CN106281714A - A kind of characteristic Camellia nitidissima Chi tobacco aromatics using and preparation method and application - Google Patents

A kind of characteristic Camellia nitidissima Chi tobacco aromatics using and preparation method and application Download PDF

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Publication number
CN106281714A
CN106281714A CN201610740050.2A CN201610740050A CN106281714A CN 106281714 A CN106281714 A CN 106281714A CN 201610740050 A CN201610740050 A CN 201610740050A CN 106281714 A CN106281714 A CN 106281714A
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China
Prior art keywords
camellia nitidissima
nitidissima chi
characteristic
cigarette
tobacco aromatics
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Pending
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CN201610740050.2A
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Chinese (zh)
Inventor
李志华
宋凌勇
刘绍华
吴彦
陈义昌
胡超
黄善松
务文涛
班强
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China Tobacco Guangxi Industrial Co Ltd
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China Tobacco Guangxi Industrial Co Ltd
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Priority to CN201610740050.2A priority Critical patent/CN106281714A/en
Publication of CN106281714A publication Critical patent/CN106281714A/en
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11BPRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B9/00Essential oils; Perfumes
    • C11B9/02Recovery or refining of essential oils from raw materials
    • C11B9/025Recovery by solvent extraction
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24BMANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
    • A24B15/00Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
    • A24B15/18Treatment of tobacco products or tobacco substitutes
    • A24B15/24Treatment of tobacco products or tobacco substitutes by extraction; Tobacco extracts
    • A24B15/241Extraction of specific substances
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24BMANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
    • A24B15/00Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
    • A24B15/18Treatment of tobacco products or tobacco substitutes
    • A24B15/24Treatment of tobacco products or tobacco substitutes by extraction; Tobacco extracts
    • A24B15/26Use of organic solvents for extraction
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11BPRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B9/00Essential oils; Perfumes
    • C11B9/02Recovery or refining of essential oils from raw materials
    • C11B9/022Refining

Abstract

The invention discloses a kind of characteristic Camellia nitidissima Chi tobacco aromatics using and preparation method thereof, described characteristic Camellia nitidissima Chi tobacco aromatics using primary raw material is the flower of Camellia nitidissima Chi, its preparation method is: by the flower ethanol extraction 2 times of cryodesiccated Camellia nitidissima Chi, after merging filtrate under conditions of pressure 0.02 0.09MPa with temperature 25 35 DEG C concentrating under reduced pressure.The present invention also disclosed the application of characteristic Camellia nitidissima Chi tobacco aromatics using: is dissolved in the ethanol of 50 95%, is uniformly sprayed on cigarette shreds according to perfuming flow process, and consumption is 0.1 1%wt of tobacco shred weight.After described tobacco aromatics using is applied to Medicated cigarette, there is during can making cigarette smoking the peculiar fragrance of Camellia nitidissima Chi coordinated with Medicated cigarette cigarette perfume (or spice), increase fragrance value and the perfume quantity of smoking property of cigarette, miscellaneous QI and zest can be reduced simultaneously, improve cigarette taste, promote the suction quality of Medicated cigarette.

