilizer mixture product is to weed when harrowing a field in paddy rice, Fushou spiral shell is killed spiral shell medicine fertilizer evenly be spread on the land for growing field crops, and amount of application is 5-150 kilogram/mu.
Advantage of the present invention:
1. the first Application Avrmectin is that main effective constituent is prevented and treated the rice field Fushou spiral shell.
2. to rice seedling safety, under the triple prerequisite of recommending consumption, still fool proof to paddy rice.
3. it is effective to use this medicament to prevent and kill off Fushou spiral shell, efficacy stability, and the lasting period is long.
4. use this Avrmectin to kill the fertile mixed preparation of spiral shell medicine in the rice seedling phase, have the double effects of spiral shell fertilising extremely, reach the purpose of saving of work and time.
In order to understand the practical application effect of invention better, contriver in 2011 uses and of the present inventionly kills the agent of spiral shell agricultural chemicals list and carried out drug effect test of field zone to the Fushou spiral shell of rice terrace:
Test medicine: 0.05% Avrmectin medicine is fertile, forms according to following examples 3.
Contrast medicament: 50% niclosamide ethanolamine salt wettable powder
Controlling object: paddy rice Fushou spiral shell
0.05% Avrmectin medicine is fertile
Field control test of pesticide effectiveness cartogram to the rice terrace Fushou spiral shell
Test-results shows: 10 kilograms, 20 kilograms, 30 kilograms control effect to the rice terrace Fushou spiral shell of 0.05% Avrmectin medicine fertile mu amount of application improve along with the increase of dosage, and 1 day average preventive effect is respectively 85.10%, 95.35% behind the medicine; 100%, 7 days average preventive effect is respectively 96.35%, 100% behind the medicine; 100%, 14 days average preventive effect is respectively 93.51%, 100% behind the medicine; 100%, 21 days average preventive effect is respectively 91.80%, 99.00% behind the medicine; 100.00%, all be superior to contrasting the preventive effect of medicament 50% niclosamide ethanolamine salt wettable powder.Finding in the process of the test has the poisoning phenomenon and non-rake is marked the detrimentally affect of growing, and final increasing production of rice rate is bigger, and the highest raising the output reaches 35.7%, and minimum raising the output reaches 23.8%, and contrast medicament on year-on-year basis and surpass 15% stimulation ratio, the fertile combination of medicine, synergism is obvious.
Embodiment
In order to make the object of the invention, technical scheme clearer, below in conjunction with embodiment, the present invention is described further, specific embodiment described herein is only in order to explaining the present invention, and is not used in qualification the present invention.
Embodiment 1
The spiral shell medicament-fertilizer mixture that kills of 0.2% Avrmectin Fushou spiral shell is made and method of use
100% Avrmectin, 2 Kg
Tensio-active agent: castor oil polyoxyethylene ether 0.2Kg
Tensio-active agent: No. 500 0.2Kg of farming breast
Diffusant: X 2073 0.2Kg
Water 2Kg
Nitrogenous fertilizer: urea 950 Kg
Zeyssatite complements to 1000Kg
At first, Avrmectin, tensio-active agent, diffusant and suitable quantity of water are prepared into stable suspension mixture;
At last, the Avrmectin mixture that suspends is sprayed coating equably to the nitrogenous fertilizer carrier, mix, promptly get product.
The product method of use: paddy rice weed harrow a field after, directly be spread on the land for growing field crops, the preparation amount of application is 5 kilograms/mu.
Embodiment 2
The spiral shell medicament-fertilizer mixture that kills of 0.1% Avrmectin Fushou spiral shell is made and method of use
10% Avrmectin ointment, 10 Kg
Tensio-active agent: castor oil polyoxyethylene ether 0.2Kg
Tensio-active agent: No. 500 0.3Kg of farming breast
Diffusant: X 2073 0.2Kg
Water 1Kg
Nitrogenous fertilizer: urea 500 Kg
Nitrogenous fertilizer: bicarbonate of ammonia 400 Kg
Potter's clay complements to 1000Kg
At first, Avrmectin, tensio-active agent, diffusant and suitable quantity of water are prepared into stable suspension mixture;
At last, the Avrmectin mixture that suspends is sprayed coating equably to the nitrogenous fertilizer carrier, mix, promptly get product.
The product method of use: paddy rice weed harrow a field after, directly be spread on the land for growing field crops, the preparation amount of application is 5 kilograms-10 kilograms/mu.
Embodiment 3
The spiral shell medicament-fertilizer mixture that kills of 0.05% Avrmectin Fushou spiral shell is made and method of use
10% Avrmectin ointment 5Kg
Tensio-active agent: castor oil polyoxyethylene ether 0.1Kg
Tensio-active agent: No. 500 0.2Kg of farming breast
Diffusant: X 2073 0.5Kg
Water 1Kg
Nitrogenous fertilizer: urea 200 Kg
Nitrogenous fertilizer: ammonium chloride 300 Kg
Potash fertilizer: Repone K 100 Kg
Nitrogen phosphorus fertilizer: monoammonium phosphate 50 Kg
Phosphate fertilizer: fused(calcium magnesium)phosphate 200 Kg
Trace element: zinc sulfate 7Kg
Stopping composition: kaolin complements to 1000 Kg
At first, Avrmectin, tensio-active agent, diffusant and suitable quantity of water are prepared into stable suspension mixture;
Secondly, be that nitrogenous fertilizer, phosphate fertilizer, potash fertilizer and trace element, stopping composition kaolin are mixed, make the carrier fertiliser granulates through granulation, oven dry;
At last, the Avrmectin mixture that suspends is sprayed coating equably to the carrier fertiliser granulates, mix, promptly get product.
