CN102318897B - Cigarette additive for reducing cigarette harm and preparation and application thereof - Google Patents
Cigarette additive for reducing cigarette harm and preparation and application thereof Download PDFInfo
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- CN102318897B CN102318897B CN 201110250997 CN201110250997A CN102318897B CN 102318897 B CN102318897 B CN 102318897B CN 201110250997 CN201110250997 CN 201110250997 CN 201110250997 A CN201110250997 A CN 201110250997A CN 102318897 B CN102318897 B CN 102318897B
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- evodia rutaecarpa
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Abstract
The invention relates to a cigarette additive for reducing cigarette harm and preparation and application thereof. The cigarette additive disclosed by the invention is effective ingredient extracts of traditional Chinese herbal medicine of fructus evodiae. The invention further provides a preparation method of the cigarette additive and the application to the cigarette preparation. In the method, raw materials are cheap and are easy to obtain, the process is simple, the fragrance of the prepared cigarettes can be enhanced, but the harm can be reduced, in addition, the release quantity of carbonyl compounds such as crotonic aldehyde and the like in mainstream smoke of the cigarettes can be obviously reduced, so the goal of effectively reducing the cigarette harm is reached.
Description
Technical field
The present invention relates to a kind of cigarette additive and preparation and application thereof that reduce cigarette harm, relate to specifically a kind ofly can promote cigarette fragrance, alternative cigarette additive and the preparation and application thereof that reduce carbonyl complex content such as crotonaldehyde in the cigarette mainstream flue gas.
Background technology
Smoking and health problem are the main uncertain factors of restriction industry long-term stability development always.How reducing in the cigarette content of harmful components in the tar and main flume, reduce and suck cigarette to the harm of smoker's health, is the difficult problem of one pendulum in face of the tobacco scientific worker; Simultaneously, assorted gas, astringent taste, bitter taste and flue gas in the cigarette all has very big relation with the sucking quality of cigarette to excitement of human oral cavity, throat etc., how to reduce or cover assorted gas, astringent taste and bitter taste etc. in the flue gas, reduce excitement, the characteristic perfume that the increase cigarette is difficult to copy has been another difficult problem that the tobacco scientific worker faces, and present many correlative study work are all launching around this two difficult problems.
Chinese medicinal herbs is used for the existing many patents of lowering harm and decreasing coking and the reported in literature of cigarette, selects suitable Chinese medicine extract to can be used for tobacco flavouring, removal of impurities, lowering harm and decreasing coking, promotion tobacco leaf biofermentation etc. as additive, and this is the emerging hot research in tobacco field.Advantage and the characteristic of giving full play to Chinese medicine improved the cigarette quality, reduced the harm of cigarette harmful components, promotes the tobacco leaf biofermentation, and huge impetus is played in the development of tobacco industry.
Evodia rutaecarpa is hot in nature, bitter, nontoxic, main product in Guizhou, ground such as Guangxi, Hunan, Sichuan.Has eliminating cold to stop pain, stopping nausea and vomiting by lowering the adverse flow of QI, effects such as supporing yang antidiarrheal.Chemical composition contains rutaecarpin, Rutaecarpine, hydroxyevodiamine, lemon lactone, synephrine, evodene etc.This patent is raw material with the evodia rutaecarpa, finds that it has the effect that promotes cigarette fragrance, reduces carbonyl compound contents such as crotonaldehyde in the cigarette mainstream flue gas.
Summary of the invention
The objective of the invention is to overcome defective of the prior art, provide a kind of and promote cigarette fragrance, optionally reduce cigarette additive and the preparation and application thereof of carbonyl complex content such as crotonaldehyde in the cigarette mainstream flue gas.
First aspect of the present invention provides a kind of and has promoted cigarette fragrance, optionally reduced the cigarette additive of carbonyl complex content such as crotonaldehyde in the cigarette mainstream flue gas, is the effective component extracts of Chinese medicine evodia rutaecarpa.
