CN102066425A - 用于聚合物的颜色稳定化的体系和组合物 - Google Patents
用于聚合物的颜色稳定化的体系和组合物 Download PDFInfo
- Publication number
- CN102066425A CN102066425A CN2009801229797A CN200980122979A CN102066425A CN 102066425 A CN102066425 A CN 102066425A CN 2009801229797 A CN2009801229797 A CN 2009801229797A CN 200980122979 A CN200980122979 A CN 200980122979A CN 102066425 A CN102066425 A CN 102066425A
- Authority
- CN
- China
- Prior art keywords
- butyl
- antioxidant
- zinc
- dithiocarbamate
- thioether
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/39—Thiocarbamic acids; Derivatives thereof, e.g. dithiocarbamates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/005—Stabilisers against oxidation, heat, light, ozone
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0091—Complexes with metal-heteroatom-bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
未老化的 | |||||
亮度 | 61.25 | 61.86 | 60.55 | 63.60 | 64.27 |
L | 80.71 | 81.05 | 80.43 | 81.98 | 82.36 |
A | .41 | .36 | .49 | .54 | .61 |
B | 3.78 | 3.80 | 3.18 | 3.42 | 3.42 |
24小时 | |||||
亮度 | 61.01 | 61.19 | 59.91 | 64.02 | 64.60 |
L | 80.71 | 80.72 | 79.53 | 82.52 | 82.72 |
A | .16 | .29 | .57 | .18 | -.10 |
B | 3.84 | 3.50 | 3.37 | 3.75 | 3.48 |
δE | 0.26 | 0.45 | 0.92 | 0.73 | 0.39 |
96小时 | |||||
亮度 | 59.37 | 61.73 | 59.14 | 61.94 | 62.03 |
L | 79.79 | 81.08 | 79.40 | 81.31 | 80.98 |
A | .42 | .28 | .40 | .48 | .61 |
B | 4.19 | 3.73 | 3.83 | 4.01 | 3.51 |
δE | 1.01 | 0.11 | 1.22 | 0.89 | 1.01 |
120小时 | |||||
亮度 | 59.01 | 62.07 | 59.01 | 61.92 | 61.63 |
L | 79.45 | 81.09 | 79.03 | 81.56 | 80.72 |
A | .41 | .30 | .64 | .43 | .68 |
B | 4.06 | 3.60 | 3.51 | 4.24 | 3.48 |
δE | 1.29 | 0.21 | 1.45 | 0.83 | 1.27 |
192小时 | |||||
亮度 | 59.48 | 62.15 | 61.74 | 60.91 | 62.61 |
L | 79.92 | 81.53 | 80.90 | 80.88 | 81.55 |
A | .34 | .24 | .68 | .51 | .80 |
B | 4.36 | 4.05 | 3.60 | 4.45 | 3.45 |
δE | 0.98 | 0.55 | 0.66 | 1.51 | 0.50 |
288小时 | |||||
亮度 | 60.52 | 61.52 | 61.78 | 61.50 | 63.11 |
L | 80.93 | 81.38 | 81.32 | 81.68 | 81.74 |
A | .11 | .21 | .15 | .13 | .55 |
B | 4.56 | 4.64 | 4.27 | 5.18 | 3.86 |
δE | 0.86 | 0.91 | 1.45 | 1.83 | 0.50 |
408小时 |
亮度 | 60.10 | 59.73 | 57.60 | 58.81 | 61.78 |
L | 80.67 | 80.86 | 78.64 | 80.77 | 80.87 |
A | -.17 | -.01 | .43 | -.12 | .79 |
B | 5.02 | 5.58 | 4.43 | 6.19 | 3.69 |
δE | 1.37 | 1.83 | 2.18 | 3.09 | 1.17 |
432小时 | |||||
亮度 | 57.66 | 58.26 | 56.46 | 57.63 | 61.91 |
L | 79.61 | 79.91 | 78.02 | 79.96 | 80.98 |
A | .12 | .03 | .21 | -.04 | .52 |
B | 5.61 | 5.49 | 4.43 | 6.18 | 3.66 |
δE | 2.15 | 2.07 | 2.73 | 3.47 | 1.03 |
504小时 | |||||
