KR101745737B1 - 고 효율 촉매가 노화될 때 고 효율 촉매를 사용하는 간편화된 알킬렌 옥사이드 생산 방법 - Google Patents
고 효율 촉매가 노화될 때 고 효율 촉매를 사용하는 간편화된 알킬렌 옥사이드 생산 방법 Download PDFInfo
- Publication number
- KR101745737B1 KR101745737B1 KR1020117027498A KR20117027498A KR101745737B1 KR 101745737 B1 KR101745737 B1 KR 101745737B1 KR 1020117027498 A KR1020117027498 A KR 1020117027498A KR 20117027498 A KR20117027498 A KR 20117027498A KR 101745737 B1 KR101745737 B1 KR 101745737B1
- Authority
- KR
- South Korea
- Prior art keywords
- catalyst
- reaction temperature
- concentration
- effectiveness
- total
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
- C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
- C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/22—Synthesis of the oxirane ring by oxidation of saturated compounds with air or molecular oxygen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/24—Synthesis of the oxirane ring by splitting off HAL—Y from compounds containing the radical HAL—C—C—OY
- C07D301/26—Y being hydrogen
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Epoxy Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US17124809P | 2009-04-21 | 2009-04-21 | |
| US61/171,248 | 2009-04-21 | ||
| PCT/US2010/031668 WO2010123842A1 (en) | 2009-04-21 | 2010-04-20 | Simplified method for producing alkylene oxides with a high efficiency catalyst as it ages |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20120014159A KR20120014159A (ko) | 2012-02-16 |
| KR101745737B1 true KR101745737B1 (ko) | 2017-06-09 |
Family
ID=42307796
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020117027498A Expired - Fee Related KR101745737B1 (ko) | 2009-04-21 | 2010-04-20 | 고 효율 촉매가 노화될 때 고 효율 촉매를 사용하는 간편화된 알킬렌 옥사이드 생산 방법 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US8389751B2 (https=) |
| EP (1) | EP2421840B1 (https=) |
| JP (1) | JP2012524785A (https=) |
| KR (1) | KR101745737B1 (https=) |
| CN (1) | CN102414187B (https=) |
| CA (1) | CA2758818C (https=) |
| SG (1) | SG175770A1 (https=) |
| TW (1) | TWI508955B (https=) |
| WO (1) | WO2010123842A1 (https=) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2010123844A1 (en) * | 2009-04-21 | 2010-10-28 | Dow Technology Investments Llc | Improved method of achieving and maintaining a specified alkylene oxide production parameter with a high efficiency catalyst |
| US8742147B2 (en) | 2010-12-08 | 2014-06-03 | Shell Oil Company | Process for improving the selectivity of an EO catalyst |
| KR101886462B1 (ko) * | 2010-12-10 | 2018-08-07 | 다우 테크놀로지 인베스트먼츠 엘엘씨. | 고효율 촉매를 사용하는 알킬렌 옥사이드 제조 방법에서 알킬렌 옥사이드 생산 변수의 값을 감소시키는 방법 |
| SG190901A1 (en) * | 2010-12-15 | 2013-07-31 | Dow Technology Investments Llc | Method of starting-up a process of producing an alkylene oxide using a high-efficiency catalyst |
| CN103502229B (zh) | 2011-04-29 | 2016-02-03 | 国际壳牌研究有限公司 | 用于改善环氧乙烷催化剂选择性的方法 |
| WO2013059225A1 (en) * | 2011-10-18 | 2013-04-25 | Al-Ahmadi Hassan Eisa | Epoxidation process with added moderator |
| EP2788337B1 (en) | 2011-12-09 | 2016-03-02 | Dow Technology Investments LLC | Method of maintaining the value of an alkylene oxide production parameter in a process of making an alkylene oxide using a high efficiency catalyst |
| CN105143161B (zh) * | 2013-03-15 | 2018-08-10 | 陶氏技术投资有限责任公司 | 用于制造环氧乙烷的方法 |
| JP6340895B2 (ja) * | 2014-04-24 | 2018-06-13 | 東ソー株式会社 | 触媒性能の経時変化解析方法および触媒性能の経時変化解析装置 |
| CN105330617B (zh) * | 2014-07-18 | 2018-12-28 | 中国石油化工股份有限公司 | 一种生产环氧乙烷的方法 |
| US10208005B2 (en) | 2014-12-30 | 2019-02-19 | Dow Technology Investments Llc | Process for manufacturing ethylene oxide using scaled selectivity values |
| EP3495445B1 (en) | 2016-08-05 | 2023-11-15 | Konoshima Chemical Co., Ltd. | Method for producing al-doped gadolinium oxysulfide cold storage medium |
| CN111450778B (zh) * | 2019-01-22 | 2023-04-07 | 中国石化工程建设有限公司 | 一种用于制备聚α-烯烃的聚合反应系统和方法 |
| CN111939846B (zh) * | 2019-05-17 | 2023-01-03 | 中国石化工程建设有限公司 | 一种合成聚α-烯烃的装置及方法 |
