CN102134300B - 一种功能化可调两性聚羧酸系水泥助磨剂的制备方法 - Google Patents
一种功能化可调两性聚羧酸系水泥助磨剂的制备方法 Download PDFInfo
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- CN102134300B CN102134300B CN2011100246402A CN201110024640A CN102134300B CN 102134300 B CN102134300 B CN 102134300B CN 2011100246402 A CN2011100246402 A CN 2011100246402A CN 201110024640 A CN201110024640 A CN 201110024640A CN 102134300 B CN102134300 B CN 102134300B
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- 239000004568 cement Substances 0.000 title claims abstract description 37
- 238000000227 grinding Methods 0.000 title claims abstract description 37
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- 229920005646 polycarboxylate Polymers 0.000 title abstract 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 32
- 238000006243 chemical reaction Methods 0.000 claims abstract description 21
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 18
- 239000002253 acid Substances 0.000 claims abstract description 17
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000007864 aqueous solution Substances 0.000 claims abstract description 8
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 6
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 5
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- 238000006386 neutralization reaction Methods 0.000 claims abstract 2
- 239000000243 solution Substances 0.000 claims description 11
- 238000007306 functionalization reaction Methods 0.000 claims description 9
- QTMDXZNDVAMKGV-UHFFFAOYSA-L copper(ii) bromide Chemical compound [Cu+2].[Br-].[Br-] QTMDXZNDVAMKGV-UHFFFAOYSA-L 0.000 claims description 8
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 6
- -1 methyl thiazolinyl Chemical group 0.000 claims description 6
- 150000003460 sulfonic acids Chemical class 0.000 claims description 6
- 229910021589 Copper(I) bromide Inorganic materials 0.000 claims description 4
- 229910021590 Copper(II) bromide Inorganic materials 0.000 claims description 4
- NKNDPYCGAZPOFS-UHFFFAOYSA-M copper(i) bromide Chemical compound Br[Cu] NKNDPYCGAZPOFS-UHFFFAOYSA-M 0.000 claims description 4
- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 claims description 3
- 229920000536 2-Acrylamido-2-methylpropane sulfonic acid Polymers 0.000 claims description 3
- XHZPRMZZQOIPDS-UHFFFAOYSA-N 2-Methyl-2-[(1-oxo-2-propenyl)amino]-1-propanesulfonic acid Chemical compound OS(=O)(=O)CC(C)(C)NC(=O)C=C XHZPRMZZQOIPDS-UHFFFAOYSA-N 0.000 claims description 3
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- 239000004160 Ammonium persulphate Substances 0.000 claims description 3
- ROFVEXUMMXZLPA-UHFFFAOYSA-N Bipyridyl Chemical group N1=CC=CC=C1C1=CC=CC=N1 ROFVEXUMMXZLPA-UHFFFAOYSA-N 0.000 claims description 3
- JPAOMENBKRZQDR-UHFFFAOYSA-N CC=CC.[Na] Chemical compound CC=CC.[Na] JPAOMENBKRZQDR-UHFFFAOYSA-N 0.000 claims description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 3
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 3
- 235000019395 ammonium persulphate Nutrition 0.000 claims description 3
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 3
- 150000002978 peroxides Chemical class 0.000 claims description 3
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 claims description 3
- BWYYYTVSBPRQCN-UHFFFAOYSA-M sodium;ethenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C=C BWYYYTVSBPRQCN-UHFFFAOYSA-M 0.000 claims description 3
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 3
- DGEZNRSVGBDHLK-UHFFFAOYSA-N [1,10]phenanthroline Chemical group C1=CN=C2C3=NC=CC=C3C=CC2=C1 DGEZNRSVGBDHLK-UHFFFAOYSA-N 0.000 claims description 2
- 238000000034 method Methods 0.000 abstract description 7
- 230000000694 effects Effects 0.000 abstract description 5
- 238000013461 design Methods 0.000 abstract description 3
- 238000010526 radical polymerization reaction Methods 0.000 abstract description 2
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000010790 dilution Methods 0.000 abstract 1
- 239000012895 dilution Substances 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 239000003446 ligand Substances 0.000 abstract 1
