CN1026652C - Process for producing products containing indispensable metal elements from bees - Google Patents
Process for producing products containing indispensable metal elements from bees Download PDFInfo
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- CN1026652C CN1026652C CN89103072A CN89103072A CN1026652C CN 1026652 C CN1026652 C CN 1026652C CN 89103072 A CN89103072 A CN 89103072A CN 89103072 A CN89103072 A CN 89103072A CN 1026652 C CN1026652 C CN 1026652C
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- zinc
- selenium
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- Jellies, Jams, And Syrups (AREA)
Abstract
To obtain a honey bee product containing essential trace metal elements which are not usually included in it, especially selenium or zinc, by feeding bees with a food to which a water-soluble selenium compd. or a water- soluble org. zinc compd. is compounded. A water-soluble selenium compd. such as sodium selenite or potassium selenite is compounded by <=10ppm, preferably <=4ppm into an usual food for bees, or a water-soluble org. zinc compd. such as zinc gluconate is compounded by about 50ppm, to feed bees and to harvest royal jelly.
Description
The invention relates to the manufacture method of the bee products that contains trace element, more particularly, is the manufacture method about the bee products that contains trace elements of selenium component and zinc.
The kind of bee products is a lot.Wherein, particularly honey, royal jelly, honeybee etc. are edible since ancient times, particularly recently as health food, are worth very high.Honey is the sweet material that honeybee is gathered the floral nectary secretion that is stored in the honeycomb, is main component with invert sugar, and next contains mineral matter etc.On the other hand, royal jelly is the secretion of young worker bee pharynx gland, is for the edible a kind of high protein thing of queen bee nit in the honeycomb, and is identical with honey, contains minerals and vitamins.In addition, what honeybee was used now might be mass-produced honeybee drone, also contains protein, sugar, fat (vitamin D is many) and mineral matter.
It is said that mineral matter contained in these bee products is digested and assimilated easily, it is active and effective to be imbued with nourishing and fit keeping function and tool.
The assay value of contained mineral matter is shown in table 1 and table 2 in the royal jelly:
Mineral matter in table 1 raw royal jelly (ppm)
Potassium 529
Sodium 107
Calcium 27
Magnesium 59
Copper 2.6
Iron 3.8
Manganese 0.7
Zinc 19.6
Table 2
Phosphorus 215mg/100g
Iron 1.35mg/100g
Calcium 12.8mg/100g
Sodium 19.6mg/100g
Magnesium 30.1mg/100g
Copper 4.87ppm
Zinc 23.7ppm
Manganese 0.49ppm
But the content of bee product mineral and kind often fluctuate very big, and in addition, some does not contain the bee product to the useful so-called necessary trace element of health yet.For example selenium has the activity as vitamin E, symptoms such as liver defect, hepatonecrosis, kidney dystrophia can occur when lacking selenium.Each necessary selenium amount is g/ days/50kg of 100-200 μ, but the selenium of volume is harmful to.Do not contain selenium in the royal jelly.
In addition, the trace element that the concentration ratio of zinc in animal vegetable tissue is general is high, and it is wide to distribute, and for example, contains 15-25ppm in the royal jelly.On physiology, as insulin, the constituent of various biologic ferments such as nuclease plays an important role, can occur during shortage suppressing growing, grow stop, symptom such as damage of poor appetite, skin, hair, nail etc., reproduction insufficiency, hypoplasia.
Therefore, the object of the present invention is to provide and contain trace element, particularly contain the manufacture method of the bee product of selenium and zinc.
Above-mentioned and other purpose of the present invention, feature, advantage etc. can be clearer by the following description and accompanying drawing.
Fig. 1-Fig. 9 is illustrated in the royal jelly moisture that records in an example of the present invention, the result of receipts amount and various content of mineral substances.
The inventor, promptly can make by honeybee to contain the trace element that is necessary in the bee product through discovering repeatedly to edible certain trace compound of honeybee in view of above-mentioned problem.Based on this understanding, finished this invention.
That is, the invention provides mixed fodder, make the method that contains selenium component bee product and reach to the edible feed of water-soluble organic zinc compound, the method that manufacturing contains the zinc bee product of adding of honeybee to the edible interpolation of honeybee water soluble selenium.
The water soluble selenium compound that uses among the present invention has sodium selenite, potassium selenite etc.Selenium compound is poisonous, and its toxicity becomes because of the form of the content of selenium, compound and picked-up time length, continuity etc.LD toward mouse
51Be 3mg/kg during lumbar injection, be 7mg/kg when oral.The present invention adds the less selenite of toxicity and feeds honeybee in honeybee forage.Blended amount is more satisfactory below the 10ppm in feed, and 4ppm is following better.This small blended amount brings harmful effect can for growth and the activity of honeybee, can also obtain containing the bee product of suitable selenium concentration.
