CN102010261A - High-activity earthworm microbe organic fertilizer and preparation method thereof - Google Patents

High-activity earthworm microbe organic fertilizer and preparation method thereof Download PDF

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CN102010261A
CN102010261A CN2010102994812A CN201010299481A CN102010261A CN 102010261 A CN102010261 A CN 102010261A CN 2010102994812 A CN2010102994812 A CN 2010102994812A CN 201010299481 A CN201010299481 A CN 201010299481A CN 102010261 A CN102010261 A CN 102010261A
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fertilizer
earthworm
wormcast
weight percent
organic fertilizer
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王浩铭
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Abstract

The invention discloses a high-activity earthworm microbe organic fertilizer and a preparation method thereof, belonging to a fertilizer and a preparation method thereof. The high-activity earthworm microbe organic fertilizer comprises the following components in percentage by weight: 35-60% of wormcast, 25-45% of compound fertilizer containing nitrogen, phosphorus and potassium and 15-25% of organic silicon. The preparation method comprises the following steps of fully fermenting animal emission and breeding earthworm to obtain wormcast through reproduction and full digestion of earthworm; adding N, P, K, trace-element fertilizer and 20-25% of powdery organic silicon according to the properties of soil and crops, wherein a drought-resistant water-saving bag is attached to each bag of finished fertilizer product. The invention overcomes the defects of inorganic fertilizer and organic fertilizer and combines the advantages to obtain the organic fertilizer with the advantages of high microbe activity, long fertilizer efficiency, water retention and drought resistance.

