CN109233566A - A kind of color antiskid thin layer and preparation method thereof - Google Patents
A kind of color antiskid thin layer and preparation method thereof Download PDFInfo
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- CN109233566A CN109233566A CN201810970554.2A CN201810970554A CN109233566A CN 109233566 A CN109233566 A CN 109233566A CN 201810970554 A CN201810970554 A CN 201810970554A CN 109233566 A CN109233566 A CN 109233566A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J163/00—Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins
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- E—FIXED CONSTRUCTIONS
- E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
- E01C—CONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
- E01C11/00—Details of pavings
- E01C11/24—Methods or arrangements for preventing slipperiness or protecting against influences of the weather
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2265—Oxides; Hydroxides of metals of iron
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- Civil Engineering (AREA)
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- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
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- Road Paving Structures (AREA)
Abstract
The invention discloses a kind of color antiskid thin layers and preparation method thereof, and according to parts by weight, color antiskid thin layer is prepared from the following raw materials: 1~2.5 part of adhesive, 7~9 parts of aggregate and 0.1~0.5 part of protection layer for paint.Adhesive according to parts by weight, is made of following raw material: 100 parts of epoxy resin, 20~50 parts of curing agent, 1~8 part of pigment.Protection layer for paint according to parts by weight, is made of following raw material: 100 parts of epoxy resin, 20~50 parts of reactive diluent, 0.5~1.2 part of defoaming agent, 10~50 parts of filler, 1~8 part of pigment, 20~50 parts of curing agent.Curing agent according to parts by weight, is made of following raw material: 0~18 part of ethylenediamine, 0~14 part of diethylenetriamine, and 0~28 part of triethylene tetramine, 0~8.5 part of tetraethylenepentamine, 0~17 part of N- amine ethyl piperazidine, 1~5 part of amantadine.Color antiskid thin layer compression strength of the invention, tensile strength and shear strength are higher, and antiskid particles are not easily to fall off, antiskid is wear-resisting and are readily cleaned.
Description
Technical field
The invention belongs to municipal administration and highway construction technical fields, and in particular to a kind of color antiskid thin layer and its preparation side
Method.
Background technique
With China's urban construction and the fast development of road construction, there is tremendous promotion in quantity, but full
Sufficient people are also promoting the safety of highway communication and municipal traffic and the demand of quality.Especially in secure context, with grade separation
The increase of bridge and tunnel, the biggish road quantity of the gradient are consequently increased.In recent years, subtract haze for drop dirt, people more take
Bus or cycling trip.It, can be significant in the road surfacings color antiskid thin layer such as bus station, ramp, cycle track
Improve the safety of bus or bicycle running and stopped process.The Lamina of China's antiskid at present is asked there are still following
Topic: resistance to compression, tension and shear strength are insufficient, and antiskid particles are easy to fall off and the inconvenient stain resistance of cleaning is weak etc..
Summary of the invention
For the defects in the prior art and insufficient, the present invention provides a kind of color antiskid thin layer and its methods, overcome
Existing antiskid Lamina resistance to compression, tension and the insufficient defect of shear strength.
In order to achieve the above objectives, the invention adopts the following technical scheme:
A kind of color antiskid thin layer is prepared from the following raw materials according to parts by weight: 1~2.5 part of adhesive, aggregate 7~9
Part and 0.1~0.5 part of protection layer for paint.
Optionally, the adhesive according to parts by weight, is made of following raw material: 100 parts of epoxy resin, curing agent 20~
50 parts, 1~8 part of pigment.
Optionally, the protection layer for paint according to parts by weight, is made of following raw material: 100 parts of epoxy resin, activity is dilute
Release 20~50 parts of agent, 0.5~1.2 part of defoaming agent, 10~50 parts of filler, 1~8 part of pigment, 20~50 parts of curing agent.
Optionally, the curing agent according to parts by weight, is made of following raw material: 0~18 part of ethylenediamine, diethylenetriamine
0~14 part, 0~28 part of triethylene tetramine, 0~8.5 part of tetraethylenepentamine, 0~17 part of N- amine ethyl piperazidine, amantadine 1~5
Part.
Optionally, the epoxy resin is bisphenol A type epoxy resin；The epoxy resin is NEPL-128 type asphalt mixtures modified by epoxy resin
Rouge, E51 type epoxy resin or E44 type epoxy resin.
