CN102311883A - 一种制备高纯度生物柴油的方法 - Google Patents
一种制备高纯度生物柴油的方法 Download PDFInfo
- Publication number
- CN102311883A CN102311883A CN201110228437A CN201110228437A CN102311883A CN 102311883 A CN102311883 A CN 102311883A CN 201110228437 A CN201110228437 A CN 201110228437A CN 201110228437 A CN201110228437 A CN 201110228437A CN 102311883 A CN102311883 A CN 102311883A
- Authority
- CN
- China
- Prior art keywords
- oil
- methyl alcohol
- reaction
- fatty acid
- raw material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 60
- 239000003225 biodiesel Substances 0.000 title claims abstract description 12
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims abstract description 174
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 33
- 235000019387 fatty acid methyl ester Nutrition 0.000 claims abstract description 31
- 239000002994 raw material Substances 0.000 claims abstract description 25
- 238000005809 transesterification reaction Methods 0.000 claims abstract description 22
- 239000010779 crude oil Substances 0.000 claims abstract description 17
- 235000011187 glycerol Nutrition 0.000 claims abstract description 16
- 238000004821 distillation Methods 0.000 claims abstract description 12
- 239000012535 impurity Substances 0.000 claims abstract description 7
- 238000000746 purification Methods 0.000 claims abstract description 3
- 238000006243 chemical reaction Methods 0.000 claims description 49
- 239000003921 oil Substances 0.000 claims description 38
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 30
- 239000002551 biofuel Substances 0.000 claims description 26
- 238000005406 washing Methods 0.000 claims description 13
- 239000002253 acid Substances 0.000 claims description 12
- 239000012071 phase Substances 0.000 claims description 11
- 239000000463 material Substances 0.000 claims description 10
- 239000010426 asphalt Substances 0.000 claims description 8
- 238000000605 extraction Methods 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 5
- 238000011084 recovery Methods 0.000 claims description 5
- 239000007791 liquid phase Substances 0.000 claims description 4
- 238000000926 separation method Methods 0.000 claims description 4
- 230000005484 gravity Effects 0.000 claims description 3
- 238000002203 pretreatment Methods 0.000 claims description 2
- 238000005886 esterification reaction Methods 0.000 abstract description 30
- 230000032050 esterification Effects 0.000 abstract description 29
- 239000003054 catalyst Substances 0.000 abstract description 11
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract description 5
- 230000011218 segmentation Effects 0.000 abstract 1
- 235000019198 oils Nutrition 0.000 description 34
- 239000002283 diesel fuel Substances 0.000 description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 16
- 239000004519 grease Substances 0.000 description 14
- 230000008569 process Effects 0.000 description 12
- 239000000047 product Substances 0.000 description 12
- 241000196324 Embryophyta Species 0.000 description 9
- 238000003756 stirring Methods 0.000 description 9
- 239000002699 waste material Substances 0.000 description 9
- 238000004519 manufacturing process Methods 0.000 description 7
- 238000005265 energy consumption Methods 0.000 description 6
- 150000004702 methyl esters Chemical class 0.000 description 6
- 241001465754 Metazoa Species 0.000 description 5
- 239000003513 alkali Substances 0.000 description 5
- 239000007789 gas Substances 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 230000009466 transformation Effects 0.000 description 5
- 238000007599 discharging Methods 0.000 description 4
