CN102010506A - 一种新的石油发酵尼龙1212合成工艺 - Google Patents
一种新的石油发酵尼龙1212合成工艺 Download PDFInfo
- Publication number
- CN102010506A CN102010506A CN 201010160308 CN201010160308A CN102010506A CN 102010506 A CN102010506 A CN 102010506A CN 201010160308 CN201010160308 CN 201010160308 CN 201010160308 A CN201010160308 A CN 201010160308A CN 102010506 A CN102010506 A CN 102010506A
- Authority
- CN
- China
- Prior art keywords
- petroleum
- nylon
- carbon
- reaction
- fermentation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003208 petroleum Substances 0.000 title claims abstract description 96
- 239000004677 Nylon Substances 0.000 title claims abstract description 64
- 229920001778 nylon Polymers 0.000 title claims abstract description 64
- 238000000855 fermentation Methods 0.000 title claims abstract description 56
- 230000004151 fermentation Effects 0.000 title claims abstract description 56
- 238000000034 method Methods 0.000 title claims abstract description 30
- 238000003786 synthesis reaction Methods 0.000 title claims abstract description 18
- 230000015572 biosynthetic process Effects 0.000 title claims abstract description 17
- TVIDDXQYHWJXFK-UHFFFAOYSA-N dodecanedioic acid Chemical compound OC(=O)CCCCCCCCCCC(O)=O TVIDDXQYHWJXFK-UHFFFAOYSA-N 0.000 claims abstract description 57
- 238000006243 chemical reaction Methods 0.000 claims abstract description 48
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims abstract description 31
- 150000003839 salts Chemical class 0.000 claims abstract description 24
- 229910021529 ammonia Inorganic materials 0.000 claims abstract description 15
- 239000003054 catalyst Substances 0.000 claims abstract description 13
- 230000008569 process Effects 0.000 claims abstract description 9
- 238000000926 separation method Methods 0.000 claims abstract description 6
- 229910052799 carbon Inorganic materials 0.000 claims description 74
- -1 carbon diamines Chemical class 0.000 claims description 42
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 36
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 35
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 32
- NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 claims description 30
- 229910052739 hydrogen Inorganic materials 0.000 claims description 26
- 239000001257 hydrogen Substances 0.000 claims description 26
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 24
- 238000005516 engineering process Methods 0.000 claims description 22
- 238000005984 hydrogenation reaction Methods 0.000 claims description 19
- 239000003795 chemical substances by application Substances 0.000 claims description 18
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 16
- 230000003712 anti-aging effect Effects 0.000 claims description 16
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 15
- 229910052759 nickel Inorganic materials 0.000 claims description 12
- SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 claims description 11
- 150000002431 hydrogen Chemical class 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 11
- 238000003756 stirring Methods 0.000 claims description 11
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 claims description 11
- 229910021626 Tin(II) chloride Inorganic materials 0.000 claims description 10
- 239000007789 gas Substances 0.000 claims description 10
- 238000009413 insulation Methods 0.000 claims description 10
- 239000007788 liquid Substances 0.000 claims description 10