Description

A kind of characteristic Camellia nitidissima Chi tobacco aromatics using and preparation method and application
Technical field
The present invention relates to field of cigarette producing technology, prepare for raw material particularly to a kind of flower with Camellia nitidissima Chi, can carry Rise the characteristic Camellia nitidissima Chi tobacco aromatics using of suction quality of Medicated cigarette, and its preparation method of this tobacco aromatics using and application.
Technical background
Along with going deep into of " Framework Convention on Tobacco Control " each performing states Smoking control, and cigarette consumption person is to own health Growing interest, low tar Less harmful cigarette is increasingly becoming the main flow of world Medicated cigarette development.But the fall along with tar content in cigarette Low, smoke is thin out, and fragrance weakens, and cigarette product loses original style, it is difficult to be esthetically acceptable to the consumers.Perfuming technology can be fine Play make up fall defocused fragrance loss, cover the effect of the miscellaneous taste of flue gas, be widely used in tobacco business.In previous generation Recording in the Medicated cigarette technology evolution at end, a lot of enterprises use the tobacco aromatics using that some are general, cause the same of Medicated cigarette fragrance style Matterization tendency is serious, and since entering new century, each enterprise, in order to increase the uniqueness of brand style, more stress exploitation and has uniqueness Style characteristic, particularly has the tobacco aromatics using of clear and definite region feature.
Nineteen sixty, Chinese science worker is found that a kind of flavous Flos Camelliae Japonicae at Nanning one band first, is ordered Entitled Camellia nitidissima Chi.Camellia nitidissima Chi (Yellow Flower Camellia), vegetable formal name is: Camellia chrysantha (Hu) Tuyama, Theaceae Camellia Camellia Section Chrysantha.Camellia nitidissima Chi is only distributed in south and the west and south in Guangxi in China.Guangxi becomes For the Camellia nitidissima Chi distribution center being currently known, it is described as the native place of Camellia nitidissima Chi.Camellia nitidissima Chi not only has high ornamental value, because of Rich in the natural materials of multiple participation body metabolism, its medicines and health protection is worth the most high, is described as " national treasure god's tea ".
Chemical constitution study shows: Camellia nitidissima Chi contains 400 multiple nutrients materials.Rich in tea polysaccharide, tea polyphenols, Total saponin, Total flavones, tea pigment, caffeine, protein, vitamin B1, B2, vitamin C, vitamin E, folic acid, fatty acid, B-carotene Etc. multiple natural nutrition composition;Camellia nitidissima Chi contains tens kinds of aminoacid such as theanine, threonine, and multiple to human body rich in having There is the trace element such as the natural organic germanium (Ge) of important health-care effect, selenium (Se), molybdenum (Mo), zinc (Zn), vanadium (V), and potassium (K), calcium (Ca), magnesium (Mg) etc..
Clinical trial and pharmaceutical research show, leaf of Camellia nitidissima Chi has suppression tumor, defying age, antimicrobial antiphlogistic, strengthens machine Body immunity, enhancing myocardial contraction and blood vessel elasticity, promote liver metabolism, and blood fat reducing particularly reduces cholesterol, reduces blood pressure And improve the various symptoms that are not suitable with caused because of hypertension, blood sugar lowering and glucose in urine, and without obvious toxic-side effects.