Water-soluble organic acid zinc compound used among the present invention does not have special restriction, but wherein zinc gluconate is more satisfactory.Blended amount in the honeybee forage with in the feed about 50ppm for well.
According to the present invention natively (rather than artificially) obtain containing the bee product of the necessary trace meter selenium that does not have usually, infer that said metallic selenium is an organic coordination compound.Simultaneously, to the edible this feed of honeybee, can also play the effect of quickening to cultivate bee colony.
Further describe the present invention with example below.
Example 1
To the edible sodium selenite (Na that is added with of honeybee
2SeO
3) syrup and the pollen load feed of the aqueous solution.In this case, the feed of honeybee is divided into following 6 districts, and the collection of royal jelly still uses common king's bowl (king Bowl) method to carry out.
Se concentration 4ppm in the B1 district feed
Camp is raised outward
Se concentration 40ppm in the B2 district feed
Camp is raised outward
Se concentration 4ppm in the B3 district feed
Raise in the camp
Se concentration 40ppm in the B4 district feed
Raise in the camp
1 district, contrast district does not add Na
2SeO
3
Camp is raised outward
2 districts, contrast district do not add Na
2SeO
3
Raise in the camp
Raise 18 days (from November 19 to December 7 days) as stated above, gathered in each district in per 3 days the royal jelly that produces once.To the royal jelly gathered in the 12nd day and part honeybee bulk measurement selenium concentration.The result is as shown in table 3.
Table 3
Sample Se concentration
1)Remarks
（ppm）
The B1 district produces royal jelly 0.10 the present invention
The B2 district produces royal jelly 0.93 the present invention
The B3 district produces royal jelly 0.35 the present invention
The B4 district produces royal jelly 0.27 the present invention
1 district, contrast district produces royal jelly and does not measure comparative example
2 districts, contrast district produce royal jelly and do not measure comparative example
Honeybee body 5.40 the present invention of B4 district
Annotate 1) detection method: the I.C.P emission spectrometry method
Quantitation limit value: 0.01ppm
The result of table 3 shows that the B1-B4 district eaten interpolation sodium selenite feed of the present invention to honeybee has produced the royal jelly that contains selenium.And do not measure selenium in the royal jelly of comparative example.Selenium concentration height in the feed in addition, and in the hive in the B4 district that in camp, raises, queen to lay eggs occurred and counted influences such as minimizing.The selenium concentration of honeybee body is also up to 5.40ppm.
Almost not variation is set group (B2 district) lining in high concentration the bee colony of raising outside camp, measures to contain selenium 0.93ppm in the royal jelly.If consider that long-time continuous is edible, to fix on 10ppm following for well for selenium concentration in the feed, better below the 4ppm.
Example 2
To eat ZnG [Zn(C
6H
11O)
7] aqueous solution joins in syrup and the pollen load, makes honeybee forage, and is identical with example 1, gather common king's bowl formula royal jelly harvester and raise.The raising of honeybee is divided into following 6 district groups and carries out.
Zn concentration 10ppm in the C1 district feed
Camp is raised outward
Zn concentration 100ppm in the C2 district feed
Camp is raised outward
Zn concentration 10ppm in the C3 district feed
Raise in the camp
Zn concentration 100ppm in the C4 district feed
Raise in the camp
1 district, contrast district does not add ZnG
Camp is raised outward
2 districts, contrast district do not add ZnG
Raise in the camp
Raised as stated above 18 days, taked in each district in per 3 days the royal jelly that produces once.The royal jelly of collection in the 12nd day and the zinc concentration of a part of honeybee body are measured.The result is as shown in table 4.
Table 4
The appendix of sample Zn concentration
（ppm）
The C1 district produces royal jelly 26.1 the present invention
The C2 district produces royal jelly 31.7 the present invention
The C3 district produces royal jelly 33.8 the present invention
The C4 district produces royal jelly 40.6 the present invention
1 district, contrast district produces royal jelly 31.2 comparative examples
2 districts, contrast district produce royal jelly 32.2 comparative examples
C4 district honeybee body 99.9 comparative examples
Contrast district 2 district's honeybee body 48.5 comparative examples
B4 district honeybee body (example 1) 22.7 (the present invention)
Annotate 1) detection method: the I.C.P emission spectrometry method
Result by table 4 learns, in the royal jelly that the raising district (C1 district-C4 district) of employing the inventive method produces, zinc concentration is compared with comparative example not have significantly to be increased, can think that thus the zinc input amount has saturation capacity, the zinc that necessary amount is above or be discharged from the external of worker bee, or be stored in certain part of honeybee body.See that by table 4 zinc concentration in the honeybee body in C4 of the present invention district is about 2 times of comparative example.We know, and are general, and zinc is the content height in the ovary of the following glandulae pharyngeae of worker bee and queen bee, and this can think that zinc is significant in the queen bee differentiation.
