CN1037927C - Manufacturing method of bee produts with necessary trace metal elements - Google Patents

Manufacturing method of bee produts with necessary trace metal elements Download PDF

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CN1037927C
CN1037927C CN93117356A CN93117356A CN1037927C CN 1037927 C CN1037927 C CN 1037927C CN 93117356 A CN93117356 A CN 93117356A CN 93117356 A CN93117356 A CN 93117356A CN 1037927 C CN1037927 C CN 1037927C
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district
zinc
bee
royal jelly
concentration
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CN1087465A (en
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野膘润一朗
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Chief Resources Ltd
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Chief Resources Ltd
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Abstract

The invention relates to obtaining a honey bee product containing essential trace metal elements which are not usually included in it, especially selenium or zinc, by feeding bees with a food to which a water-soluble selenium compd. or a water- soluble org. zinc compd. is compounded.

Description

The manufacture method that contains the bee products of indispensable metal elements
The invention relates to the manufacture method of the bee products that contains trace element, more particularly, is the manufacture method about the bee products that contains trace element zinc
The kind of bee products is a lot.Wherein, particularly honey, royal jelly, honeybee etc. are edible since ancient times, particularly recently as health food, are worth very high.Honey is the sweet material that honeybee is gathered the floral nectary secretion that is stored in the honeycomb, is main component with invert sugar, and next contains mineral matter etc.On the other hand, royal jelly is the secretion of young worker bee pharynx gland, is for the edible a kind of high protein thing of queen bee nit in the honeycomb, and is identical with honey, contains minerals and vitamins.In addition, what honeybee was used now might be mass-produced honeybee drone, also contains protein, sugar, fat (vitamin D is many) and mineral matter.
It is said that mineral matter contained in these bee products is digested and assimilated easily, it is active and effective to be imbued with nourishing and fit keeping function and tool.
The assay value of contained mineral matter is shown in table 1 and table 2 in the royal jelly: the mineral matter in table 1 raw royal jelly (ppm) potassium 529 sodium 107 calcium 27 magnesium 59 bronze medals 2.6 iron 3.8 manganese 0.7 zinc 19.6 table 2 phosphorus 215 mg/100g iron 1.35mg/100g calcium 12.8mg/100g sodium 19.6mg/100g magnesium 30.1mg/100g copper 4.87ppm zinc 23.7ppm manganese 0.49ppm
But the content of bee product mineral and kind often fluctuate very big, and in addition, some does not contain the bee product to the useful so-called necessary trace element of health yet.For example, selenium has the activity as vitamin E, symptoms such as liver defect, hepatonecrosis kidney dystrophia can occur when lacking selenium.Everyone necessary selenium amount is g/ days/50kg of 100-200 μ, but the selenium of volume is harmful to.Do not contain selenium in the royal jelly.
In addition, the trace element that the concentration ratio of zinc in animal vegetable tissue is general is high, and it is wide to distribute, and for example, contains 15-25ppm in the royal jelly.On physiology, as insulin, the constituent of various biologic ferments such as nuclease plays an important role, can occur during shortage suppressing growing, grow stop, symptom such as damage of poor appetite, skin, hair, nail etc., reproduction insufficiency, hypoplasia.
Therefore, the object of the present invention is to provide and contain trace element, particularly contain the manufacture method of the bee product of zinc.
Above-mentioned and other purpose of the present invention, feature, advantage etc. can be clearer by the following description and accompanying drawing.
Fig. 1-Fig. 9 is illustrated in the royal jelly moisture that records in an example of the present invention, the result of receipts amount and various content of mineral substances.
The inventor, promptly can make by honeybee to contain the trace element that is necessary in the bee product through discovering repeatedly to edible certain trace compound of honeybee in view of above-mentioned problem.Based on this understanding, finished this invention.
Water-soluble organic acid zinc compound used among the present invention does not have special restriction, but wherein ZnG is more satisfactory.Blended amount in the honeybee forage with in the feed about 50ppm for well.
According to the present invention natively (rather than artificially) obtain containing the bee product of the necessary trace meter selenium that does not have usually.Simultaneously, to the edible this feed of honeybee, can also play the effect of quickening to cultivate bee colony.
Further describe the present invention with example below.
Example 1
To eat ZnG [Zn (C 6H 11O) 7] aqueous solution joins in syrup and the pollen load, makes honeybee forage, gather common king's bowl formula royal jelly harvester and raise.The raising of honeybee is divided into following 6 district groups and carries out.
Zn concentration 10ppm in the C1 district feed
Camp is raised outward
Zn concentration 100ppm in the C2 district feed
Camp is raised outward
Zn concentration 10ppm in the C3 district feed
Raise in the camp
Zn concentration 100ppm in the C4 district feed
Raise in the camp
1 district, contrast district does not add ZnG
Camp is raised outward
2 districts, contrast district add ZnG
Raise in the camp
Raised as stated above 18 days, taked in each district in per 3 days the royal jelly that produces once.The royal jelly of collection in the 12nd day and the zinc concentration of a part of honeybee body are measured.The result is as shown in table 3.
Table 3
The appendix of test portion Zn concentration
(ppm)
The C1 district produces royal jelly 26.1 the present invention
The C2 district produces royal jelly 31.7 the present invention
The C3 district produces royal jelly 33.8 the present invention
The C4 district produces royal jelly 40.6 the present invention
1 district, contrast district produces royal jelly 31.2 comparative examples
2 districts, contrast district produce royal jelly 32.2 comparative examples
C4 district honeybee body 99.9 comparative examples
Contrast district 2 district's honeybee body 48.5 comparative examples
B4 district honeybee body (example 1) 22.7 (the present invention)
Annotate 1) detection method: the I.C.P emission spectrometry method
