CN102482186B - 阴离子聚合引发剂和工艺 - Google Patents

阴离子聚合引发剂和工艺 Download PDF

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Publication number
CN102482186B
CN102482186B CN201080038722.6A CN201080038722A CN102482186B CN 102482186 B CN102482186 B CN 102482186B CN 201080038722 A CN201080038722 A CN 201080038722A CN 102482186 B CN102482186 B CN 102482186B
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polymerization
polymer
typically
initiator
group
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Expired - Fee Related
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Chinese (zh)
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CN102482186A (zh
Inventor
燕远勇
秦增全
潘晓东
大卫·M·罗格曼
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Bridgestone Corp
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Bridgestone Corp
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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C43/00Ethers; Compounds having groups, groups or groups
    • C07C43/02Ethers
    • C07C43/235Ethers having an ether-oxygen atom bound to a carbon atom of a six-membered aromatic ring and to a carbon atom of a ring other than a six-membered aromatic ring
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01Preparation of ethers
    • C07C41/18Preparation of ethers by reactions not forming ether-oxygen bonds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F1/00Compounds containing elements of Groups 1 or 11 of the Periodic Table
    • C07F1/02Lithium compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/46Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkali metals
    • C08F4/48Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkali metals selected from lithium, rubidium, caesium or francium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/46Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkali metals
    • C08F4/48Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkali metals selected from lithium, rubidium, caesium or francium
    • C08F4/484Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkali metals selected from lithium, rubidium, caesium or francium an alkali metal bound to a cyclic carbon
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02Monomers containing only one unsaturated aliphatic radical
    • C08F12/04Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F12/06Hydrocarbons
    • C08F12/08Styrene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F136/00Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F136/02Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F136/04Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2810/00Chemical modification of a polymer
    • C08F2810/40Chemical modification of a polymer taking place solely at one end or both ends of the polymer backbone, i.e. not in the side or lateral chains

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polymerization Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CN201080038722.6A 2009-06-30 2010-06-28 阴离子聚合引发剂和工艺 Expired - Fee Related CN102482186B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US22162209P 2009-06-30 2009-06-30
US61/221,622 2009-06-30
PCT/US2010/040242 WO2011008501A2 (en) 2009-06-30 2010-06-28 Anionic polymerization initiators and processes

Publications (2)

Publication Number Publication Date
CN102482186A CN102482186A (zh) 2012-05-30
CN102482186B true CN102482186B (zh) 2015-09-30

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Country Link
US (1) US9365660B2 (enExample)
EP (1) EP2448900B1 (enExample)
JP (1) JP5792162B2 (enExample)
KR (1) KR101752934B1 (enExample)
CN (1) CN102482186B (enExample)
BR (1) BRPI1015023A2 (enExample)
ES (1) ES2633097T3 (enExample)
WO (1) WO2011008501A2 (enExample)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101604566B1 (ko) 2007-12-28 2016-03-17 가부시키가이샤 브리지스톤 히드록시아릴 관능화 중합체
BRPI1014609B1 (pt) 2009-06-30 2021-09-08 Bridgestone Corporation Polímeros funcionalizados com difenil-etileno contendo grupo de hidroxila
US9926400B2 (en) * 2009-07-01 2018-03-27 Bridgestone Corporation Method of making hydroxyaryl-functionalized interpolymer by free radical initiated polymerization
JP5841134B2 (ja) 2010-05-31 2016-01-13 株式会社ブリヂストン 水酸基含有メチルスチレン及び該水酸基含有メチルスチレンを組み込んだポリマー
US8637600B2 (en) 2010-08-11 2014-01-28 Bridgestone Corporation Processing of rubber compositions including siliceous fillers
CN104541135B (zh) * 2012-08-21 2018-04-20 高准公司 具有改进的量表零位的科里奥利流量计和方法
DE102012017797B4 (de) * 2012-09-10 2014-09-18 Krohne Ag Durchflussmessgerät
HUE033097T2 (en) 2013-07-22 2017-11-28 Trinseo Europe Gmbh Polymerization initiators
EP3325518B1 (en) 2015-07-22 2021-05-12 Bridgestone Corporation Silane-functionalized polymer and process for making and using same
JP6809755B2 (ja) 2015-11-13 2021-01-06 株式会社ブリヂストン アニオン重合のための官能性開始剤
JP6901198B2 (ja) 2015-11-16 2021-07-14 株式会社ブリヂストン アニオン重合のための官能性開始剤
KR102014521B1 (ko) * 2016-04-25 2019-10-21 주식회사 엘지화학 변성 공액디엔계 중합체 및 이의 제조방법
WO2017188641A2 (ko) * 2016-04-25 2017-11-02 주식회사 엘지화학 변성 공액디엔계 중합체 및 이의 제조방법
US11332556B2 (en) 2016-12-28 2022-05-17 Bridgestone Americas Tire Operations, Llc Methods of making polymers with reduced tack, and rubber compositions incorporating these polymers
WO2019066279A1 (ko) * 2017-09-29 2019-04-04 주식회사 엘지화학 양 말단 변성 공액디엔계 중합체 및 이의 제조방법
KR102102986B1 (ko) 2017-09-29 2020-04-21 주식회사 엘지화학 양 말단 변성 공액디엔계 중합체 및 이의 제조방법
CN109627382B (zh) 2017-10-06 2022-03-18 台橡股份有限公司 共轭二烯聚合物及其组合物及制造方法
KR102241925B1 (ko) * 2018-11-26 2021-04-20 주식회사 엘지화학 블록 공중합체 조성물, 이의 제조방법 및 이를 포함하는 아스팔트 조성물

