CN102206111A - Method for producing high-efficiency compound fertilizer by using yellow phosphorus slag and waste edible fungus bag material - Google Patents

Method for producing high-efficiency compound fertilizer by using yellow phosphorus slag and waste edible fungus bag material Download PDF

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CN102206111A
CN102206111A CN2011100836560A CN201110083656A CN102206111A CN 102206111 A CN102206111 A CN 102206111A CN 2011100836560 A CN2011100836560 A CN 2011100836560A CN 201110083656 A CN201110083656 A CN 201110083656A CN 102206111 A CN102206111 A CN 102206111A
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bag material
yellow phosphorus
compound fertilizer
furnace slag
edible mushrooms
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CN102206111B (en
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张兴华
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Weng'an Yiye Phosphorus Chemical Industry Co ltd
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Abstract

The invention provides a method for producing high-efficiency compound fertilizer by using yellow phosphorus slag and waste edible fungus bag material. The formula of the high-efficiency compound fertilizer comprises 30 percent of yellow phosphorus slag, 20 percent of waste edible fungus bag material, 10 percent of humic acid, 2 percent of caustic soda, 20 percent of urine, 10 percent of monoammonium phosphate and 8 percent of potassium sulfate. The preparation method comprises the following steps: 1) placing the yellow phosphorus slag in a ball mill and milling to 200 meshes for later use; 2) grinding the waste edible fungus bag material to 100 meshes for later use; 3) adding clean water in an amount which is twice to the total amount into humic acid and caustic soda, uniformly stirring, heating to 95 DEG C and obtaining paste after 2 hours for later use; 4) placing the materials into a stirrer together and uniformly stirring; 5) placing uniformly stirred materials into a sphere making plate for granulation; 6) screening particles, grinding particles with a diameter of more than 4.5 millimeters, and re-granulating; and 7) drying the particles to obtain finished products. In the invention, waste resources are fully utilized as a main raw material, the produced compound fertilizer has various nutrients and therefore has a good fertilizing effect, the high-efficiency compound fertilizer can improve soil effectively and low in cost, and the high-efficiency compound fertilizer is common and low in investment.

