CN102232364A - Method for preparing substrate material of Chinese herbal slow-release injection for environmental friendly aquaculture by using natural zeolite - Google Patents

Method for preparing substrate material of Chinese herbal slow-release injection for environmental friendly aquaculture by using natural zeolite Download PDF

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Publication number
CN102232364A
CN102232364A CN2010101772646A CN201010177264A CN102232364A CN 102232364 A CN102232364 A CN 102232364A CN 2010101772646 A CN2010101772646 A CN 2010101772646A CN 201010177264 A CN201010177264 A CN 201010177264A CN 102232364 A CN102232364 A CN 102232364A
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natural zeolite
aquatic products
chinese herbal
aquatic
aquaculture
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CN2010101772646A
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张玉明
张媛洁
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A40/00Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
    • Y02A40/80Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in fisheries management
    • Y02A40/81Aquaculture, e.g. of fish

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Abstract

In the invention, medical plants or a small amount of animal and mineral Chinese herbs are used with the purposes of preventing and treating diseases of aquatic animals or the purpose of health care, and effective components for effectively preventing and treating the aquatic animals are decocted into juice; or, an aquatic preparation produced by a production enterprise of medicaments for professional aquiculture is used; natural zeolite is selected as a medical raw material; components of the Chinese herb are sufficiently absorbed into holes and channels of the natural zeolite for preparing a slow-release injection of the Chinese herb; and the slow-release injection has double functions of slowly releasing medical components for preventing and treating the diseases and absorbing toxic and harmful elements in an aquaculture water body. After being especially processed, the natural zeolite is put into biochemical bacteria for preparing the aquaculture material of an aquatic product and the cultivation material can effectively block the vicious circle of the toxic and harmful elements and the aquaculture water body in substrate pollutants. A substrate environmental friendly environment beneficial to the aquaculture of the aquatic product is built in order to enhance the quality of the aquatic product, and the surviving rate, the rate of finished products and the commodity value rate of the aquatic animals are increased.

