CN106189618A - Ground non-skid coating and preparation method thereof - Google Patents

Ground non-skid coating and preparation method thereof Download PDF

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Publication number
CN106189618A
CN106189618A CN201610571058.0A CN201610571058A CN106189618A CN 106189618 A CN106189618 A CN 106189618A CN 201610571058 A CN201610571058 A CN 201610571058A CN 106189618 A CN106189618 A CN 106189618A
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China
Prior art keywords
ground
content
skid coating
parts
coating
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Pending
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CN201610571058.0A
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Chinese (zh)
Inventor
翟彬
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WUHU HAOXUAN NEW ENVIRONMENTAL PROTECTION MATERIAL Co Ltd
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WUHU HAOXUAN NEW ENVIRONMENTAL PROTECTION MATERIAL Co Ltd
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Priority to CN201610571058.0A priority Critical patent/CN106189618A/en
Publication of CN106189618A publication Critical patent/CN106189618A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D143/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
    • C09D143/04Homopolymers or copolymers of monomers containing silicon
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses ground non-skid coating and preparation method thereof, described ground non-skid coating is made up of following raw material: water, silicone acrylic emulsion, anti-wear agent, sclerosing agent, isopropanol, preservative, viscosity stabiliser and bentonite;In parts by weight, wherein, relative to 230 parts of silicone acrylic emulsions, the content of described water is 100 140 parts, the content of anti-wear agent is 30 70 parts, the content of sclerosing agent is 10 40 parts, the content of isopropanol is 30 60 parts, the content of preservative is 10 20 parts, the content of viscosity stabiliser is 30 70 parts, bentonitic content is 15 35 parts.It is good that ground disclosed by the invention non-skid coating has adhesive force, coarse and can be the most anti-skidding characteristic.