- 238000004090 dissolution Methods 0.000 description 4
- 230000007935 neutral effect Effects 0.000 description 4
- XBASCYIHBSLATF-UHFFFAOYSA-M sodium;methanol;hydroxide;hydrate Chemical compound O.[OH-].[Na+].OC XBASCYIHBSLATF-UHFFFAOYSA-M 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 239000002028 Biomass Substances 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 239000005864 Sulphur Substances 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- 230000006378 damage Effects 0.000 description 3
- 210000003298 dental enamel Anatomy 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 150000002148 esters Chemical group 0.000 description 3
- 239000000446 fuel Substances 0.000 description 3
- 230000035484 reaction time Effects 0.000 description 3
- 238000010992 reflux Methods 0.000 description 3
- 239000011973 solid acid Substances 0.000 description 3
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 3
- 235000015112 vegetable and seed oil Nutrition 0.000 description 3
- 239000008158 vegetable oil Substances 0.000 description 3
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 238000005815 base catalysis Methods 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 239000003245 coal Substances 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- -1 methoxyl group Chemical group 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000006386 neutralization reaction Methods 0.000 description 2
- 230000001473 noxious effect Effects 0.000 description 2
- 230000009965 odorless effect Effects 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000012266 salt solution Substances 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000003760 tallow Substances 0.000 description 2
- 239000003643 water by type Substances 0.000 description 2
- RBNPOMFGQQGHHO-UHFFFAOYSA-N -2,3-Dihydroxypropanoic acid Natural products OCC(O)C(O)=O RBNPOMFGQQGHHO-UHFFFAOYSA-N 0.000 description 1
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910000975 Carbon steel Inorganic materials 0.000 description 1
- 244000174788 Crambe maritima Species 0.000 description 1
- 235000005664 Crambe maritima Nutrition 0.000 description 1
- RBNPOMFGQQGHHO-UWTATZPHSA-N D-glyceric acid Chemical compound OC[C@@H](O)C(O)=O RBNPOMFGQQGHHO-UWTATZPHSA-N 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 235000019483 Peanut oil Nutrition 0.000 description 1
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 1
- 235000019484 Rapeseed oil Nutrition 0.000 description 1
- 206010067171 Regurgitation Diseases 0.000 description 1
- 241000269319 Squalius cephalus Species 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 238000007171 acid catalysis Methods 0.000 description 1
- 239000003377 acid catalyst Substances 0.000 description 1
- 238000003916 acid precipitation Methods 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000010828 animal waste Substances 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 239000010962 carbon steel Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 239000008162 cooking oil Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 125000004494 ethyl ester group Chemical group 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 235000021050 feed intake Nutrition 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000010794 food waste Substances 0.000 description 1
- 125000005456 glyceride group Chemical group 0.000 description 1
- 125000005908 glyceryl ester group Chemical group 0.000 description 1
- 125000003976 glyceryl group Chemical group [H]C([*])([H])C(O[H])([H])C(O[H])([H])[H] 0.000 description 1
- JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 239000000383 hazardous chemical Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 230000000266 injurious effect Effects 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 239000010806 kitchen waste Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 235000012054 meals Nutrition 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- WCYAALZQFZMMOM-UHFFFAOYSA-N methanol;sulfuric acid Chemical compound OC.OS(O)(=O)=O WCYAALZQFZMMOM-UHFFFAOYSA-N 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 239000000312 peanut oil Substances 0.000 description 1
- 125000005575 polycyclic aromatic hydrocarbon group Chemical group 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 210000000582 semen Anatomy 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 235000020238 sunflower seed Nutrition 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- ZPHGMBGIFODUMF-UHFFFAOYSA-N thiophen-2-ylmethanol Chemical compound OCC1=CC=CS1 ZPHGMBGIFODUMF-UHFFFAOYSA-N 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000007039 two-step reaction Methods 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
- C10L1/026—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only for compression ignition
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/03—Preparation of carboxylic acid esters by reacting an ester group with a hydroxy group
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B13/00—Recovery of fats, fatty oils or fatty acids from waste materials
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
- C11C1/00—Preparation of fatty acids from fats, fatty oils, or waxes; Refining the fatty acids
- C11C1/08—Refining
- C11C1/10—Refining by distillation
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
- C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
- C11C3/003—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by esterification of fatty acids with alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
- C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
- C11C3/04—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by esterification of fats or fatty oils
- C11C3/10—Ester interchange
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/02—Preparation of carboxylic acid esters by interreacting ester groups, i.e. transesterification
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/74—Recovery of fats, fatty oils, fatty acids or other fatty substances, e.g. lanolin or waxes
Abstract
Description
Claims (7)
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2011102284377A CN102311883B (zh) | 2011-08-10 | 2011-08-10 | 一种制备高纯度生物柴油的方法 |
US14/237,888 US9145527B2 (en) | 2011-08-10 | 2012-08-09 | Method for preparing high purity biodiesel |
MYPI2014700276A MY169247A (en) | 2011-08-10 | 2012-08-09 | Method for preparing high purity biodiesel |
PCT/CN2012/079875 WO2013020514A1 (zh) | 2011-08-10 | 2012-08-09 | 一种制备高纯度生物柴油的方法 |
EP20120822433 EP2743336A4 (en) | 2011-08-10 | 2012-08-09 | PROCESS FOR THE PRODUCTION OF HIGH-PURITY BIODIESEL |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2011102284377A CN102311883B (zh) | 2011-08-10 | 2011-08-10 | 一种制备高纯度生物柴油的方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN102311883A true CN102311883A (zh) | 2012-01-11 |
CN102311883B CN102311883B (zh) | 2013-04-24 |
Family
ID=45425456
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN2011102284377A Expired - Fee Related CN102311883B (zh) | 2011-08-10 | 2011-08-10 | 一种制备高纯度生物柴油的方法 |
Country Status (5)
Country | Link |
---|---|
US (1) | US9145527B2 (zh) |
EP (1) | EP2743336A4 (zh) |
CN (1) | CN102311883B (zh) |