Optionally, the aggregate is ceramic particle, corundum grain or diamond dust；The partial size of the aggregate is 1mm~4mm.
Preferably, the color antiskid thin layer according to parts by weight, is prepared from the following raw materials: 1.5 parts of adhesive, aggregate 8
Part and 0.3 part of protection layer for paint；The adhesive according to parts by weight, is made of following raw material: 100 parts of epoxy resin, solidification
25 parts of agent, 5 parts of pigment；The protection layer for paint according to parts by weight, is made of following raw material: 100 parts of epoxy resin, activity is dilute
Release 42 parts of agent, 1 part of defoaming agent, 30 parts of filler, 5 parts of pigment, 25 parts of curing agent；The curing agent according to parts by weight, by following
Raw material composition: 14 parts of diethylenetriamine, 5 parts of triethylene tetramine, 3 parts of N- amine ethyl piperazidine, 3 parts of amantadine；
The epoxy resin is NEPL-128 type epoxy resin；
The partial size of the aggregate is the ceramic particle of 2mm~3.5mm.
The present invention also provides the preparation methods of the color antiskid thin layer, method includes the following steps:
Step 1, road surface pretreatment: road pavement basal plane polished, dried, dust removal process；
Step 2, adhesive coating: in step 1 treated roadway applications adhesive；
Step 3, pave aggregate: aggregate paving above the adhesive thin layer that step 2 is handled well in 1h, room temperature is solid
Change 6~remove extra aggregate afterwards for 24 hours；
Step 4, sprayed protection coating: the aggregate surface after step 3 is cured applies protection layer for paint by spraying.
Optionally, the adhesive the preparation method comprises the following steps: the raw material of curing agent is added in stirred tank, stirring and dissolving is standby
With；Stirred tank is added in epoxy resin, the curing agent dissolved will have been prepared under stirring and has been added by its mass fraction to asphalt mixtures modified by epoxy resin
In the stirred tank of rouge, pigment is added, is uniformly mixing to obtain adhesive；
The protection layer for paint the preparation method comprises the following steps: epoxy resin, reactive diluent, defoaming agent, filler and pigment are added
Enter in stirred tank, is stirring evenly and then adding into prepared curing agent and is again stirring for uniformly obtaining protection layer for paint.
Specifically, the amantadine is the primary amine with three-dimensional cagelike structure adamantane substituent group, concrete structure formula are as follows:
It is three-dimensional cagelike structure that end is formed after the primary amine group of amantadine is reacted with the epoxy group of epoxy resin
Long chain, specifically, the product structure that amantadine is reacted with bisphenol A type epoxy resin molecule:
Compared with prior art, the present invention beneficial has the technical effect that
(I) the color antiskid thin layer compression strength prepared by the present invention, tensile strength and shear strength are higher, anti-skidding
Particle is not easily to fall off, antiskid is wear-resisting and is readily cleaned.
(II) since the present invention is using the curing agent of various structures amine compounding, particularly with the addition of the organic of cage structure
Amine makes color antiskid thin layer prepared by the present invention compression strength, tensile strength and shear strength with higher.
(III) present invention sprays antiskid protective layer on antiskid aggregate surface, make that antiskid particles are not easily to fall off, wearability is good and
The advantages of road surface is readily cleaned.
(IV) the present invention provides a kind of hardener formula mentalities of designing, go in optimization antiskid thin layer from molecular structure angle
The reticular structure of macromolecular chain composition, and then improve its comprehensive performance.Amantadine is with three-dimensional cagelike structure in the present invention
The primary amine of adamantane substituent group.The long molecule that end is three-dimensional cagelike structure is formed after primary amine group is reacted with epoxy group
Chain.The structure is with following advantage: the adamantane group of solid cage modle present in molecular structure has stronger molecule
Rigidity, can enhance the compression strength of adhesive layer；Since the three-dimensional cage modle group of end of the chain adamantane group has biggish space bit
Resistance, can be improved the tensile strength of reticular structure.
Specific embodiment
In order to enable those skilled in the art to more fully understand, technical solution of the present invention is practiced, below with reference to specific
The invention will be further described for embodiment, but illustrated embodiment is not as a limitation of the invention.
