CN102361901B - 具有改进的储存稳定性的可湿固化甲硅烷基化聚合物 - Google Patents
具有改进的储存稳定性的可湿固化甲硅烷基化聚合物 Download PDFInfo
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- CN102361901B CN102361901B CN201080013146.XA CN201080013146A CN102361901B CN 102361901 B CN102361901 B CN 102361901B CN 201080013146 A CN201080013146 A CN 201080013146A CN 102361901 B CN102361901 B CN 102361901B
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- Prior art keywords
- silane
- amino
- sulfydryl
- methyl
- propyl
- Prior art date
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- 238000003860 storage Methods 0.000 title abstract description 16
- 229920000642 polymer Polymers 0.000 title description 56
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims abstract description 142
- 229910000077 silane Inorganic materials 0.000 claims abstract description 84
- 239000000376 reactant Substances 0.000 claims abstract description 27
- 125000003545 alkoxy group Chemical group 0.000 claims abstract description 13
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 13
- -1 methoxyl groups Chemical group 0.000 claims description 202
- 239000000203 mixture Substances 0.000 claims description 101
- SOPZLXDKMICEMF-UHFFFAOYSA-N diethoxysilicon Chemical compound CCO[Si]OCC SOPZLXDKMICEMF-UHFFFAOYSA-N 0.000 claims description 78
- 239000000126 substance Substances 0.000 claims description 62
- 239000003795 chemical substances by application Substances 0.000 claims description 43
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 42
- 229920001730 Moisture cure polyurethane Polymers 0.000 claims description 37
- 239000002585 base Substances 0.000 claims description 36
- 238000006884 silylation reaction Methods 0.000 claims description 29
- 238000002360 preparation method Methods 0.000 claims description 27
- MUXOBHXGJLMRAB-UHFFFAOYSA-N Dimethyl succinate Chemical compound COC(=O)CCC(=O)OC MUXOBHXGJLMRAB-UHFFFAOYSA-N 0.000 claims description 24
- UGJLGGUQXBCUIA-UHFFFAOYSA-N CCO[SiH](OC)OC Chemical compound CCO[SiH](OC)OC UGJLGGUQXBCUIA-UHFFFAOYSA-N 0.000 claims description 21
- 229910052799 carbon Inorganic materials 0.000 claims description 21
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 21
- 150000001412 amines Chemical class 0.000 claims description 20
- 239000002516 radical scavenger Substances 0.000 claims description 19
- 229920000570 polyether Polymers 0.000 claims description 18
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 18
- 125000003944 tolyl group Chemical group 0.000 claims description 18
- 238000007789 sealing Methods 0.000 claims description 17
- YUXIBTJKHLUKBD-UHFFFAOYSA-N Dibutyl succinate Chemical compound CCCCOC(=O)CCC(=O)OCCCC YUXIBTJKHLUKBD-UHFFFAOYSA-N 0.000 claims description 16
- DKMROQRQHGEIOW-UHFFFAOYSA-N Diethyl succinate Chemical compound CCOC(=O)CCC(=O)OCC DKMROQRQHGEIOW-UHFFFAOYSA-N 0.000 claims description 16
- 229960002097 dibutylsuccinate Drugs 0.000 claims description 16
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 15
- 150000002148 esters Chemical class 0.000 claims description 14