The product method of use: paddy rice weed harrow a field after, will kill the fertile uniform particles of spiral shell medicine and be sprinkled into the land for growing field crops, the preparation amount of application is 10 kilograms-20 kilograms/mu.
Embodiment 4
The spiral shell medicament-fertilizer mixture that kills of 0.03% Avrmectin Fushou spiral shell is made and method of use
10% Avrmectin ointment, 3 Kg
Tensio-active agent: castor oil polyoxyethylene ether 0.2Kg
Tensio-active agent: No. 500 0.3Kg of farming breast
Diffusant: sodium lauryl sulphate 3 Kg
Water 2 Kg
Nitrogenous fertilizer: urea 250 Kg
Nitrogen phosphorus fertilizer: monoammonium phosphate 100 Kg
Phosphate fertilizer: fused(calcium magnesium)phosphate 50 Kg
Potash fertilizer: Repone K 50 Kg
Organic fertilizer: manioc waste, fish meal fermented product 500 Kg
Stopping composition: lime carbonate complements to 1000 Kg
At first, Avrmectin, tensio-active agent, diffusant and suitable quantity of water are prepared into stable suspension mixture;
Secondly, be that nitrogenous fertilizer, phosphate fertilizer, potash fertilizer and organic fertilizer are mixed, make carrier organic and inorganic fertilizer particle through granulation, oven dry;
At last, the Avrmectin mixture that suspends is sprayed coating equably to carrier organic and inorganic fertilizer fertiliser granulates, mix, promptly get product.
The product method of use: weed when harrowing a field in paddy rice, be spread on the land for growing field crops, the preparation amount of application is a 25-50kg/ mu.
Embodiment 5
The spiral shell medicament-fertilizer mixture that kills of 0.01% Avrmectin Fushou spiral shell is made and method of use
1% Avrmectin slag, 10 Kg
Diffusant: sodium lauryl sulphate 5 Kg
Diffusant: bitter edible plant sulfonic acid and formaldehyde 5 Kg
Nitrogenous fertilizer: bicarbonate of ammonia 500 Kg
Phosphate fertilizer: fused(calcium magnesium)phosphate 250 Kg
Trace element: iron vitriol 10Kg
Trace element: zinc sulfate 7Kg
Organic fertilizer: the rice bran fermented product complements to 1000 Kg
Above-mentioned avermectin slag, diffusant, organic fertilizer and micro-mixing are thrown in the whisking appliance, evenly processed the fertile mixed preparation of spiral shell medicine extremely through thorough mixing.
The product method of use: weed when harrowing a field in paddy rice, be spread on the land for growing field crops, the preparation amount of application is a 75-150kg/ mu.
Embodiment 6
The spiral shell medicament-fertilizer mixture that kills of 0.02% Avrmectin Fushou spiral shell is made and method of use
10% Avrmectin ointment, 2 Kg
Tensio-active agent: castor oil polyoxyethylene ether 0.2Kg
Tensio-active agent: No. 500 0.3Kg of farming breast
Diffusant: sodium lauryl sulphate 3 Kg
Water 2 Kg
Nitrogenous fertilizer: urea 250 Kg
Nitrogen phosphorus fertilizer: monoammonium phosphate 100 Kg
Phosphate fertilizer: fused(calcium magnesium)phosphate 50 Kg
Potash fertilizer: Repone K 50 Kg
Trace element: copper sulfate 2 Kg
Trace element: manganous sulfate 1Kg
Organic fertilizer: filter mud of sugar refinery, peanut press pulp fermented product 500 Kg
Stopping composition: lime carbonate complements to 1000 Kg
At first, Avrmectin, tensio-active agent, diffusant and suitable quantity of water are prepared into stable suspension mixture;
Secondly, be that nitrogenous fertilizer, phosphate fertilizer, potash fertilizer and organic fertilizer, trace element are mixed, make carrier organic and inorganic fertilizer particle through granulation, oven dry;
At last, the Avrmectin mixture that suspends is sprayed coating equably to carrier organic and inorganic fertilizer fertiliser granulates, mix, promptly get product.
The product method of use: weed when harrowing a field in paddy rice, be spread on the land for growing field crops, the preparation amount of application is a 25-50kg/ mu.