Described Chinese medicine evodia rutaecarpa is the dry immature fruit of Rutaceae Evodia plant evodia rutaecarpa (Fructus Evodiae).
Above-mentioned cigarette additive provided by the present invention can adopt following method to obtain:
Be raw material with described Chinese medicine evodia rutaecarpa, adopt water, organic solvent or water-containing organic solvent to extract repeatedly, filter and merging filtrate, filtrate concentrate or evaporate to dryness after obtain additive.That is, described additive can be the concentrate that obtains after filtrate concentrates, and also can be the solid matter that obtains behind the filtrate evaporate to dryness.
Described organic solvent is selected from absolute ethyl alcohol, acetoneand ethyl acetate; Described water-containing organic solvent is that volumn concentration is 30～95% ethanol water; Extracting method is extracted for adding hot reflux, Soxhlet, temperature is soaked, cold soaking, decoction, Microwave Extraction or ultrasonic extraction etc.
Preferably, adopt the following step to prepare described additive:
1) be raw material with the Chinese medicine evodia rutaecarpa, be that 30～95% ethanol water is as extracting solvent with water, absolute ethyl alcohol, acetone, ethyl acetate or the volumn concentration of 2～5 times of amounts of crude drug weight after crushed, extract to add hot reflux, Soxhlet, temperature is soaked, cold soaking, decoction, Microwave Extraction or the ultrasonic extracting method that is extracted as, extract and also filter (extraction time decides on extracting method); Repeat to extract merging filtrate 2～4 times;
2) after being concentrated, gained filtrate makes solution shape additive or medicinal extract (one be concentrated into crude drug weight 1～20 times).
Second aspect of the present invention also provides the purposes of the effective component extracts of above-mentioned Chinese medicine evodia rutaecarpa, and namely the effective component extracts of described Chinese medicine evodia rutaecarpa is as cigarette additive.
The present invention also provides the purposes of described cigarette additive, that is, and and the content that described cigarette additive is used for promoting cigarette fragrance and/or optionally reduces cigarette mainstream flue gas harmful components carbonyl complex; And described cigarette additive is as promoting cigarette fragrance and/or optionally reducing the natural additive of harmful components carbonyl complex content in the cigarette mainstream flue gas for the preparation of filter stick, pipe tobacco, stem or the reconstituted tobacoo of cigarette, cigarette.
Described carbonyl complex is selected from crotonaldehyde, formaldehyde, acetaldehyde, propionic aldehyde, butyraldehyde, methacrylaldehyde and methyl ethyl ketone etc.
Further, when preparation pipe tobacco, stem or reconstituted tobacoo, the addition of described cigarette additive in pipe tobacco, stem or reconstituted tobacoo is the 0.05-3.0% of pipe tobacco, stem or reconstituted tobacoo weight; When the preparation cigarette, the addition of described cigarette additive in cigarette is the 0.05-3.0% of pipe tobacco in the cigarette, stem and reconstituted tobacoo gross weight, or is the 0.15-8.0% of the filter stick weight of cigarette.Can only contain pipe tobacco in the described cigarette and not contain stem and reconstituted tobacoo, also can both contain pipe tobacco and also contain in stem and the reconstituted tobacoo one or both.
The 3rd aspect of the present invention also provides a kind of cigarette, it is characterized in that, contains above-mentioned cigarette additive in the pipe tobacco of described cigarette and/or the filter stick.That is, described cigarette additive both can add in the pipe tobacco of cigarette, also can add in the filter stick of cigarette, can also add simultaneously in pipe tobacco and filter stick.
Preferable, the addition of described cigarette additive in pipe tobacco is the 0.05-3.0% of pipe tobacco gross weight, the addition in filter stick is the 0.15-8.0% of filter stick weight.
Further, except pipe tobacco, can also contain in stem and the reconstituted tobacoo one or both in the described cigarette, the addition of described cigarette additive this moment in pipe tobacco is the 0.05-3.0% of pipe tobacco, stem and reconstituted tobacoo gross weight.
