CN102504679A - Novel anti-skidding coating for deck and preparation method thereof - Google Patents
Novel anti-skidding coating for deck and preparation method thereof Download PDFInfo
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- CN102504679A CN102504679A CN2011103133707A CN201110313370A CN102504679A CN 102504679 A CN102504679 A CN 102504679A CN 2011103133707 A CN2011103133707 A CN 2011103133707A CN 201110313370 A CN201110313370 A CN 201110313370A CN 102504679 A CN102504679 A CN 102504679A
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- 238000002360 preparation method Methods 0.000 title claims abstract description 7
- 239000011248 coating agent Substances 0.000 title abstract description 23
- 238000000576 coating method Methods 0.000 title abstract description 23
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 35
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000000945 filler Substances 0.000 claims abstract description 10
- 239000001038 titanium pigment Substances 0.000 claims abstract description 10
- 239000002270 dispersing agent Substances 0.000 claims abstract description 9
- 238000009736 wetting Methods 0.000 claims abstract description 9
- 229920000126 latex Polymers 0.000 claims abstract description 5
- 239000004816 latex Substances 0.000 claims abstract description 3
- 239000003973 paint Substances 0.000 claims description 26
- 239000000839 emulsion Substances 0.000 claims description 20
- 238000003756 stirring Methods 0.000 claims description 15
- 238000000034 method Methods 0.000 claims description 12
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 12
- 239000000463 material Substances 0.000 claims description 11
- 230000003712 anti-aging effect Effects 0.000 claims description 10
- 238000004581 coalescence Methods 0.000 claims description 10
- 239000002002 slurry Substances 0.000 claims description 10
- 230000008719 thickening Effects 0.000 claims description 10
- 239000002245 particle Substances 0.000 claims description 8
- 239000000843 powder Substances 0.000 claims description 8
- 230000003449 preventive effect Effects 0.000 claims description 8
- 229920001971 elastomer Polymers 0.000 claims description 7
- 229920002635 polyurethane Polymers 0.000 claims description 7
- 239000004814 polyurethane Substances 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 6
- 230000008569 process Effects 0.000 claims description 6
- PRPAGESBURMWTI-UHFFFAOYSA-N [C].[F] Chemical compound [C].[F] PRPAGESBURMWTI-UHFFFAOYSA-N 0.000 claims description 5
- 230000015572 biosynthetic process Effects 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 4
- 239000002699 waste material Substances 0.000 claims description 4
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 3
- 239000010445 mica Substances 0.000 claims description 3
- 229910052618 mica group Inorganic materials 0.000 claims description 3
- 239000007787 solid Substances 0.000 claims description 2
- 239000004408 titanium dioxide Substances 0.000 claims description 2
- 239000003112 inhibitor Substances 0.000 abstract description 5
- 238000012360 testing method Methods 0.000 abstract description 5
- 230000032683 aging Effects 0.000 abstract description 4
- 238000005516 engineering process Methods 0.000 abstract description 4
- 239000013535 sea water Substances 0.000 abstract description 4
- 230000007797 corrosion Effects 0.000 abstract description 3
- 238000005260 corrosion Methods 0.000 abstract description 3
- 239000004615 ingredient Substances 0.000 abstract description 2
- 150000003839 salts Chemical class 0.000 abstract description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 4
- 229910052742 iron Inorganic materials 0.000 abstract 2
- 239000000853 adhesive Substances 0.000 abstract 1
- 230000001070 adhesive effect Effects 0.000 abstract 1
- 238000005536 corrosion prevention Methods 0.000 abstract 1
- 239000004088 foaming agent Substances 0.000 abstract 1
- 239000003595 mist Substances 0.000 abstract 1
- 239000011814 protection agent Substances 0.000 abstract 1
- 239000002562 thickening agent Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 9
- 239000008188 pellet Substances 0.000 description 6
- 239000004576 sand Substances 0.000 description 5
- 235000010215 titanium dioxide Nutrition 0.000 description 4
- 239000000080 wetting agent Substances 0.000 description 4
- 239000003963 antioxidant agent Substances 0.000 description 3
- 230000003078 antioxidant effect Effects 0.000 description 3
- 238000010276 construction Methods 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 238000012544 monitoring process Methods 0.000 description 3
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical class [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 101100412856 Mus musculus Rhod gene Proteins 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000006750 UV protection Effects 0.000 description 1