Description

Natural zeolite prepares the method for aquaculture environmental protection Chinese herbal medicine sustained release agent substrate material
Technical background
Along with the living standard of global human and improving constantly of the self-health perception of nuisancelessization of food, the edible safety of aquatic products more and more has been subjected to showing great attention to of people.Growth along with the Export of Chinese Aquatic Products amount, the common concern of consumer both at home and abroad comprises that poisonous and harmful substance is residual in the food of aquatic products and limits the quantity of, its standard-required is along with development in science and technology, and detection means is accurately and more and more higher, and what have becomes " green " fort in the foreign trade.
Chinese herbal medicine is meant medicinal plant or a small amount of animal and the mineral of harnessing the river upright fish shrimp crab eel loach aquatic product disease or keeping healthy and use for purpose for anti-.Along with developing rapidly of China's aquatic products fish shrimp crab eel bullhead aquaculture, chemical synthetic drug is widely used in the feed of aquatic products industry and in the water body, but use for a long time with a kind of chemical synthetic drug, pathogene is developed immunity to drugs, reduce drug effect, also occur problems such as environmental pollution, medicament residue simultaneously.And the Chinese herbal medicine medicament has natural, efficient, characteristics such as toxic and side effect is few, aboundresources have concurrently medicinal and the nutrition double action simultaneously, and its range of application more and more is subjected to people's attention.The application of Chinese herbal medicine in aquatic products industry is cultured be mainly reflected in following several aspect:
One, the immunity that enhance immunity, disease preventing and treating strengthen the various fish of aquatic products industry is to improve one of its premunition effective method, and the medium-height grass efficacy stability, lasting also contained polysaccharide, alkaloid, organic acid, glycoside, volatilization wet goods all can improve body tissue.For antibiotic and sulfa drug can't be obtained.
Two, improvement quality improves the aquatic product quality Chinese herbal medicine as quality improver, can effectively improve the colour of skin of aquatic products fish, improves the aquatic product value-added content of product.Because the fin fish itself that have in the aquatic products category that has can not be synthesized carotenoid, carotene carotene content directly influences the body colours of fish in the feed and in the water body, when carotenoid content was not enough in the feed and in the water body, the body colour in the aquatic products fish, muscle, fin etc. will become ash.And many for example pot marigolds, Aztec marigold, orange peel etc. contain abundant carotenoid in the Chinese herbal medicine, be converted into astaxanthin through biochemical reaction in vivo, be stored in body surface, the muscle, the aquatic products commercial fish species is played hyperchromic effect preferably, improve its commodity value ratio.
Three, a lot of Chinese herbal medicines of food calling effect as anistree, bacterium is fragrant, cordate houttuynia, early Mo Lian etc. has tangible food calling to do to have to the aquatic products fish, because these Chinese herbal medicines contain ester, aldehyde, phenol, small molecular organic acid and the nitrogen-containing compound etc. of a large amount of aromaticity.
Four, promote growth, reduce feed coefficient and promote growth, reduce feed coefficient, produce by the multiple function acting in conjunction of Chinese herbal medicine.Divine Comedy, Fructus Hordei Germinatus etc. contain abundant vitamin, digestive ferment and unknown somatomedin, can promote digesting and assimilating of aquatic products fish, increase food ration, reduce feed coefficient.The Radix Astragali, Radix Codonopsis, wilsonii etc. contain immune polysaccharide, can improve the immunity of body, thereby improve efficiency of feed utilization effectively.
This shows that using Chinese herbal medicine is a kind of method of preventing and treating of desirable, environmental type, and Chinese herbal medicine being meant according to the material of Chinese traditional medicine theory in order to control humans and animals disease, is developing jewel of China's medicine.The herbal variety that is used for preventing and treating diseases is numerous, and China has found out that through for many years generaI investigation Chinese herbal medicine resource reaches kind more than 12800.Confirm according to long-term practice, to treatment aquatic products fish curative effect preferably Chinese herbal medicine kind surplus the big head of garlic, gall nut, rheum officinale, Chinese tallow tree, wolf's milk, eucalyptus robusta, Herba Andrographitis, the Radix Isatidis etc. 50 is arranged, can be used to prevent and treat the various diseases that pathogenicity disease, nutritive disease, physiological disease and the environmental factor of multiple aquatic products fish cause.
Natural zeolite (Zeolite) is the general name of zeolite family nonmetallic mineral, comprises a series of moisture calcium, sodium and barium, the aluminium silicon salt mineral of potassium.Because because of the different sodalite Na[AlSi that are divided into composition 2] H 2O, scolecite Ca[Al 2Si 3O 10] H 2O Cheng Gu etc. are the mineral body of tens kinds nearly.Zeolite is a kind of at right cheap mineral, and its structure is the aluminosilicate crystal of a kind of shape structure, and many holes and passage are contained in inside.Clinoptilolite in its mesolite family has huge specific surface area, and the balance cation on the zeolite framework combines not closely with framework, under natural environmental condition very easily with water in cation generation exchange interaction, thereby zeolite particularly clinoptilolite have characteristics such as good adsorption performance, switching performance, decoloration performance and catalytic performance.
Natural zeolite generally is light color, glassy lustre, hardness 3-5.5, proportion 1.9-2.4.Wherein using natural clinoptilolite is the monocrystalline italic, light green color, suction amine value (NH 4) 1.86mmol/g, zeolite content 85%, zeolite pore is through between 3-10A, and the most clinoptilolites of China have the feature of the low sodium of the rich calcium potassium of high sial, i.e. CaO>Na 2O.So natural zeolite particularly clinoptilolite has stronger selective absorption function to mercury, cadmium, copper, zinc, lead, chromium, arsenic in the ammonia nitrogen phosphorus in the breeding water body of kinds such as aquatic products fish, shrimps, crab class and other organic element and heavy metal element, particularly the aquaculture water body.Can reduce the content of these metallic elements in breeding water body preferably.
Summary of the invention