Experimental method described in following each embodiments is unless otherwise specified conventional method.
Embodiment 1:
The present embodiment provides a kind of color antiskid thin layer and is prepared from the following raw materials according to parts by weight: 1.5 parts of adhesive,
8 parts and 0.3 part of protection layer for paint of aggregate.
Wherein, adhesive according to parts by weight, is made of following raw material: 100 parts of epoxy resin, 25 parts of curing agent, and pigment 5
Part；Curing agent according to parts by weight, is made of following raw material: 14 parts of diethylenetriamine, 5 parts of triethylene tetramine, and N- amine ethyl piperazine
3 parts of piperazine, 3 parts of amantadine.
Protection layer for paint according to parts by weight, is made of following raw material: 100 parts of epoxy resin, 42 parts of reactive diluent, being disappeared
1 part of infusion, 30 parts of filler, 5 parts of pigment, 25 parts of curing agent；Curing agent according to parts by weight, is made of following raw material: divinyl
14 parts of triamine, 5 parts of triethylene tetramine, 3 parts of N- amine ethyl piperazidine, 3 parts of amantadine.
In the present embodiment, epoxy resin NEPL-128；Aggregate is ceramic particle, and the partial size of aggregate is 2mm~3.5mm；
Reactive diluent is allyl glycidyl ether, defoaming agent HX-2013, filler are the silica of 400 mesh, pigment is oxidation
Iron.
The preparation method of the color antiskid thin layer of the present embodiment, method includes the following steps:
Step 1, road surface pretreatment: road pavement basal plane polished, dried, dust removal process；
Step 2, adhesive coating: in step 1 treated roadway applications adhesive；The preparation method of the adhesive
Are as follows: the raw material of curing agent is added in stirred tank, stirring and dissolving is spare；Stirred tank is added in epoxy resin, will have been matched under stirring
It makes the curing agent dissolved to be added by its mass fraction into the stirred tank of epoxy resin, adds pigment, be uniformly mixing to obtain
Adhesive.Adhesive dosage is 1.5kg/m2；
Step 3, pave aggregate: aggregate paving above the adhesive thin layer that step 2 is handled well in 1h, at room temperature
Solidify 8h, extra aggregate is removed after solidification；
Step 4, sprayed protection coating: the aggregate surface after step 3 is cured applies protection layer for paint by spraying, institute
State protection layer for paint the preparation method comprises the following steps: epoxy resin, reactive diluent, defoaming agent, filler and pigment are added in stirred tank,
It is stirring evenly and then adding into prepared curing agent to be again stirring for uniformly obtaining protection layer for paint, protection layer for paint dosage is 0.3kg/
m2。
Embodiment 2:
The present embodiment provides a kind of color antiskid thin layer and is prepared from the following raw materials according to parts by weight: 1 part of adhesive, bone
7 parts and 0.1 part of protection layer for paint of material.
Wherein, adhesive according to parts by weight, is made of following raw material: 100 parts of epoxy resin, 20 parts of curing agent, and pigment 1
Part；Curing agent according to parts by weight, is made of following raw material: 18 parts of ethylenediamine, 2 parts of amantadine.
Protection layer for paint according to parts by weight, is made of following raw material: 100 parts of epoxy resin, 20 parts of reactive diluent, being disappeared
0.5 part of infusion, 10 parts of filler, 1 part of pigment, 20 parts of curing agent；Curing agent according to parts by weight, is made of following raw material: second two
18 parts of amine, 2 parts of amantadine.
In the present embodiment, epoxy resin NEPL-128；Aggregate is corundum grain, and the partial size of aggregate is 1mm~4mm；Activity
Diluent is allyl glycidyl ether, defoaming agent HX-2013, filler are the silica of 400 mesh, pigment is iron oxide.