Description

Ground non-skid coating and preparation method thereof
Technical field
The present invention relates to coating prepare, be specifically related to ground non-skid coating and preparation method thereof.
Background technology
Coating can be coated in by different construction technologies to be protected or decorated body surface, and can be with coated article shape Become to adhere to firmly, there is some strength, continuous print solid film.The thin film common name film formed, also known as paint film or coating.Coating It is typically based on other preparations such as resin, oil, emulsion, cooperation pigment, additives, with formulated the mixing of organic solvent or water Compound.Currently, having many uses of coating is general, has decoration functions based on coating to be coated on the colored drawing picture of body surface, base The anticorrosion moisture barrier coatings etc. of body surface it is coated in the defencive function of coating.According to the purposes that coating is different, to coating Performance has the requirement of different aspect and degree.When coating is for ground, the non-skid property in addition to beautiful decoration, to coating There are more strict requirements.Currently, for ground especially outdoor ground coating through rainwater drench profit after, coating surface is the wettest Sliding, it is easily caused when pedestrian walks and slips.
Summary of the invention
It is an object of the invention to provide ground non-skid coating and preparation method thereof, the paint adhesion prepared by the method Good, coarse and can be the most anti-skidding.
To achieve these goals, the invention provides ground non-skid coating, be made up of following raw material: water, silicone acrylic emulsion, Anti-wear agent, sclerosing agent, isopropanol, preservative, viscosity stabiliser and bentonite;In parts by weight, wherein, relative to 230 parts of silicon Acrylic emulsion, the content of described water be 100-140 part, the content of anti-wear agent be 30-70 part, the content of sclerosing agent be 10-40 part, different The content of propanol be 30-60 part, the content of preservative be 10-20 part, the content of viscosity stabiliser be 30-70 part, bentonitic Content is 15-35 part.
Present invention also offers the preparation method of above-mentioned ground non-skid coating, the method includes: by 100-140 part water, 230 Part silicone acrylic emulsion and the mixing of 30-60 part isopropanol, obtained solution;Again by 30-70 part anti-wear agent, 10-40 part sclerosing agent, 10-20 Part preservative, 30-70 part viscosity stabiliser and 15-35 part bentonite add in above-mentioned solution, stirring mixing, prepare ground anti-skidding Coating.
By technique scheme, the present invention by being first stirred mixing in reaction vessel by the feed liquid of each weight portion Obtained solution, more each powder is added thereto mixing, under agitation it is in close contact between material, react generation association each other Same-action, thus prepare ground non-skid coating.The method is a kind of with low cost, mild condition, environmental protection and simple to operate Stirring means, it is good that prepared ground non-skid coating has adhesive force, coarse and can be the most anti-skidding characteristic.
Other features and advantages of the present invention will be described in detail in detailed description of the invention part subsequently.
Detailed description of the invention
Hereinafter the detailed description of the invention of the present invention is described in detail.It should be appreciated that described herein specifically Embodiment is merely to illustrate and explains the present invention, is not limited to the present invention.
The invention provides ground non-skid coating, be made up of following raw material: be water, silicone acrylic emulsion, anti-wear agent, sclerosing agent, different Propanol, preservative, viscosity stabiliser and bentonite;In parts by weight, wherein, relative to 230 parts of silicone acrylic emulsions, containing of described water Amount is 100-140 part, the content of anti-wear agent is 30-70 part, the content of sclerosing agent is 10-40 part, the content of isopropanol is 30-60 Part, the content of preservative be 10-20 part, the content of viscosity stabiliser be 30-70 part, bentonitic content be 15-35 part.
In the non-skid coating of above-mentioned ground, the concrete kind of anti-wear agent used can select in wide scope, but is The roughness of further raising ground non-skid coating, it is preferable that anti-wear agent is selected from fluvial sand, corundum, cement and rubber-plastic particle In one or more.
In the non-skid coating of above-mentioned ground, the concrete kind of sclerosing agent used can select in wide scope, but is The adhesive force of further raising ground non-skid coating, it is preferable that sclerosing agent is selected from vinyl triamine, diamino-cyclohexane, Asia One or more in methyl bicycle hexane amine and m-xylene diamine.
In the non-skid coating of above-mentioned ground, the concrete kind of preservative used can select in wide scope, but is The nonslip properties of further raising ground non-skid coating, it is preferable that preservative is selected from benzyl alcohol, phenethanol and chlorobutanol In one or more.
In the non-skid coating of above-mentioned ground, the concrete kind of viscosity stabiliser used can select in wide scope, but It is the effective nonslip properties in order to be further ensured that ground non-skid coating, it is preferable that viscosity stabiliser is selected from polyacrylamide, gathers One or more in vinylpyrrolidone and polyethylene glycol oxide.