- 239000000945 filler Substances 0.000 claims description 14
- 239000003054 catalyst Substances 0.000 claims description 13
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 13
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 12
- 239000008199 coating composition Substances 0.000 claims description 12
- 239000001257 hydrogen Substances 0.000 claims description 12
- 229910052739 hydrogen Inorganic materials 0.000 claims description 12
- 239000004902 Softening Agent Substances 0.000 claims description 11
- 239000000853 adhesive Substances 0.000 claims description 10
- 230000001070 adhesive effect Effects 0.000 claims description 10
- 229910052760 oxygen Inorganic materials 0.000 claims description 10
- 239000013008 thixotropic agent Substances 0.000 claims description 10
- XSQUKJJJFZCRTK-UHFFFAOYSA-N urea group Chemical group NC(=O)N XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 10
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 9
- 239000003292 glue Substances 0.000 claims description 9
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 claims description 8
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 8
- 239000003112 inhibitor Substances 0.000 claims description 8
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 claims description 8
- BUZRAOJSFRKWPD-UHFFFAOYSA-N isocyanatosilane Chemical compound [SiH3]N=C=O BUZRAOJSFRKWPD-UHFFFAOYSA-N 0.000 claims description 8
- 230000003647 oxidation Effects 0.000 claims description 8
- 238000007254 oxidation reaction Methods 0.000 claims description 8
- 239000001301 oxygen Substances 0.000 claims description 8
- 239000013543 active substance Substances 0.000 claims description 7
- 239000008187 granular material Substances 0.000 claims description 7
- 239000003960 organic solvent Substances 0.000 claims description 7
- FZHAPNGMFPVSLP-UHFFFAOYSA-N silanamine Chemical compound [SiH3]N FZHAPNGMFPVSLP-UHFFFAOYSA-N 0.000 claims description 7
- ZZHNUBIHHLQNHX-UHFFFAOYSA-N butoxysilane Chemical class CCCCO[SiH3] ZZHNUBIHHLQNHX-UHFFFAOYSA-N 0.000 claims description 6
- 125000000031 ethylamino group Chemical group [H]C([H])([H])C([H])([H])N([H])[*] 0.000 claims description 6
- 125000000524 functional group Chemical group 0.000 claims description 6
- 229910052757 nitrogen Inorganic materials 0.000 claims description 6
- HCOKJWUULRTBRS-UHFFFAOYSA-N propan-2-yloxysilane Chemical compound CC(C)O[SiH3] HCOKJWUULRTBRS-UHFFFAOYSA-N 0.000 claims description 6
- ZMYXZXUHYAGGKG-UHFFFAOYSA-N propoxysilane Chemical compound CCCO[SiH3] ZMYXZXUHYAGGKG-UHFFFAOYSA-N 0.000 claims description 6
- YUYCVXFAYWRXLS-UHFFFAOYSA-N trimethoxysilane Chemical compound CO[SiH](OC)OC YUYCVXFAYWRXLS-UHFFFAOYSA-N 0.000 claims description 6
- UQGBCDGMUYQNLX-UHFFFAOYSA-N 3-[ethoxy(dimethoxy)silyl]propan-1-amine Chemical compound CCO[Si](OC)(OC)CCCN UQGBCDGMUYQNLX-UHFFFAOYSA-N 0.000 claims description 5
- 239000005058 Isophorone diisocyanate Substances 0.000 claims description 5
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 claims description 5
