CN102093802A - Method for preparing fluorine-containing latex paint - Google Patents
Method for preparing fluorine-containing latex paint Download PDFInfo
- Publication number
- CN102093802A CN102093802A CN 201110031523 CN201110031523A CN102093802A CN 102093802 A CN102093802 A CN 102093802A CN 201110031523 CN201110031523 CN 201110031523 CN 201110031523 A CN201110031523 A CN 201110031523A CN 102093802 A CN102093802 A CN 102093802A
- Authority
- CN
- China
- Prior art keywords
- add
- fluorine
- rotating speed
- sand milling
- emulsion paint
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003973 paint Substances 0.000 title claims abstract description 47
- 239000011737 fluorine Substances 0.000 title claims abstract description 31
- 229910052731 fluorine Inorganic materials 0.000 title claims abstract description 31
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 title claims abstract description 30
- 239000004816 latex Substances 0.000 title claims abstract description 10
- 229920000126 latex Polymers 0.000 title claims abstract description 10
- 238000000034 method Methods 0.000 title abstract description 6
- 239000000839 emulsion Substances 0.000 claims abstract description 61
- 238000003756 stirring Methods 0.000 claims abstract description 26
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims abstract description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229920002313 fluoropolymer Polymers 0.000 claims abstract description 10
- 239000004811 fluoropolymer Substances 0.000 claims abstract description 10
- 239000002562 thickening agent Substances 0.000 claims abstract description 8
- 239000000080 wetting agent Substances 0.000 claims abstract description 8
- 238000005303 weighing Methods 0.000 claims abstract description 7
- 238000003801 milling Methods 0.000 claims description 30
- 239000004576 sand Substances 0.000 claims description 30
- 239000002002 slurry Substances 0.000 claims description 18
- 239000013530 defoamer Substances 0.000 claims description 13
- 238000002360 preparation method Methods 0.000 claims description 13
- 230000008719 thickening Effects 0.000 claims description 13
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 12
- 239000006185 dispersion Substances 0.000 claims description 11
- 239000002253 acid Substances 0.000 claims description 8
- 239000003513 alkali Substances 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- 238000004581 coalescence Methods 0.000 claims description 7
- 239000000463 material Substances 0.000 claims description 7
- 239000005995 Aluminium silicate Substances 0.000 claims description 6
- 241000276489 Merlangius merlangus Species 0.000 claims description 6
- 235000012211 aluminium silicate Nutrition 0.000 claims description 6
- 238000010009 beating Methods 0.000 claims description 6
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 6
- 239000004922 lacquer Substances 0.000 claims description 6
- 239000004408 titanium dioxide Substances 0.000 claims description 6
- 239000002585 base Substances 0.000 claims description 5
- 239000000049 pigment Substances 0.000 claims description 5
- 239000001913 cellulose Substances 0.000 claims description 4
- 229920002678 cellulose Polymers 0.000 claims description 4
- 230000008961 swelling Effects 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 238000004140 cleaning Methods 0.000 abstract description 5
- 238000004519 manufacturing process Methods 0.000 abstract description 5
- 235000011114 ammonium hydroxide Nutrition 0.000 abstract description 4
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 abstract description 2
- 230000001105 regulatory effect Effects 0.000 abstract 3
- 239000002518 antifoaming agent Substances 0.000 abstract 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 abstract 1
- 239000002270 dispersing agent Substances 0.000 abstract 1
- 239000000945 filler Substances 0.000 abstract 1
- 239000003755 preservative agent Substances 0.000 abstract 1
- 230000002335 preservative effect Effects 0.000 abstract 1
- 238000005187 foaming Methods 0.000 description 20
- 238000001035 drying Methods 0.000 description 8
- 230000003712 anti-aging effect Effects 0.000 description 5
- 230000001680 brushing effect Effects 0.000 description 4
- 239000004568 cement Substances 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 238000011056 performance test Methods 0.000 description 4
- 239000004033 plastic Substances 0.000 description 4
- 210000002268 wool Anatomy 0.000 description 4
- 238000005299 abrasion Methods 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- 150000001721 carbon Chemical class 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 2
- 239000002223 garnet Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000012855 volatile organic compound Substances 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- -1 TEXANOL alcohol ester Chemical class 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 150000002221 fluorine Chemical class 0.000 description 1