亮度 | 56.08 | 57.72 | 58.49 | 56.27 | 62.47 |
L | 79.12 | 79.93 | 79.70 | 79.75 | 81.47 |
A | -.40 | -.32 | .23 | -.36 | .42 |
B | 6.45 | 6.13 | 4.94 | 7.11 | 3.77 |
δE | 3.21 | 2.67 | 1.92 | 4.40 | 0.63 |
672小时 | |||||
亮度 | 54.73 | 58.90 | 59.97 | 53.97 | 62.64 |
L | 79.03 | 81.18 | 81.22 | 79.36 | 81.72 |
A | -.56 | -.40 | -.12 | -.64 | .44 |
B | 7.59 | 6.81 | 5.85 | 8.98 | 4.01 |
δE | 4.28 | 3.11 | 2.85 | 6.26 | 0.65 |
696小时 | |||||
亮度 | 55.15 | 55.49 | 53.96 | 51.38 | 60.09 |
L | 79.59 | 79.65 | 77.68 | 77.88 | 80.50 |
A | -.67 | -.67 | -.25 | -.61 | .65 |
B | 7.96 | 7.71 | 6.46 | 9.07 | 4.70 |
δE | 4.46 | 4.28 | 4.34 | 7.07 | 1.96 |
744小时 | |||||
亮度 | 56.18 | 56.09 | 56.84 | 53.94 | 61.54 |
L | 79.88 | 80.08 | 79.89 | 79.71 | 81.25 |
A | -.60 | -.65 | -.15 | -.76 | .37 |
B | 7.45 | 7.74 | 6.74 | 9.19 | 4.40 |
δE | 3.90 | 4.18 | 3.66 | 6.34 | 1.23 |
840时 | 失效 | ||||
亮度 | 55.29 | 56.07 | 4.08 | 51.72 | 60.13 |
L | 80.21 | 80.28 | 43.30 | 79.36 | 80.61 |
A | -.85 | -.89 | 18.23 | -.88 | .78 |
B | 8.74 | 8.13 | 23.78 | 10.86 | 4.62 |
δE | 5.14 | 4.57 | 46.02 | 8.01 | 1.84 |
1008小时 | 失效 | 失效 | |||
亮度 | 52.44 | 25.02 | 23.38 | 57.24 | |
L | 78.66 | 70.66 | 75.40 | 79.78 | |
A | -1.05 | 1.87 | 2.83 | .30 | |
B | 9.25 | 25.65 | 31.95 | 6.17 |
δE | 6.02 | 24.24 | 29.37 | 3.53 | |
1200小时 | 失效 | ||||
亮度 | 36.32 | 57.90 | |||
L | 80.49 | 80.32 | |||
A | -1.12 | .15 | |||
B | 25.87 | 6.46 | |||
δE | 22.14 | 3.49 | |||
1224小时 | 失效 | ||||
亮度 | 55.15 | ||||
L | 81.77 | ||||
A | -1.50 | ||||
B | 10.81 | ||||
δE | 7.67 |
L | 81.61 | 80.00 | ||
A. | -.75 | -.33 | ||
B | 3.01 | 2.65 | ||
δE | 2.34 | 0.49 | 1.85 | |
1248小时 | ||||
亮度 | 63.44 | 65.81 | ||
L | 81.82 | 82.30 | ||
a | -.92 | -.50 | ||
b | 3.53 | 2.05 | ||
δE | 2.91 | 0.25 | 2.66 | |
1344小时 | ||||
亮度 | 62.61 | 63.15 | ||
L | 81.47 | 80.91 | ||
a | -.95 | -.45 | ||
b | 3.79 | 2.43 | ||
δE | 3.34 | 0.83 | 2.51 | |
1440小时 | ||||
亮度 | 60.71 | 60.70 | ||
L | 80.99 | 80.10 | ||
a | -1.28 | -.70 | ||
b | 4.84 | 3.47 | ||
δE | 4.49 | 1.93 | 2.56 | |
1512小时. | ||||
亮度 | 60.77 | 60.50 | ||
L | 81.55 | 80.02 | ||
a | -1.46 | -.79 | ||
b | 5.61 | 3.57 | ||
δE | 4.88 | 2.97 | 1.91 | |
1680小时 | ||||
亮度 | 57.45 | 56.79 | ||
L | 79.50 | 79.21 | ||
a | -1.65 | -1.18 | ||
b | 5.75 | 5.86 | ||
δE | 6.19 | 5.12 | 1.07 | |
1738小时 | 1696 | |||
亮度 | 58.88 | 62.04 | ||
L | 81.06 | 81.36 | ||
a | -1.64 | -1.01 | ||
b | 6.53 | 4.15 | ||
δE | 5.94 | 2.48 | 3.46 | |
1848小时 | ||||
亮度 | 62.45 | |||
L | 81.60 | |||
a | -.95 |
b | 4.09 | |||
δE | 2.31 | |||
2040小时 | ||||
亮度 | 47.22 | |||
L | 81.13 | |||
