CN102482592B - 使用反应抑制剂进行的石脑油的选择性脱硫 - Google Patents

使用反应抑制剂进行的石脑油的选择性脱硫 Download PDF

Info

Publication number
CN102482592B
CN102482592B CN201080040426.XA CN201080040426A CN102482592B CN 102482592 B CN102482592 B CN 102482592B CN 201080040426 A CN201080040426 A CN 201080040426A CN 102482592 B CN102482592 B CN 102482592B
Authority
CN
China
Prior art keywords
inhibitor
temperature
wppm
catalyst
reactor
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201080040426.XA
Other languages
English (en)
Chinese (zh)
Other versions
CN102482592A (zh
Inventor
约翰·彼得·格里利
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
ExxonMobil Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ExxonMobil Research and Engineering Co filed Critical ExxonMobil Research and Engineering Co
Publication of CN102482592A publication Critical patent/CN102482592A/zh
Application granted granted Critical
Publication of CN102482592B publication Critical patent/CN102482592B/zh
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1037—Hydrocarbon fractions
    • C10G2300/1044—Heavy gasoline or naphtha having a boiling range of about 100 - 180 °C
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/202—Heteroatoms content, i.e. S, N, O, P
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4006—Temperature
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4018—Spatial velocity, e.g. LHSV, WHSV
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/80—Additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/02—Gasoline

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
CN201080040426.XA 2009-09-11 2010-09-09 使用反应抑制剂进行的石脑油的选择性脱硫 Expired - Fee Related CN102482592B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US27635109P 2009-09-11 2009-09-11
US61/276,351 2009-09-11
PCT/US2010/048228 WO2011031828A2 (en) 2009-09-11 2010-09-09 Selective desulfurization of naphtha using reaction inhibitors

Publications (2)

Publication Number Publication Date
CN102482592A CN102482592A (zh) 2012-05-30
CN102482592B true CN102482592B (zh) 2014-07-30

Family

ID=43733089

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201080040426.XA Expired - Fee Related CN102482592B (zh) 2009-09-11 2010-09-09 使用反应抑制剂进行的石脑油的选择性脱硫

Country Status (8)

Country Link
US (1) US8329029B2 (enExample)
EP (1) EP2475748A4 (enExample)
JP (1) JP5386638B2 (enExample)
CN (1) CN102482592B (enExample)
AU (1) AU2010292297A1 (enExample)
CA (1) CA2772061A1 (enExample)
SG (1) SG178875A1 (enExample)
WO (1) WO2011031828A2 (enExample)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8894844B2 (en) 2011-03-21 2014-11-25 Exxonmobil Research And Engineering Company Hydroprocessing methods utilizing carbon oxide-tolerant catalysts
CN113990409B (zh) * 2021-10-22 2024-09-24 南通大学 一种基于混合特征选择的辛烷值损失预测方法
CN114595781B (zh) * 2022-03-17 2024-06-28 南京星环智能科技有限公司 一种辛烷值损失预测方法、装置、设备及存储介质

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2913405A (en) * 1957-08-27 1959-11-17 Houdry Process Corp Desulfurization of olefinic gasoline
US20030220186A1 (en) * 2002-03-13 2003-11-27 Brignac Garland B. Selectively suppressing catalytic hydrogenation
US20030217952A1 (en) * 2002-03-13 2003-11-27 Brignac Garland B. Naphtha desulfurization with selectively suppressed hydrogenation
US20030221994A1 (en) * 2002-05-28 2003-12-04 Ellis Edward S. Low CO for increased naphtha desulfurization
US7361265B2 (en) * 2002-06-26 2008-04-22 Petroleo Brasileiro S.A.-Petrobras Process for the selective hydrodesulfurization of olefinic naphtha streams
US20090145807A1 (en) * 2007-11-30 2009-06-11 Saudi Arabian Oil Company Process to produce low sulfur catalytically cracked gasoline without saturation of olefinic compounds
US20090223866A1 (en) * 2008-03-06 2009-09-10 Opinder Kishan Bhan Process for the selective hydrodesulfurization of a gasoline feedstock containing high levels of olefins

