CN102452886A - 一种由费托合成油品中提纯1-辛烯的方法 - Google Patents
一种由费托合成油品中提纯1-辛烯的方法 Download PDFInfo
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- CN102452886A CN102452886A CN2010105269980A CN201010526998A CN102452886A CN 102452886 A CN102452886 A CN 102452886A CN 2010105269980 A CN2010105269980 A CN 2010105269980A CN 201010526998 A CN201010526998 A CN 201010526998A CN 102452886 A CN102452886 A CN 102452886A
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- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical group CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 title claims abstract description 90
- 238000000034 method Methods 0.000 title claims abstract description 70
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 54
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 43
- 238000010533 azeotropic distillation Methods 0.000 claims abstract description 35
- 150000001336 alkenes Chemical class 0.000 claims abstract description 28
- 238000000895 extractive distillation Methods 0.000 claims abstract description 21
- 238000004821 distillation Methods 0.000 claims abstract description 19
- 238000005520 cutting process Methods 0.000 claims abstract description 16
- 239000002994 raw material Substances 0.000 claims abstract description 13
- 239000002253 acid Substances 0.000 claims abstract description 10
- 150000001335 aliphatic alkanes Chemical class 0.000 claims abstract description 9
- 239000002904 solvent Substances 0.000 claims description 45
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 claims description 44
- 238000010992 reflux Methods 0.000 claims description 35
- 239000003795 chemical substances by application Substances 0.000 claims description 25
- 238000005516 engineering process Methods 0.000 claims description 25
- 238000000605 extraction Methods 0.000 claims description 25
- 238000011084 recovery Methods 0.000 claims description 19
- 230000015572 biosynthetic process Effects 0.000 claims description 17
- 239000012046 mixed solvent Substances 0.000 claims description 17
- 238000000746 purification Methods 0.000 claims description 16
- 238000003786 synthesis reaction Methods 0.000 claims description 16
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 claims description 15
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims description 14
- 150000007524 organic acids Chemical class 0.000 claims description 12
- 238000000926 separation method Methods 0.000 claims description 6
- 230000018044 dehydration Effects 0.000 claims description 3
- 238000006297 dehydration reaction Methods 0.000 claims description 3
- 238000010521 absorption reaction Methods 0.000 claims description 2
- ZNNZYHKDIALBAK-UHFFFAOYSA-M potassium thiocyanate Chemical compound [K+].[S-]C#N ZNNZYHKDIALBAK-UHFFFAOYSA-M 0.000 claims description 2
- 230000001476 alcoholic effect Effects 0.000 claims 2
- ILPBINAXDRFYPL-UHFFFAOYSA-N 2-octene Chemical compound CCCCCC=CC ILPBINAXDRFYPL-UHFFFAOYSA-N 0.000 claims 1
- 208000005156 Dehydration Diseases 0.000 claims 1
- 238000010438 heat treatment Methods 0.000 claims 1
- 150000002500 ions Chemical class 0.000 claims 1
- 239000007788 liquid Substances 0.000 claims 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract description 8
- 150000001875 compounds Chemical class 0.000 abstract description 8
- 229910052760 oxygen Inorganic materials 0.000 abstract description 8
- 239000001301 oxygen Substances 0.000 abstract description 8
- 230000008901 benefit Effects 0.000 abstract description 3
- 238000013461 design Methods 0.000 abstract description 3
- 150000007513 acids Chemical class 0.000 abstract 1
- 239000003921 oil Substances 0.000 description 42
- 235000019441 ethanol Nutrition 0.000 description 23
- 239000004215 Carbon black (E152) Substances 0.000 description 22
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 18
- 229930195733 hydrocarbon Natural products 0.000 description 18
- 150000002430 hydrocarbons Chemical class 0.000 description 18
- 239000000047 product Substances 0.000 description 16
- 230000008569 process Effects 0.000 description 13
- 241000282326 Felis catus Species 0.000 description 11
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 11
- 239000000203 mixture Substances 0.000 description 9
- 238000004519 manufacturing process Methods 0.000 description 6
- -1 trifluoromethyl sulphonyl Chemical group 0.000 description 6
- 229910052799 carbon Inorganic materials 0.000 description 5
- AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 4
