CN111995291A - Waterborne epoxy acrylic acid modified bi-component pavement anti-skid paint and preparation method thereof - Google Patents
Waterborne epoxy acrylic acid modified bi-component pavement anti-skid paint and preparation method thereof Download PDFInfo
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- CN111995291A CN111995291A CN202010876315.8A CN202010876315A CN111995291A CN 111995291 A CN111995291 A CN 111995291A CN 202010876315 A CN202010876315 A CN 202010876315A CN 111995291 A CN111995291 A CN 111995291A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/10—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C04B26/14—Polyepoxides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00241—Physical properties of the materials not provided for elsewhere in C04B2111/00
- C04B2111/00362—Friction materials, e.g. used as brake linings, anti-skid materials
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00482—Coating or impregnation materials
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/0075—Uses not provided for elsewhere in C04B2111/00 for road construction
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/2038—Resistance against physical degradation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2265—Oxides; Hydroxides of metals of iron
- C08K2003/2272—Ferric oxide (Fe2O3)
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Ceramic Engineering (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Structural Engineering (AREA)
- Road Paving Structures (AREA)
- Paints Or Removers (AREA)
Abstract
The invention provides a waterborne epoxy acrylic acid modified bi-component pavement anti-skid coating, which comprises a component A and a component B. The component A contains water-based epoxy resin and water-based acrylic resin at the same time, so that the coating has better ductility, toughness and strength after being cured. In the preferable scheme of the invention, the color ceramic particles with different particle sizes are added into the coating as aggregate, so that the formed pavement has good skid resistance and wear resistance. The invention also provides a preparation method of the road surface anti-skid coating, which enables construction to be simpler and quicker, and two components are mixed and stirred for direct use without adding auxiliary materials. The material usage is lower, and can be recoated many times, and the secondary renovation is swift convenient, with low costs.
Description
Technical Field
The invention relates to the technical field of epoxy resin coatings, in particular to a water-based epoxy acrylic acid modified bi-component pavement anti-skid coating and a preparation method thereof.
Background
The epoxy resin is a high-performance resin variety and is widely applied. It has several advantages including strong forced adhesion to various base layers, high hardness of coating, good water resistance, chemical resistance and wear resistance, etc. and is commonly used in building coating and road surface coating.
The epoxy resin pavement paint has low requirement on a base surface and is well bonded with dry and wet base surfaces. However, the existing epoxy resin coating does not have good anti-skid property and wear resistance due to the problems of high brittleness, easy yellowing, easy pulverization and other rigidity and aging, so the epoxy resin coating needs to be modified.
In view of this, the invention is particularly proposed.
Disclosure of Invention
The first purpose of the invention is to provide a water-based epoxy acrylic acid modified two-component road surface antiskid coating.
The second purpose of the invention is to provide a preparation method of the coating.
In order to achieve the purpose, the technical scheme of the invention is as follows:
the invention relates to a water-based epoxy acrylic acid modified bi-component road surface anti-skid paint, which comprises a component A and a component B, wherein,
the component A comprises the following components in parts by weight: 25-40 parts of water-based epoxy resin, 5-15 parts of water-based acrylic resin, 0.1-1 part of water-based anti-settling agent, 0.05-0.5 part of water-based defoaming agent, 0.1-1 part of water-based dispersing agent, 0.05-0.5 part of wetting agent, 0.06-0.6 part of fumed silica, 0.1-1 part of organic bentonite, 1-10 parts of inorganic iron oxide pigment, 1-8 parts of talcum powder and 10-25 parts of silica fume.
The component B comprises the following components in parts by weight: 8-15 parts of a water-based epoxy curing agent and 3-10 parts of deionized water.
The mass ratio of the component A to the component B is (5-10) to 1.
Preferably, the mass ratio of the water-based epoxy resin to the water-based acrylic resin is (4-5): 1.
Preferably, the water-based anti-settling agent is selected from at least one of water-based system anti-settling agent HT200, German Bick BYK-420 water-based anti-settling agent, water-based anti-settling sagging agent/W-10 and water-based anti-settling dispersant XH-8400A.
Preferably, the aqueous dispersant is at least one selected from TEGO 750W aqueous dispersant, TEGO 760W aqueous dispersant, BYK180 aqueous dispersant and KX-5040 aqueous dispersant.
Preferably, the aqueous defoamer is selected from at least one of FT-301 defoamer, FT-3065 defoamer, TEGO AIREX902W defoamer, NOPROCEAC defoamer NXZ.
Preferably, the wetting agent is selected from at least one of wetting agents DA, BYK-220S, and ANTI-TERRA-203.