The 4th aspect of the present invention, a kind of method that promotes cigarette fragrance and/or optionally reduce harmful components carbonyl complex content in the cigarette mainstream flue gas also is provided: for diluting on after-applied pipe tobacco in cigarettes plus, stem, reconstituted tobacoo and/or the filter stick with cigarette additive stoste of the present invention or with cigarette additive, and balance was not less than 48 hours under the condition of constant temperature and humidity.The addition of described cigarette additive in cigarette is the 0.05-3.0% of pipe tobacco in the cigarette, stem and reconstituted tobacoo gross weight, or is the 0.15-8.0% of the filter stick weight of cigarette.
Described applying method can be to spray before rolling or roll the back to inject.For example before rolling, evenly be sprayed at after diluting by the conventional adding method of cigarette additive (being that 30～95% ethanol water dilutes with absolute ethyl alcohol, acetone, ethyl acetate or volume ratio for example) with the stoste of additive of the present invention or with additive and roll into cigarette on cigarette shreds, stem and/or the reconstituted tobacoo again and prop up, perhaps test also can be by being injected into cigarette with cigarette pipe tobacco and/or the mode in the filter stick additive is added cigarette.
Further, described balance temperature is 22 ± 1 ℃, and balance humidity is relative humidity 60 ± 2%.
The present invention will have the dry immature fruit of the natural plants evodia rutaecarpa of medicinal efficacy, extract its active ingredient, add in sample pipe tobacco or the filter stick, can reduce harmful substance in the cigarette mainstream flue gas, alleviate harm of smoking, especially crotonaldehyde in the cigarette mainstream flue gas there is tangible reduction effect, can promotes the fragrance of cigarette again.Cigarette of the present invention is simple with natural additive preparation technology, cost is low, has important market prospects.
The specific embodiment
Further set forth the present invention below in conjunction with embodiment.Should be understood that these embodiment only are used for explanation the present invention, but not limit the scope of the invention.
Embodiment 1
(1) get evodia rutaecarpa 20 grams, pulverize the back and use the 50ml soaked in absolute ethyl alcohol after 10 minutes, ultrasonic extraction is 45 minutes under the room temperature, filters with qualitative filter paper, collects filtrate.Repeat again to extract once, merge extract.This evodia rutaecarpa extract rotary evaporation under 40～70 ℃ of water bath condition is evaporated to 30ml, obtains natural tobacco additive solution.
(2) the above-mentioned natural tobacco additive solution that makes is injected the sample cigarette, inject the amount of 50ul in the pipe tobacco of every sample cigarette and the filter stick respectively, the experiment cigarette that makes balance 48 hours in constant temperature (22 ± 1 ℃) constant humidity (relative humidity 60 ± 2%) environment.
Adopt high performance liquid chromatography to record to add in the main flume of the cigarette sample behind the evodia extract carbonyl class harmful substance contents such as crotonaldehyde to decrease, wherein crotonaldehyde content is down to 14.2ug/cig by 21.5ug/cig, and reduced rate is 33.95%.
(3) experimental result shows: this cigarette additive can significantly reduce harmful substance in the cigarette mainstream flue gas, alleviates harm of smoking, and especially the reduction effect to crotonaldehyde in the cigarette mainstream flue gas is the most obvious.
(4) sensory evaluating smoking result shows: this cigarette has can promote cigarette fragrance, can significantly reduce the assorted gas in the flue gas, makes cigarette smoke finer and smoother, soft.
Embodiment 2
(1) gets evodia rutaecarpa 20 grams, pulverize the back and steep with the 100ml water logging, and decocted 120 minutes, filter, collect filtrate.With this evodia rutaecarpa extract heating evaporation, make medicinal extract.