- 230000004523 agglutinating effect Effects 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 238000013467 fragmentation Methods 0.000 description 1
- 238000006062 fragmentation reaction Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- ODUCDPQEXGNKDN-UHFFFAOYSA-N nitroxyl Chemical class O=N ODUCDPQEXGNKDN-UHFFFAOYSA-N 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 230000004224 protection Effects 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000007634 remodeling Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
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- Paints Or Removers (AREA)
Abstract
The invention provides a novel anti-skidding coating for a deck, which is composed of the following components in parts by weight: 30-45 parts of latex, 2-5 parts of film forming accessory ingredient, 15-25 parts of titanium pigment, 5-20 parts of filler, 0.2-1.0 part of wetting dispersant, 5-15 parts of anti-skidding agent, 0.1-0.5 part of de-foaming agent, 0.5-1.0 part of age inhibitor, 0.5-2.0 parts of thickening agent, 0.5-1.0 part of anti-mildew corrosion-protection agent, and 10-25 parts of water. The coating of the invention has very high wearing resistance and anti-skidding degree; the formed coat has good adhesive ability, wearing resistance, weather resistance, light-proof aging resistance, seawater resistance and salt mist resistance, wherein the artificial weathering aging test (ultraviolet UVB-313 resistance) is 4000 h, and the wearing resistance (1000g/1000r) is not more than 30mg; the coating is applied to the corrosion prevention of the decks and the iron surfaces of the sea apparatus of boats and ocean platforms, wherein the decks and the iron surfaces require to have weather resistance, anti-skidding property, wearing resistance, and seawater corrosion resistance. The preparation method of the anti-skidding coating for the deck is simple in technology, low in cost and is performed without special apparatus.
Description
Technical field
The present invention relates to a kind of preparation method of ship deck coating, especially relate to a kind of novel nonskiddeck paint and preparation method thereof, belong to paint field.
Background technology
Common skid-resistant coating can be divided into following three types by the kind branch that adds slipproofing agent: one type is to be slipproofing agent with the inorganics sand grains, and like silica sand, silica sand, glass hollow bead, silicon carbide, haydite, crystalline aluminum oxide etc., the characteristics of this type skid-resistant coating are: frictional force is big; Raw material is easy to get, and is with low cost, but this slipproofing agent is than great; Being mixed with paint vehicle is prone to deposition, and the stifled rifle of spraying has to take artificial stucco; Deal with problems arising from an accident and sweep agglutinating sand not, operating efficiency is low, and sand grains is irregular; Though initial stage frictional force is big, easy to wear coming off of later stage, application life is short; Second type of slipproofing agent adopts the organic cpds pellet, like synthetic resins, waste rubber particle, though the price of this type slipproofing agent is higher than inorganic pellet, has suitable stiffness and elasticity; Do not have arris edge, can stand friction and impact difficult fragmentation, clinging power is good, difficult drop-off; Initial stage is a little bit smaller compared with inorganic pellet frictional force, but the life-span is long, and proportion and base-material are similar, not free settling; It is convenient to execute, and is suitable for spraying, and pellet is even, but must prevent pellet and the stratified phenomenon of solvent-swollen; The 3rd type of skid-resistant coating is without the slipproofing agent pellet, mainly is that the binder resin with coating carries out molecular designing, and high reactivity group composition produces strong polarity at coating surface, and the surface contact produces moving resistance, and this skid-resistant coating is in the trial period at present.Present skid-resistant coating is difficult to satisfy the request for utilization of ship deck, and mainly have following shortcoming: weathering resistance is bad, is prone to aging; Construction is complicated, and construction process contaminate environment operating efficiency is low; Sticking power and erosion resistance are not good enough; Replacing property of cold-and-heat resistent is relatively poor or the like.
Summary of the invention
To the deficiency that prior art exists, technical problem to be solved by this invention is that a kind of novel nonskiddeck paint and preparation method thereof is provided; Good antiskid effect, shelf-stable, easy construction; Corrosion resistance nature and sticking power are good, coating life is long, have solved the skid-resistance requirements of ship deck.