Preferably, the aqueous epoxy curing agent is an aliphatic polyamine curing agent selected from at least one of polyethylene polyamine, dimethylaminopropylamine, diethylaminopropylamine, trimethylhexamethylenediamine, and hexamethylenediamine modified product.
Preferably, the component A also comprises 50-100 parts of colored ceramic particles, and the particle size of the colored ceramic particles is 30-100 meshes.
Preferably, the color ceramic particles comprise color ceramic particles with the particle size of 30-50 meshes and color ceramic particles with the particle size of 60-100 meshes, and the mass ratio of the color ceramic particles to the color ceramic particles is 1: 1.
The invention also relates to a preparation method of the bi-component road surface antiskid coating, which comprises the following steps:
(1) preparation of the component A: uniformly mixing the fumed silica, the organic bentonite, the inorganic iron oxide pigment, the talcum powder, the wollastonite powder and the colored ceramic particles to obtain an inorganic mixture, then adding the aqueous epoxy resin and the aqueous acrylic resin into the inorganic mixture to be uniformly mixed, and then adding the aqueous anti-settling agent, the aqueous defoaming agent, the aqueous dispersing agent and the wetting agent to be uniformly mixed to obtain a component A;
(2) preparation of the component B: uniformly mixing the waterborne epoxy curing agent and deionized water to obtain a component B;
(3) and uniformly mixing the component A and the component B to obtain the bi-component road surface antiskid coating.
The invention has the beneficial effects that:
the invention provides a waterborne epoxy acrylic acid modified bi-component pavement anti-skid coating, which comprises a component A and a component B. The component A contains water-based epoxy resin and water-based acrylic resin at the same time, so that the coating has better ductility, toughness and strength after being cured.
In a preferred embodiment of the invention, colored ceramic particles of different particle sizes are added to the coating as aggregate. After the paint is demulsified and cured, the ceramic particles can be embedded in the paint and exposed out of the surface of the paint to form a non-slip surface. The high wear resistance of the color ceramic particle aggregate enables the formed pavement to have good skid resistance and wear resistance.
The invention also provides a preparation method of the road surface anti-skid coating, which enables construction to be simpler and quicker, and two components are mixed and stirred for direct use without adding auxiliary materials. The material usage is lower, and can be recoated many times, and the secondary renovation is swift convenient, with low costs.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more apparent, the technical solutions of the present invention will be described in detail below. It is to be understood that the described embodiments are merely exemplary of the invention, and not restrictive of the full scope of the invention. All other embodiments, which can be derived by a person skilled in the art from the examples given herein without any inventive step, are within the scope of the present invention.
The embodiment of the invention relates to a waterborne epoxy acrylic acid modified bi-component pavement anti-skid coating, which comprises a component A and a component B. Wherein the content of the first and second substances,
the component A comprises the following components in parts by weight: 25-40 parts of water-based epoxy resin, 5-15 parts of water-based acrylic resin, 0.1-1 part of water-based anti-settling agent, 0.05-0.5 part of water-based defoaming agent, 0.1-1 part of water-based dispersing agent, 0.05-0.5 part of wetting agent, 0.06-0.6 part of fumed silica, 0.1-1 part of organic bentonite, 1-10 parts of inorganic iron oxide pigment, 1-8 parts of talcum powder and 10-25 parts of silica fume.
The component B comprises the following components in parts by weight: 8-15 parts of a water-based epoxy curing agent and 3-10 parts of deionized water.
The mass ratio of the component A to the component B is (5-10): 1.
In one embodiment of the invention, the mass ratio of the water-based epoxy resin to the water-based acrylic resin is (4-5): 1. The applicant researches and discovers that when the component A is simultaneously used with the water-based epoxy resin and the water-based acrylic resin, the coating has better ductility, toughness and strength after being cured.
In one embodiment of the invention, the aqueous anti-settling agent is selected from at least one of aqueous system anti-settling agent HT200, ByK-420, waterborne anti-settling sagging/W-10, waterborne anti-settling dispersant XH-8400A. The water-based defoaming agent is at least one selected from FT-301 defoaming agent, FT-3065 defoaming agent, TEGO AIREX902W defoaming agent and NXZ defoaming agent in Nopock family. The aqueous dispersant is at least one selected from TEGO 750W aqueous dispersant, TEGO 760W aqueous dispersant, BYK180 aqueous dispersant and KX-5040 aqueous dispersant. The wetting agent is at least one selected from wetting agent DA, BYK-220S and ANTI-TERRA-203. The water-based epoxy curing agent is selected from aliphatic polyamine curing agents and at least one of polyethylene polyamine, dimethylamino propylamine, diethylamino propylamine, trimethyl hexamethylene diamine and hexamethylene diamine modified substances.
