CN101990462A - 制备催化剂的方法和作为电催化剂的用途 - Google Patents

制备催化剂的方法和作为电催化剂的用途 Download PDF

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Publication number
CN101990462A
CN101990462A CN200880124347XA CN200880124347A CN101990462A CN 101990462 A CN101990462 A CN 101990462A CN 200880124347X A CN200880124347X A CN 200880124347XA CN 200880124347 A CN200880124347 A CN 200880124347A CN 101990462 A CN101990462 A CN 101990462A
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catalyst
metal
platinum group
temperature
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S·科特尔
G·科克斯
E·施瓦布
A·潘琴科
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BASF SE
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08Heat treatment
    • B01J37/082Decomposition and pyrolysis
    • B01J37/086Decomposition of an organometallic compound, a metal complex or a metal salt of a carboxylic acid
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/92Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9445Simultaneously removing carbon monoxide, hydrocarbons or nitrogen oxides making use of three-way catalysts [TWC] or four-way-catalysts [FWC]
    • B01D53/945Simultaneously removing carbon monoxide, hydrocarbons or nitrogen oxides making use of three-way catalysts [TWC] or four-way-catalysts [FWC] characterised by a specific catalyst
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46Ruthenium, rhodium, osmium or iridium
    • B01J23/462Ruthenium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/30Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/391Physical properties of the active metal ingredient
    • B01J35/393Metal or metal oxide crystallite size
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/04Mixing
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/86Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90Selection of catalytic material
    • H01M4/92Metals of platinum group
    • H01M4/921Alloys or mixtures with metallic elements
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/86Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90Selection of catalytic material
    • H01M4/92Metals of platinum group
    • H01M4/925Metals of platinum group supported on carriers, e.g. powder carriers
    • H01M4/926Metals of platinum group supported on carriers, e.g. powder carriers on carbon or graphite
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/10Noble metals or compounds thereof
    • B01D2255/102Platinum group metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/207Transition metals
    • B01D2255/20746Cobalt
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/207Transition metals
    • B01D2255/20753Nickel
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/70Non-metallic catalysts, additives or dopants
    • B01D2255/702Carbon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15X-ray diffraction
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/30Scanning electron microscopy; Transmission electron microscopy
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56Platinum group metals
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/1009Fuel cells with solid electrolytes with one of the reactants being liquid, solid or liquid-charged
    • H01M8/1011Direct alcohol fuel cells [DAFC], e.g. direct methanol fuel cells [DMFC]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02TCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00Road transport of goods or passengers
    • Y02T10/10Internal combustion engine [ICE] based vehicles
    • Y02T10/12Improving ICE efficiencies

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • Biomedical Technology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Analytical Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Inert Electrodes (AREA)
CN200880124347XA 2007-11-09 2008-11-06 制备催化剂的方法和作为电催化剂的用途 Pending CN101990462A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP07120359.0 2007-11-09
EP07120359 2007-11-09
PCT/EP2008/065039 WO2009060019A1 (de) 2007-11-09 2008-11-06 Verfahren zur herstellung eines katalysators sowie verwendung als elektrokatalysator

Publications (1)

Publication Number Publication Date
CN101990462A true CN101990462A (zh) 2011-03-23

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US (1) US8293675B2 (https=)
EP (1) EP2217372A1 (https=)
JP (1) JP5579071B2 (https=)
KR (1) KR101541207B1 (https=)
CN (1) CN101990462A (https=)
CA (1) CA2704667A1 (https=)
RU (1) RU2010123285A (https=)
WO (1) WO2009060019A1 (https=)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103915633A (zh) * 2014-04-01 2014-07-09 上海交通大学 一种复合碳纤维载金属催化剂及其制备方法和应用
CN106605325A (zh) * 2014-10-24 2017-04-26 株式会社科特拉 燃料电池用电极催化剂及其制造方法
CN109937091A (zh) * 2016-10-20 2019-06-25 巴斯夫欧洲公司 生产包含金属间化合物的催化剂的方法和由该方法制成的催化剂
CN113437318A (zh) * 2021-06-25 2021-09-24 北京大学 一种碳负载的贵金属合金纳米颗粒及其制备方法和应用
CN115863678A (zh) * 2022-12-20 2023-03-28 佛山仙湖实验室 一种富含缺陷的铂基纳米片催化剂及其制备方法和应用