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3404085A (en) 1966-08-30 1968-10-01 Exxon Research Engineering Co Hydrocracking process for high octane product
US3816296A (en) * 1972-11-13 1974-06-11 Union Oil Co Hydrocracking process
US4155835A (en) * 1978-03-06 1979-05-22 Mobil Oil Corporation Desulfurization of naphtha charged to bimetallic catalyst reforming
US6231754B1 (en) * 1996-02-02 2001-05-15 Exxon Research And Engineering Company High temperature naphtha desulfurization using a low metal and partially deactivated catalyst
US6231753B1 (en) * 1996-02-02 2001-05-15 Exxon Research And Engineering Company Two stage deep naphtha desulfurization with reduced mercaptan formation
JP3729621B2 (ja) * 1997-09-24 2005-12-21 新日本石油株式会社 接触分解ガソリンの水素化脱硫方法及びガソリン
KR20010089180A (ko) 1998-09-01 2001-09-29 노미야마 아키히콰 수소첨가분해 방법 및 수소첨가분해용 촉매
FR2841798B1 (fr) * 2002-07-03 2005-03-04 Inst Francais Du Petrole Catalyseur d'hydrotraitement contenant un compose organique azote et son utilisation

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2913405A (en) * 1957-08-27 1959-11-17 Houdry Process Corp Desulfurization of olefinic gasoline
US20030220186A1 (en) * 2002-03-13 2003-11-27 Brignac Garland B. Selectively suppressing catalytic hydrogenation
US20030217952A1 (en) * 2002-03-13 2003-11-27 Brignac Garland B. Naphtha desulfurization with selectively suppressed hydrogenation
US20030221994A1 (en) * 2002-05-28 2003-12-04 Ellis Edward S. Low CO for increased naphtha desulfurization
US7361265B2 (en) * 2002-06-26 2008-04-22 Petroleo Brasileiro S.A.-Petrobras Process for the selective hydrodesulfurization of olefinic naphtha streams
US20090145807A1 (en) * 2007-11-30 2009-06-11 Saudi Arabian Oil Company Process to produce low sulfur catalytically cracked gasoline without saturation of olefinic compounds
US20090223866A1 (en) * 2008-03-06 2009-09-10 Opinder Kishan Bhan Process for the selective hydrodesulfurization of a gasoline feedstock containing high levels of olefins

Also Published As

Publication number Publication date
WO2011031828A2 (en) 2011-03-17
SG178875A1 (en) 2012-04-27
EP2475748A2 (en) 2012-07-18
CA2772061A1 (en) 2011-03-17
WO2011031828A3 (en) 2011-07-21
US8329029B2 (en) 2012-12-11
CN102482592A (zh) 2012-05-30
US20110180457A1 (en) 2011-07-28
AU2010292297A1 (en) 2012-04-19
JP5386638B2 (ja) 2014-01-15
JP2013504659A (ja) 2013-02-07
EP2475748A4 (en) 2013-03-27

Similar Documents

Publication Publication Date Title
EP3395929B1 (en) Process for the deep desulfurization of heavy pyrolysis gasoline
CN110719949A (zh) 具有部分催化剂再循环的高苛刻度流化催化裂化系统和方法
CA2845340A1 (en) Hydroprocessing of heavy hydrocarbon feeds
JP5396084B2 (ja) 高温メルカプタン分解を伴う選択的ナフサ水素化脱硫
JP4958792B2 (ja) 段間分離を含む、選択的水素化脱硫およびメルカプタン分解プロセス
AU2012350179A1 (en) Method for the hydroconversion of petroleum feedstocks in fixed beds for the production of fuel oils having a low sulphur content
EP1506270B1 (en) Multi-stage hydrodesulfurization of cracked naphtha streams with a stacked bed reactor
JP4276956B2 (ja) 水素添加を選択的に抑制したナフサ脱硫
AU2013296947A1 (en) Residue hydrocracking
JP4740544B2 (ja) ナフサストリームの選択的水素化脱硫
WO2000051729A1 (en) Improved catalyst activation method for selective cat naphtha hydrodesulfurization
CN102482592B (zh) 使用反应抑制剂进行的石脑油的选择性脱硫
KR101695502B1 (ko) 저황 경유 기재의 제조 방법 및 저황 경유
EP1682636B1 (en) Nitrogen removal from olefinic naphtha feedstreams to improve hydrodesulfurization versus olefin saturation selectivity
US8828218B2 (en) Pretreatment of FCC naphthas and selective hydrotreating
EP1509322A1 (en) Selectively suppressing catalytic hydrogenation
JP5581396B2 (ja) 脱硫前に捕捉触媒を用いてヒ素を除去するための方法
WO2023150414A1 (en) Integrated hydrotreating and hydrocracking with continuous hydrotreating catalyst regeneration
WO2021045886A1 (en) Slurry hydroconversion with pitch recycle
JP2001064655A (ja) 炭化水素油の水素化処理方法

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20140730

Termination date: 20150909

EXPY Termination of patent right or utility model