CN102318897A - Cigarette additive for reducing cigarette harm and preparation and application thereof - Google Patents
Cigarette additive for reducing cigarette harm and preparation and application thereof Download PDFInfo
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- CN102318897A CN102318897A CN201110250997A CN201110250997A CN102318897A CN 102318897 A CN102318897 A CN 102318897A CN 201110250997 A CN201110250997 A CN 201110250997A CN 201110250997 A CN201110250997 A CN 201110250997A CN 102318897 A CN102318897 A CN 102318897A
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- cigarette
- additive
- pipe tobacco
- evodia rutaecarpa
- chinese medicine
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Abstract
The invention relates to a cigarette additive for reducing cigarette harm and preparation and application thereof. The cigarette additive disclosed by the invention is effective ingredient extracts of traditional Chinese herbal medicine of fructus evodiae. The invention further provides a preparation method of the cigarette additive and the application to the cigarette preparation. In the method, raw materials are cheap and are easy to obtain, the process is simple, the fragrance of the prepared cigarettes can be enhanced, but the harm can be reduced, in addition, the release quantity of carbonyl compounds such as crotonic aldehyde and the like in mainstream smoke of the cigarettes can be obviously reduced, so the goal of effectively reducing the cigarette harm is reached.
Description
Technical field
The present invention relates to a kind of cigarette additive that reduces cigarette harm and preparation thereof and use, relate to specifically a kind ofly can promote cigarette fragrance, alternative cigarette additive and preparation and the application that reduces carbonyl complex content such as crotonaldehyde in the cigarette mainstream flue gas.
Background technology
Smoking and health problem are the main uncertain factors of restriction industry long-term stability development always.How reducing in the cigarette content of harmful components in the tar and main flume, reduce and suck the harm of cigarette to smoker's health, is the difficult problem of one pendulum in face of the tobacco scientific worker; Simultaneously; Assorted gas, astringent taste, bitter taste and flue gas in the cigarette all has very big relation with the sucking quality of cigarette to excitement of human oral cavity, throat etc.; How to reduce or cover assorted gas, astringent taste and the bitter taste etc. in the flue gas; Reduce excitement, the characteristic perfume that the increase cigarette is difficult to copy has been another difficult problem that the tobacco scientific worker faces, and present many correlative study work are all launching around this two difficult problems.
Chinese medicinal herbs is used for the existing many patents of lowering harm and decreasing coking and the reported in literature of cigarette, selects suitable Chinese medicine extract to can be used for tobacco flavouring, removal of impurities, lowering harm and decreasing coking, promotion tobacco leaf biofermentation etc. as additive, and this is the emerging hot research of field of tobacco.Advantage and the characteristic of giving full play to Chinese medicine improved the cigarette quality, reduced the harm of cigarette harmful components, promotes the tobacco leaf biofermentation, and huge impetus is played in the development of tobacco industry.
Evodia rutaecarpa is hot in nature, bitter, nontoxic, main product in Guizhou, ground such as Guangxi, Hunan, Sichuan.Has eliminating cold to stop pain, stopping nausea and vomiting by lowering the adverse flow of QI, effects such as supporing yang antidiarrheal.Chemical composition contains rutaecarpin, Rutaecarpine, hydroxyevodiamine, lemon lactone, synephrine, evodene etc.This patent is a raw material with the evodia rutaecarpa, finds that it has the effect that promotes cigarette fragrance, reduces carbonyl compound contents such as crotonaldehyde in the cigarette mainstream flue gas.
Summary of the invention
The objective of the invention is to overcome defective of the prior art, provide a kind of and promote cigarette fragrance, optionally reduce cigarette additive and the preparation and application of carbonyl complex content such as crotonaldehyde in the cigarette mainstream flue gas.
First aspect of the present invention provides a kind of and has promoted cigarette fragrance, optionally reduced the cigarette additive of carbonyl complex content such as crotonaldehyde in the cigarette mainstream flue gas, is the effective component extracts of Chinese medicine evodia rutaecarpa.
