CN102414187B - 采用催化剂随其老化而制备环氧烷的方法 - Google Patents

采用催化剂随其老化而制备环氧烷的方法 Download PDF

Info

Publication number
CN102414187B
CN102414187B CN201080017744.4A CN201080017744A CN102414187B CN 102414187 B CN102414187 B CN 102414187B CN 201080017744 A CN201080017744 A CN 201080017744A CN 102414187 B CN102414187 B CN 102414187B
Authority
CN
China
Prior art keywords
catalyst
concentration
reaction temperature
total
effect
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201080017744.4A
Other languages
English (en)
Chinese (zh)
Other versions
CN102414187A (zh
Inventor
张丽萍
赫维利·索奥
威廉·亨斯托克
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Technology Investments LLC
Original Assignee
Dow Technology Investments LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=42307796&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=CN102414187(B) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Dow Technology Investments LLC filed Critical Dow Technology Investments LLC
Publication of CN102414187A publication Critical patent/CN102414187A/zh
Application granted granted Critical
Publication of CN102414187B publication Critical patent/CN102414187B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
    • C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/22—Synthesis of the oxirane ring by oxidation of saturated compounds with air or molecular oxygen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/24—Synthesis of the oxirane ring by splitting off HAL—Y from compounds containing the radical HAL—C—C—OY
    • C07D301/26—Y being hydrogen
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Epoxy Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CN201080017744.4A 2009-04-21 2010-04-20 采用催化剂随其老化而制备环氧烷的方法 Active CN102414187B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US17124809P 2009-04-21 2009-04-21
US61/171,248 2009-04-21
PCT/US2010/031668 WO2010123842A1 (en) 2009-04-21 2010-04-20 Simplified method for producing alkylene oxides with a high efficiency catalyst as it ages

Publications (2)

Publication Number Publication Date
CN102414187A CN102414187A (zh) 2012-04-11
CN102414187B true CN102414187B (zh) 2016-06-01

Family

ID=42307796

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201080017744.4A Active CN102414187B (zh) 2009-04-21 2010-04-20 采用催化剂随其老化而制备环氧烷的方法

Country Status (9)

Country Link
US (1) US8389751B2 (https=)
EP (1) EP2421840B1 (https=)
JP (1) JP2012524785A (https=)
KR (1) KR101745737B1 (https=)
CN (1) CN102414187B (https=)
CA (1) CA2758818C (https=)
SG (1) SG175770A1 (https=)
TW (1) TWI508955B (https=)
WO (1) WO2010123842A1 (https=)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010123844A1 (en) * 2009-04-21 2010-10-28 Dow Technology Investments Llc Improved method of achieving and maintaining a specified alkylene oxide production parameter with a high efficiency catalyst
US8742147B2 (en) 2010-12-08 2014-06-03 Shell Oil Company Process for improving the selectivity of an EO catalyst
KR101886462B1 (ko) * 2010-12-10 2018-08-07 다우 테크놀로지 인베스트먼츠 엘엘씨. 고효율 촉매를 사용하는 알킬렌 옥사이드 제조 방법에서 알킬렌 옥사이드 생산 변수의 값을 감소시키는 방법
SG190901A1 (en) * 2010-12-15 2013-07-31 Dow Technology Investments Llc Method of starting-up a process of producing an alkylene oxide using a high-efficiency catalyst
CN103502229B (zh) 2011-04-29 2016-02-03 国际壳牌研究有限公司 用于改善环氧乙烷催化剂选择性的方法
WO2013059225A1 (en) * 2011-10-18 2013-04-25 Al-Ahmadi Hassan Eisa Epoxidation process with added moderator
EP2788337B1 (en) 2011-12-09 2016-03-02 Dow Technology Investments LLC Method of maintaining the value of an alkylene oxide production parameter in a process of making an alkylene oxide using a high efficiency catalyst
CN105143161B (zh) * 2013-03-15 2018-08-10 陶氏技术投资有限责任公司 用于制造环氧乙烷的方法
JP6340895B2 (ja) * 2014-04-24 2018-06-13 東ソー株式会社 触媒性能の経時変化解析方法および触媒性能の経時変化解析装置
CN105330617B (zh) * 2014-07-18 2018-12-28 中国石油化工股份有限公司 一种生产环氧乙烷的方法
US10208005B2 (en) 2014-12-30 2019-02-19 Dow Technology Investments Llc Process for manufacturing ethylene oxide using scaled selectivity values
EP3495445B1 (en) 2016-08-05 2023-11-15 Konoshima Chemical Co., Ltd. Method for producing al-doped gadolinium oxysulfide cold storage medium
CN111450778B (zh) * 2019-01-22 2023-04-07 中国石化工程建设有限公司 一种用于制备聚α-烯烃的聚合反应系统和方法
CN111939846B (zh) * 2019-05-17 2023-01-03 中国石化工程建设有限公司 一种合成聚α-烯烃的装置及方法
US11249446B2 (en) 2019-10-25 2022-02-15 Dow Global Technologies Llc Nonlinear model predictive control of a process
CA3204704A1 (en) * 2020-12-29 2022-07-07 Shell Internationale Research Maatschappij B.V. Process for the production of ethylene oxide
CN117099163A (zh) 2021-04-08 2023-11-21 国际壳牌研究有限公司 乙烯环氧化的缓和剂和催化剂性能优化
CN118019732A (zh) * 2021-09-23 2024-05-10 陶氏环球技术有限责任公司 用于降低高选择性环氧乙烷催化剂的老化相关失活的方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1282772C (en) * 1989-02-17 1991-04-09 Union Carbide Corporation Carbonate-supported catalytic system for epoxidation of alkenes
CN1260788A (zh) * 1997-06-23 2000-07-19 阿科化学技术公司 用经有机氯化物预处理的载体上的银催化剂进行的环氧化方法
CN1809419A (zh) * 2003-04-01 2006-07-26 国际壳牌研究有限公司 烯烃环氧化方法及用于该方法的催化剂
CN1860109A (zh) * 2003-09-29 2006-11-08 联合碳化化学及塑料技术公司 使用气相助催化剂系统制备烯化氧的方法