(2) the above-mentioned natural tobacco additive that makes is injected the sample cigarette in perfuming method dilution back routinely, inject respectively in the pipe tobacco of every sample cigarette and the filter stick be equivalent to pipe tobacco weight 0.05% and be equivalent to the additive of 0.15% step (1) gained of filter stick weight, the cigarette that makes balance 48 hours in constant temperature (22 ± 1 ℃) constant humidity (relative humidity 60 ± 2%) environment.
(3) effect is with embodiment 1, and carbonyl complex content such as crotonaldehyde obviously reduces in the cigarette mainstream flue gas.
Embodiment 3
(1) get evodia rutaecarpa 20 grams, pulverize the back and use 80ml ethyl acetate to soak after 10 minutes, ultrasonic extraction is 60 minutes under the room temperature, filters with qualitative filter paper, collects filtrate.Repeat again to extract once, merge extract.This evodia rutaecarpa extract rotary evaporation under 70～90 ℃ of water bath condition is evaporated to 20ml, obtains natural tobacco additive solution.
(2) with the ratio of prepared natural tobacco additive solution in pipe tobacco weight 0.05%, the process of perfuming evenly is sprayed on the sample cigarette shreds routinely, sealing was preserved 24 hours, make cigarette, and cigarette balance under constant temperature (22 ± 1 ℃) constant humidity (relative humidity 60 ± 2%) condition was not less than 48 hours.
(3) effect is with embodiment 1, and carbonyl complex content such as crotonaldehyde reduces in the cigarette mainstream flue gas.
Embodiment 4
(1) get evodia rutaecarpa 20 grams, pulverize the back and use 50ml acetone to soak after 10 minutes, ultrasonic extraction is 45 minutes under the room temperature, filters with qualitative filter paper, collects filtrate.Repeat again to extract once, merge extract.With the concentrated medicinal extract of making of this evodia rutaecarpa extract rotary evaporation decompression under 40～70 ℃ of water bath condition.
(2) with the ratio of prepared natural tobacco additive in pipe tobacco weight 3%, the process of perfuming evenly is sprayed on the sample cigarette shreds routinely, sealing was preserved 24 hours, make cigarette, and cigarette balance under constant temperature (22 ± 1 ℃) constant humidity (relative humidity 60 ± 2%) condition was not less than 48 hours.
(3) effect is with embodiment 1, and carbonyl complex content such as crotonaldehyde obviously reduces in the cigarette mainstream flue gas.
Embodiment 5
(1) get evodia rutaecarpa 20 grams, pulverize the ethanol water of using 80ml 30% in the back and soak after 10 minutes, ultrasonic extraction is 45 minutes under the room temperature, filters, and collects filtrate.This evodia rutaecarpa extract is made medicinal extract.
(2) with the ratio of prepared natural tobacco additive in filter stick weight 8%, the process of perfuming evenly is sprayed on the sample cigarette filter rod material routinely, sealing was preserved 24 hours, make cigarette, and cigarette balance under constant temperature (22 ± 1 ℃) constant humidity (relative humidity 60 ± 2%) condition was not less than 48 hours.
(3) effect is with embodiment 1, and carbonyl complex content such as crotonaldehyde obviously reduces in the cigarette mainstream flue gas.
Embodiment 6
(1) get evodia rutaecarpa 20 grams, the soaked in absolute ethyl alcohol of using 60ml 95% after pulverizing is after 10 minutes, and ultrasonic extraction is 45 minutes under the room temperature, filters, and collects filtrate.Repeat again to extract once, merge extract.This evodia rutaecarpa extract rotary evaporation under 40～70 ℃ of water bath condition is evaporated to 20ml, obtains natural tobacco additive solution.
(2) with the ratio of prepared natural tobacco additive solution in filter stick weight 0.15%, the process of perfuming evenly is sprayed on the sample cigarette filter rod material routinely, sealing was preserved 24 hours, make cigarette, and cigarette balance under constant temperature (22 ± 1 ℃) constant humidity (relative humidity 60 ± 2%) condition was not less than 48 hours.
(3) effect is with embodiment 1, and carbonyl complex content such as crotonaldehyde reduces in the cigarette mainstream flue gas.
