CN101637304B - Natural extract added into cigarettes, extracting method thereof and cigarettes - Google Patents
Natural extract added into cigarettes, extracting method thereof and cigarettes Download PDFInfo
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- CN101637304B CN101637304B CN2009101094556A CN200910109455A CN101637304B CN 101637304 B CN101637304 B CN 101637304B CN 2009101094556 A CN2009101094556 A CN 2009101094556A CN 200910109455 A CN200910109455 A CN 200910109455A CN 101637304 B CN101637304 B CN 101637304B
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Abstract
The invention discloses a natural extract added into cigarettes, an extracting method thereof and cigarettes, which aim at solving the technical problem of reducing harms to the human body from the cigarettes. The natural extract can be prepared by adopting the following steps: crushing dried stem leaves of ampelopsis grossedentata, refluxing by ethanol, decompressing and concentrating at 0.05Mpa and 80 DEG C for 2 hours, adding water, heating, dissolving, filtering, adding macroporous resin columns, eluting by ethanol, and recrystallizing eluant at 0-10 DEG C to obtain 99 percent of natural extract of dihydromyricetin. The cigarettes contain the natural extract of the dihydromyricetin, which accounts for 0.01-10 percent of cut tobaccos in weight percent. Compared with the prior art, the invention keeps the original taste and style of the cigarettes, can reduce the contents of nitrosamine, CO, phenol and crotonic aldehyde in cigarette smoke, and releases the adverse reactions of cough, asthma, phlegm stasis, throat obstruction, and the like caused by smoking.
Description
Technical field
The present invention relates to a kind of extract and method for distilling thereof that adds the reduction cigarette harm in the cigarette to, add the cigarette of this extract, particularly a kind of natural extract and method for distilling thereof, add the cigarette of this extract.
Background technology
In recent years, China's tobacco business is done a lot of work in cigarette harm reduction technical research and application field, has obtained certain effect.The practicality of developing a collection of reduction cigarette smoke harmful components is added product and in cigarette, is applied.But; The level of China's harm reduction product can't satisfy the needs of China's current development Chinese style cigarette fully at present; Lack the ripe relatively strong selective harm reduction product of selectivity height, good stability, industrial usability; Since 2005, State Tobacco Monopoly Bureau has organized the work of cigarette harmfulness Research on Index System, and finishing screen is selected CO, HCN, NNK, NH
3, benzo [α] pyrene, phenol, 7 indexs of crotonaldehyde characterize cigarette mainstream flue gas biohazard property.Carry out this type of research, particularly the extract harm reduction of appliable plant to reduce cigarette harm around reducing these seven indexs, need do a large amount of work.
Summary of the invention
The purpose of this invention is to provide a kind of natural extract and method for distilling thereof, cigarette that adds in the cigarette, the technical problem that solve is to reduce the harm of cigarette to human body.
The present invention adopts following technical scheme: a kind of natural extract that adds in the cigarette, and the said natural extract that adds in the cigarette can obtain with following method: with 1 kilogram of pulverizing of dry cauline leaf of ampelopsis grossdentata, with 6000 milliliters of 70-95% alcohol refluxs 2 times; Time was respectively 2 and 1 hours; 0.05Mpa, be evaporated to alcohol flavor paste under 80 ℃, 2 hours time condition, add 80 ℃ of dissolvings of water heating-up temperature of 4 times of cream amounts, filter; Add 4 kilograms of macroporous resin column D101 in the filtrating; With the 20-95% ethanol elution of 6 times of macroreticular resin column volumes, eluent obtains the plain natural extract of 99% pair of hydrogen red bayberry at 0-10 ℃ of recrystallization.
A kind of natural extract that adds in the cigarette, the said natural extract that adds in the cigarette can obtain with following method: with 1 kilogram of pulverizing of dry cauline leaf of ampelopsis grossdentata, soaked 24 hours with 10-20 kilogram 50-95% ethanol; Be evaporated under the percolate 0.05Mpa, 80 ℃, 2 hours time condition and do not have alcohol flavor paste; The water heating for dissolving that adds 4 times of cream amounts, 80 ℃ of heating-up temperatures are filtered; Filtrating was placed 24 hours; Separate out crystallization,, obtain containing the plain natural extract of 10% pair of hydrogen red bayberry again at 0-10 ℃ of recrystallization.