a | -2.73 | |||
b | 16.97 | |||
δE | 15.17 |
条目 | 近似累计小时 | 平均δE差值 |
1 | 0-1000 | 0.23 |
2 | 1000-2000 | 2.20 |
a | -.00 | -.34 | .85 | 1.06 |
b | 4.54 | 1.85 | 3.55 | 3.22 |
δE | 0.75 | 0.82 | 2.38 | 4.27 |
840小时 | ||||
亮度 | 53.70 | 64.04 | 57.01 | 56.24 |
L | 77.10 | 81.33 | 77.93 | 77.09 |
a | .12 | -.44 | .76 | .76 |
b | 3.42 | 2.21 | 3.95 | 3.49 |
δE | 2.56 | 1.23 | 2.46 | 3.22 |
1008小时 | ||||
亮度 | 56.86 | 65.12 | 54.72 | 57.34 |
L | 78.59 | 81.81 | 76.13 | 78.12 |
a | .35 | -.39 | .98 | .79 |
b | 5.59 | 1.94 | 3.55 | 3.74 |
δE | 1.79 | 0.75 | 4.26 | 2.21 |
1104小时 | ||||
亮度 | 54.54 | 61.42 | 57.15 | 57.65 |
L | 77.08 | 80.00 | 78.30 | 78.41 |
A | .88 | -.33 | .61 | .75 |
B | 5.73 | 2.65 | 3.08 | 4.06 |
δE | 2.96 | 0.49 | 2.15 | 1.99 |
1248小时 | ||||
亮度 | 54.24 | 65.81 | 57.13 | 55.98 |
L | 77.49 | 82.30 | 78.18 | 77.59 |
a | -.27 | -.50 | .43 | .47 |
b | 7.10 | 2.05 | 4.17 | 4.31 |
δE | 3.74 | 0.25 | 2.22 | 2.86 |
1344小时 | ||||
亮度 | 54.44 | 63.15 | 56.82 | 58.47 |
L | 77.92 | 80.91 | 78.14 | 79.46 |
a | .05 | -.45 | .27 | .45 |
b | 6.53 | 2.43 | 4.26 | 4.65 |
δE | 2.97 | 0.83 | 2.29 | 1.49 |
1440小时 | ||||
亮度 | 54.86 | 60.70 | 57.13 | 54.16 |
L | 78.30 | 80.10 | 77.95 | 76.99 |
a | .08 | -.70 | .32 | .53 |
b | 6.75 | 3.47 | 3.45 | 5.03 |
δE | 2.97 | 1.93 | 2.41 | 3.68 |
1512小时 | 1360小时时 | |||
亮度 | 52.89 | 60.50 | 54.34 | |
L | 77.62 | 80.02 | 76.96 | |
a | -.92 | -.79 | .22 | |
b | 7.15 | 3.57 | 5.27 | |
δE | 3.91 | 2.97 | 3.84 | |
1680小时 | ||||
亮度 | 18.59 | 56.79 | 55.03 | |
L | 70.27 | 79.21 | 77.46 | |
a | 6.26 | -1.18 | -.01 | |
b | 31.33 | 5.86 | 5.30 |
δE | 29.32 | 5.12 | 3.47 | |
(1572小时) | ||||
1738小时 | ||||
亮度 | 62.04 | 52.82 | ||
L | 81.36 | 75.78 | ||
a | -1.01 | .06 | ||
b | 4.15 | 4.40 | ||
δE | 2.48 | 4.67 | ||
. | ||||
1848小时 | ||||
亮度 | 62.45 | 44.78 | ||
L | 81.60 | 82.12 | ||
a | -.95 | -2.46 | ||
b | 4.09 | 20.29 | ||
δE | 2.31 | 17.22 | ||
(1836小时) | ||||
2040小时 | ||||
亮度 | 47.22 | |||
L | 81.13 | |||
a | -2.73 | |||
b | 16.97 | |||
δE | 15.17 |
Claims (11)
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US7326208P | 2008-06-17 | 2008-06-17 | |
US61/073,262 | 2008-06-17 | ||
US12/354,902 | 2009-01-16 | ||
US12/354,902 US8287765B2 (en) | 2008-06-17 | 2009-01-16 | Systems and compositions for color stabilization of polymer |
PCT/US2009/047487 WO2009155279A1 (en) | 2008-06-17 | 2009-06-16 | Systems and compositions for color stabilization of polymer |
Publications (2)
Publication Number | Publication Date |
---|---|
CN102066425A true CN102066425A (zh) | 2011-05-18 |
CN102066425B CN102066425B (zh) | 2013-02-20 |
