CN102643517A - 液晶环氧/蒙脱土共混改性环氧树脂制备复合材料的方法 - Google Patents
液晶环氧/蒙脱土共混改性环氧树脂制备复合材料的方法 Download PDFInfo
- Publication number
- CN102643517A CN102643517A CN2012101517069A CN201210151706A CN102643517A CN 102643517 A CN102643517 A CN 102643517A CN 2012101517069 A CN2012101517069 A CN 2012101517069A CN 201210151706 A CN201210151706 A CN 201210151706A CN 102643517 A CN102643517 A CN 102643517A
- Authority
- CN
- China
- Prior art keywords
- epoxy resin
- hours
- montmorillonite
- epoxy
- liquid crystalline
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003822 epoxy resin Substances 0.000 title claims abstract description 39
- 229920000647 polyepoxide Polymers 0.000 title claims abstract description 39
- 238000002156 mixing Methods 0.000 title claims abstract description 22
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 title claims abstract description 11
- 238000000034 method Methods 0.000 title claims abstract description 11
- 229910052901 montmorillonite Inorganic materials 0.000 title claims abstract description 11
- 239000002131 composite material Substances 0.000 title abstract description 6
- MQJKPEGWNLWLTK-UHFFFAOYSA-N Dapsone Chemical compound C1=CC(N)=CC=C1S(=O)(=O)C1=CC=C(N)C=C1 MQJKPEGWNLWLTK-UHFFFAOYSA-N 0.000 claims abstract description 29
- 238000006243 chemical reaction Methods 0.000 claims abstract description 17
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 claims abstract description 7
- 229910000831 Steel Inorganic materials 0.000 claims abstract description 6
- 239000010959 steel Substances 0.000 claims abstract description 6
- 239000003153 chemical reaction reagent Substances 0.000 claims abstract description 4
- 238000010438 heat treatment Methods 0.000 claims abstract description 3
- 239000004593 Epoxy Substances 0.000 claims description 36
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 claims description 34
- 239000007788 liquid Substances 0.000 claims description 31
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 21
- 230000004048 modification Effects 0.000 claims description 21
- 238000012986 modification Methods 0.000 claims description 21
- 239000011159 matrix material Substances 0.000 claims description 20
- FJKROLUGYXJWQN-UHFFFAOYSA-N 4-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 claims description 15
- 238000005303 weighing Methods 0.000 claims description 13
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 12
- 239000007787 solid Substances 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- 239000000463 material Substances 0.000 claims description 8
- 238000001291 vacuum drying Methods 0.000 claims description 7
- LRWZZZWJMFNZIK-UHFFFAOYSA-N 2-chloro-3-methyloxirane Chemical compound CC1OC1Cl LRWZZZWJMFNZIK-UHFFFAOYSA-N 0.000 claims description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- 238000005406 washing Methods 0.000 claims description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 5
- 230000006837 decompression Effects 0.000 claims description 5
- 239000011734 sodium Substances 0.000 claims description 5
- 229910052708 sodium Inorganic materials 0.000 claims description 5
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims description 3
- 206010013786 Dry skin Diseases 0.000 claims description 3
- 230000009471 action Effects 0.000 claims description 3
- 239000013256 coordination polymer Substances 0.000 claims description 3
- 239000008367 deionised water Substances 0.000 claims description 3
- 229910021641 deionized water Inorganic materials 0.000 claims description 3
- 238000004821 distillation Methods 0.000 claims description 3
- 239000012153 distilled water Substances 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 239000012046 mixed solvent Substances 0.000 claims description 3
- 239000003444 phase transfer catalyst Substances 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- 239000004576 sand Substances 0.000 claims description 3
- 238000000967 suction filtration Methods 0.000 claims description 3
- JRMUNVKIHCOMHV-UHFFFAOYSA-M tetrabutylammonium bromide Chemical compound [Br-].CCCC[N+](CCCC)(CCCC)CCCC JRMUNVKIHCOMHV-UHFFFAOYSA-M 0.000 claims description 3
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 claims description 3