Result by table 3 learns, in the royal jelly that the raising district (C1 district-C4 district) of employing the inventive method produces, zinc concentration is compared with comparative example not have significantly to be increased, can think that thus the zinc input amount has saturation capacity, the zinc that necessary amount is above or be discharged from the external of worker bee, or be stored in certain part of honeybee body.See that by table 4 zinc concentration in the honeybee body in C4 of the present invention district is about 2 times of comparative example.We know, and are general, and zinc is the content height in the ovary of the following glandulae pharyngeae of worker bee and queen bee, and this can think that zinc is significant in the queen bee differentiation.
In the raising of this example 2, do not observe yet and drop into the harmful effect that zinc causes, the tendency of strengthening bee colony is arranged on the contrary, may be actively drop into zinc in the winter time breeding period effective especially.
Therefore, the inventive method can be regarded as except that the effect that increases zinc content in the bee product is arranged, also to winter feeding can increase the queen to lay eggs ability, to accelerate to educate honeybee speed effective especially.
As mentioned above, there is saturation value in the input amount of zinc, and considers from economic angle, contains in the feed about 50ppm for well.
Example 2
Various mineral matters are dissolved in the syrup, make it to reach the concentration shown in the table 4 (ppm of metallic element), with this as A liquid.Then A liquid is diluted to 1/2 concentration, with this as B liquid.And the concentration of sugar is 40%.
Table 4
Reagent
Concentration of element (ppm) uses reagent concentration (g/l) ratio (%)
K 3,000 KCl 5.72 42.8
Mg 1,000 MgCl 2 3.92 29.3
Ca 500 CaCl 2 1.38 10.3
Na 300 NaHCO 3 1.10 8.2
Fe 100 FeSO 4·7H 2O 0.50 3.7
Zn 100 * ZnGs 0.70 5.2
Mn 10 MnCl 2· 2H 2O 0.04 0.3
(total) 13.36 100.0
Annotate) the * molecular weight: 455.69 Zn:14.35%
Give 5 groups of honeybees edible respectively the A liquid and the B liquid that connect above-mentioned method modulation.The district that uses A liquid is as the A district, and the district that uses B liquid only uses the control zone of syrup as F district (4 groups of honeybees) as the B district.
Fed one month, and adopted common king's bowl formula royal jelly acquisition method therebetween, adopted once, be divided into and do not take 10 times every 3 days.Collection capacity, moisture and content of mineral substances to each royal jelly are measured.The mineral matter analysis is carried out with the I.C.P emission spectrometry method.The gained measured value is resolved by the T calibrating.Result such as Fig. 1-shown in Figure 9.
Fig. 1 represents the moisture of royal jelly.See between each district that by figure is clear significant difference is not arranged.The A district, the B district, the mean value in F district is respectively 66.4%, 66.0%, 66.3%, is normal value.
Fig. 2 represents the collection capacity of royal jelly.The mean value in each district is respectively 275.6g, 302.3g, and 258.0g, 44.3g manys than the F district in the B district, but the A district, and the B district is to F district there was no significant difference all.
Fig. 3 represents potassium content.The mean value in each district is respectively 3110ppm, 2878.6ppm, and 2736.3ppm, there is significant difference in the A district to the F district, and potassium content is many, and the forage feed of expression 3000ppm is effective.Table 5 is mensuration examples that common royal jelly mineral is filtered.Potassium content in this table is almost identical with F district (control zone), and 400ppm manys approximately than it in the A district.
Mineral matter (unit: ppm) in table 5 raw royal jelly
Calcium 153.8 manganese 0.75 lead is not measured
Magnesium 297.8 zinc 20.9 total mercurys are not measured
Phosphorus 1906.8 total chromium 0.14 cadmiums are not measured
Sodium 125.5 selenium are not measured aluminium 183.0
Potassium 2669.0 lithiums are not measured arsenic and are not measured
Iron 11.0 nickel are not measured germanium and are not measured
Copper 3.81 cobalts are not measured sulphur 1173.1
Molybdenum 0.91 alum is not measured
Analytical method: I.C.P emission spectrometry method (do not have the food of interpolation dealer and buy synergistic combination inspection center, 1984).
Fig. 4 represents content of magnesium.The A district, the B district, the mean value in F district is respectively 410.8ppm, 355ppm, 317ppm, the A district, the B district all is 1% to the level of significance in F district, for the high-load of significant difference is arranged.Therefore, magnesium is compared with the control sample when the concentration that drops into less than 500ppm, has been considered to the conspicuousness strengthening effect.
Fig. 5 represents sodium content.The A district, all there is significant difference in the B district to the F district, and because of the B district has higher mean value (200ppm compares many 75-90ppm with common royal jelly), can think that the following input of 150ppm concentration is for well.Common royal jelly sodium content is more much lower than potassium, and the balance of potassium/sodium has nothing different with general case in this example.
Fig. 6 represents calcium content.Though the A district, the B district all is the high-load that significant difference is arranged to the F district, the A district, and therefore the mean value in B district is not seen difference, can think, it is the limit that calcium is transferred to amount in the royal jelly compound concentration about with 160ppm.
Fig. 7 represents iron content.Having only the A district is 1% to the level of significance in F district, has conspicuousness to strengthen., the tendency that A district (concentration 100ppm) has honeybee to avoid to keep away is suitable compound concentration about hint 70ppm.
Fig. 8 represents the content of zinc.The A district, the B district, the mean value in F district is respectively 22.5ppm, 28.2ppm.21.4ppm, the A district, the B district all has conspicuousness to increase to the F district, and the mean value in B district is higher than A district significantly and contrasts with the result who feeds the example 2 of giving independent interpolation ZnG feed, owing to the reasons such as opposing of calcium in this example, the zinc content of A district (zinc drops into concentration 100ppm) is also lower than B district (50ppm).
Fig. 9 represents the content of manganese.Manganese content in the common royal jelly is about 0.7-1.0ppm, but the A district, B district (being respectively 10ppm, the input concentration of 5ppm) compared conspicuousness to be increased with the F district., the A district, the mean value in B district does not almost have difference.
By above result as can be known, though necessity that each mineral concentration that drops into is carried out some adjustment in addition, in proper range, contained mineral in the common royal jelly of interpolation can significantly increase each content of mineral substances in syrup etc.