- 229960004839 potassium iodide Drugs 0.000 claims description 10
- 235000007715 potassium iodide Nutrition 0.000 claims description 10
- 235000011150 stannous chloride Nutrition 0.000 claims description 10
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical group C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 claims description 10
- AXZWODMDQAVCJE-UHFFFAOYSA-L tin(II) chloride (anhydrous) Chemical compound [Cl-].[Cl-].[Sn+2] AXZWODMDQAVCJE-UHFFFAOYSA-L 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 238000007333 cyanation reaction Methods 0.000 claims description 9
- 238000006386 neutralization reaction Methods 0.000 claims description 9
- 238000006116 polymerization reaction Methods 0.000 claims description 6
- 230000035484 reaction time Effects 0.000 claims description 6
- 238000007259 addition reaction Methods 0.000 claims description 5
- 238000005266 casting Methods 0.000 claims description 5
- 230000004087 circulation Effects 0.000 claims description 5
- 239000002826 coolant Substances 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 5
- 230000006837 decompression Effects 0.000 claims description 5
- 230000018044 dehydration Effects 0.000 claims description 5
- 238000006297 dehydration reaction Methods 0.000 claims description 5
- 150000004985 diamines Chemical class 0.000 claims description 5
- 238000007599 discharging Methods 0.000 claims description 5
- 238000004090 dissolution Methods 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 5
- 238000005194 fractionation Methods 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- 238000005453 pelletization Methods 0.000 claims description 5
- 239000000376 reactant Substances 0.000 claims description 5
- 238000003860 storage Methods 0.000 claims description 5
- 238000000108 ultra-filtration Methods 0.000 claims description 5
- 238000013022 venting Methods 0.000 claims description 5
- 238000004821 distillation Methods 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 claims description 4
- 238000012545 processing Methods 0.000 claims description 4
- YLLIGHVCTUPGEH-UHFFFAOYSA-M potassium;ethanol;hydroxide Chemical compound [OH-].[K+].CCO YLLIGHVCTUPGEH-UHFFFAOYSA-M 0.000 claims description 2
- 239000002994 raw material Substances 0.000 abstract description 8
- 230000006872 improvement Effects 0.000 abstract description 5
- 238000009776 industrial production Methods 0.000 abstract description 5
- 238000004519 manufacturing process Methods 0.000 abstract description 5
- 239000002904 solvent Substances 0.000 abstract description 4
- 238000000746 purification Methods 0.000 abstract description 3
- 238000000605 extraction Methods 0.000 abstract description 2
- 238000001914 filtration Methods 0.000 abstract description 2
- 238000005457 optimization Methods 0.000 abstract description 2
- 238000011084 recovery Methods 0.000 abstract description 2
- 238000007670 refining Methods 0.000 abstract description 2
- 150000001412 amines Chemical class 0.000 abstract 2
- 150000002825 nitriles Chemical class 0.000 abstract 2
- QFGCFKJIPBRJGM-UHFFFAOYSA-N 12-[(2-methylpropan-2-yl)oxy]-12-oxododecanoic acid Chemical compound CC(C)(C)OC(=O)CCCCCCCCCCC(O)=O QFGCFKJIPBRJGM-UHFFFAOYSA-N 0.000 abstract 1
- 125000004122 cyclic group Chemical group 0.000 abstract 1
- 239000000543 intermediate Substances 0.000 abstract 1
- 230000003472 neutralizing effect Effects 0.000 abstract 1
- 230000000379 polymerizing effect Effects 0.000 abstract 1
- 239000000047 product Substances 0.000 description 16