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US8569196B2 (en) * 2008-08-26 2013-10-29 Basf Se Process for the continuous production of a catalyst
EP2417059B1 (de) 2009-04-06 2014-12-10 Basf Se Verfahren zur umsetzung von erdgas zu aromaten mit elektrochemischer abtrennung von wasserstoff
JP2012526741A (ja) 2009-05-14 2012-11-01 ビーエーエスエフ ソシエタス・ヨーロピア 芳香族アミンの製造方法
WO2010139596A2 (en) * 2009-06-02 2010-12-09 Basf Se Catalyst for electrochemical applications
JP5471252B2 (ja) * 2009-09-30 2014-04-16 国立大学法人北海道大学 合金化度と分散性を制御したPtRu/C触媒及びその製造方法
JP5660917B2 (ja) * 2011-02-04 2015-01-28 国立大学法人東京工業大学 燃料電池用空気極触媒とその製造方法
WO2013182535A1 (de) 2012-06-06 2013-12-12 Basf Se Verfahren zur herstellung von stickstoff-dotierten übergangsmetallkatalysatoren und ihre verwendung für die elektrochemische oxidation von s(iv) verbindungen
WO2015175759A1 (en) 2014-05-16 2015-11-19 Dow Global Technologies Llc Process for synthesizing iron carbide fischer-tropsch catalysts
US20200230581A1 (en) * 2017-10-03 2020-07-23 Northwestern University Nanocatalysts for electrochemical hydrogen production and catalyst screening methods
KR102291160B1 (ko) * 2018-11-08 2021-08-19 한국과학기술원 연료전지용 금 도핑 백금계 합금 촉매 및 이의 제조 방법
KR102425528B1 (ko) * 2020-10-28 2022-07-25 한국화학연구원 화학 기상 증착법을 이용한 저온활성이 향상된 deNOx 촉매의 제조방법 및 이로부터 제조된 deNOx촉매
KR102451629B1 (ko) * 2020-11-25 2022-10-06 충남대학교산학협력단 산소 환원 반응용 백금계 촉매 및 그 제조방법
KR102468470B1 (ko) * 2020-12-09 2022-11-18 비나텍주식회사 연료전지용 백금계 합금 촉매의 제조 방법
KR102466103B1 (ko) * 2020-12-18 2022-11-11 비나텍주식회사 연료전지용 백금계 합금 촉매의 제조 방법
KR102459158B1 (ko) * 2020-12-18 2022-10-26 비나텍주식회사 코발트를 함유하는 연료전지용 백금계 합금 촉매의 제조 방법

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US20040101718A1 (en) * 2002-11-26 2004-05-27 Lixin Cao Metal alloy for electrochemical oxidation reactions and method of production thereof
WO2005069893A2 (en) * 2004-01-16 2005-08-04 T/J Technologies, Inc. Catalyst and method for its manufacture
US20050235776A1 (en) * 2004-04-22 2005-10-27 Ting He Metal and alloy nanoparticles and synthesis methods thereof

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103915633A (zh) * 2014-04-01 2014-07-09 上海交通大学 一种复合碳纤维载金属催化剂及其制备方法和应用
CN103915633B (zh) * 2014-04-01 2016-08-24 上海交通大学 一种复合碳纤维载金属催化剂及其制备方法和应用
CN106605325A (zh) * 2014-10-24 2017-04-26 株式会社科特拉 燃料电池用电极催化剂及其制造方法
CN106605325B (zh) * 2014-10-24 2020-12-25 株式会社科特拉 燃料电池用电极催化剂及其制造方法
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CN109937091A (zh) * 2016-10-20 2019-06-25 巴斯夫欧洲公司 生产包含金属间化合物的催化剂的方法和由该方法制成的催化剂
CN113437318A (zh) * 2021-06-25 2021-09-24 北京大学 一种碳负载的贵金属合金纳米颗粒及其制备方法和应用
CN115863678A (zh) * 2022-12-20 2023-03-28 佛山仙湖实验室 一种富含缺陷的铂基纳米片催化剂及其制备方法和应用

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JP5579071B2 (ja) 2014-08-27
US8293675B2 (en) 2012-10-23
US20100267551A1 (en) 2010-10-21
JP2011502758A (ja) 2011-01-27
CA2704667A1 (en) 2009-05-14
EP2217372A1 (de) 2010-08-18
KR20100099160A (ko) 2010-09-10
KR101541207B1 (ko) 2015-07-31
RU2010123285A (ru) 2011-12-20
WO2009060019A1 (de) 2009-05-14

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Application publication date: 20110323