Claims (13)
1. the purposes of the effective component extracts of Chinese medicine evodia rutaecarpa is characterized in that, the effective component extracts of described Chinese medicine evodia rutaecarpa is as cigarette additive; The effective component extracts of described Chinese medicine evodia rutaecarpa is to be raw material with described Chinese medicine evodia rutaecarpa, adopts water, organic solvent or water-containing organic solvent to extract repeatedly, filter and merging filtrate, filtrate concentrate or evaporate to dryness after obtain; Wherein, described organic solvent is selected from absolute ethyl alcohol, acetoneand ethyl acetate; Described water-containing organic solvent is that volumn concentration is 30～95% ethanol water; Extracting method is extracted for adding hot reflux, Soxhlet, temperature is soaked, cold soaking, decoction, Microwave Extraction or ultrasonic extraction.
2. purposes as claimed in claim 1 is characterized in that, described Chinese medicine evodia rutaecarpa is the dry immature fruit of rutaceae evodia rutaecarpa.
3. purposes as claimed in claim 1 is characterized in that, the effective component extracts of described Chinese medicine evodia rutaecarpa adopts following method to prepare:
1) be raw material with the Chinese medicine evodia rutaecarpa, be that 30～95% ethanol water is as extracting solvent with water, absolute ethyl alcohol, acetone, ethyl acetate or the volumn concentration of 2～5 times of amounts of crude drug weight after crushed, extract to add hot reflux, Soxhlet, temperature is soaked, cold soaking, decoction, Microwave Extraction or the ultrasonic extracting method that is extracted as, extract also and filter; Repeat to extract merging filtrate 2～4 times;
2) after being concentrated, gained filtrate makes solution shape additive or medicinal extract.
4. purposes as claimed in claim 1 is characterized in that, the content that described cigarette additive is used for promoting cigarette fragrance and/or optionally reduces cigarette mainstream flue gas harmful components carbonyl complex.
5. purposes as claimed in claim 1, it is characterized in that described cigarette additive is as promoting cigarette fragrance and/or optionally reducing the natural additive of harmful components carbonyl complex content in the cigarette mainstream flue gas for the preparation of filter stick, pipe tobacco, stem or the reconstituted tobacoo of cigarette, cigarette.
6. as claim 4 or 5 described purposes, it is characterized in that described carbonyl complex is selected from crotonaldehyde, formaldehyde, acetaldehyde, propionic aldehyde, butyraldehyde, methacrylaldehyde and methyl ethyl ketone.
7. cigarette, it is characterized in that, contain cigarette additive in the pipe tobacco of described cigarette and/or the filter stick, described cigarette additive is the effective component extracts of Chinese medicine evodia rutaecarpa, the effective component extracts of described Chinese medicine evodia rutaecarpa is to be raw material with described Chinese medicine evodia rutaecarpa, adopt water, organic solvent or water-containing organic solvent to extract repeatedly, filter and merging filtrate, filtrate concentrate or evaporate to dryness after obtain; Wherein, described organic solvent is selected from absolute ethyl alcohol, acetoneand ethyl acetate; Described water-containing organic solvent is that volumn concentration is 30～95% ethanol water; Extracting method is extracted for adding hot reflux, Soxhlet, temperature is soaked, cold soaking, decoction, Microwave Extraction or ultrasonic extraction.
8. cigarette as claimed in claim 7 is characterized in that, the addition of described cigarette additive in pipe tobacco is the 0.05-3.0% of pipe tobacco gross weight, and the addition in filter stick is the 0.15-8.0% of filter stick weight.
9. as claim 7 or 8 described cigarette, it is characterized in that, except pipe tobacco, also contain in stem and the reconstituted tobacoo one or both in the described cigarette; The addition of described cigarette additive in pipe tobacco is the 0.05-3.0% of pipe tobacco, stem and reconstituted tobacoo gross weight.
