CN102658162B - 一种用于合成乙撑胺的催化剂及制备乙撑胺的方法 - Google Patents
一种用于合成乙撑胺的催化剂及制备乙撑胺的方法 Download PDFInfo
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- CN102658162B CN102658162B CN201210108743.1A CN201210108743A CN102658162B CN 102658162 B CN102658162 B CN 102658162B CN 201210108743 A CN201210108743 A CN 201210108743A CN 102658162 B CN102658162 B CN 102658162B
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/75—Cobalt
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/755—Nickel
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/889—Manganese, technetium or rhenium
- B01J23/8896—Rhenium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
- B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8953—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/24—Nitrogen compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/615—100-500 m2/g
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/04—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups
- C07C209/14—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of hydroxy groups or of etherified or esterified hydroxy groups
- C07C209/16—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of hydroxy groups or of etherified or esterified hydroxy groups with formation of amino groups bound to acyclic carbon atoms or to carbon atoms of rings other than six-membered aromatic rings
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
- C07D295/02—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms containing only hydrogen and carbon atoms in addition to the ring hetero elements
- C07D295/023—Preparation; Separation; Stabilisation; Use of additives
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
- C07D295/02—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms containing only hydrogen and carbon atoms in addition to the ring hetero elements
- C07D295/027—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms containing only hydrogen and carbon atoms in addition to the ring hetero elements containing only one hetero ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
- C07D295/04—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms
- C07D295/08—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by singly bound oxygen or sulfur atoms
- C07D295/084—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by singly bound oxygen or sulfur atoms with the ring nitrogen atoms and the oxygen or sulfur atoms attached to the same carbon chain, which is not interrupted by carbocyclic rings
- C07D295/088—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by singly bound oxygen or sulfur atoms with the ring nitrogen atoms and the oxygen or sulfur atoms attached to the same carbon chain, which is not interrupted by carbocyclic rings to an acyclic saturated chain
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
- C07D295/04—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms
- C07D295/12—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by singly or doubly bound nitrogen atoms
- C07D295/125—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by singly or doubly bound nitrogen atoms with the ring nitrogen atoms and the substituent nitrogen atoms attached to the same carbon chain, which is not interrupted by carbocyclic rings
- C07D295/13—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by singly or doubly bound nitrogen atoms with the ring nitrogen atoms and the substituent nitrogen atoms attached to the same carbon chain, which is not interrupted by carbocyclic rings to an acyclic saturated chain
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210108743.1A CN102658162B (zh) | 2012-04-13 | 2012-04-13 | 一种用于合成乙撑胺的催化剂及制备乙撑胺的方法 |
| IN7644DEN2014 IN2014DN07644A (cg-RX-API-DMAC10.html) | 2012-04-13 | 2012-05-24 | |
| PCT/CN2012/075989 WO2013152548A1 (zh) | 2012-04-13 | 2012-05-24 | 一种用于合成乙撑胺的催化剂及制备乙撑胺的方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210108743.1A CN102658162B (zh) | 2012-04-13 | 2012-04-13 | 一种用于合成乙撑胺的催化剂及制备乙撑胺的方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102658162A CN102658162A (zh) | 2012-09-12 |
| CN102658162B true CN102658162B (zh) | 2013-10-30 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210108743.1A Active CN102658162B (zh) | 2012-04-13 | 2012-04-13 | 一种用于合成乙撑胺的催化剂及制备乙撑胺的方法 |
Country Status (3)
| Country | Link |
|---|---|
| CN (1) | CN102658162B (cg-RX-API-DMAC10.html) |