Said Chinese medicine evodia rutaecarpa is the dry immature fruit of Rutaceae Evodia plant evodia rutaecarpa (Fructus Evodiae).
Above-mentioned cigarette additive provided by the present invention can adopt following method to obtain:
With said Chinese medicine evodia rutaecarpa is raw material, and employing water, organic solvent or water-containing organic solvent extract repeatedly, filter and merging filtrate, obtains additive behind filtrate concentrated or the evaporate to dryness.That is, said additive can be the concentrate that obtains after filtrating concentrates, and also can be the solid matter that obtains behind the filtrating evaporate to dryness.
Said organic solvent is selected from absolute ethyl alcohol, acetoneand ethyl acetate; Said water-containing organic solvent is that volumn concentration is 30～95% ethanol water; Method for distilling is that reflux, Suo Shi are extracted, temperature is soaked, cold soaking, decoction, Microwave Extraction or ultrasonic Extraction etc.
Preferably, adopt the following step to prepare said additive:
1) be raw material with the Chinese medicine evodia rutaecarpa; Water, absolute ethyl alcohol, acetone, ethyl acetate or the volumn concentration that uses 2～5 times of amounts of crude drug weight after crushed is that 30～95% ethanol water is as extracting solvent; With reflux, Suo Shi extract, temperature is soaked, cold soaking, decoction, Microwave Extraction or ultrasonic Extraction are method for distilling, extract and filter (extraction time look method for distilling and decide); Repeat to extract merging filtrate 2～4 times;
2) after being concentrated, gained filtrating processes solution shape additive or medicinal extract (one be concentrated into crude drug weight 1～20 times).
Second aspect of the present invention also provides the purposes of the effective component extracts of above-mentioned Chinese medicine evodia rutaecarpa, and the effective component extracts of promptly said Chinese medicine evodia rutaecarpa is as cigarette additive.
The present invention also provides the purposes of said cigarette additive, that is, and and the content that said cigarette additive is used for promoting cigarette fragrance and/or optionally reduces cigarette mainstream flue gas harmful components carbonyl complex; And said cigarette additive is used to prepare filter stick, pipe tobacco, stem or the reconstituted tobacoo of cigarette, cigarette as the natural additive that promotes cigarette fragrance and/or optionally reduce harmful components carbonyl complex content in the cigarette mainstream flue gas.
Said carbonyl complex is selected from crotonaldehyde, formaldehyde, acetaldehyde, propionic aldehyde, butyraldehyde, methacrylaldehyde and methyl ethyl ketone etc.
Further, when preparation pipe tobacco, stem or reconstituted tobacoo, the addition of said cigarette additive in pipe tobacco, stem or reconstituted tobacoo is the 0.05-3.0% of pipe tobacco, stem or reconstituted tobacoo weight; When the preparation cigarette, the addition of said cigarette additive in cigarette is the 0.05-3.0% of pipe tobacco in the cigarette, stem and reconstituted tobacoo gross weight, or is the 0.15-8.0% of the filter stick weight of cigarette.Can only contain pipe tobacco in the said cigarette and not contain stem and reconstituted tobacoo, also can both contain pipe tobacco and also contain in stem and the reconstituted tobacoo one or both.
The 3rd aspect of the present invention also provides a kind of cigarette, it is characterized in that, contains above-mentioned cigarette additive in the pipe tobacco of said cigarette and/or the filter stick.That is, said cigarette additive both can add in the pipe tobacco of cigarette, also can in the filter stick of cigarette, add, and can also in pipe tobacco and filter stick, add simultaneously.
Preferable, the addition of said cigarette additive in pipe tobacco is the 0.05-3.0% of pipe tobacco gross weight, the addition in filter stick is the 0.15-8.0% of filter stick weight.