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 12
- 239000002131 composite material Substances 0.000 description 9
- 229920006351 engineering plastic Polymers 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 229920001971 elastomer Polymers 0.000 description 3
- JEIPFZHSYJVQDO-UHFFFAOYSA-N ferric oxide Chemical compound O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 3
- 239000005060 rubber Substances 0.000 description 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- OCKPCBLVNKHBMX-UHFFFAOYSA-N butylbenzene Chemical compound CCCCC1=CC=CC=C1 OCKPCBLVNKHBMX-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000002932 luster Substances 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 230000009466 transformation Effects 0.000 description 2
- 241001044684 Amadina fasciata Species 0.000 description 1
- 208000019901 Anxiety disease Diseases 0.000 description 1
- JHWNWJKBPDFINM-UHFFFAOYSA-N Laurolactam Chemical compound O=C1CCCCCCCCCCCN1 JHWNWJKBPDFINM-UHFFFAOYSA-N 0.000 description 1
- 229920000299 Nylon 12 Polymers 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 238000005576 amination reaction Methods 0.000 description 1
- 230000002929 anti-fatigue Effects 0.000 description 1
- 230000036506 anxiety Effects 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 1
- KVNRLNFWIYMESJ-UHFFFAOYSA-N butyronitrile Chemical compound CCCC#N KVNRLNFWIYMESJ-UHFFFAOYSA-N 0.000 description 1
- 238000004517 catalytic hydrocracking Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 229920003193 cis-1,4-polybutadiene polymer Polymers 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 210000003746 feather Anatomy 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 229920001084 poly(chloroprene) Polymers 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 238000010189 synthetic method Methods 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
Landscapes
- Polyamides (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
Abstract
Description
Claims (8)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2010101603084A CN102010506B (zh) | 2010-04-30 | 2010-04-30 | 一种石油发酵尼龙1212合成工艺 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2010101603084A CN102010506B (zh) | 2010-04-30 | 2010-04-30 | 一种石油发酵尼龙1212合成工艺 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN102010506A true CN102010506A (zh) | 2011-04-13 |
CN102010506B CN102010506B (zh) | 2012-08-08 |
Family
ID=43840850
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN2010101603084A Active CN102010506B (zh) | 2010-04-30 | 2010-04-30 | 一种石油发酵尼龙1212合成工艺 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN102010506B (zh) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104327265A (zh) * | 2014-09-17 | 2015-02-04 | 河南省君恒实业集团生物科技有限公司 | 一种长碳链半芳香尼龙pa14t及其制备方法 |
CN109180931A (zh) * | 2018-08-16 | 2019-01-11 | 郑州大学 | 一种长碳链尼龙pa1313的制备方法及产品 |
CN114426664A (zh) * | 2020-10-10 | 2022-05-03 | 中国石油化工股份有限公司 | 一种尼龙612盐的合成方法及装置 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5416189A (en) * | 1992-11-04 | 1995-05-16 | Solvay (Societe Anonyme) | Process for the synthesis of polyamides |
CN1255507A (zh) * | 1999-07-02 | 2000-06-07 | 郑州大学 | 石油发酵尼龙1212及其合成工艺 |
-
2010
- 2010-04-30 CN CN2010101603084A patent/CN102010506B/zh active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5416189A (en) * | 1992-11-04 | 1995-05-16 | Solvay (Societe Anonyme) | Process for the synthesis of polyamides |
CN1255507A (zh) * | 1999-07-02 | 2000-06-07 | 郑州大学 | 石油发酵尼龙1212及其合成工艺 |
