CN102006930B - 亚胺的氢化 - Google Patents

亚胺的氢化 Download PDF

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Publication number
CN102006930B
CN102006930B CN2009801129731A CN200980112973A CN102006930B CN 102006930 B CN102006930 B CN 102006930B CN 2009801129731 A CN2009801129731 A CN 2009801129731A CN 200980112973 A CN200980112973 A CN 200980112973A CN 102006930 B CN102006930 B CN 102006930B
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CN
China
Prior art keywords
formula
imines
diphenyl phosphine
under
methyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
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CN2009801129731A
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English (en)
Chinese (zh)
Other versions
CN102006930A (zh
Inventor
加德夫·拉耶尼肯特·施洛夫
维克拉姆·拉耶尼肯特·施洛夫
比耶·尚卡尔
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UPL Ltd
Original Assignee
United Phosphorus Ltd
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Publication date
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Publication of CN102006930A publication Critical patent/CN102006930A/zh
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Expired - Fee Related legal-status Critical Current
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C233/00—Carboxylic acid amides
    • C07C233/01—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms
    • C07C233/16—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms
    • C07C233/17—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by an acyclic carbon atom
    • C07C233/18—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by an acyclic carbon atom having the carbon atom of the carboxamide group bound to a hydrogen atom or to a carbon atom of an acyclic saturated carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C213/00—Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton
    • C07C213/02—Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton by reactions involving the formation of amino groups from compounds containing hydroxy groups or etherified or esterified hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B2200/00—Indexing scheme relating to specific properties of organic compounds
    • C07B2200/07—Optical isomers

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
CN2009801129731A 2008-04-17 2009-04-16 亚胺的氢化 Expired - Fee Related CN102006930B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
IN877/MUM/2008 2008-04-17
IN877MU2008 2008-04-17
PCT/IN2009/000237 WO2009136409A2 (en) 2008-04-17 2009-04-16 Hydrogenation of imines

Publications (2)

Publication Number Publication Date
CN102006930A CN102006930A (zh) 2011-04-06
CN102006930B true CN102006930B (zh) 2013-09-25

Family

ID=41265115

Family Applications (1)

Application Number Title Priority Date Filing Date
CN2009801129731A Expired - Fee Related CN102006930B (zh) 2008-04-17 2009-04-16 亚胺的氢化

Country Status (10)

Country Link
US (1) US8461386B2 (enExample)
EP (1) EP2265373A4 (enExample)
JP (1) JP2011518150A (enExample)
KR (1) KR101245065B1 (enExample)
CN (1) CN102006930B (enExample)
AU (1) AU2009245307B2 (enExample)
BR (1) BRPI0907343A8 (enExample)
RU (1) RU2476422C2 (enExample)
UA (1) UA100732C2 (enExample)
WO (1) WO2009136409A2 (enExample)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103189341B (zh) * 2010-11-02 2015-06-17 Upl有限公司 用于制备羟基膦配位体的手性中间体
EP2892877B1 (en) * 2012-09-06 2017-06-21 Council of Scientific and Industrial Research Process for the preparation of (s)-2-ethyl-n-(1-methoxypropan -2-yl)-6-methyl aniline
WO2014164801A1 (en) * 2013-03-11 2014-10-09 Rutgers, The State University Of New Jersey Metallorganocatalysis for asymmetric transformations
CN104445068B (zh) * 2014-11-21 2016-09-28 山东侨昌化学有限公司 一种异丙甲草胺生产过程中副产氢气的回收方法
CN108218726B (zh) * 2016-12-14 2020-08-18 浙江省化工研究院有限公司 一种制备(s)-mea胺醚的方法
CN110551034B (zh) * 2018-05-31 2021-11-09 中国科学院大连化学物理研究所 一种酮的不对称还原胺化方法
CN110551037B (zh) * 2018-05-31 2021-11-09 中国科学院大连化学物理研究所 一种铱/手性双膦体系催化亚胺不对称氢化方法
CN109096137A (zh) * 2018-07-30 2018-12-28 山东万豪肥业有限公司 一种精异丙甲草胺的合成方法
EP4003957B1 (en) * 2019-07-25 2024-04-17 Medichem, S.A. Process for the synthesis of n-alkyl-4-pyridinamines
GB202216812D0 (en) * 2022-11-10 2022-12-28 Univ Court Univ St Andrews Process
CN120699067B (zh) * 2025-08-18 2025-11-21 瑞博(苏州)制药有限公司 新型手性二茂铁桥联联萘骨架膦配体及其应用

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007101769A1 (en) * 2006-03-09 2007-09-13 Evonik Degussa Gmbh Process for the hydrogenation of imines

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DD112988A5 (enExample) * 1972-06-06 1975-05-12
EP0256982B1 (de) * 1986-08-04 1991-08-28 Ciba-Geigy Ag Verfahren zur Herstellung von optisch aktiven sekundären Arylaminen
MY109091A (en) * 1992-12-29 1996-11-30 Syngenta Participations Ag Process for the preparation of 2-alkyl-6-methyl-n-(1''''''''- methoxy-2''''''''-propyl)-aniline and a process for the preparation of their chloracetanilides.
ES2123953T3 (es) * 1994-02-02 1999-01-16 Novartis Ag Proceso para la hidrogenacion de iminas.
FR2750423B1 (fr) 1996-06-28 1998-08-14 Rhone Poulenc Chimie Procede d'hydrogenation asymetrique d'un compose cetonique
EP1206427B1 (en) * 1999-08-23 2005-11-09 The Penn State Research Foundation Chiral ligands, transition-metal complexes thereof and uses thereof in asymmetric reactions
DE10223593A1 (de) * 2002-05-27 2003-12-11 Degussa Hydroxydiphosphine und deren Verwendung in der Katalyse
EP1595888A1 (en) * 2004-05-11 2005-11-16 Degussa AG Cycloolefin phosphine ligands and their use in catalysis

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007101769A1 (en) * 2006-03-09 2007-09-13 Evonik Degussa Gmbh Process for the hydrogenation of imines

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
"A new hydrocydiphosphine as a ligand for Rh(Ⅰ)-catalyzed enantioselective hydrogenation;Igor V. Komarov et al.;《Tetrahedron: asymmetry》;20021231;第13卷;第1616页 *

Also Published As

Publication number Publication date
KR20100133370A (ko) 2010-12-21
US20110054217A1 (en) 2011-03-03
AU2009245307B2 (en) 2014-01-30
EP2265373A4 (en) 2014-04-23
BRPI0907343A2 (pt) 2015-07-28
WO2009136409A3 (en) 2009-12-30
RU2476422C2 (ru) 2013-02-27
RU2010145490A (ru) 2012-05-27
JP2011518150A (ja) 2011-06-23
BRPI0907343A8 (pt) 2017-05-23
KR101245065B1 (ko) 2013-03-18
EP2265373A2 (en) 2010-12-29
US8461386B2 (en) 2013-06-11
UA100732C2 (ru) 2013-01-25
WO2009136409A2 (en) 2009-11-12
AU2009245307A1 (en) 2009-11-12
CN102006930A (zh) 2011-04-06

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Owner name: UPL LTD.

Free format text: FORMER NAME: UNITED PHOSPHORUS LTD.

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Address after: Maharashtra

Patentee after: UNITED PHOSPHORUS LIMITED

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CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20130925

Termination date: 20160416