In recent years, along with improving constantly of people's living standard, public demands to aquatic products such as aquatic product fish, shrimp, crab, eel, loach are increasing, and the scale of propagating artificially is enlarging in recent years, China's fresh water and mariculture industry development are rapid, and breed distributes extensively, area is big, wide in variety.But, along with the raising of culturing the intensification degree, aquatic products disease problem also comes out gradually, particularly the pollution of breeding water body is more and more serious, thereby cause the aquatic products disease to increase, and China is in weak state to aquatic products disease control technology at present, and the mechanism that aquatic products fish, shrimp, crab etc. are caused a disease, disease spread are known little about it by way of, disease prediction and Prevention Technique etc.This not only makes culturists suffer enormous economic loss, also becomes brackish water simultaneously and cultures a developing important bottleneck problem.Because drug use control aquatic products disease is improper, causes the aquatic products security incident to happen occasionally yet.Therefore seek the ecological shape science of a kind of environmental protection, rationally, the depot drug product product of standard and safety cultures the brackish water product and already expects.
The present invention selects China nearly kind of Chinese herbal medicine and preparation thereof surplus 50 in more than the 12800 kind of Chinese herbal medicine for use, utilize Chinese natural zeolite particularly in the clinoptilolite big aperture to the adsorption capacity of organic element and nonmetalloid and heavy metal element uniqueness, will be at a certain temperature after the drying through the natural zeolite particle of special activation processing, directly drop into and fill in the container of Chinese herbal medicine concoction or Chinese herbal and crude drugs preparations, make it fully adsorb the concoction composition among the hole that differs in size, form pharmaceutical carrier, will wherein make the Chinese herbal medicine sustained release agent after the low temperature drying then.Or will wear into after the special activation of natural zeolite particle greater than 180 purpose powder, directly with after Chinese herbal juice or medicament mix, granulation formation Chinese herbal medicine pill sustained release agent on granulator.After sustained release agent drops in the breeding water body, the medicine that is made of organic molecule divides to overflow slowly and is dissolved among the breeding water body, the medicine branch that constitutes owing to organic molecule overflows simultaneously, nonmetalloid and heavy metal element generation ion exchanges such as hole in the natural zeolite and the cation in the passage and the nitrogen in the breeding water body, phosphorus, copper, mercury, cadmium, lead, chromium, arsenic can have the double action that endangers element to aquatic products in the purifying aquatic water again thereby reach tool slowly-releasing medicinal herb components control aquatic products disease.
Aquatic products are many all to be zoobenthos such as shrimp, crab, eel etc., water-bed movable, ingest, also need when danger, slip in the substrate or in substrate and have a rest.Water quality and substrate are mutual restriction and interactional, in the water at the bottom of the sedimentation basin such as suspended organic matter, and anaerobic decay at the bottom of the pond, its catabolite is dissolved in the water and influences water quality, and the chemical element in the water influences the chemical change in the substrate, forms constantly circulation.This circulates in environment and allows situation subordinate benign cycle, otherwise will form vicious circle, and production has destructive effect to aquatic products.So can not only pay attention to the improvement and the improvement of an aspect of water quality with isolating, meanwhile also should pay much attention to the improvement of substrate.
The present invention adopts the using natural clinoptilolite particle through the specially treated activation, and implant biochemical bacterial classification such as nitrifier etc., natural zeolite can improve flocculating effect again when making it possess stronger adsorption function, can effectively increase the sedimental density of substrate, reduce the substrate volume, meanwhile, so the natural zeolite particle that precipitation is gone down forms one and covers layer, blocked in the substrate particularly heavy metal the vicious circle that breeding water body is formed of the harmful nonmetal organic element of aquatic products and metallic element, artificial brings up a good habitat for the benthic aquatic products animal, and it is vigorous that it is ingested, have a rest fully, grow smoothly.And natural zeolite can discharge useful metal ions such as potassium, sodium, displacement poisonous and harmful heavy metallic ion, and the virus in the adsorbed water product animal intestinal, pernicious gas, toxin etc.Also can slowly discharge simultaneously the aquatic products animal required such as trace elements such as zinc, iron, manganese, potassium, calcium, help improving the aquatic products quality, replenish the mine trace element that the aquatic products animal of causing because of food trace element deficiency lacks.
Embodiment:
Embodiment one: particle diameter 0.5-2 millimeter natural zeolite particle, behind the soda acid calcination activation, when making it maintain the temperature at 80-120 ℃, its Chinese herbal medicine that drops into certain proportion purposes consumption is fried in shallow oil in the juice, make it keep fully absorption more than 90 minutes, carry out then packing after the middle low temperature drying that temperature is lower than 100 ℃ and dispatch from the factory.
Embodiment two: particle diameter 0.5-2 millimeter natural zeolite particle, behind the soda acid calcination activation, when making it maintain the temperature at 80-120 ℃, it is dropped in the aqueous formulation liquid of being produced by professional aquaculture medication manufacturing enterprise, make it keep fully absorption more than 90 minutes, carry out temperature then and be lower than 100 ℃ middle low temperature drying packing and dispatch from the factory.
Embodiment three: particle diameter is less than 6 millimeters natural zeolite particles, behind the soda acid calcination activation, perhaps not activated, heat drying makes it keep below 300 ℃ of temperature insulations 90 minutes, after making the zeolite water forfeiture in the natural zeolite particle, in Chinese herbal medicine concoction that production decocts its input or the other dose liquid of water-based produced by professional aquaculture medication enterprise, air-dry cooling obtain drying completely natural zeolite particle substrate material packing dispatch from the factory.
Embodiment four: particle diameter 4-6 millimeter natural zeolite particle; behind the soda acid calcination activation; its diameter sent into remove to be processed into 180 order to 200 order powder in the abrasive dust equipment; after using Chinese herbal medicine concoction or Chinese herbal medicine medicament to mix on the granulator; granulating on granulator forms Chinese herbal medicine pill sustained release agent, and dry back packing is dispatched from the factory.