Description

A kind of high reactivity earthworm microbial organic fertilizer and manufacture method thereof
Technical field
The present invention relates to a kind of fertilizer and manufacture method thereof, relate in particular to a kind of high reactivity earthworm microbial organic fertilizer and manufacture method thereof.
Background technology
The development of society is more and more higher to the demand of agricultural, livestock industry.A large amount of rises of aquaculture, the feces of livestock and poultry discharging increasingly sharpens to the pollution of environment; Chemical fertilizer, agricultural chemicals, the agent of hoeing up weeds etc. are used in a large number, and its residuals has also been accelerated the degeneration of soil property.In view of the situation down, various fertilizers occur in a large number, have solved the problems referred to above to a certain extent, but also there are many problems in itself: there is fertilising back Secondary Fermentation in (1) common fertilizer as fermentation finished thoroughly1 not, produces " burning seedling ", and peculiar smell even foreign odor are arranged.(2) common fertilizer does not all change into simple material soluble in water to various nutrients, be difficult for by plant absorbing, and phosphorus potash fertilizer wretched insufficiency has wherein restricted its fertilizer efficiency.In addition, the growth of the good and bad direct relation crop of microorganism living environment, the microorganism active in the common fertilizer can decay rapidly along with fertilization time, and during the soil lack of water, problem is more serious.
Summary of the invention
Problem at above-mentioned prior art existence, the object of the invention is to provide a kind of high reactivity earthworm microbial organic fertilizer and manufacture method thereof, overcome shortcoming inorganic, fertilizer,, obtain the fertilizer of microorganism active height, fertilizer efficiency length, water conservation drought resisting in conjunction with its advantage.
Technical scheme of the present invention is: a kind of high reactivity earthworm microbial organic fertilizer, prescription comprises the composite fertilizer and the organosilicon of wormcast, nitrogenous, phosphorus and potassium element, its weight percent is: wormcast 35~60%, phosphorus-ammonium compound fertilizer nitrogenous and potassium element is 25~45%, and organosilicon is 15~25%.
Further, in order to realize the effect of fertilizer of the present invention better, this microbial organic fertilizer also comprises trace element fertilizer and resisting drought saving water bag, the weight percent of described prescription is: wormcast 35~50%, the composite fertilizer of nitrogenous, phosphorus and potassium element is 25~35%, organosilicon is 15~24%, and 3~12% trace element fertilizer and at least one resisting drought saving water bag.
In order to realize the effect of this microorganism organic chemical fertilizer better, each weight percentages of components of the composite fertilizer of described nitrogenous, phosphorus and potassium element is: 45~60% urea, 12~25% Repone K and 20~32% calcium superphosphate, each weight percentages of components of described trace element fertilizer is: 5~10% sal epsom, 5~10% boric acid, 60~75% humic acidss and 12~20% ammonium sulfate.As the peculiar concrete prescription of a kind of effect: the weight percent of described prescription is: wormcast 42%, urea 14%, Repone K 4%, calcium superphosphate 7%, sal epsom 0.5%, boric acid 0.5%, humic acids 5%, ammonium sulfate 1%, organosilicon 23%, one of resisting drought saving water bag accounts for 3%.
In order to realize the effect of this microorganism organic chemical fertilizer better, each weight percentages of components of the composite fertilizer of described nitrogenous, phosphorus and potassium element is: 30~45% ammonium chloride, 12~30% Repone K and 28~50% calcium superphosphate, each weight percentages of components of described trace element fertilizer is: 10~20% manganous sulfates and 80~90% humic acidss.As the peculiar concrete prescription of a kind of effect: the weight percent of described prescription is: wormcast 40%, and ammonium chloride 12%, Repone K 7%, calcium superphosphate 14.4%, manganous sulfate 0.6%, humic acids 3%, organosilicon 17%, two of resisting drought saving water bags account for 6%.
In order to realize the effect of this microorganism organic chemical fertilizer better, each weight percentages of components of the composite fertilizer of described nitrogenous, phosphorus and potassium element is: 30~40% ammonium chloride, 25~35% Repone K and 35~45% calcium superphosphate, each weight percentages of components of described trace element fertilizer is: 5~12% boric acid and 88~95% humic acidss.As the peculiar concrete prescription of a kind of effect: the weight percent of described prescription is: wormcast 45%, and ammonium chloride 9%, Repone K 8%, calcium superphosphate 10%, boric acid 0.5%, humic acids 6.5%, organosilicon 18%, one of resisting drought saving water bag accounts for 3%.
A kind of manufacture method of high reactivity earthworm microbial organic fertilizer is characterized in that may further comprise the steps:
1) gather the discharges of various livestock and poultry, after abundant fermentation, the breeding earthworm, allow earthworm fully digest livestock and poultry discharge after the fermentation after, obtain wormcast, then the earthworm adult is separated with wormcast, with the wormcast dried and crushed of collection;
2) according to the characteristic of soil and crop, add nitrogenous, phosphorus and the K composite fertilizer and the trace element fertilizer of Different Weight ratio, and 15~25% powdery organosilicon, and be equipped with some bag resisting drought saving water bags.