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4006187A (en) * 1971-10-06 1977-02-01 Lithium Corporation Of America Preparation of aryllithium compounds by metalation
CN1120341A (zh) * 1993-03-11 1996-04-10 国际壳牌研究有限公司 具有末端甲硅烷基的丁二烯聚合物

Family Cites Families (65)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3109871A (en) 1960-12-27 1963-11-05 Phillips Petroleum Co Production and curing of polyfunctional terminally reactive polymers
US3668263A (en) * 1970-01-19 1972-06-06 Lithium Corp Organolithium polymerization initiators and use thereof in polymerization processes
US3978103A (en) 1971-08-17 1976-08-31 Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler Sulfur containing organosilicon compounds
US3873489A (en) 1971-08-17 1975-03-25 Degussa Rubber compositions containing silica and an organosilane
BE790802A (fr) * 1971-11-04 1973-04-30 Takeda Chemical Industries Ltd Nouveaux derives de chromone et leur fabrication
JPS4941116A (enExample) 1972-09-06 1974-04-17
US3931107A (en) * 1973-06-21 1976-01-06 Phillips Petroleum Company Polyalkoxy monovinylaromatic compound in copolymerization of a conjugated diene with a monovinyl-substituted aromatic compound
SU580840A3 (ru) 1974-02-07 1977-11-15 Дегусса (Фирма) Способ получени серосодержащих кремнийорганических соединений
US4015061A (en) 1975-02-14 1977-03-29 The Firestone Tire & Rubber Company Protected amino-functional initiators and amino-terminated polymers and their production
US4002594A (en) 1975-07-08 1977-01-11 Ppg Industries, Inc. Scorch retardants for rubber reinforced with siliceous pigment and mercapto-type coupling agent
US4725654A (en) * 1982-04-02 1988-02-16 The Dow Chemical Company Process for anionic polymerization
US4429091A (en) 1983-03-09 1984-01-31 The Firestone Tire & Rubber Company Oligomeric oxolanyl alkanes as modifiers for polymerization of dienes using lithium-based initiators
US4499243A (en) 1983-11-07 1985-02-12 Monsanto Company Method of treating diene rubber with amino- and hydroxy aryl compounds
US4647625A (en) 1983-12-26 1987-03-03 Nippon Zeon Co., Ltd. Process for modifying conjugated diene polymers
US4616069A (en) 1984-10-26 1986-10-07 Nippon Zeon Co., Ltd. Process for making diene polymer rubbers
JPS61225202A (ja) 1985-03-29 1986-10-07 Nippon Zeon Co Ltd ゴムの変性方法
US4935471A (en) 1987-10-15 1990-06-19 The Goodyear Tire & Rubber Company Capped polydienes
US5149457A (en) 1989-06-30 1992-09-22 Cyprus Foote Mineral Company Stable mixed lithium amide reagent compositions
US5196138A (en) 1989-06-30 1993-03-23 Cyprus Foote Mineral Company Preparation of mixed lithium amide reagents
DE4003079A1 (de) 1990-02-02 1991-08-08 Bayer Ag Benzophenonderivate und polymere mit phenolischen hydroxylgruppen
US5153159A (en) 1990-04-09 1992-10-06 Bridgestone/Firestone, Inc. Elastomers and products having reduced hysteresis
US5109907A (en) 1990-04-09 1992-05-05 Bridgestone/Firestone, Inc. Diene polymers and copolymers terminated by reaction with N-alkyl and N-aryl imines