Claims (2)

1. a natural zeolite prepares the method for aquaculture environmental protection Chinese herbal medicine sustained release agent substrate material.It is characterized in that Chinese herbal medicine have natural, efficient, toxic and side effect is few, aboundresources and have organic principle medicinal and the nutrition double action concurrently, it is adsorbed in the hole of natural zeolite and the passage makes the environmental protection sustained release agent.Make it possess the double action of control aquatic products Animal diseases and purifying aquatic water.
2. a natural zeolite prepares the method for aquaculture environmental protection Chinese herbal medicine sustained release agent substrate material.It is characterized in that natural zeolite is made the biochemical substrate material of aquaculture, insert biochemical bacterium such as nitrifier and effectively blocked in the substrate particularly heavy metal element the vicious circle that breeding water body is formed of the harmful nonmetalloid of aquatic products.And can slowly discharge the required multiple trace quantity mineral substance element of aquatic products animal, help improving the aquatic products quality and replenish the essential mineral trace element deficiency disease of aquatic products animal that causes because of food trace element deficiency.
CN2010101772646A 2010-05-08 2010-05-08 Method for preparing substrate material of Chinese herbal slow-release injection for environmental friendly aquaculture by using natural zeolite Pending CN102232364A (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103601302A (en) * 2013-12-04 2014-02-26 武汉中博水产生物技术有限公司 Compound bacillus subtilis sustained-release tablet
CN104071861A (en) * 2014-07-09 2014-10-01 周振坤 Sewage purifying agent and preparation method thereof
CN104996324A (en) * 2015-03-06 2015-10-28 丰宁满族自治县利滦生态养殖有限公司 Ecological fish-farming method
CN106305554A (en) * 2016-08-23 2017-01-11 合肥申仁养殖有限公司 Lobster breeding method
CN111807482A (en) * 2020-07-21 2020-10-23 江苏福根农业科技有限公司 Aquaculture pond bottom material modifying agent and using method thereof
CN113290038A (en) * 2021-05-19 2021-08-24 江苏福砳生物环保科技有限公司 Reagent and method for reducing heavy metal pollution of Chinese herbal medicines

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103601302A (en) * 2013-12-04 2014-02-26 武汉中博水产生物技术有限公司 Compound bacillus subtilis sustained-release tablet
CN103601302B (en) * 2013-12-04 2015-08-19 武汉中博水产生物技术有限公司 A kind of compound subtilis slow releasing tablet
CN104071861A (en) * 2014-07-09 2014-10-01 周振坤 Sewage purifying agent and preparation method thereof
CN104071861B (en) * 2014-07-09 2015-12-02 周振坤 A kind of purifying agent for polluted water and preparation method thereof
CN104996324A (en) * 2015-03-06 2015-10-28 丰宁满族自治县利滦生态养殖有限公司 Ecological fish-farming method
CN106305554A (en) * 2016-08-23 2017-01-11 合肥申仁养殖有限公司 Lobster breeding method
CN111807482A (en) * 2020-07-21 2020-10-23 江苏福根农业科技有限公司 Aquaculture pond bottom material modifying agent and using method thereof
CN113290038A (en) * 2021-05-19 2021-08-24 江苏福砳生物环保科技有限公司 Reagent and method for reducing heavy metal pollution of Chinese herbal medicines

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Application publication date: 20111109