Camellia nitidissima Chi has fragmentary report as cigarette additive raw material at present, and CN101607003A discloses a kind of leaf of Camellia nitidissima Chi The highly effective extraction method of middle effective ingredient and the application in prepared by Medicated cigarette thereof, its raw material selected is mainly the leaf of Camellia nitidissima Chi, The flower that not its flavor component and functional component are enriched with most;And CN103622150A disclose a kind of Camellia nitidissima Chi cigarette additive and Its preparation method and utilization, it uses Camellia nitidissima Chi extractum to form with Mel mixture, and Camellia nitidissima Chi extractum is to pass through alcohol heating reflux Extract and obtain after concentrating, Camellia nitidissima Chi flavor component is much low-boiling point material, uses heating extraction can destroy its fragrance matter, It is substantially reduced its rich as tobacco aromatics using flavor component.
Summary of the invention
The invention provides a kind of characteristic Camellia nitidissima Chi tobacco aromatics using and preparation method and application.More specifically, the present invention One of purpose aim to tobacco aromatics using with the flower of Camellia nitidissima Chi as raw material at present and can only obtain its high boiling by heating extraction Put composition and lose the deficiency of more low boiling fragrance matter, it is provided that a kind of Camellia nitidissima Chi multiple fragrance material of holding as far as possible Characteristic Camellia nitidissima Chi tobacco aromatics using and preparation method thereof.The two of the object of the invention are to provide this characteristic Camellia nitidissima Chi tobacco aromatics using at volume Application in cigarette perfuming and effect.
A kind of characteristic Camellia nitidissima Chi tobacco aromatics using that the present invention provides, its primary raw material is the flower of Camellia nitidissima Chi, including petal, flower Stamen and alabastrum etc..
The preparation method of described a kind of characteristic Camellia nitidissima Chi tobacco aromatics using comprises the steps: A, by cryodesiccated JINHUA The flower of tea is put in clean container, adds the ethanol water that concentration is 50-95% of JINHUA Flos Camelliae Japonicae weight 5-50 times, 15~ 35 DEG C of temperature soaking and stirring are extracted 1-12 days, obtain filtrate with qualitative filter paper sucking filtration, altogether soak extraction 2 times;B, by twice immersion The ethanol extract extracted merges, and is then added in concentrator under conditions of pressure 0.02-0.09MPa with temperature 25-40 DEG C Carry out concentrating under reduced pressure, when the weight of concentrated solution is JINHUA Flos Camelliae Japonicae raw material weight 2.0-3.0 times, stop concentrating, obtain characteristic gold Scented tea tobacco aromatics using.
The preferred technical scheme of preparation method of a kind of characteristic Camellia nitidissima Chi tobacco aromatics using is: in step A, extracts process twice The ethanol water that concentration is 60-85% of middle addition JINHUA Flos Camelliae Japonicae weight 10-30 times, carries 20~30 DEG C of temperature soaking and stirring Take 3-9 days;In step B, under conditions of pressure 0.04-0.08MPa with temperature 25-35 DEG C, carry out concentrating under reduced pressure.
The preferred technical scheme of preparation method of a kind of characteristic Camellia nitidissima Chi tobacco aromatics using is: in step A, twice extraction During add the ethanol water that concentration is 65-70% of JINHUA Flos Camelliae Japonicae weight 15-25 times, at 20~25 DEG C of temperature immersion 6- 8 days;Concentrating under reduced pressure is carried out under conditions of pressure 0.06-0.08MPa with temperature 25-30 DEG C.
Invention also provides the application of a kind of characteristic Camellia nitidissima Chi tobacco aromatics using: take the characteristic gold that mass fraction is 1-10 Scented tea tobacco aromatics using, is dissolved in the ethanol of the 50-95% that mass fraction is 100, is uniformly sprayed on cigarette shreds according to perfuming flow process, Consumption is the 0.1-1%wt of tobacco shred weight.