Claims (1)

1. a manufacturing contains the method for zinc bee product, and this method is that wherein the blended amount of the ZnG compound in the feed guarantees to make Zn content below 50ppm to the edible feed that has added water-soluble ZnG compound of honeybee.
CN93117356A 1988-05-09 1993-09-03 Manufacturing method of bee produts with necessary trace metal elements Expired - Fee Related CN1037927C (en)

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Application Number Priority Date Filing Date Title
JP63110584A JPH01285159A (en) 1988-05-09 1988-05-09 Production of honeybee product containing essential trace metal elements and product
JP110584/88 1988-05-09

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CN89103072A Division CN1026652C (en) 1988-05-09 1989-05-06 Process for producing products containing indispensable metal elements from bees

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CN1037927C true CN1037927C (en) 1998-04-08

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1039773C (en) * 1993-10-14 1998-09-16 马忠杰 Bee product with high content of organic trace element and its making method
KR20030071250A (en) * 2002-02-28 2003-09-03 최혁선 honey and royal jelly usedy the living body of honeybee
CN103392938A (en) * 2013-08-05 2013-11-20 山东农业大学 Pollen substitute forage specially for honeybee breeding in spring and preparation method thereof
CN107684063A (en) * 2017-09-07 2018-02-13 山东农业大学 A kind of production method of selenium-rich royal jelly

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2693420A (en) * 1953-06-12 1954-11-02 W F Straub & Company Solidified honey product and process for making the same
US3879567A (en) * 1974-02-11 1975-04-22 Honey Tein Products Inc Method of preparing a dried honey tablet
US4504516A (en) * 1982-02-09 1985-03-12 Rudolf Schanze Method for the preparation of powderized honey products, the products obtained according to the method and their use

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5675063A (en) * 1979-11-22 1981-06-20 Tsunezo Kimura Method for collecting product of honeybee

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2693420A (en) * 1953-06-12 1954-11-02 W F Straub & Company Solidified honey product and process for making the same
US3879567A (en) * 1974-02-11 1975-04-22 Honey Tein Products Inc Method of preparing a dried honey tablet
US4504516A (en) * 1982-02-09 1985-03-12 Rudolf Schanze Method for the preparation of powderized honey products, the products obtained according to the method and their use

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JPH01285159A (en) 1989-11-16
CN1087465A (en) 1994-06-08
CN1037636A (en) 1989-12-06

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