CA2040457A1 (en) 1990-04-30 1991-10-31 Timothy E. Long Block copolymers containing poly(1,3-conjugated dienes) and poly (vinylphenols), silyl protected poly (vinylphenols) or poly (metal phenolates)
JP3057508B2 (ja) * 1990-06-21 2000-06-26 日本曹達株式会社 p―アルケニルフェノール系重合体の製造方法
JP2544016B2 (ja) * 1990-10-11 1996-10-16 信越化学工業株式会社 リチウム電池
US5231152A (en) 1990-12-18 1993-07-27 Bridgestone Corporation Continuous process for preparing copolymers of conjugated dienes and aromatic vinyl compounds
JPH05230126A (ja) 1992-02-25 1993-09-07 Nippon Steel Chem Co Ltd 芳香族ヒドロキシル基を有するスチレン系ポリマーとその製造法
US5329005A (en) 1992-10-02 1994-07-12 Bridgestone Corporation Soluble anionic polymerization initiators and preparation thereof
JP3246172B2 (ja) 1994-03-18 2002-01-15 住友化学工業株式会社 ゴム組成物およびそれを用いるスチールコードとの加硫接着方法
US5567815A (en) 1994-07-18 1996-10-22 Bridgestone Corporation Teritary amine containing antonic initiators used in preparing polymers and process for the preparation thereof
US5521309A (en) 1994-12-23 1996-05-28 Bridgestone Corporation Tertiary-amino allyl-or xylyl-lithium initiators and method of preparing same
US5496940A (en) 1995-02-01 1996-03-05 Bridgestone Corporation Alkyllithium compounds containing cyclic amines and their use in polymerization
US5580919A (en) 1995-03-14 1996-12-03 The Goodyear Tire & Rubber Company Silica reinforced rubber composition and use in tires
EP0745655A3 (en) 1995-06-02 1998-04-29 National Starch and Chemical Investment Holding Corporation Dissipative laminating adhesive
US5610227A (en) 1995-06-07 1997-03-11 Bridgestone/Firestone, Inc. Lithium amino magnesiate polymerization initiators and elastomers having reduced hysteresis
US5583245A (en) 1996-03-06 1996-12-10 The Goodyear Tire & Rubber Company Preparation of sulfur-containing organosilicon compounds
US5663398A (en) 1996-05-17 1997-09-02 Fmc Corporation Processes for preparing functionalized alkyllithium compounds
US5696197A (en) 1996-06-21 1997-12-09 The Goodyear Tire & Rubber Company Heterogeneous silica carbon black-filled rubber compound
US5663396A (en) 1996-10-31 1997-09-02 The Goodyear Tire & Rubber Company Preparation of sulfur-containing organosilicon compounds
US5786441A (en) 1996-12-31 1998-07-28 Bridgestone Corporation Polymers, elastomeric compounds and products thereof, derived from novel amine compounds containing side-chain organolithium moieties
US5684171A (en) 1997-02-11 1997-11-04 The Goodyear Tire & Rubber Company Process for the preparation of organosilicon polysulfide compounds
US5684172A (en) 1997-02-11 1997-11-04 The Goodyear Tire & Rubber Company Process for the preparation of organosilicon polysulfide compounds
US6525118B2 (en) 1997-07-11 2003-02-25 Bridgestone Corporation Processability of silica-filled rubber stocks with reduced hysteresis
US6977281B1 (en) 1999-11-12 2005-12-20 Bridgestone Corporation Modified polymers prepared with lanthanide-based catalysts
JP2002179621A (ja) * 2000-12-08 2002-06-26 Adchemco Corp 4−アセトキシスチレンの製造方法