- 230000008447 perception Effects 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a method for preparing a fluorine-containing latex paint, which comprises the following steps of: weighing 18 to 40 weight parts of water, 0.3 to 0.5 weight part of propylene glycol, dispersing at a rotating speed of 400 to 600r/min, adding 0.1 to 0.3 part of wetting agent, 0.3 to 0.5 part of dispersing agent and 0.2 to 0.3 part of defoaming agent, regulating the rotating speed to be 1,200-1,500r/min, adding 28 to 35 parts of filler and dispersing for 20 to 30 minutes; regulating the rotating speed to be 800-1,200r/min, and sanding for 30 to 60 minutes; cleaning size by using 6 to 10 parts of water; and adding 0.1 to 0.3 part of defoaming agent and 1.2 to 1.5 parts of film forming aid at a rotating speed of 400 to 600r/min, stirring for 10 to 20 minutes, adding 25 to 40 parts of emulsion and 3 to 15 parts of fluoropolymer emulsion, regulating the pH to be 7-9 by using ammonia water or multifunctional aid AMP-95, adding 0.2 to 0.7 part of thickening agent and 0.6 to 1.2 parts of preservative, and stirring for 10 to 20 minutes to obtain the fluorine-containing latex paint. The method is simple in production process; the fluoropolymer emulsion is directly applied to the latex paint, and the excellent self-cleaning performance, weather resistance and stain resistance of C-F bonds are fully reflected; and the prepared fluorine-containing latex paint is environment-friendly, safe and high in cost performance.
Description
Technical field
The present invention relates to the preparation method of the fluorine-containing emulsion paint of a kind of used for building exterior wall.
Background technology
Because people are to the enhancing day by day of environmental protection and self health perception, emulsion paint is just low and progressively replace in the fitting-out work that solvent based coating is applied to external wall with its volatile organic compounds (VOC) content.At present common emulsion paint abrasion resistance, self-cleaning property, acid resistance, alkali resistance, weathering resistance, resistance to soiling are poor, in order to improve the above-mentioned shortcoming of architectural latex coating, released on the market have overlength weathering resistance, resistance to soiling and acid resistance, alkali-proof fluorocarbon coating, fluorocarbon coating is because the employing Fluorine containing olefine is a raw material, copolymerization under certain pressure, the production investment is big, starting material are expensive, and cost is higher.Also do not have production technique simple at present, have good abrasion resistance, self-cleaning property, acid resistance, alkali resistance, weathering resistance, resistance to soiling, and emulsion paint with low cost.
Summary of the invention
It is simple that technical problem to be solved by this invention provides a kind of production technique, has good abrasion resistance, acid resistance, alkali resistance, weathering resistance, resistance to soiling, and the preparation method of fluorine-containing emulsion paint with low cost.
Technical solution of the present invention is:
A kind of preparation method of fluorine-containing emulsion paint, its step is as follows:
1. making beating: take by weighing water 18-40 part, propylene glycol 0.3-0.5 part and mixing according to the parts by weight meter, under the 400-600r/min rotating speed, disperse, add wetting agent 0.1-0.3 part, dispersion agent 0.3-0.5 part, defoamer 0.2-0.3 part, add 5-10 part kaolin, 5-13 part coarse whiting and 2-20 part titanium dioxide, rotating speed transfers to 1200-1500r/min, disperses 20-30min;
2. sand milling: scattered slurry is carried out sand milling, and rotating speed is 800-1200r/min, sand milling 30-60min; Clean slurry with 6-10 part water behind the sand milling;
3. system is coated with lacquer: under the 400-600r/min rotating speed, stir the good slurry of sand milling, add defoamer 0.1-0.3 part, film coalescence aid 1.2-1.5 part, behind the stirring 10-20min, add 25-40 part emulsion, described emulsion is organosilicon crylic acid latex, pure-acrylic emulsion or the mixture of the two, and 3-15 part fluoropolymer emulsion is transferred PH to 7-9, add thickening material 0.2-0.7 part and carry out thickening, add 0.6-1.2 part sanitas again, stir 10-20min, make fluorine-containing emulsion paint.
Above-mentioned thickening material is alkali swelling type thickening material, associative thickener or cellulose thickener.
The preparation method of above-mentioned fluorine-containing emulsion paint also adds 2-10 part pigment or mill base in (2) step or (3) step, make the fluorine-containing emulsion paint of respective color.