A kind of natural extract that adds in the cigarette; The said natural extract that adds in the cigarette can obtain with following method: with 1 kilogram of pulverizing of dry cauline leaf of ampelopsis grossdentata; With 35 ℃ of carbon dioxide supercritical extraction temperature, pressure 20MPa, 2 hours time; Get coarse crystallization and separate out naturally, obtain the plain natural extract of 99% pair of hydrogen red bayberry at 0-10 ℃ of recrystallization again.
A kind of method for distilling that adds the natural extract in the cigarette to may further comprise the steps: with 1 kilogram of pulverizing of dry cauline leaf of ampelopsis grossdentata, with 6000 milliliters of 70-95% alcohol refluxs 2 times; Time was respectively 2 and 1 hours; 0.05Mpa, be evaporated to alcohol flavor paste under 80 ℃, 2 hours time condition, add 80 ℃ of dissolvings of water heating-up temperature of 4 times of cream amounts, filter; Add 4 kilograms of macroporous resin column D101 in the filtrating; With the 20-95% ethanol elution of 6 times of macroreticular resin column volumes, eluent obtains the plain natural extract of 99% pair of hydrogen red bayberry at 0-10 ℃ of recrystallization.
A kind of method for distilling that adds the natural extract in the cigarette to may further comprise the steps: with 1 kilogram of pulverizing of dry cauline leaf of ampelopsis grossdentata, soaked 24 hours with 10-20 kilogram 50-95% ethanol; Being evaporated under the percolate 0.05Mpa, 80 ℃, 2 hours time condition does not have alcohol flavor paste, adds the water heating for dissolving of 4 times of cream amounts, 80 ℃ of heating-up temperatures; Filter, filtrating was placed 24 hours, separated out crystallization; At 0-10 ℃ of recrystallization, obtain containing the plain natural extract of 10% pair of hydrogen red bayberry again.
A kind of method for distilling that adds the natural extract in the cigarette to; May further comprise the steps: with 1 kilogram of pulverizing of dry cauline leaf of ampelopsis grossdentata; With 35 ℃ of carbon dioxide supercritical extraction temperature, pressure 20MPa, 2 hours time; Get coarse crystallization and separate out naturally, obtain the plain natural extract of 99% pair of hydrogen red bayberry at 0-10 ℃ of recrystallization again.
A kind of cigarette has pipe tobacco, contains in the said cigarette and the plain natural extracts of two hydrogen red bayberries of the 0.01-10% ratio of pipe tobacco weight.
The present invention compared with prior art adds two hydrogen myricetins to cigarette, has kept original suction flavor of cigarette and style; Reach " cigarette perfume ", " medicine is fragrant ", " fragrant section is fragrant " three fragrant unifications, coordination is closed humorous, strengthens flue gas; Pure and mild time of mouthfeel is sweet; Pharmacological action shows, adds the low harm cigarette of two hydrogen myricetins, can reduce the content of nitrosamine in the cigarette smoke, CO, phenol, crotonaldehyde; And the mutagenicity that obviously suppresses BaP, bad reactions such as alleviating cough that smoking causes, breathe, stasis of blood phlegm, throat are not smooth.
The specific embodiment
Below in conjunction with embodiment the present invention is done further explain.The natural extract that adds in the cigarette of the present invention is two hydrogen myricetins, and the extraction purifying of two hydrogen myricetins adopts following three kinds of methods:
One, with 1 kilogram of pulverizing of dry cauline leaf of ampelopsis grossdentata (Ampelopsis grossedentata is commonly called as sweet tea or vine tea), with 6000 milliliters of 70-95% alcohol refluxs 2 times; Time was respectively 2 and 1 hours; 0.05Mpa, be evaporated to alcohol flavor paste under 80 ℃, 2 hours time condition, add 80 ℃ of dissolvings of water heating-up temperature of 4 times of cream amounts, filter; Add 4 kilograms of macroporous resin column D101 in the filtrating; With the 20-95% ethanol elution of 6 times of macroreticular resin column volumes, eluent obtains the plain natural extract of 99% pair of hydrogen red bayberry at 0-10 ℃ of recrystallization.