The preparation method of the color antiskid thin layer of the present embodiment, method includes the following steps:
Step 1, road surface pretreatment: road pavement basal plane polished, dried, dust removal process；
Step 2, adhesive coating: in step 1 treated roadway applications adhesive；The preparation method of the adhesive
Are as follows: the raw material of curing agent is added in stirred tank, stirring and dissolving is spare；Stirred tank is added in epoxy resin, will have been matched under stirring
It makes the curing agent dissolved to be added by its mass fraction into the stirred tank of epoxy resin, adds pigment, be uniformly mixing to obtain
Adhesive.Adhesive dosage is 1kg/m2；
Step 3, pave aggregate: aggregate paving above the adhesive thin layer that step 2 is handled well in 1h, at room temperature
Solidify 6h, extra aggregate is removed after solidification；
Step 4, sprayed protection coating: the aggregate surface after step 3 is cured applies protection layer for paint by spraying, institute
State protection layer for paint the preparation method comprises the following steps: epoxy resin, reactive diluent, defoaming agent, filler and pigment are added in stirred tank,
It is stirring evenly and then adding into prepared curing agent to be again stirring for uniformly obtaining protection layer for paint, protection layer for paint dosage is 0.1kg/
m2。
Embodiment 3:
The present embodiment provides a kind of color antiskid thin layer and is prepared from the following raw materials according to parts by weight: 2.5 parts of adhesive,
9 parts and 0.5 part of protection layer for paint of aggregate.
Wherein, adhesive according to parts by weight, is made of following raw material: 100 parts of epoxy resin, 50 parts of curing agent, and pigment 8
Part；Curing agent according to parts by weight, is made of following raw material: 4 parts of diethylenetriamine, 28 parts of triethylene tetramine, and N- amine ethyl piperazine
17 parts of piperazine, 1 part of amantadine.
Protection layer for paint according to parts by weight, is made of following raw material: 100 parts of epoxy resin, 50 parts of reactive diluent, being disappeared
1.2 parts of infusion, 50 parts of filler, 8 parts of pigment, 50 parts of curing agent；Curing agent according to parts by weight, is made of following raw material: diethyl
4 parts of alkene triamine, 28 parts of triethylene tetramine, 17 parts of N- amine ethyl piperazidine, 1 part of amantadine.
In the present embodiment, epoxy resin NEPL-128；Aggregate is diamond dust, and the partial size of aggregate is 2mm~4mm；Activity
Diluent is allyl glycidyl ether, defoaming agent HX-2013, filler are the silica of 400 mesh, pigment is iron oxide.
The preparation method of the color antiskid thin layer of the present embodiment, method includes the following steps:
Step 1, road surface pretreatment: road pavement basal plane polished, dried, dust removal process；
Step 2, adhesive coating: in step 1 treated roadway applications adhesive；The preparation method of the adhesive
Are as follows: the raw material of curing agent is added in stirred tank, stirring and dissolving is spare；Stirred tank is added in epoxy resin, will have been matched under stirring
It makes the curing agent dissolved to be added by its mass fraction into the stirred tank of epoxy resin, adds pigment, be uniformly mixing to obtain
Adhesive.Adhesive dosage is 2.5kg/m2；
Step 3, pave aggregate: aggregate paving above the adhesive thin layer that step 2 is handled well in 1h, at room temperature
Solidification removes extra aggregate for 24 hours, after solidification；
Step 4, sprayed protection coating: the aggregate surface after step 3 is cured applies protection layer for paint by spraying, institute
State protection layer for paint the preparation method comprises the following steps: epoxy resin, reactive diluent, defoaming agent, filler and pigment are added in stirred tank,
It is stirring evenly and then adding into prepared curing agent to be again stirring for uniformly obtaining protection layer for paint, protection layer for paint dosage is 0.5kg/
m2。
Embodiment 4:
The present embodiment provides a kind of color antiskid thin layer and is prepared from the following raw materials according to parts by weight: 1.5 parts of adhesive,
8 parts and 0.2 part of protection layer for paint of aggregate.
Wherein, adhesive according to parts by weight, is made of following raw material: 100 parts of epoxy resin, 30 parts of curing agent, and pigment 4
Part；Curing agent according to parts by weight, is made of following raw material: 11.5 parts of diethylenetriamine, 5 parts of triethylene tetramine, and four ethylene five
8.5 parts of amine, 5 parts of amantadine.
Protection layer for paint according to parts by weight, is made of following raw material: 100 parts of epoxy resin, 40 parts of reactive diluent, being disappeared
0.8 part of infusion, 35 parts of filler, 4 parts of pigment, 25 parts of curing agent；Curing agent according to parts by weight, is made of following raw material: diethyl
11.5 parts of alkene triamine, 8.5 parts of tetraethylenepentamine, 2.5 parts of N- amine ethyl piperazidine, 2.5 parts of amantadine.