Description

The method of utilizing the discarded Bag Material of yellow phosphorus furnace slag and edible mushrooms to produce efficient compound fertilizer
Technical field
The present invention relates to a kind of agricultural composite fertilizer, a kind of specifically method of utilizing yellow phosphorus furnace slag and the discarded Bag Material of edible mushrooms to produce efficient compound fertilizer.
Background technology
Compound manure is to make with chemical process, content has the fertilizer of two or more nutritive element, the compound manure of Xiao Shouing is with nitrogen in the market, phosphorus, the nutrition of potassium ternary is main raw material, some also adds the fill material of some phosphogypsums and so on therein in order to gain in weight, after using these composite fertilizers, the farm crop primary growth is effective, but to middle period crops in the pollination of blooming, grouting knot grain and late period particle during the ripening stage, fertilizer efficiency has not just caught up with, mainly be because the nitrogen in the chemical fertilizer, phosphorus, the potassium nutrition element is after the immersion that is subjected to water and soil solution, the release that is decomposed very soon of its nutritive element, then cost is excessive for the high composite fertilizer of nutritive element content, fertilizer efficiency than long organic farm manure for various reasons, the rural area is difficult to pile up and uses now, for this reason, fertilizer efficiency is long, the source of manure that cost is low is the urgent need of current agricultural development and increases in grain production.
Summary of the invention
The objective of the invention is to solve the urgent need of current rural area for durable composite fertilizer, a kind of method of utilizing yellow phosphorus furnace slag and the discarded Bag Material of edible mushrooms to produce efficient compound fertilizer is provided, can make farm crop can both absorb required nutritive element fully in each stage of growth whole process, and have cost low, make full use of waste resource, environmental distinguishing feature.
The present invention includes yellow phosphorus furnace slag, the discarded Bag Material of edible mushrooms, rotten resin acid, urea, monoammonium phosphate, vitriolate of tartar, the technical scheme that is adopted is:
One) desired raw material formulation weight component is all as follows in the siccative precentagewise:
Figure BSA00000466264100021
Two) preparation method is as follows:
1) yellow phosphorus furnace slag being put into ball mill by recipe ingredient, to be milled to 200 orders stand-by;
2) it is stand-by heavily to adopt pulverizer to be crushed to 100 orders by component the discarded Bag Material of edible mushrooms;
3) rotten resin acid and caustic soda are added clear water by metering mixing back with the twice of mixing gross weight, heat after stirring to 95 ℃, it is stand-by to constitute pasty state after 2 hours;
4) with above-mentioned 1), 2), 3) material processed puts into stirrer together and stirs;
5) material that stirs is put into balling disk (-sc) and carry out granulation, particle diameter is controlled at 3~4.5mm;
6) particle that will make sieves, granulation again after pulverizing greater than the particle of 4.5mm;
7) particle is sent into rotary-kiln dryer and carried out drying treatment, promptly become the particulate state finished product.
In the technique scheme: the rotten resin acid content in the recipe ingredient is more than 30%.
Urea nitrogen content in the recipe ingredient is more than 46%.
The phosphorus pentoxide content of the monoammonium phosphate in the recipe ingredient is 52%.
The potassium oxide content of the vitriolate of tartar in the recipe ingredient is 50%.
The preparation method 7) in particle drying handle its dried water ratio≤1.5%.
Technique scheme that the present invention passes through, produce slag waste and the discarded Bag Material of edible mushrooms that yellow phosphorus produces owing to made full use of, by levigate pulverizing, decomposition and emulsifying effect through rotten resin acid, and add various nutritive elements such as nitrogen, phosphorus, potassium, the composite fertilizer that is produced has the required nutritive element of each stage production of farm crop, after granulation, drying are finished product, and very convenient use.After the use, when farm crop root with growth of seedling, particularly rice seedling is turned green in the process, its effective nutrient nitrogen, phosphorus, potassium is decomposed fast to be discharged, particularly rotten resin acid stimulates the effect of farm crop development growth element, it is sturdy that seedling is grown fast, in the farm crop pollination of blooming mid-term, grouting, during knot grain process, siliceous fertilizer fertilizer efficiency in the yellow phosphorus furnace slag can play slow release and can improve photosynthesis and disease-resistant bacterium ability, promotes nitrogen, the more good utilisation of phosphorus nutrient is to the stage of maturity in late period, the abundant organic matter that forms owing to the fermentation maturity that is subjected to the discarded Bag Material of organic compost edible mushrooms and the slow effect complete manure of various nutrient elements, can satisfy the required nutrient in farm crop stage of maturity fully, can impel grain full, reach increasing both production and income, the present invention has made up various nutritional advantages, made full use of waste resource, and technology is simple, it is low to have a cost, fertilizer efficiency is good, positive effect such as environmental grade is the compound source of manure of popularization of the development of agriculture production from now on.
Embodiment
Embodiment 1: to produce 500kg composite fertilizer:
One) the desired raw material formulation weight is as follows in the siccative precentagewise:
Smart yellow phosphorus furnace slag 30% 150kg, edible mushrooms discarded Bag Material 20% 100kg, rotten resin acid 10% 100kg, caustic soda 2% 10kg, urea 20% 100kg, monoammonium phosphate 10% 50kg, vitriolate of tartar 8% 40kg,
Two) preparation method is as follows:
1) yellow phosphorus furnace slag being put into ball mill by recipe ingredient, to be milled to 200 orders stand-by; 2) it is stand-by heavily to adopt pulverizer to be crushed to 100 orders by component the discarded Bag Material of edible mushrooms; 3) rotten resin acid and caustic soda are added clear water by metering mixing back with the twice of mixing gross weight, heat after stirring to 95 ℃, it is stand-by to constitute pasty state after 2 hours; 4) with above-mentioned 1), 2), 3) material processed puts into stirrer together and stirs; 5) material that stirs is put into balling disk (-sc) and carry out granulation, particle diameter is controlled at 3~4.5mm; 6) particle that will make sieves, granulation again after pulverizing greater than the particle of 4.5mm; 7) particle is sent into rotary-kiln dryer and carried out drying treatment, promptly become the particulate state finished product.Rotten resin acid content in the recipe ingredient is more than 30%, and the urea nitrogen content in the recipe ingredient is more than 46%, and the phosphorus pentoxide content of the monoammonium phosphate in the recipe ingredient is 52%, and the potassium oxide content of the vitriolate of tartar in the recipe ingredient is 50%.The preparation method 7) in particle drying handle its dried water ratio≤1.5%.