Two, with 1 kilogram of pulverizing of dry cauline leaf of ampelopsis grossdentata, percolation normal temperature extracts, and soaks 24 hours with 10-20 kilogram 50-95% ethanol; Being evaporated under the percolate 0.05Mpa, 80 ℃, 2 hours time condition does not have alcohol flavor paste, adds the water heating for dissolving of 4 times of cream amounts, 80 ℃ of heating-up temperatures; Filter, filtrating was placed 24 hours, separated out crystallization; At 0-10 ℃ of recrystallization, obtain containing the plain natural extract of 10% pair of hydrogen red bayberry again.
Three, with 1 kilogram of pulverizing of dry cauline leaf of ampelopsis grossdentata,, get coarse crystallization and separate out naturally, obtain the plain natural extract of 99% pair of hydrogen red bayberry at 0-10 ℃ of recrystallization again with 35 ℃ of carbon dioxide supercritical extraction temperature, pressure 20MPa, 2 hours time.
Cigarette of the present invention; With content is that two hydrogen myricetins of 0.01-99.5% are made into 10% solution with 50-80% ethanol; Evenly spray the plain natural extract of two hydrogen red bayberries to pipe tobacco in the 0.01-10% ratio that accounts for pipe tobacco weight again, dry, process cigarette by conventional cigarette process again.
Embodiment 1, and the 1 kilogram of pulverizing of dry cauline leaf with ampelopsis grossdentata was respectively for 2 times 2,1 hours with 6000 milliliter of 95% alcohol reflux; Decompression concentrates 0.05Mpa, 80 ℃, 2 hours time condition and distinguishes the flavor of down to alcohol; Add 80 ℃ of dissolvings of 4 times of cream water gaging heating-up temperatures, filter, filtrating adds 4 kilograms of macroporous resin column D101; With 6 times of column volume 75% ethanol elutions, the eluent recrystallization promptly gets below 10 ℃ and contains the plain natural extract of 99% pair of hydrogen red bayberry.To contain the plain natural extract 1 of 99% pair of hydrogen red bayberry again and restrain alcohol dilution, and press 0.3% of pipe tobacco part by weight and add, process cigarette with 100 milliliter 80%.
Embodiment 2, with 1 kilogram of pulverizing of dry cauline leaf of ampelopsis grossdentata, extract 10 kilogram of 95% ethanol with 95% ethanol with percolation and soak 24 hours; The percolate decompression concentrates 0.05Mpa, and 80 ℃, 2 hours time to nothing alcohol flavor add 4 times of cream water gaging dissolvings; 80 ℃ of heating-up temperatures are filtered, and filtrating was placed 24 hours; Separate out crystallization, be recrystallized again promptly to get below 10 ℃ and contain the plain natural extract of 10% pair of hydrogen red bayberry.To contain the plain natural extract 1 of 10% pair of hydrogen red bayberry again and restrain alcohol dilution, and press 0.1% of pipe tobacco part by weight and add, process cigarette with 100 milliliter 75%.
Embodiment 3, with 1 kilogram of pulverizing of dry cauline leaf of ampelopsis grossdentata, with 35 ℃ of carbon dioxide supercritical extraction temperature, pressure 20MPa, 2 hours time, get coarse crystallization, and being recrystallized obtains containing the plain natural extract of 50% pair of hydrogen red bayberry again below 10 ℃.To contain the plain natural extract 1 of 50% pair of hydrogen red bayberry again and restrain alcohol dilution, and press 0.2% of pipe tobacco part by weight and add, process cigarette with 100 milliliter 50%.
Embodiment 4; 1 kilogram of pulverizing of dry cauline leaf with ampelopsis grossdentata was respectively for 2 times 2,1 hours with 95% alcohol reflux, and decompression concentrates 0.05Mpa, 80 ℃ of 2 hours time to alcohol flavors; Add 80 ℃ of dissolvings of 4 times of cream water gaging heating-up temperatures; Filter, filtrating is washed recrystallization below 10 ℃ with 1000 milliliters of 20% ethanol, obtains containing the plain natural extract of 1% pair of hydrogen red bayberry.To contain the plain natural extract 1 of 1% pair of hydrogen red bayberry again and restrain alcohol dilution, and press 1% of pipe tobacco part by weight and add, process cigarette with 100 milliliter 80%.