In one embodiment of the invention, the component A further comprises 50-100 parts of colored ceramic particles, and the particle size of the colored ceramic particles is 30-100 meshes. The applicant researches and discovers that the colored ceramic particles not only have a decoration effect, but also can be used as aggregate. After the paint is demulsified and cured, the ceramic particles can be embedded in the paint and exposed out of the surface of the paint to form a non-slip surface. The high wear resistance of the color ceramic particle aggregate enables the formed pavement to have good skid resistance and wear resistance.
Furthermore, the color ceramic particles comprise color ceramic particles with the particle size of 30-50 meshes and color ceramic particles with the particle size of 60-100 meshes, and the mass ratio of the color ceramic particles to the color ceramic particles is 1: 1. The coating surface satisfying the above ratio has the best anti-skid and wear-resistant properties.
The embodiment of the invention also relates to a preparation method of the bi-component road surface antiskid coating, which comprises the following steps:
(1) preparation of the component A: uniformly mixing fumed silica, organic bentonite, inorganic iron oxide pigment, talcum powder, wollastonite powder and colored ceramic particles to obtain an inorganic mixture, then adding aqueous epoxy resin and aqueous acrylic resin into the inorganic mixture to uniformly mix, and then adding an aqueous anti-settling agent, an aqueous defoaming agent, an aqueous dispersing agent and a wetting agent to uniformly mix to obtain a component A;
(2) preparation of the component B: uniformly mixing the waterborne epoxy curing agent and deionized water to obtain a component B;
(3) and uniformly mixing the component A and the component B to obtain the bi-component road surface antiskid coating.
In actual use, the prepared bi-component road surface antiskid coating is sprayed on a construction road surface by using spraying equipment, is uniformly coated by rolling by using a roller, and can be used after being cured.
Examples
The preparation method of the water-based epoxy acrylic acid modified two-component road surface anti-skid paint comprises the components A and B. Specific substances and contents of the A, B component in examples 1-6 and comparative example are shown in table 1.
TABLE 1
And (3) uniformly mixing the component A and the component B of the examples and the comparative examples according to the proportion, standing for 20min until bubbles are eliminated, uniformly coating the coating on the surface of the concrete sample plate, and curing to form a coating with the thickness of 1-2 mm. The mechanical properties of the coatings were tested and the results are shown in table 2.
TABLE 2
Comparing examples 2 and 3 with example 1, it is clear that when the mass ratio of the water-based epoxy resin to the water-based acrylic resin is not in the range of (4-5): 1, the mechanical properties of the coating layer are reduced, but the coefficient of dynamic friction is not changed.
Comparing examples 4 and 5 with example 1, it can be seen that the mechanical properties and the coefficient of dynamic friction of the coating do not vary much when the species and the amounts of the components are varied while the amounts of the species are still within the range required by the present invention.
Comparing example 6 with example 1, it can be seen that if the colored ceramic particles are not added, the mechanical properties of the coating are slightly improved, but the coefficient of dynamic friction of the coating is significantly reduced.
Comparing the comparative example with example 1, it can be seen that if only the waterborne epoxy resin is used and no waterborne acrylic resin is added, the mechanical properties of the coating are significantly reduced, but the coefficient of dynamic friction is not significantly changed.
The above description is only for the specific embodiments of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art can easily conceive of the changes or substitutions within the technical scope of the present invention, and all the changes or substitutions should be covered within the scope of the present invention. Therefore, the protection scope of the present invention shall be subject to the protection scope of the appended claims.
Claims (10)
1. A water-based epoxy acrylic acid modified bi-component road surface anti-skid paint comprises a component A and a component B, and is characterized in that,
the component A comprises the following components in parts by weight: 25-40 parts of water-based epoxy resin, 5-15 parts of water-based acrylic resin, 0.1-1 part of water-based anti-settling agent, 0.05-0.5 part of water-based defoaming agent, 0.1-1 part of water-based dispersing agent, 0.05-0.5 part of wetting agent, 0.06-0.6 part of fumed silica, 0.1-1 part of organic bentonite, 1-10 parts of inorganic iron oxide pigment, 1-8 parts of talcum powder and 10-25 parts of silica fume;
the component B comprises the following components in parts by weight: 8-15 parts of a water-based epoxy curing agent and 3-10 parts of deionized water;
the mass ratio of the component A to the component B is (5-10) to 1.
2. The two-component road surface antiskid coating of claim 1, wherein the mass ratio of the water-based epoxy resin to the water-based acrylic resin is (4-5): 1.
3. The two-component road surface anti-slip coating according to claim 1, wherein the water-based anti-settling agent is at least one selected from the group consisting of water-based system anti-settling agent HT200, ByK-420 water-based anti-settling agent Germany, water-based anti-settling sagging agent/W-10, and water-based anti-settling dispersant XH-8400A.
