CA2772061A1 - Selective desulfurization of naphtha using reaction inhibitors - Google Patents

Selective desulfurization of naphtha using reaction inhibitors Download PDF

Info

Publication number
CA2772061A1
CA2772061A1 CA2772061A CA2772061A CA2772061A1 CA 2772061 A1 CA2772061 A1 CA 2772061A1 CA 2772061 A CA2772061 A CA 2772061A CA 2772061 A CA2772061 A CA 2772061A CA 2772061 A1 CA2772061 A1 CA 2772061A1
Authority
CA
Canada
Prior art keywords
temperature
feed
amount
catalyst
reactor
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA2772061A
Other languages
English (en)
French (fr)
Inventor
John Peter Greeley
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
ExxonMobil Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ExxonMobil Research and Engineering Co filed Critical ExxonMobil Research and Engineering Co
Publication of CA2772061A1 publication Critical patent/CA2772061A1/en
Abandoned legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1037—Hydrocarbon fractions
    • C10G2300/1044—Heavy gasoline or naphtha having a boiling range of about 100 - 180 °C
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/202—Heteroatoms content, i.e. S, N, O, P
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4006—Temperature
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4018—Spatial velocity, e.g. LHSV, WHSV
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/80—Additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/02—Gasoline

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
CA2772061A 2009-09-11 2010-09-09 Selective desulfurization of naphtha using reaction inhibitors Abandoned CA2772061A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US27635109P 2009-09-11 2009-09-11
US61/276,351 2009-09-11
PCT/US2010/048228 WO2011031828A2 (en) 2009-09-11 2010-09-09 Selective desulfurization of naphtha using reaction inhibitors

Publications (1)

Publication Number Publication Date
CA2772061A1 true CA2772061A1 (en) 2011-03-17

Family

ID=43733089

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2772061A Abandoned CA2772061A1 (en) 2009-09-11 2010-09-09 Selective desulfurization of naphtha using reaction inhibitors

Country Status (8)

Country Link
US (1) US8329029B2 (enExample)
EP (1) EP2475748A4 (enExample)
JP (1) JP5386638B2 (enExample)
CN (1) CN102482592B (enExample)
AU (1) AU2010292297A1 (enExample)
CA (1) CA2772061A1 (enExample)
SG (1) SG178875A1 (enExample)
WO (1) WO2011031828A2 (enExample)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113990409A (zh) * 2021-10-22 2022-01-28 南通大学 一种基于混合特征选择的辛烷值损失预测方法

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8894844B2 (en) 2011-03-21 2014-11-25 Exxonmobil Research And Engineering Company Hydroprocessing methods utilizing carbon oxide-tolerant catalysts
CN114595781B (zh) * 2022-03-17 2024-06-28 南京星环智能科技有限公司 一种辛烷值损失预测方法、装置、设备及存储介质

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2913405A (en) * 1957-08-27 1959-11-17 Houdry Process Corp Desulfurization of olefinic gasoline
US3404085A (en) 1966-08-30 1968-10-01 Exxon Research Engineering Co Hydrocracking process for high octane product
US3816296A (en) * 1972-11-13 1974-06-11 Union Oil Co Hydrocracking process
US4155835A (en) * 1978-03-06 1979-05-22 Mobil Oil Corporation Desulfurization of naphtha charged to bimetallic catalyst reforming
US6231754B1 (en) * 1996-02-02 2001-05-15 Exxon Research And Engineering Company High temperature naphtha desulfurization using a low metal and partially deactivated catalyst
US6231753B1 (en) * 1996-02-02 2001-05-15 Exxon Research And Engineering Company Two stage deep naphtha desulfurization with reduced mercaptan formation
JP3729621B2 (ja) * 1997-09-24 2005-12-21 新日本石油株式会社 接触分解ガソリンの水素化脱硫方法及びガソリン
KR20010089180A (ko) 1998-09-01 2001-09-29 노미야마 아키히콰 수소첨가분해 방법 및 수소첨가분해용 촉매
US6893554B2 (en) * 2002-03-13 2005-05-17 Exxonmobil Research And Engineering Company Naphtha desulfurization with selectively suppressed hydrogenation
US7074735B2 (en) * 2002-03-13 2006-07-11 Exxonmobil Research And Engineering Company Selectively suppressing catalytic hydrogenation
US7422679B2 (en) * 2002-05-28 2008-09-09 Exxonmobil Research And Engineering Company Low CO for increased naphtha desulfurization
BR0202413A (pt) * 2002-06-26 2004-05-11 Petroleo Brasileiro Sa Processo de hidrodessulfurização seletiva de correntes olefìnicas
FR2841798B1 (fr) * 2002-07-03 2005-03-04 Inst Francais Du Petrole Catalyseur d'hydrotraitement contenant un compose organique azote et son utilisation
US8142646B2 (en) * 2007-11-30 2012-03-27 Saudi Arabian Oil Company Process to produce low sulfur catalytically cracked gasoline without saturation of olefinic compounds
US20090223866A1 (en) * 2008-03-06 2009-09-10 Opinder Kishan Bhan Process for the selective hydrodesulfurization of a gasoline feedstock containing high levels of olefins

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113990409A (zh) * 2021-10-22 2022-01-28 南通大学 一种基于混合特征选择的辛烷值损失预测方法
CN113990409B (zh) * 2021-10-22 2024-09-24 南通大学 一种基于混合特征选择的辛烷值损失预测方法

Also Published As

Publication number Publication date
WO2011031828A2 (en) 2011-03-17
SG178875A1 (en) 2012-04-27
EP2475748A2 (en) 2012-07-18
WO2011031828A3 (en) 2011-07-21
US8329029B2 (en) 2012-12-11
CN102482592A (zh) 2012-05-30
US20110180457A1 (en) 2011-07-28
AU2010292297A1 (en) 2012-04-19
JP5386638B2 (ja) 2014-01-15
CN102482592B (zh) 2014-07-30
JP2013504659A (ja) 2013-02-07
EP2475748A4 (en) 2013-03-27

Similar Documents

Publication Publication Date Title
EP1349905B1 (en) Method for forming a low-sulfur, high-octane naphtha for gasoline blending
CA2630340C (en) Selective naphtha hydrodesulfurization with high temperature mercaptan decomposition
CA2486670C (en) Multi-stage hydrodesulfurization of cracked naphtha streams with a stacked bed reactor
CA2593062C (en) Selective hydrodesulfurization and mercaptan decomposition process with interstage separation
US20050187100A1 (en) Naphtha desulfurization with selectively suppressed hydrogenation
JP4740544B2 (ja) ナフサストリームの選択的水素化脱硫
CA3049804A1 (en) Desulfurization of a naphtha boiling range feed
US8329029B2 (en) Selective desulfurization of naphtha using reaction inhibitors
KR101695502B1 (ko) 저황 경유 기재의 제조 방법 및 저황 경유
EP1682636B1 (en) Nitrogen removal from olefinic naphtha feedstreams to improve hydrodesulfurization versus olefin saturation selectivity
US20130118952A1 (en) Pretreatment of fcc naphthas and selective hydrotreating
AU2009356146B2 (en) Process for removing arsenic with a trap catalyst before desulfurizating it
AU2004261970A1 (en) A catalyst system and its use in manufacturing low sulfur fuels
JP2001064655A (ja) 炭化水素油の水素化処理方法

Legal Events

Date Code Title Description
FZDE Dead

Effective date: 20160909