Present invention also offers the preparation method of a kind of above-mentioned ground non-skid coating, the method includes: by described water, silicon third Emulsion and isopropanol mixing, obtained solution;Again described anti-wear agent, sclerosing agent, preservative, viscosity stabiliser and bentonite are added Described solution, stirring mixing, prepare described ground non-skid coating.
In above-mentioned preparation method, the temperature of mixing can select, from the preparation of ground non-skid coating in wide scope Consider on productivity and energy-conserving and environment-protective angle, it is preferable that the temperature of mixing is 10-35 DEG C.
In above-mentioned preparation method, speed and the time of stirring mixing can select in wide scope, but in order to enter What one step improved ground non-skid coating prepares productivity, it is preferable that the speed of stirring mixing is 1500-2000rpm, and the time is 8- 18h。
Hereinafter will be described the present invention by embodiment.
Embodiment 1
At 10 DEG C, select a reaction vessel, by the raw material of following weight portion: 100 parts of water, 230 parts of silicone acrylic emulsions and 30 Part isopropanol is under the rotating speed of 1500rpm, and stirring mixes, obtained solution;Again by 30 parts of fluvial sand, 10 parts of vinyl triamine, 10 parts Benzyl alcohol, 30 parts of polyacrylamides and 15 parts of bentonite add described solution, under the rotating speed of 1500rpm, and stirring mixing 18h, Prepare ground non-skid coating A1.
Embodiment 2
At 35 DEG C, select a reaction vessel, by the raw material of following weight portion: 140 parts of water, 230 parts of silicone acrylic emulsions and 60 Part isopropanol is under the rotating speed of 2000rpm, and stirring mixes, obtained solution;Again by 70 parts of corundum, 40 parts of diamino-cyclohexane, 20 parts of phenethanol, 70 parts of polyvinylpyrrolidones and 35 parts of bentonite add described solution, under the rotating speed of 2000rpm, and stirring Mixing 10h, prepares ground non-skid coating A2.
Embodiment 3
At 20 DEG C, select a reaction vessel, by the raw material of following weight portion: 120 parts of water, 230 parts of silicone acrylic emulsions and 50 Part isopropanol is under the rotating speed of 1800rpm, and stirring mixes, obtained solution;Again by 50 parts of cement, 25 parts of di-2-ethylhexylphosphine oxide hexamethylene Amine, 15 parts of chlorobutanols, 50 parts of polyethylene glycol oxides and 20 parts of bentonite add described solution, under the rotating speed of 1800rpm, stir Mix mixing 12h, prepare ground non-skid coating A3.
Embodiment 4
At 28 DEG C, select a reaction vessel, by the raw material of following weight portion: 110 parts of water, 230 parts of silicone acrylic emulsions and 35 Part isopropanol is under the rotating speed of 1600rpm, and stirring mixes, obtained solution;Again by 40 parts of rubber-plastic particles, 25 parts of m-xylene diamines, 17 parts of benzyl alcohol, 36 parts of polyvinylpyrrolidones and 31 parts of bentonite add described solution, under the rotating speed of 1600rpm, and stirring Mixing 14h, prepares ground non-skid coating A4.
Comparative example 1
Coating B1 is prepared relative to embodiment 1, except that, the consumption adding fluvial sand is 10 weight portions, vinyl three The consumption of amine is 5 weight portions.
Comparative example 2
Coating B2 is prepared relative to embodiment 2, except that, the consumption adding phenethanol is 5 weight portions, polyethylene pyrrole The consumption of pyrrolidone is 15 weight portions.
Detection example 1
The coating preparing above-described embodiment and comparative example uses portable pendulum tester to measure coefficient of sliding resistance, and concrete outcome is shown in Table 1.
Detection example 2
The coating preparing above-described embodiment and comparative example uses paint film adhesion algoscopy, marks according to GB1720-1979 Standard, detects relevant parameter, and concrete outcome is shown in Table 1.
Table 1
A1 A2 A3 A4 B1 B2
Coating state in a reservoir Without caking Without caking Without caking Without caking Caking Caking
Mohs' hardness 6 7 7 6 4 4
Skid resistance, BPN value 50 55 45 50 30 35
Paint Adhesion (method of drawing a circle) 3 3 3 2 5 6
Wherein, BPN represents portable pendulum tester, is used for representing coefficient of sliding resistance, is the evaluation index of antiskid performance, and BPN value answers 45, Skidproof effect can be reached;The non-skid coating Mohs' hardness that GB1720-1979 standard specifies answers 6, tack (method of drawing a circle) Answer 4;By above-mentioned detection example, the ground non-skid coating that the present invention provides meets GB1720-1979 standard, has attachment Power is good, coarse and can be the most anti-skidding effect, and preparation method is simple.
The preferred embodiment of the present invention described in detail above, but, the present invention is not limited in above-mentioned embodiment Detail, in the technology concept of the present invention, technical scheme can be carried out multiple simple variant, this A little simple variant belong to protection scope of the present invention.
It is further to note that each the concrete technical characteristic described in above-mentioned detailed description of the invention, at not lance In the case of shield, can be combined by any suitable means, in order to avoid unnecessary repetition, the present invention to various can The compound mode of energy illustrates the most separately.
Additionally, combination in any can also be carried out between the various different embodiment of the present invention, as long as it is without prejudice to this The thought of invention, by the raw material of each weight portion being stirred in reaction vessel mixing, the tightst between material Contact, react generation synergism each other, thus obtains ground non-skid coating, and it is public that it should be considered as present invention institute equally The content opened.