Embodiment 5, with 1 kilogram of pulverizing of dry cauline leaf of ampelopsis grossdentata, extract 20 kilogram of 50% ethanol with 95% ethanol with percolation and soak 24 hours, and the percolate decompression concentrates 0.05Mpa, 80 ℃, 2 hours time to nothing alcohol flavor; Add 4 times of cream water gaging dissolvings, heating is filtered; Filtrating adds 4 kilograms of macroporous resin column D101, and with 6 times of column volume 75% ethanol elutions, the eluent recrystallization was placed 24 hours; Separate out crystallization,, obtain containing the plain natural extract of 10% pair of hydrogen red bayberry at recrystallization below 10 ℃.To contain the plain natural extract 1 of 10% pair of hydrogen red bayberry again and restrain alcohol dilution, and press 0.05% of pipe tobacco part by weight and add, process cigarette with 100 milliliter 75%.
Two hydrogen myricetins (dihydromyricetin), structural formula are suc as formula (1): have another name called dibydro myricetrin,
Ampelopstin, cover element, dihydromyricetin flavones, ampelopsin in vain, medical circle is with its called after " the clear cigarette factor " at home.Derive from vitaceae ampelopsis grossdentata Ampelopsis grossedentata (Hand.-Mazz.) W.T.Wang.Be commonly called as Guangxi Folium hydrangeae strigosae or vine tea, have cough-relieving, eliminate the phlegm, lipopenicillinase, hypoglycemic, hepatoprotective effect, in China south among the people do medicinal permanent with edible time.Ampelopsis grossdentata mainly originates on 200～800 meters high mountain regions of height above sea level such as China Guangdong, Hainan, Jiangxi, Guizhou, Yunnan, Hunan, Fujian as the main plant source of two hydrogen myricetins.
The pharmacological action of two hydrogen myricetins: 1, antibacterial action, two hydrogen myricetins to withered grass bud pole bacterium, staphylococcus aureus, Salmonella, Escherichia coli, aerobacteria, beer bacillus, sticking red bacillus, Penicillium notatum, black-koji mould, mucor, rhizopus, Pseudomonas aeruginosa, first type haemolysis type streptococcus, beta hemolysis type streptococcus, Diplococcus pneumopniae, white is read 16 kinds of bacteriums of coccus that certain inhibition effect is all arranged.2, improve the animal immune function, thereby two hydrogen myricetin can improve the mouse monokaryon macrophage phagocytic function and hemolysin content strengthens cell and humoral immune function.3, liver protection function, two hydrogen myricetin liver protecting mechanism mainly are to suppress the fibriilar formation of liver property M cell glue, thereby reach the purpose of treatment hepatopathy.The result shows that two hydrogen myricetins can obviously suppress CCl
4Induced mice serum glutamic pyruvic transminase GPT, the active rising of glutamic-oxalacetic transaminease GOT, and reduce bilirubin direct T-BIL content.Test shows that two hydrogen Chinese waxmyrtle barks have the hepatoprotective effect of tangible reducing enzyme and treating jaundice.4, antioxidation, the antioxidant effect of two hydrogen myricetins are superior to catechol, isoflavones, these three kinds of naturals commonly used of kudzuvine root isoflavone.
The bitter earlier back of two hydrogen myricetins is sweet, the sweet cold of aftertaste.It is added in the cigarette; Have clearing heat and moistening lung, flat liver benefit blood, eliminating inflammation and expelling toxin, step-down fat reducing, eliminate tired effect; Especially to because of tobacco and wine are excessive, greasy too much, irascibility is crossed uncomfortable that prosperous guiding rises,, has uniqueness and the health-care efficacy of ethereality like sphagitis, digestive functional disturbance.It is joined the harm that reduces cigarette in the pipe tobacco, make the smoker in smoking, be of value to health thereby can suck effective medicinal ingredient.
Cigarette of the present invention behind the two hydrogen myricetins of adding, does not only influence original mouthfeel of cigarette in pipe tobacco, and the sensation of sweet cold is arranged after the suction.
The present invention has no particular limits the amount that two hydrogen myricetins join in the pipe tobacco, and the mouthfeel when mainly looking smoking decides, and its addition weight ratio can be 0.01%, the highest 10% of the pipe tobacco that accounts for.
Claims (5)
1. natural extract that adds in the cigarette, it is characterized in that: the said natural extract that adds in the cigarette can obtain with following method: with 1 kilogram of pulverizing of dry cauline leaf of ampelopsis grossdentata, soaked 24 hours with 10-20 kilogram 50-95% ethanol; Be evaporated under the percolate 0.05Mpa, 80 ℃, 2 hours time condition and do not have alcohol flavor paste; The water heating for dissolving that adds the quality of 4 times of said cream, 80 ℃ of heating-up temperatures are filtered; Filtrating was placed 24 hours; Separate out crystallization,, obtain containing the plain natural extract of 10% pair of hydrogen red bayberry again at 0-10 ℃ of recrystallization.