Family Cites Families (42)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE752859R (fr) 1969-07-10 1971-01-04 Halcon International Inc Oxydation controlee de l'oxyde
US5387751A (en) * 1978-02-10 1995-02-07 Imperial Chemical Industries Plc Production of olefine oxides
JPS6110570A (ja) * 1984-06-25 1986-01-18 Mitsui Toatsu Chem Inc エチレンオキシドの製造方法
CA1286687C (en) * 1985-08-13 1991-07-23 Michael Paul Habenschuss Process for manufacture of alkene oxide
US4766105A (en) * 1986-10-31 1988-08-23 Shell Oil Company Ethylene oxide catalyst and process for preparing the catalyst
US4761394A (en) * 1986-10-31 1988-08-02 Shell Oil Company Ethylene oxide catalyst and process for preparing the catalyst
US4820675A (en) * 1986-10-31 1989-04-11 Shell Oil Company Ethylene oxide catalyst & process for preparing the catalyst
US4808738A (en) * 1986-10-31 1989-02-28 Shell Oil Company Ethylene oxide process
IL84232A (en) 1986-10-31 1992-06-21 Shell Int Research Catalyst and process for the catalytic production of ethylene oxide
GB8626687D0 (en) * 1986-11-07 1986-12-10 Shell Int Research Preparing silver catalyst
US4908343A (en) * 1987-02-20 1990-03-13 Union Carbide Chemicals And Plastics Company Inc. Catalyst composition for oxidation of ethylene to ethylene oxide
US4769047A (en) * 1987-06-29 1988-09-06 Shell Oil Company Process for the production of ethylene oxide
GB8716653D0 (en) * 1987-07-15 1987-08-19 Shell Int Research Silver-containing catalyst
US4759313A (en) * 1987-10-30 1988-07-26 Shell Oil Company Ethylene oxide process improvement
US4874879A (en) * 1988-07-25 1989-10-17 Shell Oil Company Process for starting-up an ethylene oxide reactor
CA1339317C (en) 1988-07-25 1997-08-19 Ann Marie Lauritzen Process for producing ethylene oxide
EP0357293B1 (en) 1988-08-30 1996-02-28 Union Carbide Corporation Catalysts for the production of ethylene oxide and their preparation processes
CA1337722C (en) * 1989-04-18 1995-12-12 Madan Mohan Bhasin Alkylene oxide catalysts having enhanced activity and/or stability
GB9005964D0 (en) * 1990-03-16 1990-05-09 Shell Int Research Catalyst preparation process
US5102848A (en) * 1990-09-28 1992-04-07 Union Carbide Chemicals & Plastics Technology Corporation Catalyst composition for oxidation of ethylene to ethylene oxide
JP2720124B2 (ja) * 1990-10-12 1998-02-25 ユニオン・カーバイド、ケミカルズ、アンド、プラスチックス、テクノロジー、コーポレーション 向上された活性度及び／又は安定度を有するアルキレンオキシド触媒
CA2053404A1 (en) 1990-10-12 1992-04-13 Erlind M. Thorsteinson Ultrahigh efficiency alkylene oxide catalysts having enhanced stability
US5145824A (en) * 1991-01-22 1992-09-08 Shell Oil Company Ethylene oxide catalyst
US5228484A (en) * 1991-06-20 1993-07-20 Catalyst Technology, Inc. Air lance reel for catalyst unloading of tubular reactors
US5155242A (en) * 1991-12-05 1992-10-13 Shell Oil Company Process for starting-up an ethylene oxide reactor
US5262551A (en) * 1992-04-20 1993-11-16 Texaco Chemical Company Process for ethylene expoxidation
US5447897A (en) * 1993-05-17 1995-09-05 Shell Oil Company Ethylene oxide catalyst and process
US5380697A (en) * 1993-09-08 1995-01-10 Shell Oil Company Ethylene oxide catalyst and process
US5364826A (en) * 1993-09-13 1994-11-15 Shell Oil Company Process for preparing ethylene oxide catalysts
TW314512B (https=) * 1993-09-20 1997-09-01 Shell Int Research
US5418202A (en) * 1993-12-30 1995-05-23 Shell Oil Company Ethylene oxide catalyst and process
US5545603A (en) * 1994-11-01 1996-08-13 Shell Oil Company Ethylene oxide catalyst and process
ZA963000B (en) * 1995-04-18 1996-10-22 Shell Int Research Process for the catalytic vapour phase oxidation of ethylene
US5739075A (en) 1995-10-06 1998-04-14 Shell Oil Company Process for preparing ethylene oxide catalysts
CZ161198A3 (cs) * 1995-11-23 1998-09-16 Shell Internationale Research Maatschappij B. V. Postup přípravy alkylenglykolů
US5801259A (en) * 1996-04-30 1998-09-01 Shell Oil Company Ethylene oxide catalyst and process
US5840932A (en) * 1996-05-21 1998-11-24 Shell Oil Company Process for ethylene oxide production
WO1997046317A1 (en) * 1996-06-05 1997-12-11 Shell Internationale Research Maatschappij B.V. Epoxidation catalyst and process
BR0214282A (pt) 2001-11-20 2004-09-21 Shell Int Research Processos e sistemas para epoxidação de uma olefina
RU2005102097A (ru) 2002-06-28 2005-08-27 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. (NL) Способ введения в действие способа эпоксидирования и способ эпоксидирования олефина
WO2007123932A2 (en) 2006-04-18 2007-11-01 Dow Global Technologies Inc. Alkylene oxide catalyst and use thereof
US7803957B2 (en) 2007-09-11 2010-09-28 Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg Ethylene oxide production using fixed moderator concentration