For solving above-mentioned technical problem, the technical scheme that the present invention adopted is, a kind of novel nonskiddeck paint is made up of following component by weight:
Emulsion 30-45 part; Film coalescence aid 2-5 part; White titanium pigment 15-25 part; Filler 5-20 part; Wetting dispersing agent 0.2-1.0 part; Slipproofing agent 5-15 part; Skimmer 0.1-0.5 part; Anti-aging agent 0.5-1.0 part; Thickening material 0.5-2.0 part; Antisepticize and mildew preventive 0.5-1.0 part; Water 10-25 part
Wherein, said emulsion is one or more in aqueous polyurethane emulsion, fluorine carbon emulsion, the organosilicon crylic acid latex; The solid content of said emulsion is 35%-60%.
Above-mentioned novel nonskiddeck paint, said described white titanium pigment is a Rutile type Titanium Dioxide, granularity is 2000 orders.
Above-mentioned novel nonskiddeck paint, said filler are one or more in mica powder, talcum powder, dicalcium powder or the process white.
Above-mentioned novel nonskiddeck paint, said slipproofing agent are one or both in organic cpds slipproofing agent waste and old rubber particle or the polyurethane particles, and size range is the 120-200 order.
A kind of method of above-mentioned novel nonskiddeck paint is made up of following steps successively:
(1) according to above-mentioned formula ratio with slipproofing agent, wetting dispersing agent, anti-aging agent, Antisepticize and mildew preventive and 1/2 skimmer add and disperse in the cylinder, mix with 1/2 water, with 300-500 rev/min speed stirring at low speed 20-30min;
(2) according to above-mentioned formula ratio emulsion, film coalescence aid are added in the slurry of step (1) formation, stir;
(3) add white titanium pigment and filler successively according to above-mentioned prescription then; At last 1/2 skimmer of remainder and 1/2 water are added in the slurry, and add thickening material and stir with 600-800 rev/min speed.
Skimmer in the production stage adds at twice, is in order to suppress the foamy generation in the premix stage with disperseing the paint stage respectively, to obtain better defoaming effect.
The present invention's beneficial effect compared with prior art:
Wear-resisting anti-slippery of the present invention is very high; Its coating has good sticking power, wear resistance, weathering resistance, light fastness aging, sea water resistance and salt fog resistance; Wherein anti-artificial weathering test (ultraviolet resistance UVB-313) reaches 4000h; Wear resistance (1000g/1000r) is not more than 30mg, can be used for deck and other maritime facilities steel surfaces anticorrosion that boats and ships, ocean platform etc. need weather-proof, cloudy sliding wear-resisting, seawater corrosion resistance; The method of manufacture of nonskiddeck paint of the present invention, technology is simple, need not specific installation, cheap.
Embodiment
Through embodiment the present invention is further specified below.Wetting dispersing agent of the present invention by wetting agent or/and dispersion agent form; Antisepticize and mildew preventive of the present invention by sanitas or/and mould inhibitor form.
Embodiment 1
The nonskiddeck paint of present embodiment, the weight part prescription of each component consists of: 30 parts of aqueous polyurethane emulsions, 15 parts of fluorine carbon emulsions; 10 parts of dicalcium powders, 10 parts of process whites; 15 parts of slipproofing agents (120 order polyurethane particles); Film coalescence aid (U.S. Eastman Chemical Company, Taxanol) 5 parts; Wetting agent (Guangzhou hat will chemical industry ltd, PE-100) 1.0 parts; Anti-aging agent (Huangyan, Zhejiang East Zhejiang province rubber ingredients ltd, ketoamine class antioxidant A W), 0.8 part; Skimmer (German Bi Ke chemical company, BYK-055) 0.5 part; 0.5 part of mould inhibitor (the permanent safe Fine Chemical Co., Ltd of Beijing Jin Yuan, Hua Ke-108); 0.5 part of sanitas (the permanent safe Fine Chemical Co., Ltd of Beijing Jin Yuan, Hua Ke-088); 10 parts in water; Thickening material (U.S. Rhom and Hass, DR-73) 1 part; 25 parts of Rutile type Titanium Dioxides.