In the present embodiment, epoxy resin E-51；Aggregate is ceramic particle, and the partial size of aggregate is 2mm~3.5mm；Activity
Diluent is allyl glycidyl ether, defoaming agent HX-2013, filler are the silica of 400 mesh, pigment is iron oxide.
The preparation method of the color antiskid thin layer of the present embodiment, method includes the following steps:
Step 1, road surface pretreatment: road pavement basal plane polished, dried, dust removal process；
Step 2, adhesive coating: in step 1 treated roadway applications adhesive；The preparation method of the adhesive
Are as follows: the raw material of curing agent is added in stirred tank, stirring and dissolving is spare；Stirred tank is added in epoxy resin, will have been matched under stirring
It makes the curing agent dissolved to be added by its mass fraction into the stirred tank of epoxy resin, adds pigment, be uniformly mixing to obtain
Adhesive.Adhesive dosage is 1.5kg/m2；
Step 3, pave aggregate: aggregate paving above the adhesive thin layer that step 2 is handled well in 1h, at room temperature
Solidify 8h, extra aggregate is removed after solidification；
Step 4, sprayed protection coating: the aggregate surface after step 3 is cured applies protection layer for paint by spraying, institute
State protection layer for paint the preparation method comprises the following steps: epoxy resin, reactive diluent, defoaming agent, filler and pigment are added in stirred tank,
It is stirring evenly and then adding into prepared curing agent to be again stirring for uniformly obtaining protection layer for paint, protection layer for paint dosage is 0.2kg/
m2。
Embodiment 5:
The present embodiment provides a kind of color antiskid thin layer and is prepared from the following raw materials according to parts by weight: 1.5 parts of adhesive,
9 parts and 0.2 part of protection layer for paint of aggregate.
Wherein, adhesive according to parts by weight, is made of following raw material: 100 parts of epoxy resin, 30 parts of curing agent, and pigment 4
Part；Curing agent according to parts by weight, is made of following raw material: 8 parts of ethylenediamine, 12 parts of diethylenetriamine, and N- amine ethyl piperazidine 5
Part, 5 parts of amantadine.
Protection layer for paint according to parts by weight, is made of following raw material: 100 parts of epoxy resin, 42 parts of reactive diluent, being disappeared
0.9 part of infusion, 25 parts of filler, 4 parts of pigment, 30 parts of curing agent；Curing agent according to parts by weight, is made of following raw material: second two
8 parts of amine, 12 parts of diethylenetriamine, 5 parts of N- amine ethyl piperazidine, 5 parts of amantadine.
In the present embodiment, epoxy resin E-44；Aggregate is ceramic particle, and the partial size of aggregate is 2mm~3.5mm；Activity
Diluent is allyl glycidyl ether, defoaming agent HX-2013, filler are the silica of 400 mesh, pigment is iron oxide.
The preparation method of the color antiskid thin layer of the present embodiment, method includes the following steps:
Step 1, road surface pretreatment: road pavement basal plane polished, dried, dust removal process；
Step 2, adhesive coating: in step 1 treated roadway applications adhesive；The preparation method of the adhesive
Are as follows: the raw material of curing agent is added in stirred tank, stirring and dissolving is spare；Stirred tank is added in epoxy resin, will have been matched under stirring
It makes the curing agent dissolved to be added by its mass fraction into the stirred tank of epoxy resin, adds pigment, be uniformly mixing to obtain
Adhesive.Adhesive dosage is 1.5kg/m2；
Step 3, pave aggregate: aggregate paving above the adhesive thin layer that step 2 is handled well in 1h, at room temperature
Solidify 12h, extra aggregate is removed after solidification；
Step 4, sprayed protection coating: the aggregate surface after step 3 is cured applies protection layer for paint by spraying, institute
State protection layer for paint the preparation method comprises the following steps: epoxy resin, reactive diluent, defoaming agent, filler and pigment are added in stirred tank,
It is stirring evenly and then adding into prepared curing agent to be again stirring for uniformly obtaining protection layer for paint, protection layer for paint dosage is 0.2kg/
m2。
Comparative example 1:
The difference of this comparative example and embodiment 1 is the curing agent in adhesive and protection layer for paint in this comparative example
Using commercially available T31 type curing agent, dosage and preparation method are same as Example 1.