The present invention adopts the mode that adds fluoropolymer emulsion to obtain the preparation method of fluorine-containing emulsion paint, fluoropolymer emulsion is applied directly in the emulsion paint, demonstrate fully self-cleaning property, weathering resistance, the resistance to soiling of the excellence of C-F key, the fluorine-containing emulsion paint environmental protection, safety, the cost performance height that make.Fluorine-containing emulsion paint is detected, and washability 9000 times changes, and water-fast 200 hours non-foaming, dry lintings not allow slight loss of gloss and variable color; Acidproof 110 hours non-foaming, dry lintings not allow slight loss of gloss and variable color; Alkaline-resisting 110 hours non-foaming, and dry linting does not allow slight loss of gloss and variable color, and anti-aging test 3000 hours is non-foaming, do not peel off, do not have and split.
Embodiment
Embodiment 1
1. making beating: take by weighing end water 18.0g, propylene glycol 0.3g in the 500ml plastic beaker, open dispersion machine, turn fast 400r/min, add wetting agent 4010 0.1g, dispersion agent 1124 0.3g, defoamer BYK-014 0.2g respectively in container, stir; Rotating speed is transferred to 1200r/min, add kaolin 5.0g, coarse whiting 13.0g, titanium dioxide 10g, disperse 20min.
2. sand milling: scattered slurry is carried out sand milling, rotating speed 1200r/min sand milling 30min; Clean slurry with 6g water behind the sand milling.
3. system is coated with lacquer: the rotating speed with 400r/min stirs the good slurry of sand milling, add defoamer BYK-014 0.1g, film coalescence aid TEXANOL alcohol ester 1.2g, behind the stirring 20min, add pure-acrylic emulsion 30g, organosilicon crylic acid latex 10g, fluoropolymer emulsion 3g, multifunctional assistant AMP-95 transfers pH value to 8; Begin to add alkali swelling type thickening material 0.2g and carry out thickening, add sanitas 0.6g, stir 10min, obtain white fluorine-containing emulsion paint.
The emulsion paint preparation of specimen with wool brush brushing first road on cement plate, is treated the above-mentioned white fluorine-containing emulsion paint that makes to brush second road again behind the surface drying, and natural drying at room temperature carries out every performance test after 7 days.Fluorine-containing emulsion paint detects, No. 9000 no changes of washability, and water-fast 200 hours non-foaming, dry lintings not allow slight loss of gloss and variable color, and acidproof 110 hours non-foaming, dry lintings not allow slight loss of gloss and variable color; Alkaline-resisting 110 hours non-foaming, and dry linting does not allow slight loss of gloss and variable color, and anti-aging test 3000 hours is non-foaming, do not peel off, do not have and split.
Embodiment 2
1. making beating: take by weighing water 40.0g, propylene glycol 0.5g in the 500ml plastic beaker, open dispersion machine, turn fast 600r/min, add wetting agent X-405 0.3g, dispersion agent 5040 0.5g, defoamer BYK-088 0.3g respectively in container, stir.Rotating speed is transferred 1500r/min, add kaolin 10g, coarse whiting 5.0g, titanium dioxide 20g, disperse 30min.
2. sand milling: with scattered slurry, add the 2g carbon black pigment and carry out sand milling, rotating speed 800r/min sand milling 60min.Clean slurry with 10g water behind the sand milling.
3. make lacquer: the rotating speed with 600r/min stirs the good slurry of sand milling, adds defoamer BYK-088 0.3g, film coalescence aid 12 carbon esters alcohol 1.5g, behind the stirring 10min, adds organosilicon crylic acid latex 33g, and fluoropolymer emulsion 15g adds ammoniacal liquor and transfers pH value to 9; Associative thickener 0.7g carries out thickening, adds sanitas 1.0g, stirs 20min, obtains the fluorine-containing emulsion paint of grey.
The emulsion paint preparation of specimen, the fluorine-containing emulsion paint of above-mentioned acquisition grey with wool brush cement plate in standard code on brushing first road, treat to brush second road again behind the surface drying, natural drying at room temperature carries out every performance test after 7 days.