Preferably application scheme: taking the characteristic Camellia nitidissima Chi tobacco aromatics using that mass fraction is 2-7, being dissolved in mass fraction is 100 The ethanol of 60-85%, be uniformly sprayed on cigarette shreds according to perfuming flow process, consumption is the 0.2-0.8%wt of tobacco shred weight.
Preferred application scheme is: taking the characteristic Camellia nitidissima Chi tobacco aromatics using that mass fraction is 3-5, being dissolved in mass fraction is The 65-70% ethanol of 100, is uniformly sprayed on cigarette shreds according to perfuming flow process, and consumption is the 0.3-0.5%wt of tobacco shred weight.
The beneficial effects of the present invention is: compared with prior art, a kind of characteristic Camellia nitidissima Chi tobacco aromatics using of the present invention Preparation method be under stirring at normal temperature merceration extract, can at utmost reduce boiling point flavor components various in Camellia nitidissima Chi, make Obtain its flavor component and note feature is at utmost saved from damage.Compared with prior art, a kind of characteristic JINHUA of the present invention After tea tobacco aromatics using is applied to Medicated cigarette, there is during can making cigarette smoking the peculiar perfume (or spice) of Camellia nitidissima Chi coordinated with Medicated cigarette cigarette perfume (or spice) Gas, increases fragrance value and the perfume quantity of smoking property of cigarette, can reduce miscellaneous QI and zest simultaneously, improve cigarette taste, promote volume The suction quality of cigarette.
Detailed description of the invention
Following implementation process and embodiment are intended to further illustrate the present invention and should not be construed as limitation of the invention.
Embodiment one:
Take cryodesiccated Camellia nitidissima Chi spends 200 grams to put in clean container, adds the ethanol water that 10kg concentration is 50% Solution, extracts 12 days 35 DEG C of temperature soaking and stirring, obtains filtrate with qualitative filter paper sucking filtration, altogether soak extraction 2 times;By twice leaching The ethanol extract that bubble extracts merges, and is then added in concentrator subtract under conditions of temperature 40 DEG C at pressure 0.02MPa Pressure concentrates, and when the weight of concentrated solution is JINHUA Flos Camelliae Japonicae raw material weight 2.0-3.0 times, stops concentrating, a kind of characteristic gold obtained Scented tea tobacco aromatics using.
Take 100g characteristic Camellia nitidissima Chi tobacco aromatics using, be dissolved in the ethanol of 1000g95%, be uniformly sprayed on according to perfuming flow process After 110kg cigarette shreds, roll into Medicated cigarette.
Embodiment two:
Put in clean container for colored 1kg gram that takes cryodesiccated Camellia nitidissima Chi, add the ethanol that 5kg concentration is 95% water-soluble Liquid, extracts 1 day 15 DEG C of temperature soaking and stirring, obtains filtrate with qualitative filter paper sucking filtration, altogether soak extraction 2 times;By twice immersion The ethanol extract extracted merges, and is then added in concentrator reduce pressure under conditions of temperature 25 DEG C at pressure 0.09MPa Concentrate, when the weight of concentrated solution is JINHUA Flos Camelliae Japonicae raw material weight 2.0-3.0 times, stop concentrating, a kind of characteristic JINHUA obtained Tea tobacco aromatics using.
Take 5g characteristic Camellia nitidissima Chi tobacco aromatics using, be dissolved in the ethanol of 500g50%, be uniformly sprayed on 505kg according to perfuming flow process After cigarette shreds, roll into Medicated cigarette.
Embodiment three:
Take cryodesiccated Camellia nitidissima Chi spends 500 grams to put in clean container, adds the ethanol water that 15kg concentration is 85% Solution, extracts 9 days 30 DEG C of temperature soaking and stirring, obtains filtrate with qualitative filter paper sucking filtration, altogether soak extraction 2 times;By twice leaching The ethanol extract that bubble extracts merges, and is then added in concentrator subtract under conditions of temperature 25 DEG C at pressure 0.08MPa Pressure concentrates, and when the weight of concentrated solution is JINHUA Flos Camelliae Japonicae raw material weight 2.0-3.0 times, stops concentrating, a kind of characteristic gold obtained Scented tea tobacco aromatics using.
Take 70g characteristic Camellia nitidissima Chi tobacco aromatics using, be dissolved in the ethanol of 1000g80%, be uniformly sprayed on according to perfuming flow process After 133.75kg cigarette shreds, roll into Medicated cigarette.
Embodiment four:
Take cryodesiccated Camellia nitidissima Chi spends 2000 grams to put in clean container, adds the ethanol water that 20kg concentration is 60% Solution, extracts 3 days 20 DEG C of temperature soaking and stirring, obtains filtrate with qualitative filter paper sucking filtration, altogether soak extraction 2 times;By twice leaching The ethanol extract that bubble extracts merges, and is then added in concentrator subtract under conditions of temperature 35 DEG C at pressure 0.04MPa Pressure concentrates, and when the weight of concentrated solution is JINHUA Flos Camelliae Japonicae raw material weight 2.0-3.0 times, stops concentrating, a kind of characteristic gold obtained Scented tea tobacco aromatics using.
Take 20g characteristic Camellia nitidissima Chi tobacco aromatics using, be dissolved in the ethanol of 1000g60%, be uniformly sprayed on according to perfuming flow process After 510kg cigarette shreds, roll into Medicated cigarette.
Embodiment five:
Take cryodesiccated Camellia nitidissima Chi spends 1000 grams to put in clean container, adds the ethanol water that 20kg concentration is 65% Solution, extracts 7 days 25 DEG C of temperature soaking and stirring, obtains filtrate with qualitative filter paper sucking filtration, altogether soak extraction 2 times;By twice leaching The ethanol extract that bubble extracts merges, and is then added in concentrator subtract under conditions of temperature 30 DEG C at pressure 0.07MPa Pressure concentrates, and when the weight of concentrated solution is JINHUA Flos Camelliae Japonicae raw material weight 2.0-3.0 times, stops concentrating, a kind of characteristic gold obtained Scented tea tobacco aromatics using.
Take 40g characteristic Camellia nitidissima Chi tobacco aromatics using, be dissolved in the ethanol of 1000g65%, be uniformly sprayed on according to perfuming flow process After 260kg cigarette shreds, roll into Medicated cigarette.
Application Example 1
The Medicated cigarette adding a kind of characteristic Camellia nitidissima Chi tobacco aromatics using of embodiment five preparation, as experiment Medicated cigarette, is got and is not added with Conduct that the same category cigarette shreds of a kind of characteristic Camellia nitidissima Chi tobacco aromatics using rolls comparison Medicated cigarette, embodiment five is tested Medicated cigarette and Comparison Medicated cigarette carries out sensory quality assessment, the results are shown in Table 1.Sensory quality assessment result shows, a kind of characteristic Camellia nitidissima Chi cigarette of application There is during can making cigarette smoking with spice the peculiar fragrance of Camellia nitidissima Chi coordinated with Medicated cigarette cigarette perfume (or spice), increase the perfume (or spice) of smoking property of cigarette Gas value and perfume quantity, can reduce miscellaneous QI and zest simultaneously, improves cigarette taste, promotes the suction quality of Medicated cigarette.
Table 1 is tested Medicated cigarette and is compareed Sensory Quality of Cigarette evaluation