2. natural extract that adds in the cigarette; It is characterized in that: the said natural extract that adds in the cigarette can obtain with following method: with 1 kilogram of pulverizing of dry cauline leaf of ampelopsis grossdentata; With 35 ℃ of carbon dioxide supercritical extraction temperature, pressure 20MPa, 2 hours time; Get coarse crystallization and separate out naturally, obtain the plain natural extract of 99% pair of hydrogen red bayberry at 0-10 ℃ of recrystallization again.
3. a method for distilling that adds the natural extract in the cigarette to may further comprise the steps: with 1 kilogram of pulverizing of dry cauline leaf of ampelopsis grossdentata, soaked 24 hours with 10-20 kilogram 50-95% ethanol; Being evaporated under the percolate 0.05Mpa, 80 ℃, 2 hours time condition does not have alcohol flavor paste, adds the water heating for dissolving of the quality of 4 times of said cream, 80 ℃ of heating-up temperatures; Filter, filtrating was placed 24 hours, separated out crystallization; At 0-10 ℃ of recrystallization, obtain containing the plain natural extract of 10% pair of hydrogen red bayberry again.
4. method for distilling that adds the natural extract in the cigarette to; May further comprise the steps: with 1 kilogram of pulverizing of dry cauline leaf of ampelopsis grossdentata; With 35 ℃ of carbon dioxide supercritical extraction temperature, pressure 20MPa, 2 hours time; Get coarse crystallization and separate out naturally, obtain the plain natural extract of 99% pair of hydrogen red bayberry at 0-10 ℃ of recrystallization again.
5. a cigarette has pipe tobacco, it is characterized in that: contain the plain natural extracts of two hydrogen red bayberries that the method in the employing claim 3 or 4 of 0.1%, 0.2%, 0.3% or 1% ratio of pipe tobacco weight obtains in the said cigarette.
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Families Citing this family (8)
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| CN102894473A (en) * | 2012-10-19 | 2013-01-30 | 云南瑞升烟草技术（集团）有限公司 | Method for preparing additive capable of reducing content of phenol and crotonaldehyde of cigarette |
| CN103740465B (en) * | 2013-12-13 | 2016-05-04 | 浙江中烟工业有限责任公司 | Red bayberry medicinal extract and preparation method thereof and its purposes as tobacco additive agent for cigarette |
| CN104687242B (en) * | 2014-10-28 | 2016-11-23 | 深圳市大百汇技术有限公司 | (the R)-3-carboxyl-method of Alpha-hydroxy benzenpropanoic acid, application and medicated cigarette is extracted from Flos Plumeriae Acutifoliae |
| CN104664585B (en) * | 2015-01-08 | 2017-05-17 | 恩施市锦华生物工程有限责任公司 | Selenium-rich tea flavored chewing tobacco and production method thereof |
| CN105876846A (en) * | 2016-04-29 | 2016-08-24 | 张家界久瑞生物科技有限公司 | Ampelopsis grossedentata extract-containing electronic tobacco liquid and preparation method thereof |
| CN107397843B (en) * | 2016-05-19 | 2021-03-02 | 苏州凯祥生物科技有限公司 | Application of vine tea extract in preparation of farnesol X receptor agonist |
| CN106433974A (en) * | 2016-11-17 | 2017-02-22 | 东莞波顿香料有限公司 | Cleome viscosa extract and cut tobaccos containing cleome viscosa extract |
| CN113796565B (en) * | 2021-10-09 | 2023-05-26 | 湖北中烟工业有限责任公司 | Preparation method of vine tea flavored novel cigarette essence |
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Effective date of registration: 20160205 Address after: 518000 Guangdong province Shenzhen city road salt Yantian District grand Parkway high tech Industrial Park A building 11 floor room 1102 building B and 1B Patentee after: Shenzhen Dabaihui Technology Co., Ltd. Address before: 518102 Guangdong province Shenzhen city road salt Yantian District grand Parkway High-tech Industrial Park building A Patentee before: Dabaihui Industrial Group Co., Ltd. |