Further, except that pipe tobacco, can also contain in stem and the reconstituted tobacoo one or both in the said cigarette, the addition of said cigarette additive this moment in pipe tobacco is the 0.05-3.0% of pipe tobacco, stem and reconstituted tobacoo gross weight.
The 4th aspect of the present invention; A kind of method that promotes cigarette fragrance and/or optionally reduce harmful components carbonyl complex content in the cigarette mainstream flue gas also is provided: for diluting on after-applied pipe tobacco in cigarettes plus, stem, reconstituted tobacoo and/or the filter stick with cigarette additive stoste of the present invention or with cigarette additive, and balance was not less than 48 hours under the condition of constant temperature and humidity.The addition of said cigarette additive in cigarette is the 0.05-3.0% of pipe tobacco in the cigarette, stem and reconstituted tobacoo gross weight, or is the 0.15-8.0% of the filter stick weight of cigarette.
Said applying method can be to spray before rolling or roll the back to inject.For example before rolling; Evenly be sprayed at after diluting by the conventional adding method of cigarette additive (for example using absolute ethyl alcohol, acetone, ethyl acetate or volume ratio is 30～95% ethanol water dilution) with the stoste of additive of the present invention or with additive and roll into cigarette on cigarette shreds, stem and/or the reconstituted tobacoo again and prop up, perhaps test also can be through being injected into cigarette with cigarette pipe tobacco and/or the mode in the filter stick additive is added cigarette.
Further, it is 22 ± 1 ℃ that said balance is used temperature, and balance uses humidity to be relative humidity 60 ± 2%.
The present invention will have the dry immature fruit of the natural plants evodia rutaecarpa of medicinal efficacy; Extract its active ingredient; Add in sample pipe tobacco or the filter stick, can reduce harmful substance in the cigarette mainstream flue gas, alleviate harm of smoking property; Especially crotonaldehyde in the cigarette mainstream flue gas there is tangible reduction effect, can promotes the fragrance of cigarette again.Cigarette of the present invention is simple with natural additive preparation technology, cost is low, has important market prospects.
The specific embodiment
Further set forth the present invention below in conjunction with embodiment.Should be understood that these embodiment only are used to explain the present invention, and unrestricted scope of the present invention.
Embodiment 1
(1) get evodia rutaecarpa 20 grams, after 10 minutes, ultrasonic Extraction is 45 minutes under the room temperature with the 50ml soaked in absolute ethyl alcohol in the pulverizing back, filters with qualitative filter paper, collects filtrating.Repeat again to extract once, merge extract.This evodia rutaecarpa extract rotary evaporation under 40～70 ℃ of water bath condition is evaporated to 30ml, obtains natural tobacco additive solution.
(2) the above-mentioned natural tobacco additive solution that makes is injected the sample cigarette; Inject the amount of 50ul in the pipe tobacco of every sample cigarette and the filter stick respectively, the experiment cigarette that makes balance 48 hours in constant temperature (22 ± 1 ℃) constant humidity (relative humidity 60 ± 2%) environment.
Adopt high performance liquid chromatography to record to add in the main flume of the cigarette sample behind the evodia extract carbonyl class harmful substance contents such as crotonaldehyde to decrease, wherein crotonaldehyde content is reduced to 14.2ug/cig by 21.5ug/cig, and reduced rate is 33.95%.
(3) experimental result shows: this cigarette additive can significantly reduce harmful substance in the cigarette mainstream flue gas, alleviates harm of smoking property, and especially the reduction effect to crotonaldehyde in the cigarette mainstream flue gas is the most obvious.
(4) sensory evaluating smoking result shows: this cigarette has can promote cigarette fragrance, can significantly reduce the assorted gas in the flue gas, makes cigarette smoke finer and smoother, soft.
Embodiment 2
(1) gets evodia rutaecarpa 20 grams, pulverize the back with 100ml water logging bubble, and decocted 120 minutes, filter, collect filtrating.With this evodia rutaecarpa extract heating evaporation, process medicinal extract.