The method of above-mentioned novel nonskiddeck paint is made up of following steps successively:
(1) according to above-mentioned formula ratio with slipproofing agent, wetting dispersing agent, anti-aging agent, Antisepticize and mildew preventive and 1/2 skimmer add and disperse in the cylinder, mix with 1/2 water, with 300-500 rev/min speed stirring at low speed 20-30min;
(2) according to above-mentioned formula ratio emulsion, film coalescence aid are added in the slurry of step (1) formation, stir;
(3) add white titanium pigment and filler successively according to above-mentioned prescription then; At last 1/2 skimmer of remainder and 1/2 water are added in the slurry, and add thickening material and stir with 600-800 rev/min speed.
Below be that this skid-resistant coating checks various results of property following through national coating products quality monitoring testing station:
Table 1 is the nonskiddeck paint main performance index among the embodiment 1
Embodiment 2
The nonskiddeck paint of present embodiment, the weight part prescription of each component consists of: 15 parts of organosilicon crylic acid latexs, 15 parts of fluorine carbon emulsions; 5 parts of dicalcium powders, 10 parts of process whites, 3 parts of talcum powder; 5 parts of slipproofing agents (200 order junked tire particle); Film coalescence aid (U.S. Eastman Chemical Company, Taxanol) 2 parts; Wetting agent (Guangzhou hat will chemical industry ltd, PE-100) 0.1 part; Anti-aging agent (Guangzhou this rubber raw materials of power ltd, antioxidant D), 0.5 part; Skimmer (German Bi Ke chemical company, BYK-053) 0.1 part; 0.3 part of mould inhibitor (the permanent safe Fine Chemical Co., Ltd of Beijing Jin Yuan, Hua Ke-108); Sanitas (chemical industry ltd of Foochow confederate state, MB-16), 0.3 part; Dispersion agent (Shanghai coating institute, P-19) 0.1 part; 25 parts in water; Thickening material (the white Chemical Industry Science Co., Ltd of Shanghai space, 250HBR) 2.0 parts; 15 parts of Rutile type Titanium Dioxides.
The method of above-mentioned novel nonskiddeck paint is made up of following steps successively:
(1) according to above-mentioned formula ratio with slipproofing agent, wetting dispersing agent, anti-aging agent, Antisepticize and mildew preventive and 1/2 skimmer add and disperse in the cylinder, mix with 1/2 water, with 300-500 rev/min speed stirring at low speed 20-30min;
(2) according to above-mentioned formula ratio emulsion, film coalescence aid are added in the slurry of step (1) formation, stir;
(3) add white titanium pigment and filler successively according to above-mentioned prescription then; At last 1/2 skimmer of remainder and 1/2 water are added in the slurry, and add thickening material and stir with 600-800 rev/min speed.
Below be that this skid-resistant coating checks various results of property following through national coating products quality monitoring testing station:
Table 2 is the nonskiddeck paint main performance index among the embodiment 2
Embodiment 3
The nonskiddeck paint of present embodiment, the weight part prescription of each component consists of: 15 parts of aqueous polyurethane emulsions, 10 parts of organosilicon crylic acid latexs, 15 parts of fluorine carbon emulsions; 1.5 parts of mica powders, 1.5 parts of dicalcium powders, 2 parts of process whites; 9 parts of slipproofing agents (150 order waste and old rubber particle); Film coalescence aid (U.S. Eastman Chemical Company, Taxanol), 4 parts; Wetting agent (Shanghai Assistant Agent Factory Co., Ltd., OP-10), 0.5 part; Dispersion agent (Shanghai coating institute, P-19), 0.2 part; Anti-aging agent (Guangzhou this rubber raw materials of power ltd, antioxidant D), 1.0 parts; Skimmer (German Bi Ke chemical company, BYK-053), 0.3 part; Sanitas (chemical industry ltd of Foochow confederate state, MB-16), 0.25 part; Mould inhibitor (chemical industry ltd of Foochow confederate state, MB-11), 0.25 part; 15 parts in water; Thickening material (U.S. Rhom and Hass, DR-01), 0.5 part; 20 parts of Rutile type Titanium Dioxides.