- QQQSFSZALRVCSZ-UHFFFAOYSA-N triethoxysilane Chemical compound CCO[SiH](OCC)OCC QQQSFSZALRVCSZ-UHFFFAOYSA-N 0.000 claims description 5
- 239000004215 Carbon black (E152) Substances 0.000 claims description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 4
- 239000005864 Sulphur Substances 0.000 claims description 4
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 4
- 125000005745 ethoxymethyl group Chemical group [H]C([H])([H])C([H])([H])OC([H])([H])* 0.000 claims description 4
- 229930195733 hydrocarbon Natural products 0.000 claims description 4
- 125000001183 hydrocarbyl group Chemical group 0.000 claims description 4
- 150000002431 hydrogen Chemical class 0.000 claims description 3
- BFXIKLCIZHOAAZ-UHFFFAOYSA-N methyltrimethoxysilane Chemical compound CO[Si](C)(OC)OC BFXIKLCIZHOAAZ-UHFFFAOYSA-N 0.000 claims description 3
- 229910052710 silicon Inorganic materials 0.000 claims description 3
- 239000010703 silicon Substances 0.000 claims description 3
- OHJULZOTHVDBCO-UHFFFAOYSA-N 12-[ethoxy(dimethoxy)silyl]dodecane-1-thiol Chemical compound CCO[Si](OC)(OC)CCCCCCCCCCCCS OHJULZOTHVDBCO-UHFFFAOYSA-N 0.000 claims description 2
- LAGFJUQEHPLLIW-UHFFFAOYSA-N 12-triethoxysilyldodecane-1-thiol Chemical compound CCO[Si](OCC)(OCC)CCCCCCCCCCCCS LAGFJUQEHPLLIW-UHFFFAOYSA-N 0.000 claims description 2
- VREPHMROZZKOOL-UHFFFAOYSA-N 12-trimethoxysilyldodecane-1-thiol Chemical compound CO[Si](OC)(OC)CCCCCCCCCCCCS VREPHMROZZKOOL-UHFFFAOYSA-N 0.000 claims description 2
- DKLNFGOBGHSICQ-UHFFFAOYSA-N 18-[ethoxy(dimethoxy)silyl]octadecane-1-thiol Chemical compound CCO[Si](OC)(OC)CCCCCCCCCCCCCCCCCCS DKLNFGOBGHSICQ-UHFFFAOYSA-N 0.000 claims description 2
- UAXHQOHEACNJSR-UHFFFAOYSA-N 18-trimethoxysilyloctadecane-1-thiol Chemical compound CO[Si](OC)(OC)CCCCCCCCCCCCCCCCCCS UAXHQOHEACNJSR-UHFFFAOYSA-N 0.000 claims description 2
- HXVHPNWGIUITGP-UHFFFAOYSA-N 18-tripropoxysilyloctadecane-1-thiol Chemical compound CCCO[Si](OCCC)(OCCC)CCCCCCCCCCCCCCCCCCS HXVHPNWGIUITGP-UHFFFAOYSA-N 0.000 claims description 2
- ZAEPYIXIHJSMDG-UHFFFAOYSA-N 2-[ethoxy(dimethoxy)silyl]ethanethiol Chemical compound CCO[Si](OC)(OC)CCS ZAEPYIXIHJSMDG-UHFFFAOYSA-N 0.000 claims description 2
- IHZHYITXFSSZIZ-UHFFFAOYSA-N 2-isocyanatoethyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)CCN=C=O IHZHYITXFSSZIZ-UHFFFAOYSA-N 0.000 claims description 2
- IPJLELCCCCILNT-UHFFFAOYSA-N 2-methyl-3-triethoxysilylpropane-1-thiol Chemical compound CCO[Si](OCC)(OCC)CC(C)CS IPJLELCCCCILNT-UHFFFAOYSA-N 0.000 claims description 2
- DVNPFNZTPMWRAX-UHFFFAOYSA-N 2-triethoxysilylethanethiol Chemical compound CCO[Si](CCS)(OCC)OCC DVNPFNZTPMWRAX-UHFFFAOYSA-N 0.000 claims description 2
- LOSLJXKHQKRRFN-UHFFFAOYSA-N 2-trimethoxysilylethanethiol Chemical compound CO[Si](OC)(OC)CCS LOSLJXKHQKRRFN-UHFFFAOYSA-N 0.000 claims description 2
- BALOOCSUCFZPGY-UHFFFAOYSA-N 3-[ethoxy(dimethoxy)silyl]-2-methylpropane-1-thiol Chemical compound CCO[Si](OC)(OC)CC(C)CS BALOOCSUCFZPGY-UHFFFAOYSA-N 0.000 claims description 2
