CN102311887A - Iodine-containing antibacterial washing agent and its preparation method - Google Patents

Iodine-containing antibacterial washing agent and its preparation method Download PDF

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Publication number
CN102311887A
CN102311887A CN 201110236842 CN201110236842A CN102311887A CN 102311887 A CN102311887 A CN 102311887A CN 201110236842 CN201110236842 CN 201110236842 CN 201110236842 A CN201110236842 A CN 201110236842A CN 102311887 A CN102311887 A CN 102311887A
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China
Prior art keywords
dimethyl
amonio
brometo
iodine
amine oxide
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CN 201110236842
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Chinese (zh)
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CN102311887B (en
Inventor
宋锡高
陆兴忠
王晗
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Wengfu Group Co Ltd
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Wengfu Group Co Ltd
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Abstract

The invention discloses an iodine-containing antibacterial washing agent and its preparation method. The washing agent provided by the invention is made from the following raw materials of: 4.5% of iodine at the concentration of 95 wt%, 0.5% of potassium iodide at the concentration of 99 wt%, 6-15% of an ampholytic surfactant, 4% of Ninol of 1:1.5H, no less than 26% of fatty alcohol polyoxyethylene ether at the concentration of 99 wt%, 1-5% of a cationic surfactant, 0.01-0.1% of a TJQH chelating dispersant A-1, 0.5% of a TJQH thickening agent S, 0.1% of phosphoric acid at the concentration of 85wt%, 0.1% of glacial acetic acid, and the balance being deionized water or distilled water. The iodine-containing antibacterial washing agent provided by the invention, which is an ideal liquid laundry detergent, has not only a washing effect but also a bactericidal function. The prepared liquid laundry detergent can be used for washing as well as sterilization, and is suitable for different kinds of hyperconcentration liquid laundry detergents, hand cleansers, shampoos and detergents for silk and wool.

Description

A kind of antibacterial detergent that contains iodine and preparation method thereof
Technical field
The present invention relates to washing composition, specifically, relate to the washing composition that contains iodine.
Background technology
As everyone knows, contain the effect that the iodine washing composition has disinfecting, antimicrobial.Contain the iodine antiseptic-germicide and form, have safety, wide spectrum, efficient, degermation by iodine, potassiumiodide, phosphoric acid or acetate compound, sodium-chlor, kinds of surface promoting agent compound etc., but kill vegetative forms of bacteria, gemma, fungi, protozoon and part virus.Be used for the antimicrobial washing composition, tensio-active agent adopts plant-sourced, animal source promoting agent, and staple is: Oleum Cocois or plam oil or rapeseed oil, sorbyl alcohol, Fatty Alcohol(C12-C14 and C12-C18), sucrose, glucose, succsinic acid, citric acid derivant etc.Antibacterial detergent is the antibacterial detergent that contains iodine; Equate with the pH value (slightly acidic) of skin hair; Do not contain RBA 777 (PCMX), benzene class, alkylphenol, white dyes, essence, phosphorus, aluminium, glycol ether etc.; Be the cleaning product of strong oxidizer unlike chlorine also, behind the detergent bleach clothing, be prone to generate carcinogens methyl halide etc.
Relating to the patent that contains the iodine washing composition in the Chinese patent DB only has " disinfecting detergent and preparation method thereof " No. 95102774.3, and the prescription of this washing composition that this patent provides is: polyoxyethylenated alcohol sodium sulfate, sulfonated alkylbenzene, solvay-type nonionogenic tenside, stablizer, Xylo-Mucine, sodium ethylene diamine tetracetate, iodine, iodized salt, its surplus are water.Its antibacterial effect is also unexposed.Therefore, people continue to explore the washing composition with antibacterial.
Summary of the invention
The object of the present invention is to provide a kind of antibacterial detergent that contains iodine, to satisfy in people's daily life needs to washing composition with antibacterial.
Another purpose of the present invention is to provide the above-mentioned preparation method who contains the iodine antibacterial detergent, makes it to be able to suitability for industrialized production, meets the need of market.
The antibacterial detergent that contains iodine that the contriver provides is that the quality proportioning according to following raw material makes:
Iodine (content 95%) 4.5%
Potassiumiodide (content 99%) 0.5%
Amphoterics 6%~15%
Ni Naer (1: 1.5H) 4%
AEO (amounting to content 99%) is no less than 26%
Cats product 1%~5%
TJQH chelated dispersants A-1 0.01%~0.1%
TJQH thickening material S 0.5%
Phosphoric acid (amounting to 85%) 0.1%
Glacial acetic acid 0.1%
Deionized water or distilled water surplus;
Above-mentioned amphoterics is one or more in octadecyl dimethyl amine oxide, lauryl dimethyl amine oxide, cocounut oil alkyl dimethyl amine oxide, tetradecyl dihydroxy ethyl amine oxide, hexadecyl dihydroxy ethyl amine oxide, dodecyl dihydroxy ethyl amine oxide, octadecyl dihydroxy ethyl amine oxide, the tallow dimethyl-oxidation amine.
Above-mentioned cats product is a hexadecanol T 46155 ether dimethyl-octa alkyl ammomium chloride; Lauryl alcohol T 46155 ether dimethyl methyl ammonium chloride; Polyoxyethylene octylphenol ether base dimethyl-decyl brometo de amonio; Polyoxyethylene octylphenol ether base dimethyl-decyl ammonium chloride; Octadecyl dimethyl chloride (or bromine) is changed ammonium; Hexadecyldimethyl benzyl ammonium chlorine (or bromine) is changed ammonium; Tetradecyl dimethyl chloride (or bromine) is changed ammonium; Dodecyl dimethyl chlorine (or bromine) is changed ammonium; Decyl dimethyl chloride (or bromine) is changed ammonium; Octyl dimethyl chloride (or bromine) is changed ammonium; Palmitamide propyl-dimethyl/stearylamide propyl-dimethyl chlorine (or bromine) is changed ammonium; Myristamide propyl-dimethyl/lauramide propyl-dimethyl chlorine (or bromine) is changed ammonium; In one or more.
Above-mentioned TJQH chelated dispersants A-1, TJQH thickening material S are the commercially available prod that Tianjin light industry industry research institute produces.
The preparation of the antibacterial detergent that contains iodine that the contriver provides is conventional mixing, stirring, Packaging Method.
Above-mentioned each step all can be operated at normal temperatures.
The iodine antibacterial detergent that contains of the present invention not only has washing effect, and has germicidal action, is comparatively ideal washing liquid.The washing liquid of processing can wash, and can sterilize again.Be applicable to different varietiess such as washing liquid, Liquid soap, shampoo, detergent for silk and wool.
Embodiment
Below, further specify beneficial effect of the present invention through embodiment.
Embodiment:Get iodine (content 95%) 4.5g, potassiumiodide (content 99%) 0.5g, dodecyl dihydroxy ethyl amine oxide 10g; Ni Naer (1: 1.5H) 4g, AEO (amounting to content 99%) 28g, hexadecyldimethyl benzyl ammonium brometo de amonio 3g; TJQH chelated dispersants A-1 0.1g; TJQH thickening material S 0.5g, phosphoric acid (amounting to 85%) 0.1g, glacial acetic acid 0.1g; Will be according to each material abundant dispersing and mixing in high-shearing dispersion emulsifying machine of prescription weighing, filling and package gets final product.