Non-Patent Citations (1)
Title |
---|
《精细石油化工》 20070731 姜涛等 十一碳二元腈的合成 4-6 1-8 第24卷, 第4期 2 * |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104327265A (zh) * | 2014-09-17 | 2015-02-04 | 河南省君恒实业集团生物科技有限公司 | 一种长碳链半芳香尼龙pa14t及其制备方法 |
CN104447350A (zh) * | 2014-09-17 | 2015-03-25 | 河南省君恒实业集团生物科技有限公司 | 一种制备十四碳二元胺及长碳链尼龙pa1414的方法 |
CN104327265B (zh) * | 2014-09-17 | 2016-09-07 | 河南省君恒实业集团生物科技有限公司 | 一种长碳链半芳香尼龙pa14t及其制备方法 |
CN109180931A (zh) * | 2018-08-16 | 2019-01-11 | 郑州大学 | 一种长碳链尼龙pa1313的制备方法及产品 |
CN109180931B (zh) * | 2018-08-16 | 2021-02-02 | 郑州大学 | 一种长碳链尼龙pa1313的制备方法及产品 |
CN114426664A (zh) * | 2020-10-10 | 2022-05-03 | 中国石油化工股份有限公司 | 一种尼龙612盐的合成方法及装置 |
CN114426664B (zh) * | 2020-10-10 | 2024-04-05 | 中国石油化工股份有限公司 | 一种尼龙612盐的合成方法及装置 |
Also Published As
Publication number | Publication date |
---|---|
CN102010506B (zh) | 2012-08-08 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN102010506B (zh) | 一种石油发酵尼龙1212合成工艺 | |
CN102964278B (zh) | 连续催化加氢还原制备clt酸的方法 | |
CN101684064B (zh) | 一种二氢月桂烯水合反应生产二氢月桂烯醇的绿色工艺 | |
CN104402774B (zh) | 一种连续催化加氢还原制备clt酸的方法 | |
CN104447350A (zh) | 一种制备十四碳二元胺及长碳链尼龙pa1414的方法 | |
CN104003863B (zh) | 一种安息香的绿色合成方法 | |
CN102320982B (zh) | 多釜串联生产邻硝基苯胺的方法 | |
CN109180931B (zh) | 一种长碳链尼龙pa1313的制备方法及产品 | |
CN102796011A (zh) | 一种对氨基二苯胺的制备方法 | |
CN108689839A (zh) | 一种利用甲酸、乙酸混合物生产甲酸环己酯和乙酸环己酯的方法 | |
CN101177403A (zh) | 催化裂解制备n-二甲氨基丙基甲基丙烯酰胺方法 | |
CN102285861A (zh) | 一种液相法多相催化苯选择加氢制备环己烯反应装置 | |
CN1095479C (zh) | 石油发酵尼龙1212合成工艺 | |
CN101880458B (zh) | 一种制备尼龙1212的工艺方法 | |
CN100422238C (zh) | 一种合成尼龙612的新工艺 | |
CN108516934A (zh) | 一种隔壁反应精馏生产甲酸环己酯的生产工艺 | |
CN102336672B (zh) | 生产异戊胺的方法 | |
CN113956180B (zh) | 一种己二腈的合成方法 | |
CN102850299B (zh) | 一种(甲基)丙烯酸缩水甘油酯的制备方法 | |
CN1202195C (zh) | 长碳链尼龙热熔胶及其合成方法 | |
CN108373412B (zh) | 连续化生产丁二酰丁二酸二甲酯的方法和设备 | |
CN111943873A (zh) | 一种催化反应精馏合成高酯交换率间苯二甲酸双羟乙酯-5-磺酸钠的半连续工艺和装置 | |
CN113072461A (zh) | 丁酮肟的制备方法 | |
CN1289788A (zh) | 石油发酵尼龙1111及其合成工艺 | |
CN111943872A (zh) | 一种催化反应精馏合成高酯交换率间苯二甲酸双羟乙酯-5-磺酸钠的连续工艺和装置 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
ASS | Succession or assignment of patent right |
Owner name: ZHANG AILIN Free format text: FORMER OWNER: SHANDONG HILEAD BIOTECHNOLOGY CO., LTD. Effective date: 20111009 |
|
C41 | Transfer of patent application or patent right or utility model | ||
TA01 | Transfer of patent application right |
Effective date of registration: 20111009 Address after: 265200 Shandong Province, Laiyang City Emei Road Economic Development Zone No. 1 Applicant after: Zhang Ailin Address before: 265200 Shandong Province, Laiyang City Emei Road Economic Development Zone No. 1 Applicant before: Shandong Hilead Biotechnology Co., Ltd. |
|
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
PP01 | Preservation of patent right |
Effective date of registration: 20130207 Granted publication date: 20120808 |
|
RINS | Preservation of patent right or utility model and its discharge | ||
PD01 | Discharge of preservation of patent |
Date of cancellation: 20130424 Granted publication date: 20120808 |
|
RINS | Preservation of patent right or utility model and its discharge | ||
TR01 | Transfer of patent right |
Effective date of registration: 20190801 Address after: Room 801, Poly Center, No. 6 Qingda Third Road, Laoshan District, Qingdao City, Shandong Province Patentee after: Qingdao Think Tank Biotechnology Co., Ltd. Address before: 265200 Shandong Province, Laiyang City Emei Road Economic Development Zone No. 1 Patentee before: Zhang Ailin |
|
TR01 | Transfer of patent right |