Embodiment 2: to produce 1000kg composite fertilizer:
One) the desired raw material formulation weight is as follows in the siccative precentagewise:
Smart yellow phosphorus furnace slag 30% 300kg, edible mushrooms discarded Bag Material 20% 200kg, rotten resin acid 10% 100kg, caustic soda 2% 20kg, urea 20% 200kg, monoammonium phosphate 10% 100kg, vitriolate of tartar 8% 80kg,
Two) preparation method is as follows:
1) yellow phosphorus furnace slag being put into ball mill by recipe ingredient, to be milled to 200 orders stand-by; 2) it is stand-by heavily to adopt pulverizer to be crushed to 100 orders by component the discarded Bag Material of edible mushrooms; 3) rotten resin acid and caustic soda are added clear water by metering mixing back with the twice of mixing gross weight, heat after stirring to 95 ℃, it is stand-by to constitute pasty state after 2 hours; 4) with above-mentioned 1), 2), 3) material processed puts into stirrer together and stirs; 5) material that stirs is put into balling disk (-sc) and carry out granulation, particle diameter is controlled at 3~4.5mm; 6) particle that will make sieves, granulation again after pulverizing greater than the particle of 4.5mm; 7) particle is sent into rotary-kiln dryer and carried out drying treatment, promptly become the particulate state finished product.Rotten resin acid content in the recipe ingredient is more than 30%, and the urea nitrogen content in the recipe ingredient is more than 46%, and the phosphorus pentoxide content of the monoammonium phosphate in the recipe ingredient is 52%, and the potassium oxide content of the vitriolate of tartar in the recipe ingredient is 50%.The preparation method 7) in particle drying handle its dried water ratio≤1.5%.
Embodiment 3: to produce 2000kg composite fertilizer:
One) the desired raw material formulation weight is as follows in the siccative precentagewise:
Smart yellow phosphorus furnace slag 30% 600kg, edible mushrooms discarded Bag Material 20% 400kg, rotten resin acid 10% 200kg, caustic soda 2% 40kg, urea 20% 400kg, monoammonium phosphate 10% 200kg, vitriolate of tartar 8% 160kg,
Two) preparation method is as follows:
1) yellow phosphorus furnace slag being put into ball mill by recipe ingredient, to be milled to 200 orders stand-by; 2) it is stand-by heavily to adopt pulverizer to be crushed to 100 orders by component the discarded Bag Material of edible mushrooms; 3) rotten resin acid and caustic soda are added clear water by metering mixing back with the twice of mixing gross weight, heat after stirring to 95 ℃, it is stand-by to constitute pasty state after 2 hours; 4) with above-mentioned 1), 2), 3) material processed puts into stirrer together and stirs; 5) material that stirs is put into balling disk (-sc) and carry out granulation, particle diameter is controlled at 3~4.5mm; 6) particle that will make sieves, granulation again after pulverizing greater than the particle of 4.5mm; 7) particle is sent into rotary-kiln dryer and carried out drying treatment, promptly become the particulate state finished product.Rotten resin acid content in the recipe ingredient is more than 30%, and the urea nitrogen content in the recipe ingredient is more than 46%, and the phosphorus pentoxide content of the monoammonium phosphate in the recipe ingredient is 52%, and the potassium oxide content of the vitriolate of tartar in the recipe ingredient is 50%.The preparation method 7) in particle drying handle its dried water ratio≤1.5%.
Embodiment 4: to produce 5000kg composite fertilizer:
One) the desired raw material formulation weight is as follows in the siccative precentagewise:
Smart yellow phosphorus furnace slag 30% 1500kg, edible mushrooms discarded Bag Material 20% 1000kg, rotten resin acid 10% 500kg, caustic soda 2% 100kg, urea 20% 1000kg, monoammonium phosphate 10% 500kg, vitriolate of tartar 8% 400kg,
Two) preparation method is as follows:
1) yellow phosphorus furnace slag being put into ball mill by recipe ingredient, to be milled to 200 orders stand-by; 2) it is stand-by heavily to adopt pulverizer to be crushed to 100 orders by component the discarded Bag Material of edible mushrooms; 3) rotten resin acid and caustic soda are added clear water by metering mixing back with the twice of mixing gross weight, heat after stirring to 95 ℃, it is stand-by to constitute pasty state after 2 hours; 4) with above-mentioned 1), 2), 3) material processed puts into stirrer together and stirs; 5) material that stirs is put into balling disk (-sc) and carry out granulation, particle diameter is controlled at 3~4.5mm; 6) particle that will make sieves, granulation again after pulverizing greater than the particle of 4.5mm; 7) particle is sent into rotary-kiln dryer and carried out drying treatment, promptly become the particulate state finished product.Rotten resin acid content in the recipe ingredient is more than 30%, and the urea nitrogen content in the recipe ingredient is more than 46%, and the phosphorus pentoxide content of the monoammonium phosphate in the recipe ingredient is 52%, and the potassium oxide content of the vitriolate of tartar in the recipe ingredient is 50%.The preparation method 7) in particle drying handle its dried water ratio≤1.5%.
Embodiment 5: to produce 10000kg composite fertilizer:
One) the desired raw material formulation weight is as follows in the siccative precentagewise:
Smart yellow phosphorus furnace slag 30% 3000kg, edible mushrooms discarded Bag Material 20% 2000kg, rotten resin acid 10% 1000kg, caustic soda 2% 200kg, urea 20% 2000kg, monoammonium phosphate 10% 1000kg, vitriolate of tartar 8% 800kg,
Two) preparation method is as follows:
1) yellow phosphorus furnace slag being put into ball mill by recipe ingredient, to be milled to 200 orders stand-by; 2) it is stand-by heavily to adopt pulverizer to be crushed to 100 orders by component the discarded Bag Material of edible mushrooms; 3) rotten resin acid and caustic soda are added clear water by metering mixing back with the twice of mixing gross weight, heat after stirring to 95 ℃, it is stand-by to constitute pasty state after 2 hours; 4) with above-mentioned 1), 2), 3) material processed puts into stirrer together and stirs; 5) material that stirs is put into balling disk (-sc) and carry out granulation, particle diameter is controlled at 3~4.5mm; 6) particle that will make sieves, granulation again after pulverizing greater than the particle of 4.5mm; 7) particle is sent into rotary-kiln dryer and carried out drying treatment, promptly become the particulate state finished product.Rotten resin acid content in the recipe ingredient is more than 30%, and the urea nitrogen content in the recipe ingredient is more than 46%, and the phosphorus pentoxide content of the monoammonium phosphate in the recipe ingredient is 52%, and the potassium oxide content of the vitriolate of tartar in the recipe ingredient is 50%.The preparation method 7) in particle drying handle its dried water ratio≤1.5%.
The discarded Bag Material of edible mushrooms described in the present invention is that various that adopt in current rural area are used for auricularia auriculajudae, mushroom Bag Material dibbling results are gathered the discarded Bag Material after using, be carrier mainly in the discarded Bag Material with wood saw end and wheat bran skin, after the High Temperature Sterilization sterilization, put bacterial classification and produce auricularia auriculajudae or mushroom, pluck back depleted Bag Material; Described caustic soda is that normally used content is 96% solid caustic soda.