Claims (1)

1. antibacterial detergent that contains iodine is characterized in that this washing composition is that quality proportioning according to following raw material makes:
Massfraction is 95% iodine 4.5%
Massfraction is 99% potassiumiodide 0.5%
Amphoterics 6%~15%
1: Buddhist nun's sodium that 4% of 1.5H
Massfraction is that 99% AEO is no less than 26%
Cats product 1%~5%
TJQH chelated dispersants A-1 0.01%~0.1%
TJQH thickening material S 0.5%
Massfraction is 85% phosphoric acid 0.1%
Glacial acetic acid 0.1%
Deionized water or distilled water surplus;
Said amphoterics is one or more in octadecyl dimethyl amine oxide, lauryl dimethyl amine oxide, cocounut oil alkyl dimethyl amine oxide, tetradecyl dihydroxy ethyl amine oxide, hexadecyl dihydroxy ethyl amine oxide, dodecyl dihydroxy ethyl amine oxide, octadecyl dihydroxy ethyl amine oxide, the tallow dimethyl-oxidation amine;
Said cats product is a hexadecanol T 46155 ether dimethyl-octa alkyl ammomium chloride; Lauryl alcohol T 46155 ether dimethyl methyl ammonium chloride; Polyoxyethylene octylphenol ether base dimethyl-decyl brometo de amonio; Polyoxyethylene octylphenol ether base dimethyl-decyl ammonium chloride; Octadecyl dimethyl chloride/brometo de amonio; Hexadecyldimethyl benzyl ammonium chlorine/brometo de amonio; Tetradecyl dimethyl chloride/brometo de amonio; Dodecyl dimethyl chlorine/brometo de amonio; Decyl dimethyl chloride/brometo de amonio; Octyl dimethyl chloride/brometo de amonio; Palmitamide propyl-dimethyl/stearylamide propyl-dimethyl chlorine/brometo de amonio; In myristamide propyl-dimethyl/lauramide propyl-dimethyl chlorine/brometo de amonio one or more;
Said TJQH chelated dispersants A-1, TJQH thickening material S are the commercially available prod that Tianjin light industry industry research institute produces.
CN 201110236842 2011-08-18 2011-08-18 Iodine-containing antibacterial washing agent Active CN102311887B (en)