- 229920002521 macromolecule Polymers 0.000 abstract 1
- 239000000463 material Substances 0.000 description 10
- 239000000047 product Substances 0.000 description 7
- 238000005265 energy consumption Methods 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 4
- 238000011161 development Methods 0.000 description 3
- 230000018109 developmental process Effects 0.000 description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- 239000004567 concrete Substances 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000007689 inspection Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 125000002769 thiazolinyl group Chemical group 0.000 description 2
- 208000037656 Respiratory Sounds Diseases 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000035876 healing Effects 0.000 description 1
- 150000001261 hydroxy acids Chemical group 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 230000003335 steric effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
Abstract
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CN2011100246402A CN102134300B (zh) | 2011-01-21 | 2011-01-21 | 一种功能化可调两性聚羧酸系水泥助磨剂的制备方法 |
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CN2011100246402A CN102134300B (zh) | 2011-01-21 | 2011-01-21 | 一种功能化可调两性聚羧酸系水泥助磨剂的制备方法 |
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CN102134300A CN102134300A (zh) | 2011-07-27 |
CN102134300B true CN102134300B (zh) | 2012-11-21 |
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Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102584091B (zh) * | 2012-01-19 | 2013-10-30 | 山西大学 | 一种聚羧酸盐水泥助磨剂及其制备方法 |
CN102796234A (zh) * | 2012-08-15 | 2012-11-28 | 聊城天成水泥科技研发有限公司 | 一种高效可控聚羧酸系水泥助磨剂的制备方法 |
CN102964082B (zh) * | 2012-11-08 | 2015-05-20 | 贵州环海澳蕾建材科技有限公司 | 一种高分子合成水泥助磨剂 |
CN102965077B (zh) * | 2012-11-23 | 2014-04-02 | 东南大学 | 一种粉体矿粉添加剂 |
CN103058556B (zh) * | 2013-01-24 | 2014-12-24 | 河南省科学院高新技术研究中心 | 一种聚羧酸系高分子助磨剂及其制备方法 |
CN105314917A (zh) * | 2014-06-05 | 2016-02-10 | 镇江市船山第二水泥厂 | 一种水泥助磨剂制备方法 |
CN105669909B (zh) * | 2015-12-28 | 2018-01-19 | 江苏中铁奥莱特新材料股份有限公司 | 一种增强型聚丙烯酰胺系水泥助磨剂的制备方法 |
CN105669910B (zh) * | 2016-01-05 | 2018-03-20 | 河南新汉材料科技有限公司 | 一种聚羧酸系水泥助磨剂及制备方法 |
CN106007463A (zh) * | 2016-07-02 | 2016-10-12 | 曹平 | 一种混凝土助磨剂 |
CN106220032A (zh) * | 2016-08-23 | 2016-12-14 | 陈广圣 | 一种混凝土助磨剂 |
CN115849744A (zh) * | 2022-12-07 | 2023-03-28 | 信丰华轩建材有限公司 | 一种高性能水泥助磨剂的制备方法 |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
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EP1661871B1 (en) * | 2004-11-25 | 2010-10-20 | Mapei S.p.A. | Additive for the manufacture of cement free of soluble chromates |
EP1923370A1 (en) * | 2006-11-02 | 2008-05-21 | Mapei S.p.A. | Additives and methods for reducing hexavalent chromium in cement and cement based materials |
CN101372408A (zh) * | 2008-05-07 | 2009-02-25 | 赵洪义 | 一种液体无氯型水泥助磨剂及制备方法 |
CN101798198B (zh) * | 2010-04-03 | 2012-11-21 | 山东宏艺科技股份有限公司 | 一种聚羧酸水泥活化助磨增强剂及其制备方法 |
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Address after: 361101 Xiamen Xiangan high tech industrial base in Fujian District Patentee after: KZJ NEW MATERIALS GROUP Co.,Ltd. Patentee after: Kezhijie New Material (Zhangzhou) Co.,Ltd. Patentee after: Xiamen Academy of Building Research Group Co.,Ltd. Address before: 361101 Xiamen Xiangan high tech industrial base in Fujian District Patentee before: FUJIAN KZJ NEW MATERIALS Co.,Ltd. Patentee before: Kezhijie New Material (Zhangzhou) Co.,Ltd. Patentee before: Xiamen Academy of Building Research Group Co.,Ltd. |
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Address after: 361101 Xiamen Xiangan high tech industrial base in Fujian District Patentee after: KZJ NEW MATERIALS GROUP Co.,Ltd. Patentee after: FUJIAN KZJ NEW MATERIALS Co.,Ltd. Patentee after: Xiamen Academy of Building Research Group Co.,Ltd. Address before: 361101 Xiamen Xiangan high tech industrial base in Fujian District Patentee before: KZJ NEW MATERIALS GROUP Co.,Ltd. Patentee before: Kezhijie New Material (Zhangzhou) Co.,Ltd. Patentee before: Xiamen Academy of Building Research Group Co.,Ltd. |
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Granted publication date: 20121121 |