AU2009245307B2 - Hydrogenation of imines - Google Patents

Hydrogenation of imines Download PDF

Info

Publication number
AU2009245307B2
AU2009245307B2 AU2009245307A AU2009245307A AU2009245307B2 AU 2009245307 B2 AU2009245307 B2 AU 2009245307B2 AU 2009245307 A AU2009245307 A AU 2009245307A AU 2009245307 A AU2009245307 A AU 2009245307A AU 2009245307 B2 AU2009245307 B2 AU 2009245307B2
Authority
AU
Australia
Prior art keywords
formula
imine
diphenylphosphino
bis
ligand
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
AU2009245307A
Other languages
English (en)
Other versions
AU2009245307A1 (en
Inventor
Birja Shanker
Jaidev Rajnikant Shroff
Vikram Rajnikant Shroff
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
UPL Ltd
Original Assignee
UPL Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by UPL Ltd filed Critical UPL Ltd
Publication of AU2009245307A1 publication Critical patent/AU2009245307A1/en
Application granted granted Critical
Publication of AU2009245307B2 publication Critical patent/AU2009245307B2/en
Assigned to UPL LIMITED reassignment UPL LIMITED Alteration of Name(s) of Applicant(s) under S113 Assignors: UNITED PHOSPHORUS LIMITED
Ceased legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C233/00—Carboxylic acid amides
    • C07C233/01—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms
    • C07C233/16—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms
    • C07C233/17—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by an acyclic carbon atom
    • C07C233/18—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by an acyclic carbon atom having the carbon atom of the carboxamide group bound to a hydrogen atom or to a carbon atom of an acyclic saturated carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C213/00—Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton
    • C07C213/02—Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton by reactions involving the formation of amino groups from compounds containing hydroxy groups or etherified or esterified hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B2200/00—Indexing scheme relating to specific properties of organic compounds
    • C07B2200/07—Optical isomers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
AU2009245307A 2008-04-17 2009-04-16 Hydrogenation of imines Ceased AU2009245307B2 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
IN877/MUM/2008 2008-04-17
IN877MU2008 2008-04-17
PCT/IN2009/000237 WO2009136409A2 (en) 2008-04-17 2009-04-16 Hydrogenation of imines

Publications (2)

Publication Number Publication Date
AU2009245307A1 AU2009245307A1 (en) 2009-11-12
AU2009245307B2 true AU2009245307B2 (en) 2014-01-30

Family

ID=41265115

Family Applications (1)

Application Number Title Priority Date Filing Date
AU2009245307A Ceased AU2009245307B2 (en) 2008-04-17 2009-04-16 Hydrogenation of imines

Country Status (10)

Country Link
US (1) US8461386B2 (enExample)
EP (1) EP2265373A4 (enExample)
JP (1) JP2011518150A (enExample)
KR (1) KR101245065B1 (enExample)
CN (1) CN102006930B (enExample)
AU (1) AU2009245307B2 (enExample)
BR (1) BRPI0907343A8 (enExample)
RU (1) RU2476422C2 (enExample)
UA (1) UA100732C2 (enExample)
WO (1) WO2009136409A2 (enExample)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103189341B (zh) * 2010-11-02 2015-06-17 Upl有限公司 用于制备羟基膦配位体的手性中间体
EP2892877B1 (en) * 2012-09-06 2017-06-21 Council of Scientific and Industrial Research Process for the preparation of (s)-2-ethyl-n-(1-methoxypropan -2-yl)-6-methyl aniline
WO2014164801A1 (en) * 2013-03-11 2014-10-09 Rutgers, The State University Of New Jersey Metallorganocatalysis for asymmetric transformations
CN104445068B (zh) * 2014-11-21 2016-09-28 山东侨昌化学有限公司 一种异丙甲草胺生产过程中副产氢气的回收方法
CN108218726B (zh) * 2016-12-14 2020-08-18 浙江省化工研究院有限公司 一种制备(s)-mea胺醚的方法
CN110551034B (zh) * 2018-05-31 2021-11-09 中国科学院大连化学物理研究所 一种酮的不对称还原胺化方法
CN110551037B (zh) * 2018-05-31 2021-11-09 中国科学院大连化学物理研究所 一种铱/手性双膦体系催化亚胺不对称氢化方法
CN109096137A (zh) * 2018-07-30 2018-12-28 山东万豪肥业有限公司 一种精异丙甲草胺的合成方法
EP4003957B1 (en) * 2019-07-25 2024-04-17 Medichem, S.A. Process for the synthesis of n-alkyl-4-pyridinamines
GB202216812D0 (en) * 2022-11-10 2022-12-28 Univ Court Univ St Andrews Process
CN120699067B (zh) * 2025-08-18 2025-11-21 瑞博(苏州)制药有限公司 新型手性二茂铁桥联联萘骨架膦配体及其应用