Family
ID=41415382
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN2009801229797A Expired - Fee Related CN102066425B (zh) | 2008-06-17 | 2009-06-16 | 用于聚合物的颜色稳定化的体系和组合物 |
Country Status (13)
Country | Link |
---|---|
US (1) | US8287765B2 (zh) |
EP (1) | EP2288625B1 (zh) |
KR (1) | KR101321095B1 (zh) |
CN (1) | CN102066425B (zh) |
BR (1) | BRPI0915317A2 (zh) |
CA (1) | CA2727464C (zh) |
ES (1) | ES2443793T3 (zh) |
MX (1) | MX2010013935A (zh) |
PL (1) | PL2288625T3 (zh) |
PT (1) | PT2288625E (zh) |
SI (1) | SI2288625T1 (zh) |
TW (1) | TWI444419B (zh) |
WO (1) | WO2009155279A1 (zh) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2524944A1 (en) | 2011-05-19 | 2012-11-21 | Trading and Marketing Consultants Palmarole AG | Colouring composition for thermoplastic polymers and process of preparing and using same |
Family Cites Families (39)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3001969A (en) * | 1957-07-08 | 1961-09-26 | Eastman Kodak Co | Heat-stabilization of polyethylene and poly-mono-alpha-olefins using certain zinc dialkyldithiocarbamates |
DE1241979B (de) | 1962-12-21 | 1967-06-08 | Eastman Kodak Co | Stabilisierte Formmassen aus Poly-alpha-olefinen |
US3376250A (en) * | 1965-01-22 | 1968-04-02 | Eastman Kodak Co | Ultraviolet light stabilized, zinc oxide pigmented, 1-olefin resin composition |
US3413262A (en) * | 1965-04-08 | 1968-11-26 | Argus Chem | Stabilization of polypropylene against degradative deterioration on long-term exposure to elevated temperatures |
US3454523A (en) * | 1966-06-06 | 1969-07-08 | Eastman Kodak Co | Poly-alpha-olefins containing a stabilizer composition |
US3537967A (en) * | 1966-07-29 | 1970-11-03 | Dart Ind Inc | Radiation sterilized,thiodipropionic acid ester stabilized,propylene polymers |
US3454521A (en) * | 1967-06-14 | 1969-07-08 | Eastman Kodak Co | Poly-alpha-olefins stabilized with a synergistic combination |
US3700750A (en) * | 1970-01-07 | 1972-10-24 | Sumitomo Chemical Co | Stabilized polyphenylene oxide composition |
US3856747A (en) * | 1972-08-07 | 1974-12-24 | Mobil Oil Corp | Programmed degradation of polyolefins |
US4238575A (en) * | 1979-02-12 | 1980-12-09 | Ciba-Geigy Corporation | Stabilized compositions containing polymeric thiosynergists |
US4464496A (en) * | 1982-03-26 | 1984-08-07 | Uniroyal, Inc. | Non-yellowing polymer composition |
US4469909A (en) * | 1982-06-18 | 1984-09-04 | Mobil Oil Corporation | Heavy aromatics process |
US4590231A (en) * | 1983-10-11 | 1986-05-20 | Ciba-Geigy Corporation | Polyolefin compositions stabilized against degradation using hydroxylamine derivatives |