Claims (10)

1. a characteristic Camellia nitidissima Chi tobacco aromatics using, it is characterised in that primary raw material is the flower of Camellia nitidissima Chi, including petal, pistil and Alabastrum.
The preparation method of a kind of characteristic Camellia nitidissima Chi tobacco aromatics using the most according to claim 1, it is characterised in that include as follows Step:
A, putting in clean container by the flower of cryodesiccated Camellia nitidissima Chi, the concentration adding JINHUA Flos Camelliae Japonicae weight 5-50 times is 50- The ethanol water of 95%, extracts 1-12 days 15~35 DEG C of temperature soaking and stirring, obtains filtrate, total immersion with qualitative filter paper sucking filtration Bubble extracts 2 times;
B, the ethanol extract of twice soak extraction is merged, be then added in concentrator in pressure 0.02-0.09MPa and temperature Carry out concentrating under reduced pressure under conditions of 25-40 DEG C, when the weight of concentrated solution is JINHUA Flos Camelliae Japonicae raw material weight 2.0-3.0 times, stop Concentrate, the characteristic Camellia nitidissima Chi tobacco aromatics using obtained.
The preparation method of a kind of characteristic Camellia nitidissima Chi tobacco aromatics using the most according to claim 2, it is characterised in that in step A, The ethanol water that concentration is 60-85% of JINHUA Flos Camelliae Japonicae weight 10-30 times is added, at 20~30 DEG C during twice extraction Temperature is soaked 3-9 days;In step B, under conditions of pressure 0.04-0.08MPa with temperature 25-35 DEG C, carry out concentrating under reduced pressure.
The preparation method of a kind of characteristic Camellia nitidissima Chi tobacco aromatics using the most according to claim 3, it is characterised in that in step A, The ethanol water that concentration is 65-70% of JINHUA Flos Camelliae Japonicae weight 15-25 times is added, at 20~25 DEG C during twice extraction Temperature is soaked 6-8 days;In step B, under conditions of pressure 0.06-0.08MPa with temperature 25-30 DEG C, carry out concentrating under reduced pressure.
The preparation method of a kind of characteristic Camellia nitidissima Chi tobacco aromatics using the most according to claim 1, it is characterised in that include as follows Step: take cryodesiccated Camellia nitidissima Chi spends 1000 grams to put in clean container, adds the ethanol that 20kg concentration is 65% water-soluble Liquid, extracts 7 days 25 DEG C of temperature soaking and stirring, obtains filtrate with qualitative filter paper sucking filtration, altogether soak extraction 2 times;By twice immersion The ethanol extract extracted merges, and is then added in concentrator reduce pressure under conditions of temperature 30 DEG C at pressure 0.07MPa Concentrate, when the weight of concentrated solution is JINHUA Flos Camelliae Japonicae raw material weight 2.0-3.0 times, stop concentrating, a kind of characteristic JINHUA obtained Tea tobacco aromatics using.
6. the application of a characteristic Camellia nitidissima Chi tobacco aromatics using, it is characterised in that: taking mass fraction is that 1-10 characteristic Camellia nitidissima Chi cigarette is used Spice, is dissolved in the ethanol of the 50-95% that mass fraction is 100, is uniformly sprayed on cigarette shreds according to perfuming flow process, and consumption is cigarette The 0.1-1%wt of silk weight.
The application of a kind of characteristic Camellia nitidissima Chi tobacco aromatics using the most according to claim 6, it is characterised in that: taking mass fraction is 2-7 characteristic Camellia nitidissima Chi tobacco aromatics using, is dissolved in the ethanol of the 60-85% that mass fraction is 100, is uniformly sprayed on according to perfuming flow process Cigarette shreds, consumption is the 0.2-0.8%wt of tobacco shred weight.
The application of a kind of characteristic Camellia nitidissima Chi tobacco aromatics using the most according to claim 7, it is characterised in that: taking mass fraction is The characteristic Camellia nitidissima Chi tobacco aromatics using of 3-5, is dissolved in the 65-70% ethanol that mass fraction is 100, is uniformly sprayed on according to perfuming flow process Cigarette shreds, consumption is the 0.3-0.5%wt of tobacco shred weight.
The application of a kind of characteristic Camellia nitidissima Chi tobacco aromatics using the most according to claim 8, it is characterised in that: take 40g characteristic gold Scented tea tobacco aromatics using, is dissolved in the ethanol of 1000g65%, after being uniformly sprayed on 260kg cigarette shreds according to perfuming flow process, rolls into Medicated cigarette.
10. according to the application of described a kind of characteristic Camellia nitidissima Chi tobacco aromatics using arbitrary in claim 6-9, it is characterised in that: institute State after tobacco aromatics using is applied to Medicated cigarette, have during cigarette smoking can be made and the peculiar perfume (or spice) of Camellia nitidissima Chi that Medicated cigarette cigarette perfume (or spice) is coordinated Gas, increases fragrance value and the perfume quantity of smoking property of cigarette, can reduce miscellaneous QI and zest simultaneously, improve cigarette taste, promote volume The suction quality of cigarette.
CN201610740050.2A 2016-08-26 2016-08-26 A kind of characteristic Camellia nitidissima Chi tobacco aromatics using and preparation method and application Pending CN106281714A (en)

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CN108013500A (en) * 2017-11-24 2018-05-11 广西中港高科国宝金花茶产业有限公司 A kind of cigarette golden flower tea flavours and preparation method thereof
CN109875100A (en) * 2019-03-01 2019-06-14 福建绿色黄金生物科技有限公司 A kind of processing method and its application of chrysanthemum
CN112021643A (en) * 2020-07-10 2020-12-04 湖北中烟工业有限责任公司 Preparation method of throat-soothing tea-flavored spice and heated cigarette

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108013500A (en) * 2017-11-24 2018-05-11 广西中港高科国宝金花茶产业有限公司 A kind of cigarette golden flower tea flavours and preparation method thereof
CN109875100A (en) * 2019-03-01 2019-06-14 福建绿色黄金生物科技有限公司 A kind of processing method and its application of chrysanthemum
CN112021643A (en) * 2020-07-10 2020-12-04 湖北中烟工业有限责任公司 Preparation method of throat-soothing tea-flavored spice and heated cigarette
CN112021643B (en) * 2020-07-10 2022-05-27 湖北中烟工业有限责任公司 Preparation method of throat-soothing tea-flavored spice and heated cigarette

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Application publication date: 20170104