- DLHXNUNFSXMYPL-UHFFFAOYSA-N 3-[ethoxy(dimethoxy)silyl]cyclohexane-1-thiol Chemical compound CCO[Si](OC)(OC)C1CCCC(S)C1 DLHXNUNFSXMYPL-UHFFFAOYSA-N 0.000 claims description 2
- IUSDGVJFDZRIBR-UHFFFAOYSA-N 3-phenylpropane-1-thiol Chemical compound SCCCC1=CC=CC=C1 IUSDGVJFDZRIBR-UHFFFAOYSA-N 0.000 claims description 2
- IMTQZALMIBBSKC-UHFFFAOYSA-N 3-triethoxysilylcyclohexane-1-thiol Chemical compound CCO[Si](OCC)(OCC)C1CCCC(S)C1 IMTQZALMIBBSKC-UHFFFAOYSA-N 0.000 claims description 2
- QSUKAUDXXCSABB-UHFFFAOYSA-N 3-trimethoxysilylcyclohexane-1-thiol Chemical compound CO[Si](OC)(OC)C1CCCC(S)C1 QSUKAUDXXCSABB-UHFFFAOYSA-N 0.000 claims description 2
- FLYKYQZCCVFXBO-UHFFFAOYSA-N 4-[diethoxy(phenyl)silyl]oxybutane-1-thiol Chemical compound SCCCCO[Si](OCC)(OCC)C1=CC=CC=C1 FLYKYQZCCVFXBO-UHFFFAOYSA-N 0.000 claims description 2
- MPGJPVZZFPGZQG-UHFFFAOYSA-N 4-[dimethoxy(phenyl)silyl]oxybutane-1-thiol Chemical compound SCCCCO[Si](OC)(OC)C1=CC=CC=C1 MPGJPVZZFPGZQG-UHFFFAOYSA-N 0.000 claims description 2
- KSZNHTNYWHMIQX-UHFFFAOYSA-N 4-[ethoxy(dimethoxy)silyl]-N-ethyl-2,2-dimethylbutan-1-amine Chemical compound CCNCC(C)(C)CC[Si](OC)(OC)OCC KSZNHTNYWHMIQX-UHFFFAOYSA-N 0.000 claims description 2
- KWYVFZBQUBEEIC-UHFFFAOYSA-N 4-[ethoxy(dimethoxy)silyl]butane-1-thiol Chemical compound CCO[Si](OC)(OC)CCCCS KWYVFZBQUBEEIC-UHFFFAOYSA-N 0.000 claims description 2
- QGWKMWZKAUPKAQ-UHFFFAOYSA-N 4-[ethoxy(dimethoxy)silyl]butane-2-thiol Chemical compound CCO[Si](OC)(OC)CCC(C)S QGWKMWZKAUPKAQ-UHFFFAOYSA-N 0.000 claims description 2
- RVAVYOJYNISEQK-UHFFFAOYSA-N 4-triethoxysilylbutane-1-thiol Chemical compound CCO[Si](OCC)(OCC)CCCCS RVAVYOJYNISEQK-UHFFFAOYSA-N 0.000 claims description 2
- XUGBJJNOIWRRPH-UHFFFAOYSA-N 4-triethoxysilylbutane-2-thiol Chemical compound CCO[Si](OCC)(OCC)CCC(C)S XUGBJJNOIWRRPH-UHFFFAOYSA-N 0.000 claims description 2
- LMAFAQBMCIYHQS-UHFFFAOYSA-N 4-trimethoxysilylbutane-1-thiol Chemical compound CO[Si](OC)(OC)CCCCS LMAFAQBMCIYHQS-UHFFFAOYSA-N 0.000 claims description 2
- ZWLDNGJSJBLBFK-UHFFFAOYSA-N 4-trimethoxysilylbutane-2-thiol Chemical compound CO[Si](OC)(OC)CCC(C)S ZWLDNGJSJBLBFK-UHFFFAOYSA-N 0.000 claims description 2
- XGKJASHTURIOTP-UHFFFAOYSA-N C(CCC)NCCC[Si](OCC)(OC)OC Chemical compound C(CCC)NCCC[Si](OCC)(OC)OC XGKJASHTURIOTP-UHFFFAOYSA-N 0.000 claims description 2
- LJXQNVBHMKBSRG-UHFFFAOYSA-N C1(CCCCC1)NCCC[Si](OCC)(OC)OC Chemical compound C1(CCCCC1)NCCC[Si](OCC)(OC)OC LJXQNVBHMKBSRG-UHFFFAOYSA-N 0.000 claims description 2
- BQYNOZYISQGMOB-UHFFFAOYSA-N CC(C)CO[SiH3] Chemical compound CC(C)CO[SiH3] BQYNOZYISQGMOB-UHFFFAOYSA-N 0.000 claims description 2
- CZNCPHGQNSYQAM-UHFFFAOYSA-N CCC(C)O[SiH2]OC(C)CC Chemical compound CCC(C)O[SiH2]OC(C)CC CZNCPHGQNSYQAM-UHFFFAOYSA-N 0.000 claims description 2
- PBDYQPOAXBEPJI-UHFFFAOYSA-N CCCCO[SiH](OC)OC Chemical compound CCCCO[SiH](OC)OC PBDYQPOAXBEPJI-UHFFFAOYSA-N 0.000 claims description 2
- NZLKZJARNHCINT-UHFFFAOYSA-N CCO[Si](OC)(OC)C1=CC=CC=C1S Chemical compound CCO[Si](OC)(OC)C1=CC=CC=C1S NZLKZJARNHCINT-UHFFFAOYSA-N 0.000 claims description 2
- NAESIPXYWFEFQF-UHFFFAOYSA-N CO[SiH](OC(C)CC)OC Chemical compound CO[SiH](OC(C)CC)OC NAESIPXYWFEFQF-UHFFFAOYSA-N 0.000 claims description 2