US4575522A (en) * | 1985-03-07 | 1986-03-11 | Hydril Company | Rubber composition for geothermal application |
IT1190366B (it) | 1985-06-19 | 1988-02-16 | Bozetto Ind Chim | Composizioni polimeriche stabilizzate e sistemi stabilizzanti adatti allo scopo |
US4853154A (en) * | 1985-11-27 | 1989-08-01 | Shell Oil Company | Low smoke polypropylene insulation compositions |
JPH083006B2 (ja) * | 1987-07-31 | 1996-01-17 | 旭電化工業株式会社 | 安定化されたポリプロピレン系樹脂組成物 |
US4797511A (en) * | 1987-09-25 | 1989-01-10 | Uniroyal Chemical Company, Inc. | Polyethylene stabilized by mixture of hindered phenol and amine antioxidants |
IT1215943B (it) * | 1988-02-24 | 1990-02-22 | Enichem Sintesi | Composizione stabilizzante per polimeri organici. |
US5216056A (en) * | 1992-03-30 | 1993-06-01 | R. T. Vanderbilt Company, Inc. | Color stabilization of filled polyolefins |
EP0736064A1 (en) * | 1993-12-02 | 1996-10-09 | Bayer Antwerpen N.V. | Stabilizer system for non yellowing polymer composition |
US5624982A (en) * | 1993-12-02 | 1997-04-29 | Bayer Antwerpen Sa/Nv | Stabilizer system for non yellowing polymer composition |
US6362264B1 (en) * | 1996-12-20 | 2002-03-26 | Ck Witco Corporation | Stabilizer for food contact and medical grade PVC |
US6015854A (en) * | 1997-10-24 | 2000-01-18 | Union Carbide Chemicals & Plastics Technology Corporation | Polypropylene impact copolymers with high clarity |
WO1999023154A1 (en) | 1997-10-30 | 1999-05-14 | Uniroyal Chemical Company, Inc. | Thermoplastic resins stabilized by blends of dithiocarbamates and amines or phenols |
US6080929A (en) * | 1998-03-25 | 2000-06-27 | Uniroyal Chemical Company, Inc. | Stabilized filler compositions for cable and wire |
WO1999057190A1 (en) | 1998-05-04 | 1999-11-11 | R.T. Vanderbilt Company, Inc. | Stabilizer compositions for polymeric insulations |
US6277907B1 (en) * | 1998-11-09 | 2001-08-21 | Uniroyal Chemical Company, Inc. | Thermoplastic resins stabilized by blends of sterically hindered phenols, secondary amines, and thioethers |
GB0004437D0 (en) * | 2000-02-25 | 2000-04-12 | Clariant Int Ltd | Synergistic combinations of phenolic antioxidants |
US6538056B1 (en) * | 2000-10-10 | 2003-03-25 | Clariant International Ltd. | Polyolefin articles with long-term elevated temperature stability |
US6790888B2 (en) * | 2001-05-16 | 2004-09-14 | Crompton Corporation | Thermoplastic resins in contact with metals or metal salts stabilized by blends of dithiocarbamates and metal deactivators |