Comparative example 2:
The difference of this comparative example and embodiment 4 is the curing agent in adhesive and protection layer for paint in this comparative example
Using commercially available 593 type curing agent, dosage and preparation method are same as Example 4.
Comparative example 3:
The difference of this comparative example and embodiment 5 is the curing agent in adhesive and protection layer for paint in this comparative example
Using commercially available T31 type curing agent, dosage and preparation method are same as Example 5.
It is detected using antiskid layer material of JT/T 712-2008 and the HG/T3829-2006 standard method to preparation,
Wherein the projects such as appearance of film, water resistance, alkali resistance, coating low-temperature cracking-resistance and artificial acceleration weatherability, which comply with standard, wants
It asks.Other correlated performances are shown in Table 1.
The performance test results of 1 embodiment of the present invention of table and comparative example
The result shows that the performance indicator of color antiskid thin layer of the invention has reached professional standard, part index number is as sheared
The indexs such as intensity, tensile strength, elongation at break, coefficient of friction, compression strength and wearability are higher.Though and comparative example
There are partial properties to reach standard, but still there is part index number to be not up to standard requirements.As the result is shown using the method for the present invention preparation
Color antiskid thin layer has many advantages, such as that compression strength, shear strength are high, and antiskid particles are not easily to fall off, antiskid wearability is good.
Claims (9)
1. a kind of color antiskid thin layer, which is characterized in that according to parts by weight, be prepared from the following raw materials: 1~2.5 part of adhesive,
7~9 parts and 0.1~0.5 part of protection layer for paint of aggregate.
2. color antiskid thin layer as described in claim 1, which is characterized in that the adhesive according to parts by weight, by following
Raw material composition: 100 parts of epoxy resin, 20~50 parts of curing agent, 1~8 part of pigment.
3. color antiskid thin layer as described in claim 1, which is characterized in that the protection layer for paint according to parts by weight, by
Following raw material composition: 100 parts of epoxy resin, 20~50 parts of reactive diluent, 0.5~1.2 part of defoaming agent, 10~50 parts of filler,
1~8 part of pigment, 20~50 parts of curing agent.
4. color antiskid thin layer as claimed in claim 2 or claim 3, which is characterized in that the curing agent according to parts by weight, by with
Lower raw material composition: 0~18 part of ethylenediamine, 0~14 part of diethylenetriamine, 0~28 part of triethylene tetramine, tetraethylenepentamine 0~8.5
Part, 0~17 part of N- amine ethyl piperazidine, 1~5 part of amantadine.
5. color antiskid thin layer as claimed in claim 2 or claim 3, which is characterized in that the epoxy resin is bisphenol type epoxy tree
Rouge；The epoxy resin is NEPL-128 type epoxy resin, E51 type epoxy resin or E44 type epoxy resin.
6. color antiskid thin layer as described in claim 1, which is characterized in that the aggregate is ceramic particle, corundum grain or gold
Emery；The partial size of the aggregate is 1mm~4mm.
7. color antiskid thin layer as claimed in claim 2 or claim 3, which is characterized in that the color antiskid thin layer is in parts by weight
Meter, is prepared from the following raw materials: 1.5 parts of adhesive, 8 parts and 0.3 part of protection layer for paint of aggregate；
The adhesive according to parts by weight, is made of following raw material: 100 parts of epoxy resin, 25 parts of curing agent, 5 parts of pigment；
The protection layer for paint according to parts by weight, is made of following raw material: 100 parts of epoxy resin, 42 parts of reactive diluent, being disappeared
1 part of infusion, 30 parts of filler, 5 parts of pigment, 25 parts of curing agent；
The curing agent according to parts by weight, is made of following raw material: 14 parts of diethylenetriamine, 5 parts of triethylene tetramine, and N- amine second
3 parts of base piperazine, 3 parts of amantadine；
The epoxy resin is NEPL-128 type epoxy resin；
The partial size of the aggregate is the ceramic particle of 2mm~3.5mm.