| IN (1) | IN2014DN07644A (cg-RX-API-DMAC10.html) |
| WO (1) | WO2013152548A1 (cg-RX-API-DMAC10.html) |
Families Citing this family (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106607060B (zh) * | 2015-10-26 | 2019-08-20 | 中国石油化工股份有限公司 | 催化剂及其制备方法和应用以及乙二醇临氢胺化制乙二胺的方法 |
| CN106669836A (zh) * | 2015-11-05 | 2017-05-17 | 南通市永顺化工有限公司 | 一种用于制备乙撑胺的催化剂 |
| CN106669824A (zh) * | 2015-11-05 | 2017-05-17 | 南通市永顺化工有限公司 | 一种用于制备乙撑胺的催化剂 |
| CN106669835A (zh) * | 2015-11-05 | 2017-05-17 | 南通市永顺化工有限公司 | 一种用于制备乙撑胺的催化剂 |
| CN106669825A (zh) * | 2015-11-05 | 2017-05-17 | 南通市永顺化工有限公司 | 一种用于制备乙撑胺的催化剂 |
| CN106669826A (zh) * | 2015-11-05 | 2017-05-17 | 南通市永顺化工有限公司 | 一种用于制备乙撑胺的催化剂 |
| CN106807377A (zh) * | 2015-11-27 | 2017-06-09 | 中国科学院大连化学物理研究所 | 一种用于合成己二胺的催化剂 |
| CN106807395A (zh) * | 2015-11-27 | 2017-06-09 | 中国科学院大连化学物理研究所 | 一种用于合成己二胺的催化剂 |
| CN105801436A (zh) * | 2016-04-13 | 2016-07-27 | 四川之江高新材料股份有限公司 | N,n,n’-三甲基-n’-羟乙基-乙二胺的合成方法 |
| CN109569631A (zh) * | 2017-09-29 | 2019-04-05 | 中国科学院大连化学物理研究所 | 一种用于己炔二醇加氢制备己二醇的催化剂及制备和应用 |
| CN107913694A (zh) * | 2017-10-31 | 2018-04-17 | 山东玉皇化工有限公司 | 一种胺化催化剂载体的调变方法及其应用 |
| CN109908900B (zh) * | 2017-12-12 | 2022-05-06 | 中国科学院大连化学物理研究所 | 一种负载型催化剂及其制备方法与应用 |
| CN108311159A (zh) * | 2018-04-15 | 2018-07-24 | 陕西理工大学 | 一种用于合成三乙烯四胺的催化剂及其合成方法 |
| CN111018727A (zh) * | 2018-10-10 | 2020-04-17 | 中国石油化工股份有限公司 | 甘氨酸的生产方法 |
| CN110116004B (zh) * | 2019-06-11 | 2022-02-25 | 吉林化工学院 | 一种硝酸盐制备的一乙醇胺和液氨还原胺化合成乙撑胺的催化剂及其制备和使用方法 |
| CN112044447B (zh) * | 2020-08-18 | 2023-02-14 | 西安近代化学研究所 | 一种用于合成一乙胺的催化剂、制备方法及应用 |
| US20230381757A1 (en) | 2020-10-30 | 2023-11-30 | China Petroleum & Chemical Corporation | Amination catalyst and preparation and use thereof |
| CN114433113B (zh) * | 2020-10-30 | 2023-07-21 | 中国石油化工股份有限公司 | 具有催化醇氨化功能的催化剂和载体及其制备方法和应用 |
| US20230390747A1 (en) | 2020-10-30 | 2023-12-07 | China Petroleum & Chemical Corporation | Amination catalyst and preparation and use thereof |
| CN114436993B (zh) * | 2020-11-05 | 2023-10-13 | 中国石油化工股份有限公司 | 制备哌嗪的方法 |
| CN113713853B (zh) * | 2021-09-16 | 2024-03-22 | 中触媒新材料股份有限公司 | 一种环状亚胺制备脂肪二胺的方法及所用催化剂 |
| CN116410156B (zh) * | 2021-12-29 | 2025-05-02 | 中国科学院过程工程研究所 | 一种草酸酯氢氨化制备乙撑胺的方法 |
| CN114605268B (zh) * | 2022-03-22 | 2023-02-28 | 中国科学院大连化学物理研究所 | 一种催化合成多乙烯多胺的方法 |
| CN114713224B (zh) * | 2022-04-02 | 2023-06-23 | 厦门大学 | 一种用于催化乙醇胺化制备乙基胺的催化剂及其制备方法和应用 |
| CN119775149A (zh) * | 2023-10-07 | 2025-04-08 | 中国石油化工股份有限公司 | 化合物及其制备方法与应用 |
| CN118253311A (zh) * | 2024-04-08 | 2024-06-28 | 卫星化学股份有限公司 | 一种用于乙二胺和哌嗪制备的催化剂及其制备方法和应用 |
| CN118179609A (zh) * | 2024-04-09 | 2024-06-14 | 南京工业大学 | 一种用于二氯乙烷氨化制备乙撑胺的水溶性金属配合物催化剂、制备方法及其应用 |
| CN119241366B (zh) * | 2024-11-28 | 2025-12-12 | 卫星化学股份有限公司 | 双金属催化剂在乙烯胺合成中的应用以及乙烯胺的合成方法 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4209424A (en) * | 1977-12-12 | 1980-06-24 | Societe Chimique de la Grande Paroisse, Azote et Products Chimiques | Catalyst for manufacturing amines from alcohols |
| CN101406845A (zh) * | 2008-12-08 | 2009-04-15 | 西安近代化学研究所 | 胺化催化剂及其制备方法 |
| CN101829581A (zh) * | 2010-05-11 | 2010-09-15 | 广西壮族自治区化工研究院 | 用于乙醇胺胺化合成乙二胺的催化剂及其制备方法 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4642303A (en) * | 1985-12-27 | 1987-02-10 | Texaco Inc. | Catalyst composition |
| DE4325848A1 (de) * | 1993-07-31 | 1995-02-02 | Basf Ag | Verfahren zur Herstellung von N-(2-Hydroxyethyl)-piperazin |
| CN101704753A (zh) * | 2009-11-17 | 2010-05-12 | 中国科学院大连化学物理研究所 | 以乙醇胺和氨为原料在临氢条件下制备为乙二胺的方法 |
| CN101875014B (zh) * | 2009-11-17 | 2012-10-03 | 中国科学院大连化学物理研究所 | 一种在临氢条件下一乙醇胺和氨转化为乙二胺的催化剂 |
-
2012
- 2012-04-13 CN CN201210108743.1A patent/CN102658162B/zh active Active
- 2012-05-24 WO PCT/CN2012/075989 patent/WO2013152548A1/zh not_active Ceased
- 2012-05-24 IN IN7644DEN2014 patent/IN2014DN07644A/en unknown
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4209424A (en) * | 1977-12-12 | 1980-06-24 | Societe Chimique de la Grande Paroisse, Azote et Products Chimiques | Catalyst for manufacturing amines from alcohols |
| CN101406845A (zh) * | 2008-12-08 | 2009-04-15 | 西安近代化学研究所 | 胺化催化剂及其制备方法 |
| CN101829581A (zh) * | 2010-05-11 | 2010-09-15 | 广西壮族自治区化工研究院 | 用于乙醇胺胺化合成乙二胺的催化剂及其制备方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2013152548A1 (zh) | 2013-10-17 |
| IN2014DN07644A (cg-RX-API-DMAC10.html) | 2015-05-15 |
| CN102658162A (zh) | 2012-09-12 |
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