Silicoorganic compound in the present invention's prescription, be meant that containing the Si-O key and having an organic radical at least is the compound that directly links to each other with Siliciumatom, also often also is used as silicoorganic compound to those by the compound that oxygen, sulphur, nitrogen etc. make organic radical be connected with Siliciumatom traditionally.Wherein, (be that the polysiloxane that skeleton is formed is the most frequently used Si-O-Si-) with siloxane bond.
Described resisting drought saving water bag is to wrap up some water-absorbing materials by the seepy material net to constitute, described seepy material is a biodegradable fiber net etc., described water-absorbing material is absorbent materials such as super absorbent resin, water-absorbing material of the present invention is to do main raw material by starch and acrylate to make, its outstanding feature is that suction and water storage are surprisingly big, can reach 500~1000 times of own wt.
Described trace element is that plant and animal normal growth and life are necessary, is called " essential trace element " or " micro-nutrient ", is called for short usually " trace element ".Essential trace element has very strong specificity in the intravital effect of plant and animal, is can not lack with irreplaceable, and when undersupply, plant often shows specific shortage symptom, and crop yield reduces, and downgrade may have no harvest when serious.For crop, content is called " trace element " between the essential nutrient element of 0.2~200 milligram/kilogram (by dry restatement).These trace elements comprise boron, manganese, copper, zinc, molybdenum, iron, chlorine etc., kind reaches kind more than 20, all might relating to of the periodic table of elements,, these elements manufacture fertilizer through factory, just are called trace element fertilizer, belong to zinc fertilizer as Zinc Sulphate Heptahydrate, borax, boric acid belong to boron fertilizer, and manganous sulfate belongs to manganese fertilizer, and ammonium molybdate belongs to molydbenum fertilizer, copper sulfate belongs to copper fertilizer, and ferrous sulfate belongs to iron fertilizer etc.
Compare with fertilizer with existing inorganic fertilizer, the present invention has following beneficial effect:
(1) the hollow granular structure of wormcast uniqueness has good water conservation, permeability; Wormcast is rich in humic acid, beneficial microbe colony, 18 seed amino acids and various trace elements fertilizer, and the growth of crop is highly profitable; Wormcast contains antagonistic microbe, can suppress the native generation and the wormcast of falling ill of passing and heavily contain chemistry, heavy metal and antibiotic material in the degradable soil, plays peculiar effect to improving the soil.After using earthworm fertilizer, soil obtains improvement, recovers original biological activity gradually.
(2) organosilicon particular structure, the performance that has had both inorganic materials and organic materials, have fundamental characteristics such as surface tension is low, temperature coefficient of viscosity is little, compressibility is high, gas permeability height, its distinctive molecular structure is preserved moisture, solid fertilizer, as catalyzer fertilizer efficiency is improved greatly, its distinctive physics, chemical property have promoted microorganism living environment, thereby have improved the unit content of microorganism in soil.Organosilyl interpolation also makes earthworm fertilizer have in edatope better to exist space, the combination of organosilicon and wormcast bringing into play one-plus-one greater than two effect.
(3) the resisting drought saving water bag effect playing water conservation, preserve moisture, the moisture content that absorbs in the soil when soil humidity is excessive stores, otherwise discharge, ensured the moisture content that crop growth is an amount of, make farm crop and microorganism reach best growth and breeding environment, also improved the crop drought resistance ability simultaneously widely.
(4) interpolation of nitrogen, phosphorus, potassium and trace element has remedied nitrogen in the fertilizer, phosphorus, potassium equal size defect of insufficient, in conjunction with the advantage of inorganic fertilizer and two kinds of fertilizer of fertilizer, has obtained the microbial organic fertilizer of a kind of active height, fertilizer efficiency length, water conservation drought resisting.
Embodiment
Embodiment as a kind of high reactivity earthworm microbial organic fertilizer prescription of the present invention, a kind of high reactivity earthworm microbial organic fertilizer, prescription comprises wormcast, the composite fertilizer and the organosilicon of nitrogenous, phosphorus and potassium element, its weight percent is: wormcast 35~60%, the composite fertilizer of nitrogenous, phosphorus and potassium element is 25~45%, and organosilicon is 15~25%.
In order to realize the effect of microorganism organic chemical fertilizer of the present invention better, this microorganism organic chemical fertilizer also comprises trace element fertilizer and resisting drought saving water bag, the weight percent of described prescription is: wormcast 35~50%, the composite fertilizer of nitrogenous, phosphorus and potassium element is 25~35%, organosilicon is 15~24%, and 3~12% trace element fertilizer and at least one resisting drought saving water bag.
Silicoorganic compound in the present invention's prescription, be meant that containing the Si-O key and having an organic radical at least is the compound that directly links to each other with Siliciumatom, also often also is used as silicoorganic compound to those by the compound that oxygen, sulphur, nitrogen etc. make organic radical be connected with Siliciumatom traditionally.