This fluorine-containing emulsion paint is detected, No. 10000 no changes of washability, water-fast 220 hours non-foaming, dry lintings not allow slight loss of gloss and variable color, and acidproof 124 hours non-foaming, dry lintings not allow slight loss of gloss and variable color; Alkaline-resisting 124 hours non-foaming, and dry linting does not allow slight loss of gloss and variable color, and anti-aging test 3500 hours is non-foaming, do not peel off, do not have and split.
Embodiment 3
1. making beating: take by weighing water 30.0g, propylene glycol 0.4g in the 500ml plastic beaker, open dispersion machine, turn fast 500r/min, add wetting agent PE-100 0.2g, dispersion agent SU860 0.4g, defoamer BYK-037 0.25g respectively in container, stir.Rotating speed is transferred 1300r/min, add kaolin 8g, coarse whiting 10g, titanium dioxide 2g, disperse 26min.
2. sand milling: scattered slurry is carried out sand milling, rotating speed 1000r/min sand milling 40min; Clean slurry with 8g water behind the sand milling.
3. system is coated with lacquer: the rotating speed with 500r/min stirs the good slurry of sand milling, adds defoamer BYK-037 0.2g, film coalescence aid silicon sol 1.3g, behind the stirring 15min, adds pure-acrylic emulsion 25g, fluoropolymer emulsion 10g.Add ammoniacal liquor and transfer pH value 7; Add cellulose thickener 0.5g and carry out thickening, add sanitas 1.2g, stir 15min, make white fluorine-containing emulsion paint.
4. toning
Add 2g iron oxide red mill base, the 8g redness is starched in the fluorine-containing emulsion paint of above-mentioned white, 600r/min stirs 15min, obtains the fluorine-containing emulsion paint of garnet.
The emulsion paint preparation of specimen with wool brush brushing first road on the cement plate of standard code, is treated the fluorine-containing emulsion paint of the above-mentioned garnet that makes to brush second road again behind the surface drying, and natural drying at room temperature carries out every performance test after 7 days.
Fluorine-containing emulsion paint detects, No. 12000 no changes of washability, and water-fast 260 hours non-foaming, dry lintings not allow slight loss of gloss and variable color; Acidproof 130 hours non-foaming, dry lintings not allow slight loss of gloss and variable color; Alkaline-resisting 124 hours non-foaming, and dry linting does not allow slight loss of gloss and variable color, and anti-aging test 3500 hours is non-foaming, do not peel off, do not have and split.
Pigment among the embodiment 2-embodiment 3 and mill base can replace obtaining the emulsion paint of respective color with other pigment and mill base.
Comparative Examples
1. making beating: take by weighing water 25.0g, propylene glycol 0.4g in the 500ml plastic beaker, open dispersion machine, turn fast 500r/min, add wetting agent WR-300 0.2g, dispersion agent 6009 0.4g, defoamer BYK-088 0.25g respectively in container, stir; Rotating speed is transferred 1300r/min, add kaolin 8g, coarse whiting 10g, titanium dioxide 2g, disperse 26min.
2. sand milling: scattered slurry is carried out sand milling, rotating speed 1000r/min sand milling 40min; Clean slurry with 8g water behind the sand milling.
3. make lacquer: the rotating speed with 500r/min stirs the good slurry of sand milling, adds defoamer BYK-088 0.2g, film coalescence aid 12 carbon esters alcohol 1.3g, behind the stirring 15min, adds pure-acrylic emulsion 40g, adds ammoniacal liquor and transfers pH value to 7; Add cellulose thickener 0.5g and carry out thickening, add sanitas 1.2g, stir 15min, make pure third emulsion paint of white.
4. toning: add the 8g redness and starch in pure third emulsion paint of above-mentioned white, stir 15min, obtain red pure third emulsion paint in 600r/min.
The emulsion paint preparation of specimen with wool brush brushing first road on the cement plate of standard code, is treated red pure third emulsion paint of above-mentioned acquisition to brush second road again behind the surface drying, and natural drying at room temperature carries out every performance test after 7 days.
This emulsion paint is detected, No. 3000 no changes of washability, water-fast 100 hours non-foaming, dry lintings not allow slight loss of gloss and variable color; Acidproof 48 hours non-foaming, dry lintings not allow slight loss of gloss and variable color; Alkaline-resisting 56 hours non-foaming, and dry linting does not allow slight loss of gloss and variable color, and anti-aging test 800 hours is non-foaming, do not peel off, do not have and split.
