Background technology
The fast development of semiconductor technology and information industry; integrated circuit and the precision instrument circuit elements device low pressure that more and more becomes; take on the safety of Protective IC and electronic circuit and effectively anti-lightning, damage of electrostatic discharge effect electronic regulation, moment the over-voltage suppression silicon diode demand grow with each passing day; particularly protect voltage range to be lower than 10 volts the reliable anti-electric surge low-voltage variation silicon diode of high stable, existing home products still can not satisfy the demands fully.Enforcement of the present invention can provide a kind of highly reliable, colory anti-electric surge low pressure silicon protection new unit.
This anti-electric surge low-voltage variation silicon diode is mainly for the protection of the integrated circuit with power inductance.For example the inductance of transformer can produce transient peak voltage in the flyback converter in the voltage transitions process, in order to protect whole circuit, need to carry out the clamper restriction to this voltage.Normal RC damping circuit and the RCD damping circuit of adopting carries out the clamper restriction in the traditional circuit, and the designer also adopts single voltage stabilizing didoe to come protective circuit simultaneously.RC damping circuit and RCD damping circuit performance are more stable, eliminate the electromotive force concussion that inductance produces by the damping circuit of electric capacity and resistance, come the self induction electromotive force of absorption inductor by diode.But the damping circuit method will be used a resistance, an electric capacity and a diode usually, for realizing a kind of function, needs to install a plurality of components and parts on the circuit board like this, certainly will reduce security reliability.Using single voltage stabilizing didoe inhibition moment overvoltage, the anti-electric surge of circuit safety is new developing direction.
Feature of the present invention is to diffuse into N+ type semiconductor impurities phosphorus twice in a low-resistance P-type silicon single-crystal polishing plate minute priority, obtain for the first time interior N+ layer, obtain outer N+ layer for the second time, in addition, between inside and outside two N+ layers, by the epitaxial growth of N-type, be inserted into a N-silicon epitaxy layer, obtaining vertically is the silicon diode structure of PN+N-N+.The effect of N-silicon epitaxy layer is as one barrier, prevents when electrode metal alloy thereafter N+ layer in the circulation and the PN junction inefficacy occurs.The N+P that wherein is comprised of interior N+ layer partly is the core of the monolateral sudden change PN junction of silicon, and the function of outer N+ layer is to make to form good ohmic between silicon and the metal electrode and contact.The phosphorus impurities surface concentration of inside and outside N+ layer is 10
21/ cm
3
Table 1, table 2, table 3(Fig. 4, Fig. 5, Fig. 6) shown in the analog result resistivity Res that represented P type silicon single crystal and silicon diode protect relation between the voltage Vbr.
Table 1
Intrinsic Res |
Intrinsic concentration |
The doping junction depth |
Ns |
RS |
Vbr |
0.01ohm.cm |
7.98e18 |
7.6μm |
0.73e21 |
0.63 |
8.3V |
Table 2
Intrinsic Res |
Intrinsic concentration |
The doping junction depth |
Ns |
RS |
Vbr |
0.02ohm.cm |
2.68e18 |
8μm |
0.73e21 |
0.61 |
11.6V |
Table 3
Intrinsic Res |
Intrinsic concentration |
The doping junction depth |
Ns |
RS |
Vbr |
0.08ohm.cm |
3.28e18 |
9.5μm |
0.74e21 |
0.61 |
23.7V |
Simulated conditions: chip thickness 300 μ m, the unit length of side 50 μ m.
Summary of the invention
The objective of the invention is to overcome the deficiencies in the prior art; employing diffuses into N+ type semiconductor impurities phosphorus at P type silicon single-crystal polishing plate; carry out the epitaxially grown process of N-type in conjunction with the centre, obtain a kind of anti-electric surge low-voltage variation silicon diode, its preparation methods steps is as follows:
1) be that 250~300 μ m, resistivity are that the P type silicon single-crystal polishing plate surface of 0.01~0.08 Ω .cm diffuses into N+ type semiconductor impurities phosphorus at thickness, obtain the PN+ silicon chip, 1190~1200 ℃ of diffusion temperatures, 8~10 minutes diffusion times, the N+ type semiconductor impurities phosphorus surface concentration that diffuses into is 10
21/ cm
3
2) clean the PN+ silicon chip with electronics chemical cleaning 1# liquid, cleaning temperature is 80~85 ℃, and scavenging period is 10~15 minutes, pure water rinsing; Clean with electronics chemical cleaning 2# liquid, cleaning temperature is 80~85 ℃ again, and scavenging period is 10~15 minutes, dry, and pure water water outlet resistivity 10~12 Ω .cm, the volume ratio that electron chemistry cleans 1# liquid is: NH
4OH:H
2O
2: H
2O=1:2:5, the volume ratio that electron chemistry cleans 2# liquid is: HCL:H
2O
2: H
2O=1:2:8;
3) the PN+ silicon chip after cleaning carries out the epitaxial growth of N-type, obtains the PN+N-silicon chip, and the N-silicon epitaxy layer resistivity of PN+N-silicon chip is 0.05~0.10 Ω .cm, and thickness is 10~15 μ m;
4) diffuse into N+ type semiconductor impurities phosphorus at the PN+N-silicon chip, obtain the silicon chip of PN+N-N+, 1190~1200 ℃ of diffusion temperatures, 8~10 minutes diffusion times;
5) metal level on two plated surfaces of PN+N-N+ silicon chip carries out alloy, and sawing obtains diode chip for backlight unit;
6) with diode chip for backlight unit and encapsulation base plate welding, upper protection glue, moulded section are packaged into device.
It is general that the anti-electric surge low-voltage variation silicon diode of manufacturing of the present invention has production equipment, and the product cost performance is high, the characteristics of extensive market.
Embodiment
Anti-electric surge low-voltage variation silicon diode is: adopt and diffuse into N+ type semiconductor impurities phosphorus at P type silicon single-crystal polishing plate; carry out the epitaxially grown process of N-type in conjunction with the centre; obtain a kind of anti-electric surge low-voltage variation silicon diode, its preparation methods steps is as follows:
1) be that 250~300 μ m, resistivity are that the P type silicon single-crystal polishing plate surface of 0.01~0.08 Ω .cm diffuses into N+ type semiconductor impurities phosphorus at thickness, obtain the PN+ silicon chip, 1190~1200 ℃ of diffusion temperatures, 8~10 minutes diffusion times, the N+ type semiconductor impurities phosphorus surface concentration that diffuses into is 10
21/ cm
3
2) clean the PN+ silicon chip with electronics chemical cleaning 1# liquid, cleaning temperature is 80~85 ℃, and scavenging period is 10~15 minutes, pure water rinsing; Clean with electronics chemical cleaning 2# liquid, cleaning temperature is 80~85 ℃ again, and scavenging period is 10~15 minutes, dry, and pure water water outlet resistivity 10~12 Ω .cm, the volume ratio that electron chemistry cleans 1# liquid is: NH
4OH:H
2O
2: H
2O=1:2:5, the volume ratio that electron chemistry cleans 2# liquid is: HCL:H
2O
2: H
2O=1:2:8;
3) the PN+ silicon chip after cleaning carries out the epitaxial growth of N-type, obtains the PN+N-silicon chip, and the N-silicon epitaxy layer resistivity of PN+N-silicon chip is 0.05~0.10 Ω .cm, and thickness is 10~15 μ m;
4) diffuse into N+ type semiconductor impurities phosphorus at the PN+N-silicon chip, obtain the silicon chip of PN+N-N+, 1190~1200 ℃ of diffusion temperatures, 8~10 minutes diffusion times;
5) metal level on two plated surfaces of PN+N-N+ silicon chip carries out alloy, and sawing obtains diode chip for backlight unit;
6) with diode chip for backlight unit and encapsulation base plate welding, upper protection glue, moulded section are packaged into device.
Embodiment 1
1) be that 250 μ m, resistivity are that the P type silicon single-crystal polishing plate surface of 0.01 Ω .cm diffuses into N+ type semiconductor impurities phosphorus at thickness, obtain the PN+ silicon chip, 1190~1200 ℃ of diffusion temperatures, 8~10 minutes diffusion times, the N+ type semiconductor impurities phosphorus surface concentration that diffuses into is 10
21/ cm
3
2) clean the PN+ silicon chip with electronics chemical cleaning 1# liquid, cleaning temperature is 80~85 ℃, and scavenging period is 10~15 minutes, pure water rinsing; Clean with electronics chemical cleaning 2# liquid, cleaning temperature is 80~85 ℃ again, and scavenging period is 10~15 minutes, dry, and pure water water outlet resistivity 10~12 Ω .cm, the volume ratio that electron chemistry cleans 1# liquid is: NH
4OH:H
2O
2: H
2O=1:2:5, the volume ratio that electron chemistry cleans 2# liquid is: HCL:H
2O
2: H
2O=1:2:8;
3) the PN+ silicon chip after cleaning carries out the epitaxial growth of N-type, obtains the PN+N-silicon chip, and the N-silicon epitaxy layer resistivity of PN+N-silicon chip is 0.05 Ω .cm, and thickness is 15 μ m;
4) diffuse into N+ type semiconductor impurities phosphorus at the PN+N-silicon chip, obtain the silicon chip of PN+N-N+, 1190~1200 ℃ of diffusion temperatures, 10 minutes diffusion times;
5) metal level on two plated surfaces of PN+N-N+ silicon chip carries out alloy, and sawing obtains diode chip for backlight unit;
6) with diode chip for backlight unit and encapsulation base plate welding, upper protection glue, moulded section are packaged into device.
Embodiment 2
1) be that 280 μ m, resistivity are that the P type silicon single-crystal polishing plate surface of 0.04 Ω .cm diffuses into N+ type semiconductor impurities phosphorus at thickness, obtain the PN+ silicon chip, 1190~1200 ℃ of diffusion temperatures, 8~10 minutes diffusion times, the N+ type semiconductor impurities phosphorus surface concentration that diffuses into is 10
21/ cm
3
2) clean the PN+ silicon chip with electronics chemical cleaning 1# liquid, cleaning temperature is 80~85 ℃, and scavenging period is 10~15 minutes, pure water rinsing; Clean with electronics chemical cleaning 2# liquid, cleaning temperature is 80~85 ℃ again, and scavenging period is 10~15 minutes, dry, and pure water water outlet resistivity 10~12 Ω .cm, the volume ratio that electron chemistry cleans 1# liquid is: NH
4OH:H
2O
2: H
2O=1:2:5, the volume ratio that electron chemistry cleans 2# liquid is: HCL:H
2O
2: H
2O=1:2:8;
3) the PN+ silicon chip after cleaning carries out the epitaxial growth of N-type, obtains the PN+N-silicon chip, and the N-silicon epitaxy layer resistivity of PN+N-silicon chip is 0.10 Ω .cm, and thickness is 10 μ m;
4) diffuse into N+ type semiconductor impurities phosphorus at the PN+N-silicon chip, obtain the silicon chip of PN+N-N+, 1190~1200 ℃ of diffusion temperatures, 9 minutes diffusion times;
5) metal level on two plated surfaces of PN+N-N+ silicon chip carries out alloy, and sawing obtains diode chip for backlight unit;
6) with diode chip for backlight unit and encapsulation base plate welding, upper protection glue, moulded section are packaged into device.
Embodiment 3
1) be that 300 μ m, resistivity are that the P type silicon single-crystal polishing plate surface of 0.08 Ω .cm diffuses into N+ type semiconductor impurities phosphorus at thickness, obtain the PN+ silicon chip, 1190~1200 ℃ of diffusion temperatures, 8~10 minutes diffusion times, the N+ type semiconductor impurities phosphorus surface concentration that diffuses into is 10
21/ cm
3
2) clean the PN+ silicon chip with electronics chemical cleaning 1# liquid, cleaning temperature is 80~85 ℃, and scavenging period is 10~15 minutes, pure water rinsing; Clean with electronics chemical cleaning 2# liquid, cleaning temperature is 80~85 ℃ again, and scavenging period is 10~15 minutes, dry, and pure water water outlet resistivity 10~12 Ω .cm, the volume ratio that electron chemistry cleans 1# liquid is: NH
4OH:H
2O
2: H
2O=1:2:5, the volume ratio that electron chemistry cleans 2# liquid is: HCL:H
2O
2: H
2O=1:2:8;
3) the PN+ silicon chip after cleaning carries out the epitaxial growth of N-type, obtains the PN+N-silicon chip, and the N-silicon epitaxy layer resistivity of PN+N-silicon chip is 0.08 Ω .cm, and thickness is 12 μ m;
4) diffuse into N+ type semiconductor impurities phosphorus at the PN+N-silicon chip, obtain the silicon chip of PN+N-N+, 1190~1200 ℃ of diffusion temperatures, 10 minutes diffusion times;
5) metal level on two plated surfaces of PN+N-N+ silicon chip carries out alloy, and sawing obtains diode chip for backlight unit;
6) with diode chip for backlight unit and encapsulation base plate welding, upper protection glue, moulded section are packaged into device.