WO2002060958A2 (en) 2001-02-01 2002-08-08 Fmc Corporation Functionalized initiators for anionic polymerization, protected funtionalized polymers, deprotected analogues thereof, and methods of making the same
US6897270B2 (en) 2001-02-28 2005-05-24 Bridgestone Corporation Continuous process for the production of conjugated diene polymers having narrow molecular weight distribution and products therefrom
JP2003171422A (ja) 2001-12-06 2003-06-20 Toho Chem Ind Co Ltd 共重合物およびその製造方法
JP3797262B2 (ja) 2002-04-05 2006-07-12 住友化学株式会社 変性ジエン系重合体ゴム、その製造方法及びゴム組成物
US6770201B2 (en) * 2002-08-07 2004-08-03 Sandia National Laboratories Cast-to-shape electrokinetic trapping medium
US7153919B2 (en) 2002-10-30 2006-12-26 Bridgestone Corporation Use of sulfur containing initiators for anionic polymerization of monomers
US7208171B2 (en) 2002-10-31 2007-04-24 Northwestern University Injectable and bioadhesive polymeric hydrogels as well as related methods of enzymatic preparation
US7226979B2 (en) 2004-02-11 2007-06-05 University Of Massachusetts Lowell Copolymers comprising olefin and protected or unprotected hydroxystyrene units
US7056985B2 (en) 2004-02-11 2006-06-06 University Of Massachusetts Lowell End-capped polymer chains and products thereof
JP5249579B2 (ja) 2004-03-01 2013-07-31 株式会社ブリヂストン 連続重合反応器
ES2533455T3 (es) 2004-10-26 2015-04-10 Bridgestone Corporation Polímero funcionalizado con grupo enlazante
US7816483B2 (en) 2005-08-11 2010-10-19 Bridgestone Corporation Amine functionalized polymer
JP5079294B2 (ja) 2005-10-04 2012-11-21 株式会社ブリヂストン アミンで官能化されたポリマー
JP4934323B2 (ja) 2006-02-07 2012-05-16 株式会社ブリヂストン 変性天然ゴム及びその製造方法、並びにそれを用いたゴム組成物及びタイヤ
KR101439566B1 (ko) 2006-07-25 2014-09-11 가부시키가이샤 브리지스톤 아진 화합물로 말단 관능화된 중합체를 제공하는 방법
KR101604566B1 (ko) 2007-12-28 2016-03-17 가부시키가이샤 브리지스톤 히드록시아릴 관능화 중합체
BRPI1014609B1 (pt) 2009-06-30 2021-09-08 Bridgestone Corporation Polímeros funcionalizados com difenil-etileno contendo grupo de hidroxila
US8946355B2 (en) 2009-06-30 2015-02-03 Bridgestone Corporation Hydroxyaryl functionalized polymers
US9926400B2 (en) 2009-07-01 2018-03-27 Bridgestone Corporation Method of making hydroxyaryl-functionalized interpolymer by free radical initiated polymerization
WO2011106765A2 (en) 2010-02-28 2011-09-01 Bridgestone Corporation Rubber compositions including siliceous fillers

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4006187A (en) * 1971-10-06 1977-02-01 Lithium Corporation Of America Preparation of aryllithium compounds by metalation
CN1120341A (zh) * 1993-03-11 1996-04-10 国际壳牌研究有限公司 具有末端甲硅烷基的丁二烯聚合物

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JP2012532132A (ja) 2012-12-13
WO2011008501A2 (en) 2011-01-20
EP2448900A2 (en) 2012-05-09
KR101752934B1 (ko) 2017-07-03
KR20120046721A (ko) 2012-05-10
EP2448900B1 (en) 2017-04-26
WO2011008501A4 (en) 2011-06-03
US20120136128A1 (en) 2012-05-31
EP2448900A4 (en) 2014-07-23
WO2011008501A3 (en) 2011-04-14
JP5792162B2 (ja) 2015-10-07
US9365660B2 (en) 2016-06-14
CN102482186A (zh) 2012-05-30
BRPI1015023A2 (pt) 2019-07-09
ES2633097T3 (es) 2017-09-19

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