MY (1) | MY169247A (zh) |
WO (1) | WO2013020514A1 (zh) |
Cited By (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103374461A (zh) * | 2012-04-25 | 2013-10-30 | 聿新生物科技股份有限公司 | 以植物油制备生质柴油的方法 |
CN103421548A (zh) * | 2012-05-14 | 2013-12-04 | 陕西德融新能源股份有限公司 | 一种非精炼油脂生产生物柴油的制备工艺 |
CN103721749A (zh) * | 2013-12-30 | 2014-04-16 | 北京清研利华石油化学技术有限公司 | 避免生物柴油生产中结垢的复合催化剂及其应用 |
CN104263525A (zh) * | 2014-09-24 | 2015-01-07 | 华南理工大学 | 一种无预混生物柴油气液喷雾反应工艺及装置 |
CN104403804A (zh) * | 2013-12-11 | 2015-03-11 | 宁波杰森绿色能源科技有限公司 | 一种粗甲酯脱甲醇方法 |
US9145527B2 (en) | 2011-08-10 | 2015-09-29 | Beijing Qingyanlihua Petroleum Chemistry Co., Ltd. | Method for preparing high purity biodiesel |
CN105542970A (zh) * | 2016-01-20 | 2016-05-04 | 定陶县地元生化制品有限公司 | 一种连续生产生物柴油的方法和装置 |
CN105950299A (zh) * | 2016-06-28 | 2016-09-21 | 梁红 | 一种生物柴油 |
CN105969531A (zh) * | 2016-06-24 | 2016-09-28 | 青岛福瑞斯生物能源科技开发有限公司 | 一种生物柴油的制备方法 |
CN106811308A (zh) * | 2016-12-23 | 2017-06-09 | 惠州市鑫隆环保科技有限公司 | 一种工业燃料油的制备方法 |
CN111019720A (zh) * | 2019-12-31 | 2020-04-17 | 浙江卓尚环保能源有限公司 | 一种生物柴油的绿色生产工艺 |
CN112474725A (zh) * | 2020-11-11 | 2021-03-12 | 张茜 | 一种餐厨垃圾高效微生物降解的方法 |
CN113801707A (zh) * | 2021-09-29 | 2021-12-17 | 河南华泰粮油机械股份有限公司 | 利用餐厨剩余油脂生产生物柴油制备方法 |
CN114574233A (zh) * | 2022-03-11 | 2022-06-03 | 福州大学化肥催化剂国家工程研究中心 | 一种酸化油制备二代生物柴油的方法 |
CN114657062A (zh) * | 2022-04-25 | 2022-06-24 | 广州市朗坤环境科技有限公司 | 一种利用脂肪酶催化制备生物柴油降酸的反应器和方法 |
CN114806722A (zh) * | 2022-05-06 | 2022-07-29 | 宁波杰森绿色能源科技有限公司 | 一种连续生产脂肪酸甲酯系统及方法 |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101355141B1 (ko) * | 2013-03-20 | 2014-01-29 | 주식회사 엠알아이 | 바이오디젤의 제조방법 |
US9745530B2 (en) * | 2015-02-09 | 2017-08-29 | Regents Of The University Of Minnesota | Production of biodiesel from scum |
WO2017187237A1 (en) * | 2016-04-27 | 2017-11-02 | Ahmed Mohammed Idris | A method for preparing biodiesel (methyl ester) from animal tallow oil and a biodiesel thereof |
US10472592B1 (en) | 2016-10-06 | 2019-11-12 | Smisson-Mathis Energy, Llc | Systems and methods for purification of fats, oils, and grease from wastewater |
CN109294745A (zh) * | 2018-10-23 | 2019-02-01 | 张水生 | 一种脂肪酸甲酯植物油制备方法 |
CN109880696A (zh) * | 2019-03-04 | 2019-06-14 | 扬州中天利新材料股份有限公司 | 一种采用废弃油脂制备生物柴油的方法 |
CN110511823A (zh) * | 2019-07-17 | 2019-11-29 | 臧树良 | 一种以食品加工废油制备第二代生物柴油的方法 |
CN112457894A (zh) * | 2020-12-24 | 2021-03-09 | 河南莱帕克化工设备制造有限公司 | 固体酸碱催化生物柴油制备生产线 |
CN112852550B (zh) * | 2020-12-28 | 2023-11-28 | 石家庄睿途生物科技有限公司 | 一种利用加氢生成水对酸化油原料进行水洗的方法 |
CN113214906A (zh) * | 2021-04-30 | 2021-08-06 | 厦门卓越生物质能源有限公司 | 废弃动植物油脂碳链组分分析用脂肪酸甲酯的快速制备方法 |
CN113512469A (zh) * | 2021-05-03 | 2021-10-19 | 河北科技大学 | 一种用于高自由酸油脂甲酯化表面活性剂型催化体系及一步法工艺 |
CN115536765B (zh) * | 2021-06-29 | 2024-03-12 | 中国石油化工股份有限公司 | 一种脂肪酸甲酯的催化聚合方法 |
CN113563977B (zh) * | 2021-07-21 | 2022-08-16 | 湖北天基生物能源科技发展有限公司 | 一种废弃油脂的处理系统和处理方法 |
CN114250116B (zh) * | 2021-12-30 | 2023-11-28 | 唐河金海生物科技有限公司 | 将生物酶酯化和超临界技术相结合生产生物柴油的方法 |
CN114456066A (zh) * | 2022-01-29 | 2022-05-10 | 山东成武易信环保科技有限公司 | 一种用于纯化单丁酸甘油酯的蒸馏方法 |
CN114854496A (zh) * | 2022-04-25 | 2022-08-05 | 四川金尚环保科技有限公司 | 一种废弃动植物油脂生产生物柴油的方法 |
CN115254143B (zh) * | 2022-06-23 | 2023-07-04 | 北京科技大学 | 一种炭基固体酸催化剂的制备方法及其应用 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101020838A (zh) * | 2007-03-23 | 2007-08-22 | 江西新时代油脂工业有限公司 | 一种生物柴油的制备工艺及其装置 |
US20100043280A1 (en) * | 2007-08-13 | 2010-02-25 | Martin Allan Morris | Bio-fuel and process for making bio-fuel |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3501761A1 (de) * | 1985-01-21 | 1986-07-24 | Henkel KGaA, 4000 Düsseldorf | Verfahren zur vorveresterung freier fettsaeuren in rohfetten und/oder -oelen |