In the raising of this example 2, do not observe yet and drop into the harmful effect that zinc causes, the tendency of strengthening bee colony is arranged on the contrary, may be actively drop into zinc in the winter time breeding period effective especially.
Therefore, the inventive method can be regarded as except that the effect that increases zinc content in the bee product is arranged, also to winter feeding can increase the queen to lay eggs ability, to accelerate to educate honeybee speed effective especially.
As mentioned above, there is saturation value in the input amount of zinc, and considers from economic angle, contains in the feed about 50ppm for well.
Example 3
Various mineral matters are dissolved in the syrup, make it to reach the concentration shown in the table 5 (ppm of metallic element), with this as A liquid.Then A liquid is diluted to 1/2 concentration, with this as B liquid.And the concentration of sugar is 40%.(table 5 is seen the literary composition back)
Give 5 groups of honeybees edible respectively the A liquid and the B liquid of modulation as stated above.The district that uses A liquid is as the A district, and the district that uses B liquid only uses the control zone of syrup as F district (4 groups of honeybees) as the B district.
Fed one month, identical with example 1 therebetween, adopt common king's bowl formula royal jelly acquisition method, adopted once every 3 days, be divided into and do not take 10 times.Collection capacity, moisture and content of mineral substances to each royal jelly are measured.The mineral matter analysis is carried out with the ICP emission spectrometry method.The gained measured value is resolved by the T calibrating.Result such as Fig. 1-shown in Figure 9.
Fig. 1 represents the moisture of royal jelly.See between each district that by figure is clear significant difference is not arranged.The A district, the B district, the mean value in F district is respectively 66.4%, 60.0%, 66.3%, is normal value.
Fig. 2 represents the collection capacity of royal jelly.The mean value in each district is respectively 275.6g, 302.3g, and 258.0g, 44.3g manys than the F district in the B district, but the A district, and the B district is to F district there was no significant difference all.
Fig. 3 represents potassium content.The mean value in each district is respectively 3110ppm, 2878.6ppm, and 2736.3ppm, there is significant difference in the A district to the F district, and potassium content is many, and the forage feed of expression 3000ppm is effective.Table 6 is mensuration examples that common royal jelly mineral is filtered.Potassium content in this table is almost identical with F district (control zone), and 400ppm manys approximately than it in the A district.
Mineral matter (unit: ppm) in table 6 raw royal jelly
Calcium 153.8 manganese 0.75 lead is not measured
Magnesium 297.8 zinc 20.9 total mercurys are not measured
Phosphorus 1906.8 total chromium 0.14 are every not measuring
Sodium 125.5 selenium are not measured aluminium 183.0
Potassium 2669.0 lithiums are not measured arsenic and are not measured
Iron 11.0 nickel are not measured germanium and are not measured
Copper 3.81 cobalts are not measured sulphur 1173.1
Molybdenum 0.91 alum is not measured
Analytical method: I.C.P emission spectrometry method (do not have the food of interpolation dealer and buy synergistic combination inspection center, 1984).
Fig. 4 represents content of magnesium .A district, the B district, and the mean value in F district is respectively 410.8ppm, 355ppm.317ppm, the A district, the B district all is 1% to the level of significance in F district, for the high-load of significant difference is arranged.Therefore, magnesium is compared with the control sample when the concentration that drops into less than 500ppm, has been considered to the conspicuousness strengthening effect.
Fig. 5 represents sodium content.The A district, all there is significant difference in the B district to the F district, and because of the B district has higher mean value (200ppm compares many 75-90ppm with common royal jelly), can think that the following input of 150ppm concentration is for well.Common royal jelly sodium content is more much lower than potassium, and the balance of potassium/sodium has nothing different with general case in this example.
Fig. 6 represents calcium content.Though the A district, the B district all is the high-load that significant difference is arranged to the F district, the A district, and therefore the mean value in B district is not seen difference, can think, it is the limit that calcium is transferred to amount in the royal jelly compound concentration about with 160ppm.
Fig. 7 represents iron content.Having only the A district is 1% to the level of significance in F district, has conspicuousness to strengthen., the tendency that A district (concentration 100ppm) has honeybee to avoid to keep away is suitable compound concentration about hint 70ppm.