Claims (8)

1. a ground non-skid coating, it is characterised in that be made up of following raw material: water, silicone acrylic emulsion, anti-wear agent, sclerosing agent, different Propanol, preservative, viscosity stabiliser and bentonite;
In parts by weight, wherein, relative to 230 parts of silicone acrylic emulsions, the content of described water is 100-140 part, described anti-wear agent Content is 30-70 part, and the content of described sclerosing agent is 10-40 part, and the content of described isopropanol is 30-60 part, described preservative Content be 10-20 part, the content of described viscosity stabiliser is 30-70 part, and described bentonitic content is 15-35 part.
Ground the most according to claim 1 non-skid coating, wherein, described anti-wear agent is selected from fluvial sand, corundum, cement and rubber Mould one or more in granule.
Ground the most according to claim 1 non-skid coating, wherein, described sclerosing agent is selected from vinyl triamine, diamino basic ring One or more in hexane, di-2-ethylhexylphosphine oxide hexamethylene alkanamine and m-xylene diamine.
Ground the most according to claim 1 non-skid coating, wherein, described preservative is selected from benzyl alcohol, phenethanol and trichlorine One or more in the tert-butyl alcohol.
Ground the most according to claim 1 non-skid coating, wherein, described viscosity stabiliser is selected from polyacrylamide, poly-second One or more in alkene pyrrolidone and polyethylene glycol oxide.
6. the preparation method of the ground non-skid coating as described in any one in claim 1-5, it is characterised in that described Preparation method includes: described water, silicone acrylic emulsion and isopropanol are mixed, obtained solution;Again by described anti-wear agent, sclerosing agent, prevent Rotten agent, viscosity stabiliser and bentonite add described solution, stirring mixing, prepare described ground non-skid coating.
The preparation method of ground the most according to claim 6 non-skid coating, wherein, the temperature of described mixing is 10-35 DEG C, In described mixing, using the mode of stirring to mix, the speed of described stirring is 1500-2000rpm.
The preparation method of ground the most according to claim 6 non-skid coating, wherein, the speed of described stirring mixing is 1500-2000rpm, the time of described stirring mixing is 8-18h.
CN201610571058.0A 2016-07-20 2016-07-20 Ground non-skid coating and preparation method thereof Pending CN106189618A (en)

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Application Number Priority Date Filing Date Title
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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107142014A (en) * 2017-06-06 2017-09-08 合肥月煌新型装饰材料有限公司 A kind of ground anti-skid wearable coating and preparation method
CN107384059A (en) * 2017-06-30 2017-11-24 大冶特殊钢股份有限公司 A kind of non-skid coating and its preparation method and application
CN107418429A (en) * 2017-06-22 2017-12-01 合肥聪亨新型建材科技有限公司 A kind of ground non-skid coating in bathroom and preparation method thereof
CN111334135A (en) * 2018-12-18 2020-06-26 南京红枫环保材料有限公司 Anti-cracking quick-drying type stone-like paint and preparation method thereof
CN112552762A (en) * 2020-12-30 2021-03-26 平顶山环宇星防水科技有限公司 Composite waterproof system for accessible roof and construction method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102504679A (en) * 2011-10-17 2012-06-20 青岛爱尔家佳新材料有限公司 Novel anti-skidding coating for deck and preparation method thereof
CN103525213A (en) * 2013-09-03 2014-01-22 吴江市冰心文教用品有限公司 Anti-skid abrasion-resistant coating

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102504679A (en) * 2011-10-17 2012-06-20 青岛爱尔家佳新材料有限公司 Novel anti-skidding coating for deck and preparation method thereof
CN103525213A (en) * 2013-09-03 2014-01-22 吴江市冰心文教用品有限公司 Anti-skid abrasion-resistant coating

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107142014A (en) * 2017-06-06 2017-09-08 合肥月煌新型装饰材料有限公司 A kind of ground anti-skid wearable coating and preparation method
CN107418429A (en) * 2017-06-22 2017-12-01 合肥聪亨新型建材科技有限公司 A kind of ground non-skid coating in bathroom and preparation method thereof
CN107384059A (en) * 2017-06-30 2017-11-24 大冶特殊钢股份有限公司 A kind of non-skid coating and its preparation method and application
CN111334135A (en) * 2018-12-18 2020-06-26 南京红枫环保材料有限公司 Anti-cracking quick-drying type stone-like paint and preparation method thereof
CN112552762A (en) * 2020-12-30 2021-03-26 平顶山环宇星防水科技有限公司 Composite waterproof system for accessible roof and construction method thereof

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