8. the preparation method of color antiskid thin layer described in claim 1, which is characterized in that method includes the following steps:
Step 1, road surface pretreatment: road pavement basal plane polished, dried, dust removal process；
Step 2, adhesive coating: in step 1 treated roadway applications adhesive；
Step 3, pave aggregate: aggregate paved above the adhesive thin layer that step 2 is handled well in 1h, room temperature curing 6
~remove extra aggregate afterwards for 24 hours；
Step 4, sprayed protection coating: the aggregate surface after step 3 is cured applies protection layer for paint by spraying.
9. the preparation method of color antiskid thin layer as claimed in claim 8, which is characterized in that the preparation method of the adhesive
Are as follows: the raw material of curing agent is added in stirred tank, stirring and dissolving is spare；Stirred tank is added in epoxy resin, will have been matched under stirring
It makes the curing agent dissolved to be added by its mass fraction into the stirred tank of epoxy resin, adds pigment, be uniformly mixing to obtain
Adhesive；
The protection layer for paint stirs the preparation method comprises the following steps: epoxy resin, reactive diluent, defoaming agent, filler and pigment are added
It mixes in kettle, is stirring evenly and then adding into prepared curing agent and is again stirring for uniformly obtaining protection layer for paint.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810970554.2A CN109233566B (en) | 2018-08-24 | 2018-08-24 | Color anti-skid thin layer and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810970554.2A CN109233566B (en) | 2018-08-24 | 2018-08-24 | Color anti-skid thin layer and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN109233566A true CN109233566A (en) | 2019-01-18 |
| CN109233566B CN109233566B (en) | 2020-09-04 |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111495709A (en) * | 2020-04-22 | 2020-08-07 | 张俊 | Coating process for inner wall of connecting sleeve capable of resisting impact torsion and connecting sleeve |
| WO2020204011A1 (en) * | 2019-03-29 | 2020-10-08 | 首都高メンテナンス神奈川株式会社 | Hardener, anti-slip coating agent, anti-slip coating cover forming method and anti-slip covering material |
| CN111995291A (en) * | 2020-08-27 | 2020-11-27 | 江苏美沥特道路面材料有限公司 | Waterborne epoxy acrylic acid modified bi-component pavement anti-skid paint and preparation method thereof |
| CN114436566A (en) * | 2022-03-17 | 2022-05-06 | 广东悦谷道路材料有限公司 | Antiskid mat surface protective agent and preparation method thereof |
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| CN204080586U (en) * | 2014-08-13 | 2015-01-07 | 重庆重交沥青砼再生制造有限公司 | A kind of colored wear-resisting antiskid road structure |
| JP5907543B1 (en) * | 2014-10-14 | 2016-04-26 | 株式会社植木組 | Lining board and manufacturing method thereof |
| CN105837159A (en) * | 2016-03-18 | 2016-08-10 | 派丽(上海)管理有限公司 | High-performance neutral tile bonding material |
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN204080586U (en) * | 2014-08-13 | 2015-01-07 | 重庆重交沥青砼再生制造有限公司 | A kind of colored wear-resisting antiskid road structure |
| JP5907543B1 (en) * | 2014-10-14 | 2016-04-26 | 株式会社植木組 | Lining board and manufacturing method thereof |
| CN105837159A (en) * | 2016-03-18 | 2016-08-10 | 派丽(上海)管理有限公司 | High-performance neutral tile bonding material |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2020204011A1 (en) * | 2019-03-29 | 2020-10-08 | 首都高メンテナンス神奈川株式会社 | Hardener, anti-slip coating agent, anti-slip coating cover forming method and anti-slip covering material |
| CN111495709A (en) * | 2020-04-22 | 2020-08-07 | 张俊 | Coating process for inner wall of connecting sleeve capable of resisting impact torsion and connecting sleeve |
| CN111995291A (en) * | 2020-08-27 | 2020-11-27 | 江苏美沥特道路面材料有限公司 | Waterborne epoxy acrylic acid modified bi-component pavement anti-skid paint and preparation method thereof |
| CN114436566A (en) * | 2022-03-17 | 2022-05-06 | 广东悦谷道路材料有限公司 | Antiskid mat surface protective agent and preparation method thereof |
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| CN109233566B (en) | 2020-09-04 |
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