Described resisting drought saving water bag is to wrap up some water-absorbing materials by the seepy material net to constitute, described seepy material is a biodegradable fiber net etc., described water-absorbing material is absorbent materials such as super absorbent resin, and water-absorbing material of the present invention is to do main raw material by starch and acrylate to make.
Described trace element comprises boron, manganese, copper, zinc, molybdenum, iron, chlorine etc., and kind reaches kind more than 20, and these elements manufacture fertilizer through factory, just are called trace element fertilizer.
Embodiment one
A kind of concrete prescription of the present invention, relatively poor at soil property, relatively drier, farm crop are bigger to nitrogen, phosphorus and potassium element demand, to little situations of micro-demand such as sulphur, calcium, magnesium and boron.The composite fertilizer of nitrogenous in the described prescription, phosphorus and potassium element is urea, Repone K and calcium superphosphate, and its weight percentages of components is: 45~60% urea, 12~25% Repone K and 20~32% calcium superphosphate; Described trace element fertilizer is sal epsom, boric acid, humic acids and ammonium sulfate, and its weight percentages of components is: 5~10% sal epsom, 5~10% boric acid, 60~75% humic acidss and 12~20% ammonium sulfate.At above-mentioned soil property and the peculiar concrete prescription of the special a kind of effect of preparation of farm crop, its weight percent is: wormcast 42%, urea 14%, Repone K 4%, calcium superphosphate 7%, sal epsom 0.5%, boric acid 0.5%, humic acids 5%, ammonium sulfate 1%, organosilicon 23%, 1 of resisting drought saving water bag accounts for 3%.
This prescription has increased the content of the necessary nitrogen of plant growth, phosphorus and potassium element.Described resisting drought saving water bag is to wrap up some water-absorbing materials by the seepy material net to constitute, and described seepy material the present invention selects the biodegradable fiber net for use, and water-absorbing material of the present invention is to do main raw material by starch and acrylate to make.The solid fertilizer effect of the suction of its uniqueness will more help absorption and the growth of crop.Simultaneously also add a spot of trace element fertilizer, guaranteed the necessary growing environment of crop and microorganism.
Embodiment two
As a kind of concrete prescription of the present invention, it is less to be primarily aimed at the soil property water content, the arid area that quantity of precipitation is less, and these places often micronutrient levels are many, and required nitrogen, phosphorus and the potassium elements etc. of plant are less.So the composite fertilizer of nitrogenous, phosphorus and potassium element is ammonium chloride, Repone K and calcium superphosphate in the prescription, it is formed weight percent and is: 30~45% ammonium chloride, 12~30% Repone K and 28~50% calcium superphosphate; Described trace element fertilizer is manganous sulfate and humic acids, and its weight percentages of components is: 10~20% manganous sulfates and 80~90% humic acidss.At above-mentioned soil property and the peculiar concrete prescription of the special a kind of effect of preparation of farm crop, its weight percent is: wormcast 40%, ammonium chloride 12%, Repone K 7%, calcium superphosphate 14.4%, manganous sulfate 0.6%, humic acids 3%, organosilicon 17%, two of resisting drought saving water bags account for 6%.
This prescription has reduced content of elements such as the necessary S of plant growth, Mn and Ca, has increased a resisting drought saving water bag, and the moisture content in the fixing soil guarantees the farm crop normal growth effectively.
Embodiment three
As a kind of concrete prescription of the present invention, be primarily aimed at the less soil property of micronutrient levels, and the less situation of water content in the soil.The composite fertilizer of nitrogenous in the described prescription, phosphorus and potassium element is ammonium chloride, Repone K and calcium superphosphate, and its weight percentages of components is: 30~40% ammonium chloride, 25~35% Repone K and 35~45% calcium superphosphate; Described trace element fertilizer is boric acid and humic acids; Its weight percentages of components is: 5~12% boric acid and 88~95% humic acidss.At above-mentioned soil property and the peculiar concrete prescription of the special a kind of effect of preparation of farm crop, its weight percent is: wormcast 45%, ammonium chloride 9%, Repone K 8%, calcium superphosphate 10%, boric acid 0.5%, humic acids 6.5%, organosilicon 18%, 1 of resisting drought saving water bag accounts for 3%.
A kind of manufacture method of high reactivity earthworm microbial organic fertilizer may further comprise the steps:
1) raise livestock and poultry, as first-selection of the present invention, animals such as raise poultry, ox and sheep are collected the discharge that obtains livestock and poultry, after fully fermenting.
2) breeding earthworm is positioned over earthworm in the discharge of the livestock and poultry after the fermentation, allows earthworm grow therein, to breed, and obtains wormcast, and isolates wormcast, is ground into particle after the wormcast of collecting is dried.
3) according to the characteristic of soil and crop, add the trace element fertilizer of element compoiste fertilizer such as 25~35% nitrogenous, phosphorus and potassium and 3~12% and 15~24% powdery organosilicon, every bag of finished product fertilizer is equipped with some bag resisting drought saving water bags.
As mentioned above, just can well realize the present invention.