WO1987007632A1 (en) * | 1986-06-11 | 1987-12-17 | Bio-Energy Technology Ltd. | Bio-fuel production |
AU637595B2 (en) * | 1989-01-17 | 1993-06-03 | Davy Mckee (London) Limited | Process and apparatus |
US6965043B1 (en) * | 1997-11-10 | 2005-11-15 | Procter + Gamble Co. | Process for making high purity fatty acid lower alkyl esters |
CA2507329A1 (en) * | 2002-11-27 | 2004-06-10 | Biodiesel Australia Ltd | Method for production of alkyl esters |
RU2007145596A (ru) * | 2005-06-09 | 2009-07-20 | Биосфере Инвайроментал Энерджи Ллс (Us) | Системы и способы для эстерефикации и переэтерефикации жиров и масел |
DE102007026654A1 (de) * | 2007-06-08 | 2010-01-07 | Hölter, Heinrich, Prof. Dr. sc. Dr.-Ing. Dr. hc | Verfahren zur Herstellung von Fettsäure-Alkylestern |
US20100205853A1 (en) * | 2007-10-09 | 2010-08-19 | Council Of Scientific & Industrial Research | Process for the Preparation of Biodiesel from Vegetable Oils Containing High FFA |
CN102311883B (zh) | 2011-08-10 | 2013-04-24 | 北京清研利华石油化学技术有限公司 | 一种制备高纯度生物柴油的方法 |
-
2011
- 2011-08-10 CN CN2011102284377A patent/CN102311883B/zh not_active Expired - Fee Related
-
2012
- 2012-08-09 WO PCT/CN2012/079875 patent/WO2013020514A1/zh active Application Filing
- 2012-08-09 MY MYPI2014700276A patent/MY169247A/en unknown
- 2012-08-09 EP EP20120822433 patent/EP2743336A4/en not_active Withdrawn
- 2012-08-09 US US14/237,888 patent/US9145527B2/en not_active Expired - Fee Related
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101020838A (zh) * | 2007-03-23 | 2007-08-22 | 江西新时代油脂工业有限公司 | 一种生物柴油的制备工艺及其装置 |
US20100043280A1 (en) * | 2007-08-13 | 2010-02-25 | Martin Allan Morris | Bio-fuel and process for making bio-fuel |
Cited By (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9145527B2 (en) | 2011-08-10 | 2015-09-29 | Beijing Qingyanlihua Petroleum Chemistry Co., Ltd. | Method for preparing high purity biodiesel |
CN103374461A (zh) * | 2012-04-25 | 2013-10-30 | 聿新生物科技股份有限公司 | 以植物油制备生质柴油的方法 |
CN103421548A (zh) * | 2012-05-14 | 2013-12-04 | 陕西德融新能源股份有限公司 | 一种非精炼油脂生产生物柴油的制备工艺 |
CN104403804A (zh) * | 2013-12-11 | 2015-03-11 | 宁波杰森绿色能源科技有限公司 | 一种粗甲酯脱甲醇方法 |
CN103721749A (zh) * | 2013-12-30 | 2014-04-16 | 北京清研利华石油化学技术有限公司 | 避免生物柴油生产中结垢的复合催化剂及其应用 |
CN103721749B (zh) * | 2013-12-30 | 2015-10-28 | 北京清研利华石油化学技术有限公司 | 避免生物柴油生产中结垢的复合催化剂及其应用 |
CN104263525A (zh) * | 2014-09-24 | 2015-01-07 | 华南理工大学 | 一种无预混生物柴油气液喷雾反应工艺及装置 |
CN105542970A (zh) * | 2016-01-20 | 2016-05-04 | 定陶县地元生化制品有限公司 | 一种连续生产生物柴油的方法和装置 |
CN105969531A (zh) * | 2016-06-24 | 2016-09-28 | 青岛福瑞斯生物能源科技开发有限公司 | 一种生物柴油的制备方法 |
CN105950299A (zh) * | 2016-06-28 | 2016-09-21 | 梁红 | 一种生物柴油 |
CN106811308A (zh) * | 2016-12-23 | 2017-06-09 | 惠州市鑫隆环保科技有限公司 | 一种工业燃料油的制备方法 |
CN111019720A (zh) * | 2019-12-31 | 2020-04-17 | 浙江卓尚环保能源有限公司 | 一种生物柴油的绿色生产工艺 |
CN112474725A (zh) * | 2020-11-11 | 2021-03-12 | 张茜 | 一种餐厨垃圾高效微生物降解的方法 |
CN113801707A (zh) * | 2021-09-29 | 2021-12-17 | 河南华泰粮油机械股份有限公司 | 利用餐厨剩余油脂生产生物柴油制备方法 |
CN114574233A (zh) * | 2022-03-11 | 2022-06-03 | 福州大学化肥催化剂国家工程研究中心 | 一种酸化油制备二代生物柴油的方法 |
CN114657062A (zh) * | 2022-04-25 | 2022-06-24 | 广州市朗坤环境科技有限公司 | 一种利用脂肪酶催化制备生物柴油降酸的反应器和方法 |
CN114806722A (zh) * | 2022-05-06 | 2022-07-29 | 宁波杰森绿色能源科技有限公司 | 一种连续生产脂肪酸甲酯系统及方法 |
CN114806722B (zh) * | 2022-05-06 | 2024-04-05 | 宁波杰森绿色能源科技有限公司 | 一种连续生产脂肪酸甲酯系统及方法 |
Also Published As
Publication number | Publication date |
---|---|
WO2013020514A1 (zh) | 2013-02-14 |
CN102311883B (zh) | 2013-04-24 |
EP2743336A4 (en) | 2015-04-22 |
US20140194634A1 (en) | 2014-07-10 |
MY169247A (en) | 2019-03-19 |
US9145527B2 (en) | 2015-09-29 |
EP2743336A1 (en) | 2014-06-18 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN102311883B (zh) | 一种制备高纯度生物柴油的方法 | |