Fig. 8 represents the content of zinc.The A district, the B district, the mean value in F district is respectively 22.5ppm, 28.2ppm.21.4ppm, the A district, the B district all has conspicuousness to increase to the F district, and the mean value in B district is higher than A district significantly and contrasts with the result who feeds the example 2 of giving independent interpolation ZnG feed, owing to the reasons such as opposing of calcium in this example, the zinc content of A district (zinc drops into concentration 100ppm) is also lower than B district (50ppm).
Fig. 9 represents the content of manganese.Manganese content in the common royal jelly is about 0.7-1.0ppm, but the A district, the B district (is respectively
Table 5
Reagent
Concentration of element (ppm) uses reagent concentration (g/l) ratio (%)
Mg 1，000 MgCl
23.92 29.3
Ca 500 CaCl
21.38 10.3
Na 300 NaHCO
31.10 8.2
(total) 13.36 100.0
Annotate) the * molecular weight: 455.69 Zn:14.35%
10ppm, the input concentration of 5ppm) having compared conspicuousness with the F district increases., the A district, the mean value in B district does not almost have difference.
By above result as can be known, though necessity that each mineral concentration that drops into is carried out some adjustment in addition, in proper range, contained mineral in the common royal jelly of interpolation can significantly increase each content of mineral substances in syrup etc.
Claims (4)
1, a kind of by to the water-soluble selenite feed of the edible interpolation of honeybee, make the method for the royal jelly that contains the trace selenium component.
2, the method for claim 1, wherein water-soluble selenite are selected from one group of material of sodium selenite and potassium selenite composition.
3, the method for claim 1, wherein the blended amount of selenite in the feed guarantees that Se content is below 10ppm.
4, the method for claim 1, wherein the blended amount of selenite in the feed guarantees that Se content is below 4ppm.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP110584/88 | 1988-05-09 | ||
| JP63110584A JPH01285159A (en) | 1988-05-09 | 1988-05-09 | Production of honeybee product containing essential trace metal elements and product |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN93117356A Division CN1037927C (en) | 1988-05-09 | 1993-09-03 | Manufacturing method of bee produts with necessary trace metal elements |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1037636A CN1037636A (en) | 1989-12-06 |
| CN1026652C true CN1026652C (en) | 1994-11-23 |
Family
ID=14539552
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN89103072A Expired - Fee Related CN1026652C (en) | 1988-05-09 | 1989-05-06 | Process for producing products containing indispensable metal elements from bees |
| CN93117356A Expired - Fee Related CN1037927C (en) | 1988-05-09 | 1993-09-03 | Manufacturing method of bee produts with necessary trace metal elements |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN93117356A Expired - Fee Related CN1037927C (en) | 1988-05-09 | 1993-09-03 | Manufacturing method of bee produts with necessary trace metal elements |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JPH01285159A (en) |
| CN (2) | CN1026652C (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1039773C (en) * | 1993-10-14 | 1998-09-16 | 马忠杰 | Bee product with high content of organic trace element and its making method |
| KR20030071250A (en) * | 2002-02-28 | 2003-09-03 | 최혁선 | honey and royal jelly usedy the living body of honeybee |
| CN103392938A (en) * | 2013-08-05 | 2013-11-20 | 山东农业大学 | Pollen substitute forage specially for honeybee breeding in spring and preparation method thereof |
| CN107684063A (en) * | 2017-09-07 | 2018-02-13 | 山东农业大学 | A kind of production method of selenium-rich royal jelly |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2693420A (en) * | 1953-06-12 | 1954-11-02 | W F Straub & Company | Solidified honey product and process for making the same |
| US3879567A (en) * | 1974-02-11 | 1975-04-22 | Honey Tein Products Inc | Method of preparing a dried honey tablet |
| JPS5675063A (en) * | 1979-11-22 | 1981-06-20 | Tsunezo Kimura | Method for collecting product of honeybee |
| DE3204367A1 (en) * | 1982-02-09 | 1983-08-11 | Rudolf 8034 Germering Schanze | METHOD FOR PRODUCING PULVERIZED HONEY PRODUCTS, THE PRODUCTS OBTAINED IN THE METHOD AND THEIR USE |
-
1988
- 1988-05-09 JP JP63110584A patent/JPH01285159A/en active Pending
-
1989
- 1989-05-06 CN CN89103072A patent/CN1026652C/en not_active Expired - Fee Related
-
1993
- 1993-09-03 CN CN93117356A patent/CN1037927C/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN1087465A (en) | 1994-06-08 |
| JPH01285159A (en) | 1989-11-16 |
| CN1037927C (en) | 1998-04-08 |
| CN1037636A (en) | 1989-12-06 |
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