Claims (9)

1. a high reactivity earthworm microbial organic fertilizer is characterized in that, mainly is made up of the material of following weight percent:
Wormcast 35~60%,
The composite fertilizer 25~45% of nitrogenous, phosphorus and potassium element,
Organosilicon 15~25%.
2. a kind of high reactivity earthworm microbial organic fertilizer according to claim 1 is characterized in that, also include trace element fertilizer and resisting drought saving water bag, the weight percent of its material is:
Wormcast 35~50%,
The composite fertilizer 25~35% of nitrogenous, phosphorus and potassium element,
Organosilicon 15~24%,
Trace element fertilizer 3~12%,
Resisting drought saving water Bao Yizhi two bags 3~6%.
3. a kind of high reactivity earthworm microbial organic fertilizer according to claim 2 is characterized in that, the composite fertilizer of described nitrogenous, phosphorus and potassium element is made up of the material of following weight percent:
Urea 45~60%,
Repone K 12~25%,
Calcium superphosphate 20~32%,
Described trace element fertilizer is made up of the material of following weight percent:
Sal epsom 5~10%,
Boric acid 5~10%,
Humic acids 60~75%,
Ammonium sulfate 12~20%.
4. a kind of high reactivity earthworm microbial organic fertilizer according to claim 3 is characterized in that the weight percent of described material is:
Wormcast 42%,
Urea 14%,
Repone K 4%,
Calcium superphosphate 7%,
Sal epsom 0.5%,
Boric acid 0.5%,
Humic acids 5%,
Ammonium sulfate 1%,
Organosilicon 23%,
Resisting drought saving water wraps 3%.
5. a kind of high reactivity earthworm microbial organic fertilizer according to claim 2 is characterized in that, the composite fertilizer of described nitrogenous, phosphorus and potassium element is made up of the material of following weight percent:
Ammonium chloride 30~45%,
Repone K 12~30%,
Calcium superphosphate 28~50%,
Described trace element fertilizer is made up of the material of following weight percent:
Manganous sulfate 10~20%,
Humic acids 80~90%.
6. a kind of high reactivity earthworm microbial organic fertilizer according to claim 5 is characterized in that the weight percent of described material is:
Wormcast 40%,
Ammonium chloride 12%,
Repone K 7%,
Calcium superphosphate 14.4%,
Manganous sulfate 0.6%,
Humic acids 3%,
Organosilicon 17%,
Resisting drought saving water bag two bags 6%.
7. a kind of high reactivity earthworm microbial organic fertilizer according to claim 2 is characterized in that, the composite fertilizer of described nitrogenous, phosphorus and potassium element is made up of the material of following weight percent:
Ammonium chloride 30~45%,
Repone K 25~35%,
Calcium superphosphate 35~45%,
Described trace element fertilizer is made up of the material of following weight percent:
Boric acid 5~12%,
Humic acids 88~95%.
8. a kind of high reactivity earthworm microbial organic fertilizer according to claim 7 is characterized in that the weight percent of described material is:
Wormcast 45%,
Ammonium chloride 9%,
Repone K 8%,
Calcium superphosphate 10%,
Boric acid 0.5%,
Humic acids 6.5%,
Organosilicon 18%,
Resisting drought saving water wraps 3%.
9. the manufacture method of the described high reactivity earthworm of claim 1 microbial organic fertilizer is characterized in that may further comprise the steps:
1) gather the discharges of various livestock and poultry, after abundant fermentation, the breeding earthworm, allow earthworm fully digest livestock and poultry discharge after the fermentation after, obtain wormcast, then the earthworm adult is separated with wormcast, with the wormcast dried and crushed of collection;
2), add nitrogenous, phosphorus and the K composite fertilizer and 3~12% trace element fertilizers of 25~35% part by weight, and 15~25% powdery organosilicon, and be equipped with the resisting drought saving water bag of one to two bag according to the characteristic of soil and crop.
CN2010102994812A 2010-10-08 2010-10-08 High-activity earthworm microbe organic fertilizer and preparation method thereof Pending CN102010261A (en)