US6806304B2 (en) * | 2001-09-27 | 2004-10-19 | Cytec Technology Corp. | Process for improving the shelf life of a hindered phenol antioxidant |
JP2003331999A (ja) * | 2002-05-09 | 2003-11-21 | Honda Tsushin Kogyo Co Ltd | 電気コネクタ |
US6911492B2 (en) * | 2003-01-16 | 2005-06-28 | Ferro Corporation | Discoloration resistant polypropylene blend |
KR101104780B1 (ko) * | 2003-11-03 | 2012-01-13 | 시바 홀딩 인코포레이티드 | 할로겐 함유 중합체용 안정화제 조성물 |
WO2005116134A1 (ja) * | 2004-05-28 | 2005-12-08 | Kaneka Corporation | 硬化性組成物およびその硬化物 |
US20060058435A1 (en) * | 2004-09-16 | 2006-03-16 | Szekely Peter L | Slush molded elastomeric layer |
US8008388B2 (en) * | 2005-12-14 | 2011-08-30 | Ferro Corporation | Weatherable glass fiber reinforced polyolefin composition |
US7411407B2 (en) * | 2006-10-13 | 2008-08-12 | Agilent Technologies, Inc. | Testing target resistances in circuit assemblies |
-
2009
- 2009-01-16 US US12/354,902 patent/US8287765B2/en active Active
- 2009-06-16 PL PL09767588T patent/PL2288625T3/pl unknown
- 2009-06-16 PT PT97675888T patent/PT2288625E/pt unknown
- 2009-06-16 SI SI200930833T patent/SI2288625T1/sl unknown
- 2009-06-16 KR KR1020117000967A patent/KR101321095B1/ko active IP Right Grant
- 2009-06-16 CN CN2009801229797A patent/CN102066425B/zh not_active Expired - Fee Related
- 2009-06-16 MX MX2010013935A patent/MX2010013935A/es active IP Right Grant
- 2009-06-16 WO PCT/US2009/047487 patent/WO2009155279A1/en active Application Filing
- 2009-06-16 CA CA2727464A patent/CA2727464C/en not_active Expired - Fee Related
- 2009-06-16 ES ES09767588.8T patent/ES2443793T3/es active Active
- 2009-06-16 EP EP09767588.8A patent/EP2288625B1/en not_active Not-in-force
- 2009-06-16 BR BRPI0915317A patent/BRPI0915317A2/pt active Search and Examination
- 2009-06-17 TW TW098120221A patent/TWI444419B/zh not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
WO2009155279A1 (en) | 2009-12-23 |
CA2727464A1 (en) | 2009-12-23 |
MX2010013935A (es) | 2011-03-29 |
BRPI0915317A2 (pt) | 2015-10-27 |
US20090312465A1 (en) | 2009-12-17 |
CA2727464C (en) | 2013-08-13 |
KR20110018444A (ko) | 2011-02-23 |
ES2443793T3 (es) | 2014-02-20 |
CN102066425B (zh) | 2013-02-20 |
EP2288625B1 (en) | 2013-10-23 |
EP2288625A4 (en) | 2012-03-21 |
KR101321095B1 (ko) | 2013-10-30 |
SI2288625T1 (sl) | 2014-06-30 |
TW201005017A (en) | 2010-02-01 |
PL2288625T3 (pl) | 2014-04-30 |
EP2288625A1 (en) | 2011-03-02 |
US8287765B2 (en) | 2012-10-16 |
TWI444419B (zh) | 2014-07-11 |
PT2288625E (pt) | 2014-01-29 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN100408619C (zh) | 稳定含有交联硅烷基的聚合物 | |