- FJKROLUGYXJWQN-UHFFFAOYSA-M 4-hydroxybenzoate Chemical compound OC1=CC=C(C([O-])=O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-M 0.000 claims description 2
- 238000007872 degassing Methods 0.000 abstract 1
- 238000011031 large-scale manufacturing process Methods 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 description 11
- 239000004973 liquid crystal related substance Substances 0.000 description 5
- 239000002994 raw material Substances 0.000 description 4
- 230000035939 shock Effects 0.000 description 4
- 238000012360 testing method Methods 0.000 description 3
- 239000004927 clay Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 229910021647 smectite Inorganic materials 0.000 description 2
- 239000013589 supplement Substances 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 239000004974 Thermotropic liquid crystal Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000002929 anti-fatigue Effects 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- -1 organo montmorillonite Chemical compound 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
Landscapes
- Epoxy Resins (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
Claims (1)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN 201210151706 CN102643517B (zh) | 2012-05-16 | 2012-05-16 | 液晶环氧/蒙脱土共混改性环氧树脂制备复合材料的方法 |
Applications Claiming Priority (1)
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CN 201210151706 CN102643517B (zh) | 2012-05-16 | 2012-05-16 | 液晶环氧/蒙脱土共混改性环氧树脂制备复合材料的方法 |
Publications (2)
Publication Number | Publication Date |
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CN102643517A true CN102643517A (zh) | 2012-08-22 |
CN102643517B CN102643517B (zh) | 2013-07-24 |
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CN 201210151706 Expired - Fee Related CN102643517B (zh) | 2012-05-16 | 2012-05-16 | 液晶环氧/蒙脱土共混改性环氧树脂制备复合材料的方法 |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106827717A (zh) * | 2017-01-09 | 2017-06-13 | 三峡大学 | 一种高介电性能挠性覆铜板及其制备方法 |
CN106916415A (zh) * | 2017-02-27 | 2017-07-04 | 东北大学 | 一种液晶环氧树脂/蒙脱土复合材料及其制备方法 |
CN109929496A (zh) * | 2019-03-01 | 2019-06-25 | 翟治国 | 一种led紫外光固化封装材料的制备方法 |
CN117801181A (zh) * | 2024-02-27 | 2024-04-02 | 烟台舜康生物科技有限公司 | Uv光聚合制备有机-无机纳米复合材料的方法 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2001302766A (ja) * | 2000-04-24 | 2001-10-31 | Nippon Mitsubishi Oil Corp | 複合材料用樹脂組成物、複合材料用中間材および複合材料 |
CN1354198A (zh) * | 2001-12-26 | 2002-06-19 | 河北工业大学 | 一种环氧树脂/蒙脱土纳米复合材料及其制备方法 |
-
2012
- 2012-05-16 CN CN 201210151706 patent/CN102643517B/zh not_active Expired - Fee Related
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2001302766A (ja) * | 2000-04-24 | 2001-10-31 | Nippon Mitsubishi Oil Corp | 複合材料用樹脂組成物、複合材料用中間材および複合材料 |
CN1354198A (zh) * | 2001-12-26 | 2002-06-19 | 河北工业大学 | 一种环氧树脂/蒙脱土纳米复合材料及其制备方法 |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106827717A (zh) * | 2017-01-09 | 2017-06-13 | 三峡大学 | 一种高介电性能挠性覆铜板及其制备方法 |
CN106916415A (zh) * | 2017-02-27 | 2017-07-04 | 东北大学 | 一种液晶环氧树脂/蒙脱土复合材料及其制备方法 |
CN106916415B (zh) * | 2017-02-27 | 2019-02-26 | 东北大学 | 一种液晶环氧树脂/蒙脱土复合材料及其制备方法 |
CN109929496A (zh) * | 2019-03-01 | 2019-06-25 | 翟治国 | 一种led紫外光固化封装材料的制备方法 |
CN117801181A (zh) * | 2024-02-27 | 2024-04-02 | 烟台舜康生物科技有限公司 | Uv光聚合制备有机-无机纳米复合材料的方法 |
CN117801181B (zh) * | 2024-02-27 | 2024-05-14 | 烟台舜康生物科技有限公司 | Uv光聚合制备有机-无机纳米复合材料的方法 |
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Publication number | Publication date |
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CN102643517B (zh) | 2013-07-24 |
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Application publication date: 20120822 Assignee: Guangxi Shengxiao Trade Co.,Ltd. Assignor: GUILIN University OF TECHNOLOGY Contract record no.: X2022450000454 Denomination of invention: Preparation of composite materials by blending liquid crystalline epoxy/montmorillonite modified epoxy resin Granted publication date: 20130724 License type: Common License Record date: 20221228 |
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CF01 | Termination of patent right due to non-payment of annual fee | ||
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Granted publication date: 20130724 |