- GYMJHTOVNJOURZ-UHFFFAOYSA-N N(=C=O)C(OOOC)C Chemical compound N(=C=O)C(OOOC)C GYMJHTOVNJOURZ-UHFFFAOYSA-N 0.000 claims description 2
- XWQLYVIMMBLXPY-UHFFFAOYSA-N butan-2-yloxysilane Chemical compound CCC(C)O[SiH3] XWQLYVIMMBLXPY-UHFFFAOYSA-N 0.000 claims description 2
- YEMJITXWLIHJHJ-UHFFFAOYSA-N di(propan-2-yloxy)silane Chemical compound CC(C)O[SiH2]OC(C)C YEMJITXWLIHJHJ-UHFFFAOYSA-N 0.000 claims description 2
- ZJDOIWTYCOIHFD-UHFFFAOYSA-N dimethoxy(2-methylpropoxy)silane Chemical compound CO[SiH](OC)OCC(C)C ZJDOIWTYCOIHFD-UHFFFAOYSA-N 0.000 claims description 2
- YDFLHDHKAANHNG-UHFFFAOYSA-N dimethoxy(propan-2-yloxy)silane Chemical compound CC(O[SiH](OC)OC)C YDFLHDHKAANHNG-UHFFFAOYSA-N 0.000 claims description 2
- VOYKDLZNACQSOQ-UHFFFAOYSA-N ethoxy-(2-isocyanatoethyl)-dimethoxysilane Chemical compound CCO[Si](OC)(OC)CCN=C=O VOYKDLZNACQSOQ-UHFFFAOYSA-N 0.000 claims description 2
- CBXRNQWZWLYUFD-UHFFFAOYSA-N ethoxy-dimethoxy-phenylsilane Chemical compound CCO[Si](OC)(OC)C1=CC=CC=C1 CBXRNQWZWLYUFD-UHFFFAOYSA-N 0.000 claims description 2
- RAQWTXJGPUSSID-UHFFFAOYSA-N ethoxy-ethyl-dimethoxysilane Chemical compound CCO[Si](CC)(OC)OC RAQWTXJGPUSSID-UHFFFAOYSA-N 0.000 claims description 2
- GSTPNEYNFYKKGS-UHFFFAOYSA-N ethoxy-hexyl-dimethoxysilane Chemical compound CCCCCC[Si](OC)(OC)OCC GSTPNEYNFYKKGS-UHFFFAOYSA-N 0.000 claims description 2
- CZWLNMOIEMTDJY-UHFFFAOYSA-N hexyl(trimethoxy)silane Chemical compound CCCCCC[Si](OC)(OC)OC CZWLNMOIEMTDJY-UHFFFAOYSA-N 0.000 claims description 2
- 125000004356 hydroxy functional group Chemical group O* 0.000 claims description 2
- BPIWQMFUOJGKHK-UHFFFAOYSA-N isocyanatomethoxy-dimethoxy-methylsilane Chemical compound CO[Si](C)(OC)OCN=C=O BPIWQMFUOJGKHK-UHFFFAOYSA-N 0.000 claims description 2
- YACCECLVHQLZQK-UHFFFAOYSA-N methoxyperoxyethane Chemical compound CCOOOC YACCECLVHQLZQK-UHFFFAOYSA-N 0.000 claims description 2
- AAWMXDDKBSXJOE-UHFFFAOYSA-N n-ethyl-2,2-dimethyl-4-triethoxysilylbutan-1-amine Chemical compound CCNCC(C)(C)CC[Si](OCC)(OCC)OCC AAWMXDDKBSXJOE-UHFFFAOYSA-N 0.000 claims description 2
- YJOGKUUQSLYPQJ-UHFFFAOYSA-N n-ethyl-2,2-dimethyl-4-trimethoxysilylbutan-1-amine Chemical compound CCNCC(C)(C)CC[Si](OC)(OC)OC YJOGKUUQSLYPQJ-UHFFFAOYSA-N 0.000 claims description 2
- LFQCEHFDDXELDD-UHFFFAOYSA-N tetramethyl orthosilicate Chemical compound CO[Si](OC)(OC)OC LFQCEHFDDXELDD-UHFFFAOYSA-N 0.000 claims description 2
- KEIBTGABMNALIT-UHFFFAOYSA-N triethoxy(2-isocyanatoethyl)silane Chemical compound CCO[Si](OCC)(OCC)CCN=C=O KEIBTGABMNALIT-UHFFFAOYSA-N 0.000 claims description 2
- DENFJSAFJTVPJR-UHFFFAOYSA-N triethoxy(ethyl)silane Chemical compound CCO[Si](CC)(OCC)OCC DENFJSAFJTVPJR-UHFFFAOYSA-N 0.000 claims description 2
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- CPUDPFPXCZDNGI-UHFFFAOYSA-N triethoxy(methyl)silane Chemical compound CCO[Si](C)(OCC)OCC CPUDPFPXCZDNGI-UHFFFAOYSA-N 0.000 claims description 2
- OZWKZRFXJPGDFM-UHFFFAOYSA-N tripropoxysilane Chemical compound CCCO[SiH](OCCC)OCCC OZWKZRFXJPGDFM-UHFFFAOYSA-N 0.000 claims description 2