US4443572A (en) | Polyolefin stabilizers | |
US7452933B2 (en) | Cross-linked polyethylene having excellent inhibition of sweat-out and insulation properties | |
EP3119861B1 (en) | Corrosion resistant lubricant | |
KR100727207B1 (ko) | 스웨트-아웃 억제 및 전기 절연특성이 우수한 가교 폴리에틸렌 조성물 | |
CN102066425B (zh) | 用于聚合物的颜色稳定化的体系和组合物 | |
SK287686B6 (sk) | Izolačná kompozícia na strednonapäťové a vysokonapäťové káble a spôsob jej výroby | |
JP6094019B2 (ja) | ポリカーボネート樹脂組成物 | |
JPWO2004092263A1 (ja) | ポリオレフィン系樹脂組成物及びそれを用いた樹脂成形体の組み合わせ | |
AU615943B2 (en) | Polypropylene stabilized against oxidative degradation with mixtures of diarylamine derivatives and sterically hindered phenols | |
GB1593902A (en) | Stabilisation of polymers | |
KR101454556B1 (ko) | 실험계획법 기반 고압/초고압 케이블용 반도전층 수지 조성물 | |
KR101658309B1 (ko) | 초고압 전력선용 반도전층 수지 조성물 및 그 제조방법 | |
KR102641968B1 (ko) | 고압 케이블의 반도전층 조성물 | |
WO2016132156A1 (en) | Low temperature dielectric fluid compositions | |
EP0274200A2 (en) | Polyolefins stabilized against oxidative degradation with mixtures of aralkyl-substituted diarylamines and sterically hindered phosphites | |
CN107001725B (zh) | 交联性树脂组合物及电线/线缆 | |
KR100714094B1 (ko) | 폴리부타디엔조성물및폴리부타디엔의안정화방법 | |
US20050148715A1 (en) | Water tree resistant cable | |
JPH0831241A (ja) | 電力ケーブル | |
CN116848189A (zh) | 具有优异的可加工性的用于超高压电缆的半导体树脂组合物、及其制备方法 | |
WO2009145436A1 (en) | Cable supporting high water crosslinking temperatures and strippability | |
KR20050091201A (ko) | 열가소성 폴리에스테르 엘라스토머 조성물 및 이의 제조방법 | |
JPS6139341B2 (zh) | ||
JPH08109326A (ja) | 給電部品用組成物 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
ASS | Succession or assignment of patent right |
Owner name: VANDERBILT MINING CO., LTD. Free format text: FORMER OWNER: VANDERBILT CO. R. T. Effective date: 20130816 Owner name: VANDERBILT CHEMICALS CO., LTD. Free format text: FORMER OWNER: VANDERBILT MINING CO., LTD. Effective date: 20130816 |
|
C41 | Transfer of patent application or patent right or utility model | ||
TR01 | Transfer of patent right |
Effective date of registration: 20130816 Address after: American Connecticut Patentee after: VANDERBILT CHEMICALS, LLC Address before: American Connecticut Patentee before: Vanderbilt minerals Ltd. Effective date of registration: 20130816 Address after: American Connecticut Patentee after: Vanderbilt minerals Ltd. Address before: American Connecticut Patentee before: R.T. VANDERBILT Co.,Inc. |
|
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20130220 Termination date: 20200616 |
|
CF01 | Termination of patent right due to non-payment of annual fee |