CN101906355B (zh) | 一种利用餐厨垃圾回收油制取生物柴油的方法 | |
Chakraborty et al. | Conversion of slaughterhouse and poultry farm animal fats and wastes to biodiesel: Parametric sensitivity and fuel quality assessment | |
Enweremadu et al. | Technical aspects of production and analysis of biodiesel from used cooking oil—A review | |
CN101993776B (zh) | 一种生物柴油脱酸的方法 | |
CN1328353C (zh) | 一种动、植物油制备生物柴油的工艺 | |
Topare et al. | Biodiesel from algae oil as an alternative fuel for diesel engine | |
CN102703223B (zh) | 气相甲醇催化酯化醇解制备生物柴油工艺 | |
CN102382716A (zh) | 一种用高酸价废弃油脂制取生物柴油的方法及其设备 | |
CN102876465A (zh) | 利用餐厨废弃油脂制备生物柴油的方法 | |
US11034984B2 (en) | Method for improving yield of enzymatic preparation of biodiesel from greases | |
CN103421548A (zh) | 一种非精炼油脂生产生物柴油的制备工艺 | |
CN103087788B (zh) | 一种利用高酸值油脂制备生物柴油的方法 | |
CN100523131C (zh) | 用废油制备生物柴油的酯化反应工艺 | |
Panneerselvam et al. | Biodiesel production from mutton tallow | |
CN102492561A (zh) | 一种利用新鲜米糠制备生物柴油的方法 | |
CN201330241Y (zh) | 一种利用高酸值油脂生产精制生物柴油的装置 | |
CN101280242A (zh) | 一种分离油脂中脂肪酸的方法 | |
CN101289628A (zh) | 一种用混合脂肪酸生产生物柴油的方法 | |
Al Bari et al. | Prospect of Bio-diesel Production from soybean oil and sesame oil: An Alternative and Renewable Fuel for Diesel Engines | |
Cobb et al. | Converting floating scum from municipal wastewater treatment plants to biodiesel fuel | |
Akhtar et al. | An alkali catalyzed trans-esterification of rice bran, cottonseed and waste cooking oil | |
CN103421614B (zh) | 一种精炼油脂生产生物柴油的制备工艺 | |
CN103194255A (zh) | 催化裂化动植物油脂生产清洁燃料的方法 | |
CN203530281U (zh) | 一种棕榈油渣和酸化油炼制生物柴油的设备 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Method for preparing high-purity biodiesel Effective date of registration: 20130621 Granted publication date: 20130424 Pledgee: Bank of China Limited by Share Ltd Beijing Century Fortune Central Branch Pledgor: Beijing Qingyan Lihua Petroleum Chemical Technology Co., Ltd. Registration number: 2013110000005 |
|
PLDC | Enforcement, change and cancellation of contracts on pledge of patent right or utility model | ||
PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20140627 Granted publication date: 20130424 Pledgee: Bank of China Limited by Share Ltd Beijing Century Fortune Central Branch Pledgor: Beijing Qingyan Lihua Petroleum Chemical Technology Co., Ltd. Registration number: 2013110000005 |
|
PLDC | Enforcement, change and cancellation of contracts on pledge of patent right or utility model | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Method for preparing high-purity biodiesel Effective date of registration: 20140630 Granted publication date: 20130424 Pledgee: Bank of China Limited by Share Ltd Beijing Century Fortune Central Branch Pledgor: Beijing Qingyan Lihua Petroleum Chemical Technology Co., Ltd. Registration number: 2014110000004 |
|
PLDC | Enforcement, change and cancellation of contracts on pledge of patent right or utility model | ||
PP01 | Preservation of patent right |
Effective date of registration: 20151204 Granted publication date: 20130424 |
|
RINS | Preservation of patent right or utility model and its discharge | ||
PD01 | Discharge of preservation of patent | ||
PD01 | Discharge of preservation of patent |
Date of cancellation: 20201204 Granted publication date: 20130424 |
|
DD01 | Delivery of document by public notice | ||
DD01 | Delivery of document by public notice |
Addressee: Zhao Shitong Document name: Notice of termination of proceedings |
|
CF01 | Termination of patent right due to non-payment of annual fee | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20130424 Termination date: 20160810 |