- 125000003277 amino group Chemical group 0.000 claims 1
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- 229920001083 polybutene Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
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- 230000008569 process Effects 0.000 description 1
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- JTQPTNQXCUMDRK-UHFFFAOYSA-N propan-2-olate;titanium(2+) Chemical compound CC(C)O[Ti]OC(C)C JTQPTNQXCUMDRK-UHFFFAOYSA-N 0.000 description 1
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- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 1
- RUELTTOHQODFPA-UHFFFAOYSA-N toluene 2,6-diisocyanate Chemical compound CC1=C(N=C=O)C=CC=C1N=C=O RUELTTOHQODFPA-UHFFFAOYSA-N 0.000 description 1
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- PZJJKWKADRNWSW-UHFFFAOYSA-N trimethoxysilicon Chemical group CO[Si](OC)OC PZJJKWKADRNWSW-UHFFFAOYSA-N 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
- C09J175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
- C08G18/12—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2190/00—Compositions for sealing or packing joints
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Sealing Material Composition (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polyurethanes Or Polyureas (AREA)
- Silicon Polymers (AREA)
- Polyethers (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US12/322,882 US8138297B2 (en) | 2009-02-09 | 2009-02-09 | Moisture-curable silylated polymer possessing improved storage stability |
| US12/322,882 | 2009-02-09 | ||
| PCT/US2010/023456 WO2010091338A1 (en) | 2009-02-09 | 2010-02-08 | Moisture-curable silylated polymer possessing improved storage stability |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102361901A CN102361901A (zh) | 2012-02-22 |
| CN102361901B true CN102361901B (zh) | 2014-06-11 |
Family
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Family Applications (1)
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| CN201080013146.XA Expired - Fee Related CN102361901B (zh) | 2009-02-09 | 2010-02-08 | 具有改进的储存稳定性的可湿固化甲硅烷基化聚合物 |
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| EP (1) | EP2393861B1 (enExample) |
| JP (1) | JP5653368B2 (enExample) |
| CN (1) | CN102361901B (enExample) |
| BR (1) | BRPI1007886B1 (enExample) |
| WO (1) | WO2010091338A1 (enExample) |
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| CN104583222A (zh) * | 2012-09-04 | 2015-04-29 | 拜耳材料科技股份有限公司 | 具有硫代氨基甲酸酯结构的异氰酸根合硅烷 |
| CN105579484B (zh) * | 2013-02-26 | 2019-06-04 | 霍尼韦尔国际公司 | 含有卤代烯烃发泡剂的聚氨酯泡沫预混物和由其制造的泡沫 |
| CN103436216B (zh) * | 2013-09-05 | 2014-12-31 | 江苏天辰新材料有限公司 | 一种脱醇型低模量高伸长率的有机硅密封胶及其制备方法 |
| CN103509517B (zh) * | 2013-09-05 | 2015-10-28 | 江苏天辰硅材料有限公司 | 一种瓷化阻燃防火硅酮密封胶及其制备方法 |
| CN103436217A (zh) * | 2013-09-06 | 2013-12-11 | 江苏天辰硅材料有限公司 | 一种单组份脱醇型耐油硅酮密封胶及其制备方法 |
| CN103602306B (zh) * | 2013-09-06 | 2016-01-20 | 江苏天辰新材料股份有限公司 | 一种单组份室温硫化透明脱醇型防霉硅酮密封胶及其制备方法 |