(2) the above-mentioned natural tobacco additive that makes is injected the sample cigarette by conventional perfuming method dilution back; Inject respectively in the pipe tobacco of every sample cigarette and the filter stick be equivalent to pipe tobacco weight 0.05% with the additive of 0.15% step (1) gained that is equivalent to filter stick weight, the cigarette that makes balance 48 hours in constant temperature (22 ± 1 ℃) constant humidity (relative humidity 60 ± 2%) environment.
(3) effect is with embodiment 1, and carbonyl complex content such as crotonaldehyde obviously reduces in the cigarette mainstream flue gas.
Embodiment 3
(1) get evodia rutaecarpa 20 grams, after the pulverizing back was soaked 10 minutes with 80ml ethyl acetate, ultrasonic Extraction was 60 minutes under the room temperature, filters with qualitative filter paper, collects and filtrates.Repeat again to extract once, merge extract.This evodia rutaecarpa extract rotary evaporation under 70～90 ℃ of water bath condition is evaporated to 20ml, obtains natural tobacco additive solution.
(2) with the ratio of prepared natural tobacco additive solution in pipe tobacco weight 0.05%; Process by conventional perfuming evenly is sprayed on the sample cigarette shreds; Sealing was preserved 24 hours; Process cigarette, and cigarette balance under constant temperature (22 ± 1 ℃) constant humidity (relative humidity 60 ± 2%) condition was not less than 48 hours.
(3) effect is with embodiment 1, and carbonyl complex content such as crotonaldehyde reduces in the cigarette mainstream flue gas.
Embodiment 4
(1) get evodia rutaecarpa 20 grams, after the pulverizing back was soaked 10 minutes with 50ml acetone, ultrasonic Extraction was 45 minutes under the room temperature, filters with qualitative filter paper, collects and filtrates.Repeat again to extract once, merge extract.With the concentrated medicinal extract of processing of this evodia rutaecarpa extract rotary evaporation decompression under 40～70 ℃ of water bath condition.
(2) with the ratio of prepared natural tobacco additive in pipe tobacco weight 3%; Process by conventional perfuming evenly is sprayed on the sample cigarette shreds; Sealing was preserved 24 hours; Process cigarette, and cigarette balance under constant temperature (22 ± 1 ℃) constant humidity (relative humidity 60 ± 2%) condition was not less than 48 hours.
(3) effect is with embodiment 1, and carbonyl complex content such as crotonaldehyde obviously reduces in the cigarette mainstream flue gas.
Embodiment 5
(1) get evodia rutaecarpa 20 gram, pulverize after the back soaks 10 minutes with the ethanol water of 80ml 30%, ultrasonic Extraction is 45 minutes under the room temperature, filters, and collects and filtrates.This evodia rutaecarpa extract is processed medicinal extract.
(2) with the ratio of prepared natural tobacco additive in filter stick weight 8%; Process by conventional perfuming evenly is sprayed on the sample cigarette filter rod material; Sealing was preserved 24 hours; Process cigarette, and cigarette balance under constant temperature (22 ± 1 ℃) constant humidity (relative humidity 60 ± 2%) condition was not less than 48 hours.
(3) effect is with embodiment 1, and carbonyl complex content such as crotonaldehyde obviously reduces in the cigarette mainstream flue gas.
Embodiment 6
(1) get evodia rutaecarpa 20 gram, pulverize the back with the soaked in absolute ethyl alcohol of 60ml 95% after 10 minutes, ultrasonic Extraction is 45 minutes under the room temperature, filters, and collects and filtrates.Repeat again to extract once, merge extract.This evodia rutaecarpa extract rotary evaporation under 40～70 ℃ of water bath condition is evaporated to 20ml, obtains natural tobacco additive solution.