| US11249446B2 (en) | 2019-10-25 | 2022-02-15 | Dow Global Technologies Llc | Nonlinear model predictive control of a process |
| CA3204704A1 (en) * | 2020-12-29 | 2022-07-07 | Shell Internationale Research Maatschappij B.V. | Process for the production of ethylene oxide |
| CN117099163A (zh) | 2021-04-08 | 2023-11-21 | 国际壳牌研究有限公司 | 乙烯环氧化的缓和剂和催化剂性能优化 |
| CN118019732A (zh) * | 2021-09-23 | 2024-05-10 | 陶氏环球技术有限责任公司 | 用于降低高选择性环氧乙烷催化剂的老化相关失活的方法 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20040198993A1 (en) | 2003-04-01 | 2004-10-07 | Marek Matusz | Olefin epoxidation process and a catalyst for use in the process |
| WO2007123932A2 (en) | 2006-04-18 | 2007-11-01 | Dow Global Technologies Inc. | Alkylene oxide catalyst and use thereof |
| WO2009035809A1 (en) | 2007-09-11 | 2009-03-19 | Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg | Ethylene oxide production using fixed moderator concentration |
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| BE752859R (fr) | 1969-07-10 | 1971-01-04 | Halcon International Inc | Oxydation controlee de l'oxyde |
| US5387751A (en) * | 1978-02-10 | 1995-02-07 | Imperial Chemical Industries Plc | Production of olefine oxides |
| JPS6110570A (ja) * | 1984-06-25 | 1986-01-18 | Mitsui Toatsu Chem Inc | エチレンオキシドの製造方法 |
| CA1286687C (en) * | 1985-08-13 | 1991-07-23 | Michael Paul Habenschuss | Process for manufacture of alkene oxide |
| US4766105A (en) * | 1986-10-31 | 1988-08-23 | Shell Oil Company | Ethylene oxide catalyst and process for preparing the catalyst |
| US4761394A (en) * | 1986-10-31 | 1988-08-02 | Shell Oil Company | Ethylene oxide catalyst and process for preparing the catalyst |
| US4820675A (en) * | 1986-10-31 | 1989-04-11 | Shell Oil Company | Ethylene oxide catalyst & process for preparing the catalyst |
| US4808738A (en) * | 1986-10-31 | 1989-02-28 | Shell Oil Company | Ethylene oxide process |
| IL84232A (en) | 1986-10-31 | 1992-06-21 | Shell Int Research | Catalyst and process for the catalytic production of ethylene oxide |
| GB8626687D0 (en) * | 1986-11-07 | 1986-12-10 | Shell Int Research | Preparing silver catalyst |
| US4908343A (en) * | 1987-02-20 | 1990-03-13 | Union Carbide Chemicals And Plastics Company Inc. | Catalyst composition for oxidation of ethylene to ethylene oxide |
| US4769047A (en) * | 1987-06-29 | 1988-09-06 | Shell Oil Company | Process for the production of ethylene oxide |
| GB8716653D0 (en) * | 1987-07-15 | 1987-08-19 | Shell Int Research | Silver-containing catalyst |
| US4759313A (en) * | 1987-10-30 | 1988-07-26 | Shell Oil Company | Ethylene oxide process improvement |
| US4874879A (en) * | 1988-07-25 | 1989-10-17 | Shell Oil Company | Process for starting-up an ethylene oxide reactor |
| CA1339317C (en) | 1988-07-25 | 1997-08-19 | Ann Marie Lauritzen | Process for producing ethylene oxide |
| EP0357293B1 (en) | 1988-08-30 | 1996-02-28 | Union Carbide Corporation | Catalysts for the production of ethylene oxide and their preparation processes |
| CA1282772C (en) * | 1989-02-17 | 1991-04-09 | Union Carbide Corporation | Carbonate-supported catalytic system for epoxidation of alkenes |
| CA1337722C (en) * | 1989-04-18 | 1995-12-12 | Madan Mohan Bhasin | Alkylene oxide catalysts having enhanced activity and/or stability |
| GB9005964D0 (en) * | 1990-03-16 | 1990-05-09 | Shell Int Research | Catalyst preparation process |
| US5102848A (en) * | 1990-09-28 | 1992-04-07 | Union Carbide Chemicals & Plastics Technology Corporation | Catalyst composition for oxidation of ethylene to ethylene oxide |
| JP2720124B2 (ja) * | 1990-10-12 | 1998-02-25 | ユニオン・カーバイド、ケミカルズ、アンド、プラスチックス、テクノロジー、コーポレーション | 向上された活性度及び/又は安定度を有するアルキレンオキシド触媒 |
| CA2053404A1 (en) | 1990-10-12 | 1992-04-13 | Erlind M. Thorsteinson | Ultrahigh efficiency alkylene oxide catalysts having enhanced stability |
| US5145824A (en) * | 1991-01-22 | 1992-09-08 | Shell Oil Company | Ethylene oxide catalyst |
| US5228484A (en) * | 1991-06-20 | 1993-07-20 | Catalyst Technology, Inc. | Air lance reel for catalyst unloading of tubular reactors |