10. method that promotes cigarette fragrance and/or optionally reduce harmful components carbonyl complex content in the cigarette mainstream flue gas: for diluting on after-applied pipe tobacco in cigarettes plus, stem, reconstituted tobacoo and/or the filter stick with cigarette additive stoste of the present invention or with cigarette additive, and balance was not less than 48 hours under the condition of constant temperature and humidity; Described cigarette additive is the effective component extracts of Chinese medicine evodia rutaecarpa, the effective component extracts of described Chinese medicine evodia rutaecarpa is to be raw material with described Chinese medicine evodia rutaecarpa, adopt water, organic solvent or water-containing organic solvent to extract repeatedly, filter and merging filtrate, filtrate concentrate or evaporate to dryness after obtain; Wherein, described organic solvent is selected from absolute ethyl alcohol, acetoneand ethyl acetate; Described water-containing organic solvent is that volumn concentration is 30～95% ethanol water; Extracting method is extracted for adding hot reflux, Soxhlet, temperature is soaked, cold soaking, decoction, Microwave Extraction or ultrasonic extraction.
11. method as claimed in claim 10 is characterized in that, the addition of described cigarette additive in cigarette is the 0.05-3.0% of pipe tobacco in the cigarette, stem and reconstituted tobacoo gross weight, or is the 0.15-8.0% of the filter stick weight of cigarette.
12. method as claimed in claim 10 is characterized in that, described applying method is injected for spraying before rolling or rolling the back.
13., it is characterized in that described balance temperature is 21-23 ℃ as the described method of the arbitrary claim of claim 10-12, balance humidity is relative humidity 58-62%.
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| CN 201110250997 CN102318897B (en) | 2011-08-29 | 2011-08-29 | Cigarette additive for reducing cigarette harm and preparation and application thereof |
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| CN 201110250997 CN102318897B (en) | 2011-08-29 | 2011-08-29 | Cigarette additive for reducing cigarette harm and preparation and application thereof |
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| CN102318897A CN102318897A (en) | 2012-01-18 |
| CN102318897B true CN102318897B (en) | 2013-08-14 |
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Families Citing this family (3)
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| CN106148011A (en) * | 2016-07-20 | 2016-11-23 | 湖北中烟工业有限责任公司 | The preparation method of a kind of cigarette radix valerianae extract and the application in Medicated cigarette thereof |
| CN106198824A (en) * | 2016-09-18 | 2016-12-07 | 中国烟草总公司郑州烟草研究院 | A kind of cigarette additive screening technique based on carbonyl compound burst size |
| CN107969729B (en) * | 2017-12-16 | 2020-08-28 | 江西中烟工业有限责任公司 | Method for reducing crotonaldehyde content in flue gas |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1931271A (en) * | 2006-09-27 | 2007-03-21 | 贵州师范大学 | Evodia extract and its prepn process, medicine composition and use |
| CN101224250A (en) * | 2007-01-17 | 2008-07-23 | 广州汉方现代中药研究开发有限公司 | Preparing method for extracting medicinal evodia alkaloid by ultrasound |
| CN101775336A (en) * | 2010-02-08 | 2010-07-14 | 云南烟草科学研究院 | Macadamia shell extract and application thereof |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2959712B2 (en) * | 1997-09-12 | 1999-10-06 | スング，バエ オー | Non-smoking smoking article and method for producing the same |
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1931271A (en) * | 2006-09-27 | 2007-03-21 | 贵州师范大学 | Evodia extract and its prepn process, medicine composition and use |
| CN101224250A (en) * | 2007-01-17 | 2008-07-23 | 广州汉方现代中药研究开发有限公司 | Preparing method for extracting medicinal evodia alkaloid by ultrasound |
| CN101775336A (en) * | 2010-02-08 | 2010-07-14 | 云南烟草科学研究院 | Macadamia shell extract and application thereof |
Non-Patent Citations (1)
| Title |
|---|
| JP特开平11－79982A 1999.03.23 |
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