(2) with the ratio of prepared natural tobacco additive solution in filter stick weight 0.15%; Process by conventional perfuming evenly is sprayed on the sample cigarette filter rod material; Sealing was preserved 24 hours; Process cigarette, and cigarette balance under constant temperature (22 ± 1 ℃) constant humidity (relative humidity 60 ± 2%) condition was not less than 48 hours.
(3) effect is with embodiment 1, and carbonyl complex content such as crotonaldehyde reduces in the cigarette mainstream flue gas.
Claims (17)
1. a cigarette additive is the effective component extracts of Chinese medicine evodia rutaecarpa.
2. cigarette additive as claimed in claim 1 is characterized in that, said Chinese medicine evodia rutaecarpa is the dry immature fruit of rutaceae evodia rutaecarpa.
3. according to claim 1 or claim 2 the preparation method of cigarette additive; Comprise the following steps: that with said Chinese medicine evodia rutaecarpa be raw material; Employing water, organic solvent or water-containing organic solvent extract repeatedly, filter and merging filtrate, obtain additive behind filtrate concentrated or the evaporate to dryness.
4. the preparation method of cigarette additive as claimed in claim 3 is characterized in that, said organic solvent is selected from absolute ethyl alcohol, acetoneand ethyl acetate; Said water-containing organic solvent is that volumn concentration is 30～95% ethanol water; Method for distilling is that reflux, Suo Shi are extracted, temperature is soaked, cold soaking, decoction, Microwave Extraction or ultrasonic Extraction.
5. like the preparation method of the said cigarette additive of claim 3, it is characterized in that, specifically adopt the following step to prepare said additive:
1) be raw material with the Chinese medicine evodia rutaecarpa; Water, absolute ethyl alcohol, acetone, ethyl acetate or the volumn concentration that uses 2～5 times of amounts of crude drug weight after crushed is that 30～95% ethanol water is as extracting solvent; With reflux, Suo Shi extract, temperature is soaked, cold soaking, decoction, Microwave Extraction or ultrasonic Extraction are method for distilling, extract also and filter; Repeat to extract merging filtrate 2～4 times;
2) after being concentrated, gained filtrating processes solution shape additive or medicinal extract.
6. the purposes of the effective component extracts of Chinese medicine evodia rutaecarpa is characterized in that, the effective component extracts of said Chinese medicine evodia rutaecarpa is as cigarette additive.
7. purposes as claimed in claim 6 is characterized in that, said Chinese medicine evodia rutaecarpa is the dry immature fruit of rutaceae evodia rutaecarpa.
8. purposes as claimed in claim 6 is characterized in that, the content that said cigarette additive is used for promoting cigarette fragrance and/or optionally reduces cigarette mainstream flue gas harmful components carbonyl complex.
9. purposes as claimed in claim 6; It is characterized in that said cigarette additive is used to prepare filter stick, pipe tobacco, stem or the reconstituted tobacoo of cigarette, cigarette as the natural additive that promotes cigarette fragrance and/or optionally reduce harmful components carbonyl complex content in the cigarette mainstream flue gas.
10. like claim 8 or 9 described purposes, it is characterized in that said carbonyl complex is selected from crotonaldehyde, formaldehyde, acetaldehyde, propionic aldehyde, butyraldehyde, methacrylaldehyde and methyl ethyl ketone.
11. a cigarette is characterized in that, contains cigarette additive according to claim 1 or claim 2 in the pipe tobacco of said cigarette and/or the filter stick.
12. cigarette as claimed in claim 11 is characterized in that, the addition of said cigarette additive in pipe tobacco is the 0.05-3.0% of pipe tobacco gross weight, and the addition in filter stick is the 0.15-8.0% of filter stick weight.
13. like claim 11 or 12 described cigarette, it is characterized in that, except that pipe tobacco, also contain in stem and the reconstituted tobacoo one or both in the said cigarette; The addition of said cigarette additive in pipe tobacco is the 0.05-3.0% of pipe tobacco, stem and reconstituted tobacoo gross weight.