| US5155242A (en) * | 1991-12-05 | 1992-10-13 | Shell Oil Company | Process for starting-up an ethylene oxide reactor |
| US5262551A (en) * | 1992-04-20 | 1993-11-16 | Texaco Chemical Company | Process for ethylene expoxidation |
| US5447897A (en) * | 1993-05-17 | 1995-09-05 | Shell Oil Company | Ethylene oxide catalyst and process |
| US5380697A (en) * | 1993-09-08 | 1995-01-10 | Shell Oil Company | Ethylene oxide catalyst and process |
| US5364826A (en) * | 1993-09-13 | 1994-11-15 | Shell Oil Company | Process for preparing ethylene oxide catalysts |
| TW314512B (https=) * | 1993-09-20 | 1997-09-01 | Shell Int Research | |
| US5418202A (en) * | 1993-12-30 | 1995-05-23 | Shell Oil Company | Ethylene oxide catalyst and process |
| US5545603A (en) * | 1994-11-01 | 1996-08-13 | Shell Oil Company | Ethylene oxide catalyst and process |
| ZA963000B (en) * | 1995-04-18 | 1996-10-22 | Shell Int Research | Process for the catalytic vapour phase oxidation of ethylene |
| US5739075A (en) | 1995-10-06 | 1998-04-14 | Shell Oil Company | Process for preparing ethylene oxide catalysts |
| CZ161198A3 (cs) * | 1995-11-23 | 1998-09-16 | Shell Internationale Research Maatschappij B. V. | Postup přípravy alkylenglykolů |
| US5801259A (en) * | 1996-04-30 | 1998-09-01 | Shell Oil Company | Ethylene oxide catalyst and process |
| US5840932A (en) * | 1996-05-21 | 1998-11-24 | Shell Oil Company | Process for ethylene oxide production |
| WO1997046317A1 (en) * | 1996-06-05 | 1997-12-11 | Shell Internationale Research Maatschappij B.V. | Epoxidation catalyst and process |
| US5770746A (en) * | 1997-06-23 | 1998-06-23 | Arco Chemical Technology, L.P. | Epoxidation process using supported silver catalysts pretreated with organic chloride |
| BR0214282A (pt) | 2001-11-20 | 2004-09-21 | Shell Int Research | Processos e sistemas para epoxidação de uma olefina |
| RU2005102097A (ru) | 2002-06-28 | 2005-08-27 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. (NL) | Способ введения в действие способа эпоксидирования и способ эпоксидирования олефина |
| RU2360908C2 (ru) * | 2003-09-29 | 2009-07-10 | Дау Текнолоджи Инвестментс Ллс. | Способ получения алкиленоксида с использованием газофазной промоторной системы |
-
2010
- 2010-04-20 JP JP2012507296A patent/JP2012524785A/ja active Pending
- 2010-04-20 TW TW099112280A patent/TWI508955B/zh active
- 2010-04-20 CA CA2758818A patent/CA2758818C/en not_active Expired - Fee Related
- 2010-04-20 US US12/763,276 patent/US8389751B2/en not_active Expired - Fee Related
- 2010-04-20 EP EP10718767.6A patent/EP2421840B1/en not_active Revoked
- 2010-04-20 WO PCT/US2010/031668 patent/WO2010123842A1/en not_active Ceased
- 2010-04-20 KR KR1020117027498A patent/KR101745737B1/ko not_active Expired - Fee Related
- 2010-04-20 CN CN201080017744.4A patent/CN102414187B/zh active Active
- 2010-04-20 SG SG2011077575A patent/SG175770A1/en unknown
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20040198993A1 (en) | 2003-04-01 | 2004-10-07 | Marek Matusz | Olefin epoxidation process and a catalyst for use in the process |
| WO2007123932A2 (en) | 2006-04-18 | 2007-11-01 | Dow Global Technologies Inc. | Alkylene oxide catalyst and use thereof |
| WO2009035809A1 (en) | 2007-09-11 | 2009-03-19 | Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg | Ethylene oxide production using fixed moderator concentration |
Also Published As
| Publication number | Publication date |
|---|---|
| SG175770A1 (en) | 2011-12-29 |
| TW201100394A (en) | 2011-01-01 |
| CN102414187B (zh) | 2016-06-01 |
| EP2421840A1 (en) | 2012-02-29 |
| CA2758818C (en) | 2018-05-29 |
| KR20120014159A (ko) | 2012-02-16 |
| EP2421840B1 (en) | 2015-12-16 |
| CN102414187A (zh) | 2012-04-11 |
| US20100267974A1 (en) | 2010-10-21 |
| JP2012524785A (ja) | 2012-10-18 |
| CA2758818A1 (en) | 2010-10-28 |
| TWI508955B (zh) | 2015-11-21 |
| WO2010123842A1 (en) | 2010-10-28 |
| US8389751B2 (en) | 2013-03-05 |
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