Embodiment 7
The spiral shell medicament-fertilizer mixture that kills of 0.06% Avrmectin Fushou spiral shell is made and method of use
10% Avrmectin ointment, 2 Kg
Tensio-active agent: castor oil polyoxyethylene ether 0.2Kg
Tensio-active agent: No. 500 0.3Kg of farming breast
Diffusant: sodium lauryl sulphate 3 Kg
Water 2 Kg
Nitrogenous fertilizer: urea 250 Kg
Phosphorus potash fertilizer: potassium primary phosphate 100 Kg
Calcareous fertilisers: fused(calcium magnesium)phosphate 50 Kg
Trace element: iron vitriol 50 Kg
Trace element: zinc sulfate 2 Kg
Trace element: sodium tetraborate 1Kg
Organic fertilizer: biogas mud, peanut press pulp fermented product 500 Kg
Stopping composition: lime carbonate complements to 1000 Kg
At first, Avrmectin, tensio-active agent, diffusant and suitable quantity of water are prepared into stable suspension mixture;
Secondly, be that nitrogenous fertilizer, phosphate fertilizer, potash fertilizer and organic fertilizer, trace element are mixed, make carrier organic and inorganic fertilizer particle through granulation, oven dry;
At last, the Avrmectin mixture that suspends is sprayed coating equably to carrier organic and inorganic fertilizer fertiliser granulates, mix, promptly get product.
The product method of use: weed when harrowing a field in paddy rice, be spread on the land for growing field crops, the preparation amount of application is a 25-50kg/ mu.
Claims (7)
1. a Fushou spiral shell kills the spiral shell medicament-fertilizer mixture, it is characterized in that: it is to make after adding an amount of auxiliary agent and carrier fertilizer by Avrmectin, wherein:
Avrmectin 0.01%-0.2%;
Auxiliary agent 1%-30%;
Carrier fertilizer surplus;
Said Avrmectin can be former medicine of Avrmectin or ointment, or abamectin fermented thing;
Described carrier fertilizer is organic fertilizer or mineral manure, or the mixture of organic fertilizer, mineral manure;
Described auxiliary agent is dispersion agent and stopping composition.
2. Fushou spiral shell according to claim 1 kills the spiral shell medicament-fertilizer mixture; It is characterized in that: described dispersion agent and stopping composition are liquid dispersant and solid dispersion; Comprise sodium lauryl sulphate; X 2073, calcium lignin sulphonate; Bitter edible plant sulfonic acid and formaldehyde, alkyl polyoxyethylene ether, draw back powder, lime carbonate, dry powder, kaolin powder, clay powder, zeyssatite and potter's clay, perhaps wherein one or more the mixture of above-mentioned substance at castor oil polyoxyethylene ether, alkylphenol polyethylene oxide ether, water, No. 500, farming breast.
3. Fushou spiral shell according to claim 1 kills the spiral shell medicament-fertilizer mixture; It is characterized in that: described mineral manure is to comprise the chemical fertilizer that contains nitrogenous fertilizer, phosphate fertilizer and potash fertilizer; Comprise vitriol, nitrate salt, carbonate, chlorate and phosphate fertilizer, perhaps wherein one or more the mixture of above-mentioned substance.
4. Fushou spiral shell according to claim 1 kills the spiral shell medicament-fertilizer mixture, it is characterized in that: also comprise in the described fertilizer and contain trace element: copper, iron, calcium, zinc, manganese and boron.
5. Fushou spiral shell according to claim 1 kills the spiral shell medicament-fertilizer mixture; It is characterized in that: described organic fertilizer is the fertilizer that can directly supply with the necessary nutritive element of crop growth and be rich in organic substance, the farm manure that comprise urea, green manure, tea young slag, peanut press pulp, husk, manioc waste, filter mud of sugar refinery, weathered coal, fish meal, bone meal, plant straw powder, livestock and poultry manure, barnyard manure, compost, make compost, biogas manure and waste forms through microbiological degradation or fermentation.
6. the described Fushou spiral shell of claim 1 kills spiral shell medicament-fertilizer mixture working method, it is characterized in that concrete steps are following:
1) with water is solvent, the former medicine of Avrmectin or ointment, fermented product and auxiliary agent are prepared into the agricultural-chemical suspension mixture;
2) the agricultural-chemical suspension mixture is sprayed coating in carrier fertilizer, mix, process particulate state or powdery.
7. Fushou spiral shell according to claim 1 kills the spiral shell medicament-fertilizer mixture, it is characterized in that: the product method of use is to weed when harrowing a field in paddy rice, Fushou spiral shell is killed spiral shell medicine fertilizer evenly be spread on the land for growing field crops, and amount of application is 5-150 kilogram/mu.
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| CN103449935B (en) * | 2013-08-27 | 2014-12-17 | 周口市红旗农药有限公司 | Abamectin compound fertilizer |
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| CN103664413A (en) * | 2013-11-21 | 2014-03-26 | 山东荣吉肥业有限公司 | Abamectin active silicon calcium fertilizer and preparation method thereof |
| CN103848693B (en) * | 2014-03-21 | 2015-09-09 | 润禾泰华生物科技（北京）有限公司 | Residual Special-purpose liquid pesticide-containing fertilizer of a kind of potato volume increase desinsection degraded agriculture and preparation method thereof |
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Application publication date: 20121003 |