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1282772C (en) * 1989-02-17 1991-04-09 Union Carbide Corporation Carbonate-supported catalytic system for epoxidation of alkenes
CN1260788A (zh) * 1997-06-23 2000-07-19 阿科化学技术公司 用经有机氯化物预处理的载体上的银催化剂进行的环氧化方法
CN1809419A (zh) * 2003-04-01 2006-07-26 国际壳牌研究有限公司 烯烃环氧化方法及用于该方法的催化剂
CN1860109A (zh) * 2003-09-29 2006-11-08 联合碳化化学及塑料技术公司 使用气相助催化剂系统制备烯化氧的方法

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
《环氧乙烷银催化剂中助催化剂的研究进展》;毛东森;《石化技术》;19970331;第4卷(第1期);第59-60页 *

Also Published As

Publication number Publication date
SG175770A1 (en) 2011-12-29
TW201100394A (en) 2011-01-01
EP2421840A1 (en) 2012-02-29
CA2758818C (en) 2018-05-29
KR20120014159A (ko) 2012-02-16
EP2421840B1 (en) 2015-12-16
CN102414187A (zh) 2012-04-11
US20100267974A1 (en) 2010-10-21
JP2012524785A (ja) 2012-10-18
CA2758818A1 (en) 2010-10-28
KR101745737B1 (ko) 2017-06-09
TWI508955B (zh) 2015-11-21
WO2010123842A1 (en) 2010-10-28
US8389751B2 (en) 2013-03-05

Similar Documents

Publication Publication Date Title
CN102414187B (zh) 采用催化剂随其老化而制备环氧烷的方法
CN102414188B (zh) 使用高效催化剂的获得并保持指定的环氧烷生产参数的改进方法
CN102414189B (zh) 环氧化反应及其操作条件
JP5584284B2 (ja) レニウム促進されたエポキシ化触媒の効率を高める方法及びこれらの方法を利用したエポキシ化方法
TWI609861B (zh) 關於催化劑參考性質的調配環氧烷催化劑之方法
CA2540563C (en) A process for the production of alkylene oxide using a gas-phase promoter system
CA2819233C (en) Method of starting-up a process of producing an alkylene oxide using a high-efficiency catalyst
TWI574951B (zh) 調節高效率環氧乙烷催化劑的方法

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant