CN102186805B - 制备60%或以上的顺-环己烷-1,4-二甲酸(c4-c20)烷基酯的方法 - Google Patents

制备60%或以上的顺-环己烷-1,4-二甲酸(c4-c20)烷基酯的方法 Download PDF

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Publication number
CN102186805B
CN102186805B CN200980140773.7A CN200980140773A CN102186805B CN 102186805 B CN102186805 B CN 102186805B CN 200980140773 A CN200980140773 A CN 200980140773A CN 102186805 B CN102186805 B CN 102186805B
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cyclohexane
cis
dicarboxylic acid
ester
dicarboxylate
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CN102186805A (zh
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尹景俊
崔永均
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Hanwha Chemical Corp
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Hanwha Chemical Corp
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
    • C07C51/353—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by isomerisation; by change of size of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/74—Esters of carboxylic acids having an esterified carboxyl group bound to a carbon atom of a ring other than a six-membered aromatic ring
    • C07C69/75—Esters of carboxylic acids having an esterified carboxyl group bound to a carbon atom of a ring other than a six-membered aromatic ring of acids with a six-membered ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/38—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of titanium, zirconium or hafnium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/03—Preparation of carboxylic acid esters by reacting an ester group with a hydroxy group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C08K5/12—Esters; Ether-esters of cyclic polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B2200/00—Indexing scheme relating to specific properties of organic compounds
    • C07B2200/09—Geometrical isomers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/0016—Plasticisers

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
CN200980140773.7A 2008-10-16 2009-10-16 制备60%或以上的顺-环己烷-1,4-二甲酸(c4-c20)烷基酯的方法 Active CN102186805B (zh)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
KR10-2008-0101629 2008-10-16
KR20080101629 2008-10-16
KR10-2009-0063075 2009-07-10
KR1020090063075A KR101099127B1 (ko) 2008-10-16 2009-07-10 60%이상의 시스 디(ｃ4-ｃ20)알킬 시클로헥산-1,4-디카르복실레이트의 제조방법
PCT/KR2009/005980 WO2010044638A2 (en) 2008-10-16 2009-10-16 Method of preparing of 60% or more cis-di(c4-c20)alkyl cyclohexane-1,4-dicarboxylate

Publications (2)

Publication Number Publication Date
CN102186805A CN102186805A (zh) 2011-09-14
CN102186805B true CN102186805B (zh) 2014-04-23

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CN200980140773.7A Active CN102186805B (zh) 2008-10-16 2009-10-16 制备60%或以上的顺-环己烷-1,4-二甲酸(c4-c20)烷基酯的方法

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US (2) US8299292B2 (enExample)
EP (1) EP2344443B1 (enExample)
JP (1) JP5586612B2 (enExample)
KR (1) KR101099127B1 (enExample)
CN (1) CN102186805B (enExample)
TW (1) TWI408123B (enExample)
WO (1) WO2010044638A2 (enExample)

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WO2013143824A1 (en) 2012-03-30 2013-10-03 Exxonmobil Chemical Patents Inc. Process for the production of terephthalate esters
US20150307435A1 (en) 2012-03-30 2015-10-29 Exxonmobil Chemical Patents Inc. Esterification Process
CN103664613A (zh) * 2013-12-13 2014-03-26 佛山市顺德区天晟贸易有限公司 一种非线性增塑剂及其制备方法和应用
JP6333045B2 (ja) * 2014-04-25 2018-05-30 リケンテクノス株式会社 塩化ビニル系樹脂組成物
JP2016044296A (ja) * 2014-08-27 2016-04-04 リケンテクノス株式会社 医療用塩化ビニル系樹脂組成物、及びそれからなる医療用器具
JP6568679B2 (ja) * 2014-08-27 2019-08-28 リケンテクノス株式会社 塩化ビニル系樹脂組成物
JP2016074876A (ja) * 2014-10-08 2016-05-12 新日本理化株式会社 １，４−シクロヘキサンジカルボン酸ジエステルからなる塩化ビニル系樹脂用可塑剤
KR102090294B1 (ko) * 2016-04-22 2020-03-17 주식회사 엘지화학 가소제 조성물 및 이를 포함하는 수지 조성물
WO2018128314A1 (ko) * 2017-01-04 2018-07-12 주식회사 엘지화학 사이클로헥산 1,4-디에스터계 화합물을 포함하는 가소제 조성물 및 이를 포함하는 수지 조성물
KR102123151B1 (ko) * 2017-06-13 2020-06-15 (주)휴이노베이션 친환경 가소제 및 이를 포함하는 수지 조성물
TWI690510B (zh) * 2018-12-04 2020-04-11 南亞塑膠工業股份有限公司 一種提高環己烷-１,４-二甲酸二異辛酯產率的氫化方法
KR102501597B1 (ko) * 2019-09-25 2023-02-20 주식회사 엘지화학 디에스테르계 조성물의 제조 시스템 및 제조방법
KR102595882B1 (ko) * 2019-09-25 2023-10-30 주식회사 엘지화학 디에스터계 조성물의 제조 시스템 및 제조방법
KR102246868B1 (ko) * 2019-12-30 2021-05-03 한화솔루션 주식회사 에스테르계　화합물 및 이의 용도
SI4043517T1 (sl) * 2021-02-16 2025-07-31 Evonik Oxeno Gmbh & Co. Kg Uporaba 1,4-bis(2-etilheksil)cikloheksan dikarboksilata kot mehčalca v površinskih premazih
KR102873617B1 (ko) * 2021-02-18 2025-10-17 한화솔루션 주식회사 가소제 조성물, 및 이를 포함하는 실란트/접착제 조성물
WO2022220543A1 (ko) * 2021-04-12 2022-10-20 한국화학연구원 디메틸테레프탈레이트의 에스테르 교환 반응에 의한 테레프탈레이트 유도체 제조 방법
KR102531143B1 (ko) * 2021-05-03 2023-05-11 (주)네오 신규 사이클로헥산계 에스테르 조성물 및 이의 제조방법
KR102715007B1 (ko) * 2021-12-06 2024-10-08 한국기술교육대학교 산학협력단 사이클로헥산계 친환경 가소제를 포함하는 렌즈용 조성물 및 이를 이용한 렌즈의 제조방법

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CN1356973A (zh) * 1999-06-18 2002-07-03 巴斯福股份公司 选择的环己烷－1,3－及－1,4－二羧酸酯
CN1468272A (zh) * 2000-10-13 2004-01-14 �Ϻ���ͨ��ѧ 制备聚(1,4-环己烷二甲酸1,4-亚环己基二亚甲基酯)的方法及由其制得的反应器级聚酯

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CN1468272A (zh) * 2000-10-13 2004-01-14 �Ϻ���ͨ��ѧ 制备聚(1,4-环己烷二甲酸1,4-亚环己基二亚甲基酯)的方法及由其制得的反应器级聚酯

Also Published As

Publication number Publication date
US8299292B2 (en) 2012-10-30
TW201016658A (en) 2010-05-01
EP2344443A4 (en) 2014-08-20
US20130053492A1 (en) 2013-02-28
KR101099127B1 (ko) 2011-12-26
TWI408123B (zh) 2013-09-11
EP2344443B1 (en) 2019-09-18
KR20100042579A (ko) 2010-04-26
CN102186805A (zh) 2011-09-14
JP5586612B2 (ja) 2014-09-10
JP2012505877A (ja) 2012-03-08
US20110263770A1 (en) 2011-10-27
WO2010044638A3 (en) 2010-07-29
WO2010044638A2 (en) 2010-04-22
EP2344443A2 (en) 2011-07-20

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