Wetting agent, dispersion agent, defoamer and film coalescence aid in above-mentioned example 1-example 3 and the Comparative Examples also can be respectively replaces with the like product of other model.
By above test, this invention production technique is simple, and raw material is easy to get, and adds that the performance of the emulsion paint of fluoropolymer and pure third emulsion paint is more washablely rinsed, acidproof, alkali resistance and ageing resistance all increase, and represented the excellent properties of fluorine-containing emulsion paint.
Claims (3)
1. the preparation method of a fluorine-containing emulsion paint is characterized in that:
(1) making beating: take by weighing water 18-40 part, propylene glycol 0.3-0.5 part and mixing according to the parts by weight meter, under the 400-600r/min rotating speed, disperse, add wetting agent 0.1-0.3 part, dispersion agent 0.3-0.5 part, defoamer 0.2-0.3 part, add 5-10 part kaolin, 5-13 part coarse whiting and 2-20 part titanium dioxide, rotating speed transfers to 1200-1500r/min, disperses 20-30min;
(2) sand milling: scattered slurry is carried out sand milling, and rotating speed is 800-1200r/min, sand milling 30-60min; Clean slurry with 6-10 part water behind the sand milling;
(3) system lacquer: under the 400-600r/min rotating speed, stir the good slurry of sand milling, add defoamer 0.1-0.3 part, film coalescence aid 1.2-1.5 part, behind the stirring 10-20min, add 25-40 part emulsion, described emulsion is organosilicon crylic acid latex, pure-acrylic emulsion or the mixture of the two, and 3-15 part fluoropolymer emulsion is transferred PH to 7-9, add thickening material 0.2-0.7 part and carry out thickening, add 0.6-1.2 part sanitas again, stir 10-20min, make fluorine-containing emulsion paint.
2. the preparation method of fluorine-containing emulsion paint according to claim 1, it is characterized in that: described thickening material is alkali swelling type thickening material, associative thickener or cellulose thickener.
3. the preparation method of fluorine-containing emulsion paint according to claim 1 is characterized in that: also add 2-10 part pigment or mill base in (2) step or (3) step.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110031523 CN102093802B (en) | 2011-01-29 | 2011-01-29 | Method for preparing fluorine-containing latex paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110031523 CN102093802B (en) | 2011-01-29 | 2011-01-29 | Method for preparing fluorine-containing latex paint |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102093802A true CN102093802A (en) | 2011-06-15 |
| CN102093802B CN102093802B (en) | 2013-01-30 |
Family
ID=44127074
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201110031523 Active CN102093802B (en) | 2011-01-29 | 2011-01-29 | Method for preparing fluorine-containing latex paint |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102093802B (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102504679A (en) * | 2011-10-17 | 2012-06-20 | 青岛爱尔家佳新材料有限公司 | Novel anti-skidding coating for deck and preparation method thereof |
| CN104178010A (en) * | 2014-08-27 | 2014-12-03 | 句容市石狮冲压件厂 | Composite coating for outdoor deck chair and preparation method thereof |
| CN104263040A (en) * | 2014-09-03 | 2015-01-07 | 天长市开林化工有限公司 | Fluorine-containing latex paint |
| CN104927431A (en) * | 2015-06-16 | 2015-09-23 | 合肥启华环保科技有限公司 | Composite exterior wall latex paint with addition of activated modified fillers and preparation method thereof |
| CN107383959A (en) * | 2016-05-16 | 2017-11-24 | 济南亚福瑞装饰材料有限公司 | A kind of self-styled glaze component body of water paint and production technology |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101338163A (en) * | 2008-08-12 | 2009-01-07 | 山西天时涂料装饰有限公司 | Elastic emulsion paint and method for preparing same |
| CN101735696A (en) * | 2009-12-31 | 2010-06-16 | 上海富臣化工有限公司 | Scouring-resistance high-performance outer wall emulsion paint and preparation method |
-
2011
- 2011-01-29 CN CN 201110031523 patent/CN102093802B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101338163A (en) * | 2008-08-12 | 2009-01-07 | 山西天时涂料装饰有限公司 | Elastic emulsion paint and method for preparing same |
| CN101735696A (en) * | 2009-12-31 | 2010-06-16 | 上海富臣化工有限公司 | Scouring-resistance high-performance outer wall emulsion paint and preparation method |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102504679A (en) * | 2011-10-17 | 2012-06-20 | 青岛爱尔家佳新材料有限公司 | Novel anti-skidding coating for deck and preparation method thereof |