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- 239000003245 coal Substances 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000002283 diesel fuel Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000004508 fractional distillation Methods 0.000 description 2
- DCAYPVUWAIABOU-UHFFFAOYSA-N hexadecane Chemical compound CCCCCCCCCCCCCCCC DCAYPVUWAIABOU-UHFFFAOYSA-N 0.000 description 2
- 239000002608 ionic liquid Substances 0.000 description 2
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical group CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
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- GGQQNYXPYWCUHG-RMTFUQJTSA-N (3e,6e)-deca-3,6-diene Chemical compound CCC\C=C\C\C=C\CC GGQQNYXPYWCUHG-RMTFUQJTSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical class N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 239000012043 crude product Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000012847 fine chemical Substances 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000006317 isomerization reaction Methods 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 238000011020 pilot scale process Methods 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000001577 simple distillation Methods 0.000 description 1
- 239000013638 trimer Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
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Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103086823A (zh) * | 2013-02-07 | 2013-05-08 | 天津大学 | 一种正己烷、异己烷和苯的分离方法及设备 |
CN103360195A (zh) * | 2013-07-15 | 2013-10-23 | 上海兖矿能源科技研发有限公司 | 一种从碳氢(氧)混合物料中分离提纯1-辛烯的方法 |
CN105647575A (zh) * | 2016-02-18 | 2016-06-08 | 惠生工程(中国)有限公司 | 一种稳定轻烃升级利用的工艺 |
CN106349107A (zh) * | 2016-08-24 | 2017-01-25 | 青岛科技大学 | 一种非均相共沸精馏分离乙腈‑三乙胺混合物的方法及装置 |
CN109265307A (zh) * | 2018-08-09 | 2019-01-25 | 天津大学 | 利用反应分离耦合工艺从费托合成油中分离1-辛烯的方法与装置 |
CN109627137A (zh) * | 2018-11-14 | 2019-04-16 | 内蒙古伊泰煤基新材料研究院有限公司 | 一种用于煤基费托烯烃的分离方法 |
CN110087748A (zh) * | 2016-12-20 | 2019-08-02 | 沙特基础工业全球技术有限公司 | 分离直链α烯烃的方法 |
CN113457193A (zh) * | 2021-06-25 | 2021-10-01 | 济南大学 | 一种分离甲醇-甲缩醛-甲酸甲酯混合物的装置及方法 |
CN114409496A (zh) * | 2021-12-31 | 2022-04-29 | 国家能源集团宁夏煤业有限责任公司 | 从费托合成油中分离1-辛烯的方法和装置 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
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DE19833941A1 (de) * | 1998-07-28 | 2000-02-03 | Linde Ag | Verfahren und Destillationsvorrichtung zur Gewinnung von 1-Okten |
CN101213159A (zh) * | 2005-07-06 | 2008-07-02 | 英尼奥斯欧洲有限公司 | 生产线性α-烯烃的方法 |
-
2010
- 2010-10-22 CN CN201010526998.0A patent/CN102452886B/zh active Active
Patent Citations (2)
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DE19833941A1 (de) * | 1998-07-28 | 2000-02-03 | Linde Ag | Verfahren und Destillationsvorrichtung zur Gewinnung von 1-Okten |
CN101213159A (zh) * | 2005-07-06 | 2008-07-02 | 英尼奥斯欧洲有限公司 | 生产线性α-烯烃的方法 |
Non-Patent Citations (2)
Title |
---|
ARNO DE KLERK ET AL.: "Linear a-Olefins from Linear Internal Olefins by a Boron-Based Continuous Double-Bond Isomerization Process", 《IND. ENG. CHEM. RES.》, vol. 46, no. 2, 16 December 2006 (2006-12-16), pages 400 - 410 * |
任杰等: "F-T合成油品加工技术的研究进展", 《燃料化学学报》, vol. 37, no. 6, 31 December 2009 (2009-12-31), pages 769 - 776 * |
Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103086823B (zh) * | 2013-02-07 | 2015-07-01 | 天津大学 | 一种正己烷、异己烷和苯的分离方法及设备 |
CN103086823A (zh) * | 2013-02-07 | 2013-05-08 | 天津大学 | 一种正己烷、异己烷和苯的分离方法及设备 |
CN103360195A (zh) * | 2013-07-15 | 2013-10-23 | 上海兖矿能源科技研发有限公司 | 一种从碳氢(氧)混合物料中分离提纯1-辛烯的方法 |
CN103360195B (zh) * | 2013-07-15 | 2015-09-30 | 上海兖矿能源科技研发有限公司 | 一种从碳氢(氧)混合物料中分离提纯1-辛烯的方法 |
CN105647575A (zh) * | 2016-02-18 | 2016-06-08 | 惠生工程(中国)有限公司 | 一种稳定轻烃升级利用的工艺 |
CN106349107A (zh) * | 2016-08-24 | 2017-01-25 | 青岛科技大学 | 一种非均相共沸精馏分离乙腈‑三乙胺混合物的方法及装置 |
CN110087748A (zh) * | 2016-12-20 | 2019-08-02 | 沙特基础工业全球技术有限公司 | 分离直链α烯烃的方法 |
CN109265307A (zh) * | 2018-08-09 | 2019-01-25 | 天津大学 | 利用反应分离耦合工艺从费托合成油中分离1-辛烯的方法与装置 |
CN109265307B (zh) * | 2018-08-09 | 2021-07-30 | 天津大学 | 利用反应分离耦合工艺从费托合成油中分离1-辛烯的方法与装置 |
CN109627137A (zh) * | 2018-11-14 | 2019-04-16 | 内蒙古伊泰煤基新材料研究院有限公司 | 一种用于煤基费托烯烃的分离方法 |
CN109627137B (zh) * | 2018-11-14 | 2019-11-15 | 内蒙古伊泰煤基新材料研究院有限公司 | 一种用于煤基费托烯烃的分离方法 |
CN113457193A (zh) * | 2021-06-25 | 2021-10-01 | 济南大学 | 一种分离甲醇-甲缩醛-甲酸甲酯混合物的装置及方法 |
CN114409496A (zh) * | 2021-12-31 | 2022-04-29 | 国家能源集团宁夏煤业有限责任公司 | 从费托合成油中分离1-辛烯的方法和装置 |
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Address after: 101407 Beijing city Huairou District Yanqi Economic Development Zone Park south two Street No. 1 Patentee after: SYNEFUELS CHINA Inc. Address before: 101407 Beijing city Huairou District Yanqi Economic Development Zone C District No. 1 south two Street Park Patentee before: SYNFUELS CHINA |