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102265748A (en) * 2011-05-23 2011-12-07 黄鹰 Method for producing organic vegetables based on earthworm bioengineering technology
CN103214306A (en) * 2013-04-03 2013-07-24 广东省昆虫研究所 Wormcast biological medicine fertilizer and preparation method thereof
CN103254017A (en) * 2013-04-23 2013-08-21 苏州谷力生物科技有限公司 Compound fertilizer
CN103708878A (en) * 2013-12-10 2014-04-09 四川正东农牧集团有限责任公司 Vermicompost organic compound fertilizer capable of being used for ryegrass, and preparation method thereof
CN103951526A (en) * 2014-05-22 2014-07-30 安徽科技学院 Organic and inorganic fertilizers based on vermicompost
CN103951490A (en) * 2014-04-27 2014-07-30 钟茜花 Organic-inorganic biological compound fertilizer for cotton
CN104876668A (en) * 2015-05-20 2015-09-02 贵州大学 Organic and inorganic compound fertilizer for radix pseudostellariae
CN104961608A (en) * 2015-07-14 2015-10-07 镇江贝思特有机活性肥料有限公司 Special fertilizer for cucumbers
CN107082726A (en) * 2017-05-11 2017-08-22 河南龙之锦农业发展有限公司 A kind of preparation method of flue-cured tobacco fertilizer special for organic using wormcast as matrix
CN107935639A (en) * 2017-12-04 2018-04-20 山东庞大生物集团有限公司 The preparation method of efficient calcic organic fertilizer

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1569754A (en) * 2003-07-18 2005-01-26 赵跃国 Biological compound fertilizer of worm cast
JP2005281117A (en) * 2004-03-31 2005-10-13 Yuichi Nishida Earthworm frass soil conditioner type fertilizer using animal- and plant-based industrial waste
CN101602268A (en) * 2009-04-17 2009-12-16 昆山市金鑫塑料制品有限公司 Double-layer air bubble film
CN101607841A (en) * 2009-07-03 2009-12-23 山东农业大学 A kind of mineral manure and organic materials are raised earthworm and are prepared the method for efficient biologic-organic fertilizer
CN101786929A (en) * 2010-03-19 2010-07-28 沈阳尊龙生物技术有限公司 Method utilizing wormcast to manufacture biological organic fertilizer

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1569754A (en) * 2003-07-18 2005-01-26 赵跃国 Biological compound fertilizer of worm cast
JP2005281117A (en) * 2004-03-31 2005-10-13 Yuichi Nishida Earthworm frass soil conditioner type fertilizer using animal- and plant-based industrial waste
CN101602268A (en) * 2009-04-17 2009-12-16 昆山市金鑫塑料制品有限公司 Double-layer air bubble film
CN101607841A (en) * 2009-07-03 2009-12-23 山东农业大学 A kind of mineral manure and organic materials are raised earthworm and are prepared the method for efficient biologic-organic fertilizer
CN101786929A (en) * 2010-03-19 2010-07-28 沈阳尊龙生物技术有限公司 Method utilizing wormcast to manufacture biological organic fertilizer

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102265748A (en) * 2011-05-23 2011-12-07 黄鹰 Method for producing organic vegetables based on earthworm bioengineering technology
CN103214306A (en) * 2013-04-03 2013-07-24 广东省昆虫研究所 Wormcast biological medicine fertilizer and preparation method thereof
CN103254017A (en) * 2013-04-23 2013-08-21 苏州谷力生物科技有限公司 Compound fertilizer
CN103708878A (en) * 2013-12-10 2014-04-09 四川正东农牧集团有限责任公司 Vermicompost organic compound fertilizer capable of being used for ryegrass, and preparation method thereof
CN103951490A (en) * 2014-04-27 2014-07-30 钟茜花 Organic-inorganic biological compound fertilizer for cotton
CN103951526A (en) * 2014-05-22 2014-07-30 安徽科技学院 Organic and inorganic fertilizers based on vermicompost
CN104876668A (en) * 2015-05-20 2015-09-02 贵州大学 Organic and inorganic compound fertilizer for radix pseudostellariae
CN104876668B (en) * 2015-05-20 2018-01-30 贵州大学 A kind of radix pseudostellariae compound organic and inorganic fertilizer
CN104961608A (en) * 2015-07-14 2015-10-07 镇江贝思特有机活性肥料有限公司 Special fertilizer for cucumbers
CN107082726A (en) * 2017-05-11 2017-08-22 河南龙之锦农业发展有限公司 A kind of preparation method of flue-cured tobacco fertilizer special for organic using wormcast as matrix
CN107935639A (en) * 2017-12-04 2018-04-20 山东庞大生物集团有限公司 The preparation method of efficient calcic organic fertilizer

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Application publication date: 20110413