| CN104178010A (en) * | 2014-08-27 | 2014-12-03 | 句容市石狮冲压件厂 | Composite coating for outdoor deck chair and preparation method thereof |
| CN104263040A (en) * | 2014-09-03 | 2015-01-07 | 天长市开林化工有限公司 | Fluorine-containing latex paint |
| CN104927431A (en) * | 2015-06-16 | 2015-09-23 | 合肥启华环保科技有限公司 | Composite exterior wall latex paint with addition of activated modified fillers and preparation method thereof |
| CN107383959A (en) * | 2016-05-16 | 2017-11-24 | 济南亚福瑞装饰材料有限公司 | A kind of self-styled glaze component body of water paint and production technology |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102093802B (en) | 2013-01-30 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103113796B (en) | Water-based fluorocarbon elasticity anti-soil exterior wall paint | |
| CN107619626B (en) | Water-based high-temperature-resistant high-humidity-resistant inorganic coating and preparation method thereof | |
| CN103614062B (en) | A kind of leather surface covering with paint environmental protection coating material and preparation method | |
| CN107384195B (en) | A kind of weather-proof plucking decorative paint of organosilicon | |
| CN105462403B (en) | A kind of composite aqueous woodenware one-component semi-gloss varnish and preparation method thereof | |
| CN102876143A (en) | Marble paint and preparation method thereof | |
| CN104530874A (en) | High-washing-resistance colorful coating and preparation method thereof | |
| CN102093802B (en) | Method for preparing fluorine-containing latex paint | |
| CN102850878A (en) | Weather-resistant exterior wall paint and preparation method thereof | |
| CN101591491A (en) | A kind of fully water based granite multicolor paint and preparation method thereof | |
| CN106010184B (en) | Aqueous furniture priming paint and preparation method thereof and wood finishing construction technology | |
| CN111909610A (en) | Polyurethane waterproof coating and preparation method thereof | |
| CN105440830B (en) | Scrubbable interior wall coating of a kind of low viscosity height covering height and preparation method thereof | |
| CN102618126A (en) | Nitrocellulose transparent primer and application thereof | |
| CN105295597A (en) | Water-borne automobile polyurethane varnish and preparation method thereof | |
| CN102952461B (en) | A kind of bi-component waterborne white timber paint | |
| CN102134434A (en) | High-performance water-based white sealing primer | |
| CN106675355A (en) | Water-based alkyd coating and preparation method thereof | |
| CN101693801A (en) | Rare earth modification exterior wall water-borne fluorocarbon coating and preparation method thereof | |
| CN1434063A (en) | Aqueous epoxy modified acrylic heat-reflecting thermo-insulating coating | |
| CN102372979A (en) | Anti-sticking aqueous fluoro-silicone coating and preparation method thereof | |
| CN108676496A (en) | A kind of novel environment friendly water-repellent paint and preparation method thereof | |
| CN106810973A (en) | A kind of aqueous one-component coating and preparation method thereof | |
| CN105462426A (en) | Waterborne biological-based paint with efficient weather resistance, water resistance and stain resistance and preparation method thereof | |
| CN112280417A (en) | Water-based wood paint |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Method for preparing fluorine-containing latex paint Effective date of registration: 20170925 Granted publication date: 20130130 Pledgee: Industrial Commercial Bank of China Ltd. Jinzhou branch Pledgor: JINZHOU HUIFA TIANHE CHEMICAL Co.,Ltd. Registration number: 2017210000019 |
|
| PP01 | Preservation of patent right | ||
| PP01 | Preservation of patent right |
Effective date of registration: 20180417 Granted publication date: 20130130 |
|
| PP01 | Preservation of patent right | ||
| PP01 | Preservation of patent right |
Effective date of registration: 20180510 Granted publication date: 20130130 |
|
| PD01 | Discharge of preservation of patent | ||
| PD01 | Discharge of preservation of patent |
Date of cancellation: 20210417 Granted publication date: 20130130 |
|
| PP01 | Preservation of patent right | ||
| PP01 | Preservation of patent right |
Effective date of registration: 20210417 Granted publication date: 20130130 |