Claims (6)

1. a method of utilizing yellow phosphorus furnace slag and the discarded Bag Material of edible mushrooms to produce efficient compound fertilizer comprises yellow phosphorus furnace slag, the discarded Bag Material of edible mushrooms, rotten resin acid, urea, monoammonium phosphate, vitriolate of tartar, it is characterized in that:
One) desired raw material formulation weight component is all as follows in the siccative precentagewise:
Two) preparation method is as follows:
1) yellow phosphorus furnace slag being put into ball mill by recipe ingredient, to be milled to 200 orders stand-by;
2) it is stand-by heavily to adopt pulverizer to be crushed to 100 orders by component the discarded Bag Material of edible mushrooms;
3) rotten resin acid and caustic soda are added clear water by metering mixing back with the twice of mixing gross weight, heat after stirring to 95 ℃, it is stand-by to constitute pasty state after 2 hours;
4) with above-mentioned 1), 2), 3) material processed puts into stirrer together and stirs;
5) material that stirs is put into balling disk (-sc) and carry out granulation, particle diameter is controlled at 3~4.5mm;
6) particle that will make sieves, granulation again after pulverizing greater than the particle of 4.5mm;
7) particle being sent into rotary-kiln dryer carries out promptly becoming the particulate state finished product after the drying treatment.
2. a kind of method of utilizing yellow phosphorus furnace slag and the discarded Bag Material of edible mushrooms to produce efficient compound fertilizer according to claim 1, its feature is being: the rotten resin acid content in the recipe ingredient is more than 30%.
3. the method for utilizing yellow phosphorus furnace slag and the discarded Bag Material of edible mushrooms to produce efficient compound fertilizer according to claim 1, its feature is being: the urea nitrogen content in the recipe ingredient is more than 46%.
4. the method for utilizing yellow phosphorus furnace slag and the discarded Bag Material of edible mushrooms to produce efficient compound fertilizer according to claim 1, its feature is being: the phosphorus pentoxide content of the monoammonium phosphate in the recipe ingredient is 52%.
5. the method for utilizing yellow phosphorus furnace slag and the discarded Bag Material of edible mushrooms to produce efficient compound fertilizer according to claim 1, its feature is being: the potassium oxide content of the vitriolate of tartar in the recipe ingredient is 50%.
6. the method for utilizing the discarded Bag Material of yellow phosphorus furnace slag and edible mushrooms to produce efficient compound fertilizer according to claim 1, its feature is being: the preparation method 7) in particle drying handle its dried water ratio≤1.5%.
CN201110083656.0A 2011-03-31 2011-03-31 Method for producing high-efficiency compound fertilizer by using yellow phosphorus slag and waste edible fungus bag material Active CN102206111B (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104387158A (en) * 2014-10-28 2015-03-04 欧长城 Special phosphorus-enriched biodegradable coated slow/controlled-release fertilizer for strawberries and preparation method of slow/controlled-release fertilizer
CN104387207A (en) * 2014-11-03 2015-03-04 贵州省化工研究院 Fertilizer prepared from yellow phosphorus furnace slag and specially applied to kiwi fruits and preparation method of fertilizer

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Publication number Priority date Publication date Assignee Title
CN1368487A (en) * 2001-02-01 2002-09-11 张显军 Formula and process for preparing efficient biological organic (or semi-organic) fertilizer
CN1923766A (en) * 2006-09-19 2007-03-07 李有显 NPK composite fertilizer and preparing method thereof
CN101050141A (en) * 2007-04-30 2007-10-10 西北农林科技大学 Soil water storage-increasing agent prepared from domestic slag and production method thereof
CN101284748A (en) * 2008-05-29 2008-10-15 谢浩 Multi-element and slow-released fertilizer
CN101585735A (en) * 2009-06-12 2009-11-25 西北农林科技大学 Special storage-expanding solubilized fertilizer for corn and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1368487A (en) * 2001-02-01 2002-09-11 张显军 Formula and process for preparing efficient biological organic (or semi-organic) fertilizer
CN1923766A (en) * 2006-09-19 2007-03-07 李有显 NPK composite fertilizer and preparing method thereof
CN101050141A (en) * 2007-04-30 2007-10-10 西北农林科技大学 Soil water storage-increasing agent prepared from domestic slag and production method thereof
CN101284748A (en) * 2008-05-29 2008-10-15 谢浩 Multi-element and slow-released fertilizer
CN101585735A (en) * 2009-06-12 2009-11-25 西北农林科技大学 Special storage-expanding solubilized fertilizer for corn and preparation method thereof

Non-Patent Citations (1)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104387158A (en) * 2014-10-28 2015-03-04 欧长城 Special phosphorus-enriched biodegradable coated slow/controlled-release fertilizer for strawberries and preparation method of slow/controlled-release fertilizer
CN104387207A (en) * 2014-11-03 2015-03-04 贵州省化工研究院 Fertilizer prepared from yellow phosphorus furnace slag and specially applied to kiwi fruits and preparation method of fertilizer
CN104387207B (en) * 2014-11-03 2017-05-03 贵州省化工研究院 Fertilizer prepared from yellow phosphorus furnace slag and specially applied to kiwi fruits and preparation method of fertilizer

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Effective date of registration: 20180703

Address after: 550400 Qing Keng Industrial Park, Weng County, Qiannan Buyi and Miao Autonomous Prefecture, Guizhou

Patentee after: Weng an majestic phosphorous chemical Creative Technology Limited

Address before: 441600 Hubei Xiangyang Baokang County Chengguan Town Grain Management Office

Patentee before: Zhang Xinghua

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Effective date of registration: 20210722

Address after: 550400 Weng'an Yihua Phosphorus Chemical Industry Co., Ltd., QingKeng Industrial Park, Weng'an county, Qiannan Buyi and Miao Autonomous Prefecture, Guizhou Province

Patentee after: Weng'an Yiye Phosphorus Chemical Industry Co.,Ltd.

Address before: 550400 Qing Keng Industrial Park, Weng County, Qiannan Buyi and Miao Autonomous Prefecture, Guizhou

Patentee before: Weng an majestic phosphorous chemical Creative Technology Ltd.

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