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| PL3067375T3 (pl) * | 2015-03-11 | 2018-01-31 | Henkel Ag & Co Kgaa | Sililowane poliuretany, ich wytwarzanie i zastosowanie |
| WO2018043238A1 (ja) * | 2016-08-31 | 2018-03-08 | 富士フイルム株式会社 | 半導体ナノ粒子複合体の製造方法、半導体ナノ粒子複合体およびフィルム |
| DE102017205444A1 (de) * | 2017-03-30 | 2018-10-04 | Evonik Degussa Gmbh | Zusammensetzung umfassend ein Gemisch von Bis(triethoxysilylpropyl)amin und Bis(trimethoxysilylpropyl)amin sowie dessen Verwendung in einer 2K-Beschichtungszusammensetzung |
| FR3068633B1 (fr) * | 2017-07-04 | 2019-08-23 | Bostik Sa | Preparation d'une composition adhesive dans une extrudeuse |
| EP3565857B1 (de) * | 2017-12-15 | 2020-03-25 | Wacker Chemie AG | Vernetzbare massen auf der basis von organyloxygruppen aufweisenden organopolysiloxanen |
| CA3113952C (en) | 2018-09-24 | 2023-09-19 | Building Materials Investment Corporation | Roofing membranes with improved adhesive bonding strength |
| EP3992252A4 (en) * | 2019-06-26 | 2023-07-19 | Sekisui Polymatech Co., Ltd. | PACKAGING FOR THERMAL CONDUCTIVE COMPOSITION AND TWO COMPONENT CURING THERMAL COMPOSITION |
| CN112142945B (zh) * | 2019-06-27 | 2022-07-12 | 万华化学集团股份有限公司 | 一种高稳定性的端硅烷基聚合物树脂及其制备方法 |
| EP4110842B1 (en) | 2020-02-26 | 2024-02-07 | Akzo Nobel Coatings International B.V. | Alkoxysilane functional polyurethane-urea for adhesive or coating |
| JP2023519822A (ja) * | 2020-04-08 | 2023-05-15 | シーカ テクノロジー アクチェンゲゼルシャフト | 向上された上塗り性を有するシラン官能性ポリマーをベースとする組成物 |
| KR102820691B1 (ko) * | 2020-06-24 | 2025-06-12 | 와커 헤미 아게 | 수분-경화 컨포멀 코팅 조성물 |
| US11760900B2 (en) | 2021-10-27 | 2023-09-19 | Momentive Performance Materials Inc. | Condensation curable composition |
| CN114574155A (zh) * | 2021-12-17 | 2022-06-03 | 浙江新安化工集团股份有限公司 | 一种安全环保型单组份橡皮泥状硅酮密封胶及其制备方法 |
| CN114479741B (zh) * | 2022-02-23 | 2023-03-31 | 广州市白云化工实业有限公司 | 一种低温可快速深层固化的单组分有机硅改性密封胶及其制备方法 |
| CN119053644A (zh) | 2022-05-04 | 2024-11-29 | 美国陶氏有机硅公司 | 硅酮-聚醚共聚物、包含硅酮-聚醚共聚物的密封剂和相关方法 |
| CN116606415A (zh) * | 2023-05-31 | 2023-08-18 | 湖北回天新材料股份有限公司 | 梳型硅烷封端聚氨酯聚合物树脂及其制备方法和应用 |
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- 2010-02-08 JP JP2011549306A patent/JP5653368B2/ja not_active Expired - Fee Related
- 2010-02-08 CN CN201080013146.XA patent/CN102361901B/zh not_active Expired - Fee Related
- 2010-02-08 EP EP10703778.0A patent/EP2393861B1/en not_active Not-in-force
- 2010-02-08 BR BRPI1007886-0A patent/BRPI1007886B1/pt active IP Right Grant
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| CN101273074A (zh) * | 2005-09-15 | 2008-09-24 | 莫门蒂夫功能性材料公司 | 使用有机铋催化剂制备氨基硅烷封端的聚合物以及使用非锡催化剂由此制备固化的聚合物 |
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Also Published As
| Publication number | Publication date |
|---|---|
| EP2393861A1 (en) | 2011-12-14 |
| BRPI1007886A2 (pt) | 2017-01-17 |
| JP5653368B2 (ja) | 2015-01-14 |
| CN102361901A (zh) | 2012-02-22 |
| US20100204384A1 (en) | 2010-08-12 |
| WO2010091338A1 (en) | 2010-08-12 |
| EP2393861B1 (en) | 2013-10-23 |
| JP2012517505A (ja) | 2012-08-02 |
| BRPI1007886B1 (pt) | 2020-02-11 |
| US8138297B2 (en) | 2012-03-20 |
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