The method of above-mentioned novel nonskiddeck paint is made up of following steps successively:
(1) according to above-mentioned formula ratio with slipproofing agent, wetting dispersing agent, anti-aging agent, Antisepticize and mildew preventive and 1/2 skimmer add and disperse in the cylinder, mix with 1/2 water, with 300-500 rev/min speed stirring at low speed 20-30min;
(2) according to above-mentioned formula ratio emulsion, film coalescence aid are added in the slurry of step (1) formation, stir;
(3) add white titanium pigment and filler successively according to above-mentioned prescription then; At last 1/2 skimmer of remainder and 1/2 water are added in the slurry, and add thickening material and stir with 600-800 rev/min speed.
Below be that this skid-resistant coating checks various results of property following through national coating products quality monitoring testing station:
Table 3 is the nonskiddeck paint main performance index among the embodiment 3
The above only is preferred embodiment of the present invention, is not to be the restriction of the present invention being made other form, and any professional and technical personnel of being familiar with possibly utilize the technology contents of above-mentioned announcement to change or be modified as the equivalent embodiment of equivalent variations.But everyly do not break away from technical scheme content of the present invention, to any simple modification, equivalent variations and remodeling that above embodiment did, still belong to the protection domain of technical scheme of the present invention according to technical spirit of the present invention.
Claims (5)
1. novel nonskiddeck paint, form by weight by following component:
Emulsion 30-45 part; Film coalescence aid 2-5 part; White titanium pigment 15-25 part; Filler 5-20 part; Wetting dispersing agent 0.2-1.0 part; Slipproofing agent 5-15 part; Skimmer 0.1-0.5 part; Anti-aging agent 0.5-1.0 part; Thickening material 0.5-2.0 part; Antisepticize and mildew preventive 0.5-1.0 part; Water 10-25 part;
Wherein, said emulsion is one or more in aqueous polyurethane emulsion, fluorine carbon emulsion, the organosilicon crylic acid latex; The solid content of said emulsion is 35%-60%.
2. novel nonskiddeck paint according to claim 1, said white titanium pigment are Rutile type Titanium Dioxide, and granularity is 2000 orders.
3. novel nonskiddeck paint according to claim 1, said filler are one or more in mica powder, talcum powder, dicalcium powder or the process white.
4. novel nonskiddeck paint according to claim 1, said slipproofing agent are one or both in organic cpds slipproofing agent waste and old rubber particle or the polyurethane particles, and size range is the 120-200 order.
5. the method for the novel nonskiddeck paint in the preparation claim 1 is made up of following steps successively:
(1) according to above-mentioned formula ratio with slipproofing agent, wetting dispersing agent, anti-aging agent, Antisepticize and mildew preventive and 1/2 skimmer add and disperse in the cylinder, mix with 1/2 water, with 300-500 rev/min speed stirring at low speed 20-30min;
(2) according to above-mentioned formula ratio emulsion, film coalescence aid are added in the slurry of step (1) formation, stir;
(3) add white titanium pigment and filler successively according to above-mentioned prescription then; At last 1/2 skimmer of remainder and 1/2 water are added in the slurry, and add thickening material and stir with 600-800 rev/min speed.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110313370.7A CN102504679B (en) | 2011-10-17 | A kind of Novel anti-skidding coating for deck and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110313370.7A CN102504679B (en) | 2011-10-17 | A kind of Novel anti-skidding coating for deck and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102504679A true CN102504679A (en) | 2012-06-20 |
| CN102504679B CN102504679B (en) | 2016-12-14 |
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| CN103059677A (en) * | 2012-12-26 | 2013-04-24 | 王娟 | Silicone acrylic emulsion dope |
| CN103725127A (en) * | 2013-12-12 | 2014-04-16 | 青岛海洋新材料科技有限公司 | Marine climate resistant high-strength coating and preparation process thereof |
| CN104178010A (en) * | 2014-08-27 | 2014-12-03 | 句容市石狮冲压件厂 | Composite coating for outdoor deck chair and preparation method thereof |
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| CN104194601A (en) * | 2014-08-27 | 2014-12-10 | 句容市石狮冲压件厂 | Antiskid paint for bicycle court tracks and preparation method thereof |
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| CN105733422A (en) * | 2016-04-21 | 2016-07-06 | 苏州群力防滑材料有限公司 | Non-skid composition coating on deck |
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