4. The two-component road surface anti-slip coating of claim 1, wherein the aqueous dispersant is at least one selected from the group consisting of TEGO 750W aqueous dispersant, TEGO 760W aqueous dispersant, BYK180 aqueous dispersant, KX-5040 aqueous dispersant.
5. The two-component road surface anti-slip coating of claim 1, wherein the aqueous defoamer is selected from at least one of FT-301 defoamer, FT-3065 defoamer, TEGO air 902W defoamer, nopinaceous defoamer NXZ.
6. The two-component road ANTI-slip coating of claim 1, wherein the wetting agent is selected from at least one of wetting agents DA, BYK-220S, and ANTI-tera-203.
7. The two-component road surface anti-slip coating according to claim 1, wherein the aqueous epoxy curing agent is an aliphatic polyamine curing agent selected from at least one of polyethylene polyamine, dimethylamino propylamine, diethylamino propylamine, trimethyl hexamethylene diamine, and hexamethylene diamine modification product.
8. The two-component road surface antiskid coating of claim 1, wherein the component A further comprises 50-100 parts of colored ceramic particles, and the particle size of the colored ceramic particles is 30-100 meshes.
9. The two-component road surface antiskid coating of claim 8, wherein the color ceramic particles comprise color ceramic particles with a particle size of 30-50 meshes and color ceramic particles with a particle size of 60-100 meshes, and the mass ratio of the color ceramic particles to the color ceramic particles is 1: 1.
10. A process for preparing a two-component road surface anti-slip coating according to claim 8 or 9, comprising the steps of:
(1) preparation of the component A: uniformly mixing the fumed silica, the organic bentonite, the inorganic iron oxide pigment, the talcum powder, the wollastonite powder and the colored ceramic particles to obtain an inorganic mixture, then adding the aqueous epoxy resin and the aqueous acrylic resin into the inorganic mixture to be uniformly mixed, and then adding the aqueous anti-settling agent, the aqueous defoaming agent, the aqueous dispersing agent and the wetting agent to be uniformly mixed to obtain a component A;
(2) preparation of the component B: uniformly mixing the waterborne epoxy curing agent and deionized water to obtain a component B;
(3) and uniformly mixing the component A and the component B to obtain the bi-component road surface antiskid coating.
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN112625544A (en) * | 2020-12-13 | 2021-04-09 | 四川鑫环球科技有限公司 | Water-based epoxy self-luminous anti-slip coating, preparation process and construction method thereof |
CN117186739A (en) * | 2023-02-27 | 2023-12-08 | 西安科技大学 | Composite resin material for repairing asphalt pavement diseases and preparation method thereof |
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KR20140052604A (en) * | 2012-10-25 | 2014-05-07 | 주식회사 투에이취켐 | Antislip coating materials |
CN109233566A (en) * | 2018-08-24 | 2019-01-18 | 西安瑞腾公路工程有限公司 | A kind of color antiskid thin layer and preparation method thereof |
CN109593428A (en) * | 2018-09-27 | 2019-04-09 | 河南天华交通科技有限公司 | A kind of epoxy antislip colour floor coatings and its preparation and construction method |
CN111039596A (en) * | 2019-12-25 | 2020-04-21 | 重庆鹏方交通科技股份有限公司 | Water-based colored anti-skid paving material and preparation method and application thereof |
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2020
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Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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KR20140052604A (en) * | 2012-10-25 | 2014-05-07 | 주식회사 투에이취켐 | Antislip coating materials |
CN109233566A (en) * | 2018-08-24 | 2019-01-18 | 西安瑞腾公路工程有限公司 | A kind of color antiskid thin layer and preparation method thereof |
CN109593428A (en) * | 2018-09-27 | 2019-04-09 | 河南天华交通科技有限公司 | A kind of epoxy antislip colour floor coatings and its preparation and construction method |
CN111039596A (en) * | 2019-12-25 | 2020-04-21 | 重庆鹏方交通科技股份有限公司 | Water-based colored anti-skid paving material and preparation method and application thereof |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN112625544A (en) * | 2020-12-13 | 2021-04-09 | 四川鑫环球科技有限公司 | Water-based epoxy self-luminous anti-slip coating, preparation process and construction method thereof |
CN112625544B (en) * | 2020-12-13 | 2024-03-01 | 四川鑫环球科技有限公司 | Water-based epoxy self-luminous anti-slip coating, preparation process and construction method thereof |
CN117186739A (en) * | 2023-02-27 | 2023-12-08 | 西安科技大学 | Composite resin material for repairing asphalt pavement diseases and preparation method thereof |
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