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CN102311887B CN102311887B (en) 2013-01-16

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103006464A (en) * 2011-09-20 2013-04-03 天津博克尼科技发展有限公司 Iodine-containing disinfection hand cleaner without water
CN103897826A (en) * 2012-12-26 2014-07-02 青岛锦涟鑫商贸有限公司 Novel washing agent
CN104430326A (en) * 2014-11-26 2015-03-25 金科 Preparation method of ampholytic surfactant composition
CN106135274A (en) * 2015-04-22 2016-11-23 苏州泰利三佳纳米科技有限公司 A kind of medicated clothing skin degerming agent composition containing iodine and preparation method thereof
CN106190608A (en) * 2016-07-11 2016-12-07 武汉柏康科技股份有限公司 A kind of PGQA colloidal foam cleaning agent and production technology thereof
CN114158567A (en) * 2021-11-25 2022-03-11 佛山市正典生物技术有限公司 Iodine-containing disinfectant containing hydroxyl-containing polyol ether and preparation method and application thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1114679A (en) * 1995-03-15 1996-01-10 程宁 Disinfecting detergent and preparation method thereof
WO2000018867A1 (en) * 1998-09-25 2000-04-06 The Procter & Gamble Company Antimicrobial detergent compositions
EP1074247A2 (en) * 1999-07-20 2001-02-07 Zschimmer & Schwarz Italiana S.p.A. Cleansing or cosmetic compositions comprising zinc alkylsulphates and/or alky(poly)ethoxysulphates as surfactants and preservatives
CN1788568A (en) * 2005-12-23 2006-06-21 张慧贤 Quick-effective iodine disinfectant and production method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1114679A (en) * 1995-03-15 1996-01-10 程宁 Disinfecting detergent and preparation method thereof
WO2000018867A1 (en) * 1998-09-25 2000-04-06 The Procter & Gamble Company Antimicrobial detergent compositions
EP1074247A2 (en) * 1999-07-20 2001-02-07 Zschimmer & Schwarz Italiana S.p.A. Cleansing or cosmetic compositions comprising zinc alkylsulphates and/or alky(poly)ethoxysulphates as surfactants and preservatives
CN1788568A (en) * 2005-12-23 2006-06-21 张慧贤 Quick-effective iodine disinfectant and production method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
《邯郸农业高等专科学校学报》 20021231 高会东 碘类消毒剂存在的问题及对策 第19卷, 第4期 *

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103006464A (en) * 2011-09-20 2013-04-03 天津博克尼科技发展有限公司 Iodine-containing disinfection hand cleaner without water
CN103897826A (en) * 2012-12-26 2014-07-02 青岛锦涟鑫商贸有限公司 Novel washing agent
CN104430326A (en) * 2014-11-26 2015-03-25 金科 Preparation method of ampholytic surfactant composition
CN106135274A (en) * 2015-04-22 2016-11-23 苏州泰利三佳纳米科技有限公司 A kind of medicated clothing skin degerming agent composition containing iodine and preparation method thereof
CN106190608A (en) * 2016-07-11 2016-12-07 武汉柏康科技股份有限公司 A kind of PGQA colloidal foam cleaning agent and production technology thereof
CN114158567A (en) * 2021-11-25 2022-03-11 佛山市正典生物技术有限公司 Iodine-containing disinfectant containing hydroxyl-containing polyol ether and preparation method and application thereof

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Inventor after: He Haoming

Inventor after: Song Xigao

Inventor after: Lu Xingzhong

Inventor after: Wang Han

Inventor before: Song Xigao

Inventor before: Lu Xingzhong

Inventor before: Wang Han

COR Change of bibliographic data

Free format text: CORRECT: INVENTOR; FROM: SONG XIGAO LU XINGZHONG WANG HAN TO: HE HAOMING SONG XIGAO LU XINGZHONG WANG HAN

C14 Grant of patent or utility model
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Address after: 550500 Guizhou Province, Qiannan Buyei and Miao Autonomous Prefecture Fuquan Racecourse town Yingbin Road No. 1 Wengfu group

Patentee after: WENGFU GROUP Co.,Ltd.

Address before: 23, 550002 floor, urn Fuk international, No. 57, South City Road, Guizhou, Guiyang

Patentee before: WENGFU GROUP Co.,Ltd.

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