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DD112988A5 (enExample) * 1972-06-06 1975-05-12
EP0256982B1 (de) * 1986-08-04 1991-08-28 Ciba-Geigy Ag Verfahren zur Herstellung von optisch aktiven sekundären Arylaminen
MY109091A (en) * 1992-12-29 1996-11-30 Syngenta Participations Ag Process for the preparation of 2-alkyl-6-methyl-n-(1''''''''- methoxy-2''''''''-propyl)-aniline and a process for the preparation of their chloracetanilides.
ES2123953T3 (es) * 1994-02-02 1999-01-16 Novartis Ag Proceso para la hidrogenacion de iminas.
FR2750423B1 (fr) 1996-06-28 1998-08-14 Rhone Poulenc Chimie Procede d'hydrogenation asymetrique d'un compose cetonique
EP1206427B1 (en) * 1999-08-23 2005-11-09 The Penn State Research Foundation Chiral ligands, transition-metal complexes thereof and uses thereof in asymmetric reactions
DE10223593A1 (de) * 2002-05-27 2003-12-11 Degussa Hydroxydiphosphine und deren Verwendung in der Katalyse
EP1595888A1 (en) * 2004-05-11 2005-11-16 Degussa AG Cycloolefin phosphine ligands and their use in catalysis
US20070213540A1 (en) 2006-03-09 2007-09-13 Degussa Ag Process for the hydrogenation of imines

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
BLASER, H-U. et al., 'Selective hydrogenation for fine chemicals: Recent trends and new developments', Advanced Synthesis and Catalysis, 2003, Vol. 345, pages 103 -151. *
BLASER, H-U. et al., 'Solvias Josiphos ligands:from discovery to technical applications', Topics in Catalysis, 2002, Vol. 19, No. 1, pages 3-16. *

Also Published As

Publication number Publication date
KR20100133370A (ko) 2010-12-21
US20110054217A1 (en) 2011-03-03
EP2265373A4 (en) 2014-04-23
BRPI0907343A2 (pt) 2015-07-28
WO2009136409A3 (en) 2009-12-30
RU2476422C2 (ru) 2013-02-27
RU2010145490A (ru) 2012-05-27
JP2011518150A (ja) 2011-06-23
BRPI0907343A8 (pt) 2017-05-23
KR101245065B1 (ko) 2013-03-18
EP2265373A2 (en) 2010-12-29
CN102006930B (zh) 2013-09-25
US8461386B2 (en) 2013-06-11
UA100732C2 (ru) 2013-01-25
WO2009136409A2 (en) 2009-11-12
AU2009245307A1 (en) 2009-11-12
CN102006930A (zh) 2011-04-06

Similar Documents

Publication Publication Date Title
AU2009245307A1 (en) Hydrogenation of imines
Liu et al. Iridium-catalyzed asymmetric allylic substitutions
US6545188B2 (en) Transfer hydrogenation process and catalyst
RU2150464C1 (ru) Способ гидрогенизации иминов и способ получения амина
Hoen et al. Enantioselective synthesis of β 2-amino acids using rhodium-catalyzed hydrogenation
US6509467B1 (en) Transfer hydrogenation process
CN105712812A (zh) 利用不对称还原胺化反应制备的手性β-芳基胺类化合物及其方法
US20090036713A1 (en) Process for the hydrogenation of imines
US20220119329A1 (en) Manganese Catalysts and Their Use in Hydrogenation of Ketones
IL193064A (en) Metal complexes
Lorraine et al. Biaryl diphosphine ligands and their ruthenium complexes: Preparation and use for catalytic hydrogenation of ketones
US8729306B2 (en) Process for the preparation of nitrogen substituted aminotetralins derivatives
US10179330B2 (en) Chiral N-substituted allylic amine compounds
US20210238200A1 (en) Chiral n-substituted allylic amine compounds
US8759541B2 (en) Chiral acyclic diaminocarbene ligands, precursors therefore and their use in organic synthesis reactions
EP2070904A1 (en) Rhodium-phosphorus complexes and their use in ring opening reactions
Hoen New approaches in asymmetric rhodium-catalyzed hydrogenations with monodentate phosphoramidites
Xu Nickel-catalyzed asymmetric transfer hydrogenation of unsaturated C= C and C= N bonds using formic acid
ArBr et al. 6.5 Asymmetric Ring-Opening Reactions via C—C and C—Si Bond Cleavage
Wang Enantioselective synthesis of β-amino esters
CN111285774A (zh) 基于d-甘露醇衍生的手性单齿膦配体不对称氢化亚胺方法
CN110551033A (zh) 一种酮的不对称还原胺化制备手性胺的方法

Legal Events

Date Code Title Description
FGA Letters patent sealed or granted (standard patent)
MK14 Patent ceased section 143(a) (annual fees not paid) or expired