14. method that promotes cigarette fragrance and/or optionally reduce harmful components carbonyl complex content in the cigarette mainstream flue gas: for diluting on after-applied pipe tobacco in cigarettes plus, stem, reconstituted tobacoo and/or the filter stick with cigarette additive stoste of the present invention or with cigarette additive, and balance was not less than 48 hours under the condition of constant temperature and humidity.
15. method as claimed in claim 14 is characterized in that, the addition of said cigarette additive in cigarette is the 0.05-3.0% of pipe tobacco in the cigarette, stem and reconstituted tobacoo gross weight, or is the 0.15-8.0% of the filter stick weight of cigarette.
16. method as claimed in claim 14 is characterized in that, said applying method is injected for spraying before rolling or rolling the back.
17., it is characterized in that said balance uses temperature to be 21-23 ℃ like the described method of the arbitrary claim of claim 14-16, balance uses humidity to be relative humidity 58-62%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN 201110250997 CN102318897B (en) | 2011-08-29 | 2011-08-29 | Cigarette additive for reducing cigarette harm and preparation and application thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110250997 CN102318897B (en) | 2011-08-29 | 2011-08-29 | Cigarette additive for reducing cigarette harm and preparation and application thereof |
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| CN102318897A true CN102318897A (en) | 2012-01-18 |
| CN102318897B CN102318897B (en) | 2013-08-14 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106148011A (en) * | 2016-07-20 | 2016-11-23 | 湖北中烟工业有限责任公司 | The preparation method of a kind of cigarette radix valerianae extract and the application in Medicated cigarette thereof |
| CN106198824A (en) * | 2016-09-18 | 2016-12-07 | 中国烟草总公司郑州烟草研究院 | A kind of cigarette additive screening technique based on carbonyl compound burst size |
| CN107969729A (en) * | 2017-12-16 | 2018-05-01 | 江西中烟工业有限责任公司 | A kind of method for reducing flue gas crotons aldehyde |
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| CN1931271A (en) * | 2006-09-27 | 2007-03-21 | 贵州师范大学 | Evodia extract and its prepn process, medicine composition and use |
| CN101224250A (en) * | 2007-01-17 | 2008-07-23 | 广州汉方现代中药研究开发有限公司 | Preparing method for extracting medicinal evodia alkaloid by ultrasound |
| CN101775336A (en) * | 2010-02-08 | 2010-07-14 | 云南烟草科学研究院 | Macadamia shell extract and application thereof |
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2011
- 2011-08-29 CN CN 201110250997 patent/CN102318897B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH1179982A (en) * | 1997-09-12 | 1999-03-23 | Bae O-Sung | Smoking material serving also for prohibition of smoking and its production |
| CN1931271A (en) * | 2006-09-27 | 2007-03-21 | 贵州师范大学 | Evodia extract and its prepn process, medicine composition and use |
| CN101224250A (en) * | 2007-01-17 | 2008-07-23 | 广州汉方现代中药研究开发有限公司 | Preparing method for extracting medicinal evodia alkaloid by ultrasound |
| CN101775336A (en) * | 2010-02-08 | 2010-07-14 | 云南烟草科学研究院 | Macadamia shell extract and application thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106148011A (en) * | 2016-07-20 | 2016-11-23 | 湖北中烟工业有限责任公司 | The preparation method of a kind of cigarette radix valerianae extract and the application in Medicated cigarette thereof |
| CN106198824A (en) * | 2016-09-18 | 2016-12-07 | 中国烟草总公司郑州烟草研究院 | A kind of cigarette additive screening technique based on carbonyl compound burst size |
| CN107969729A (en) * | 2017-12-16 | 2018-05-01 | 江西中烟工业有限责任公司 | A kind of method for reducing flue gas crotons aldehyde |
| CN107969729B (en) * | 2017-12-16 | 2020-08-28 | 江西中烟工业有限责任公司 | Method for reducing crotonaldehyde content in flue gas |
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| CN102318897B (en) | 2013-08-14 |
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