CN101965635B - 将选择性钌沉积集成到半导体器件的制造中的方法 - Google Patents

将选择性钌沉积集成到半导体器件的制造中的方法 Download PDF

Info

Publication number
CN101965635B
CN101965635B CN200880106629.7A CN200880106629A CN101965635B CN 101965635 B CN101965635 B CN 101965635B CN 200880106629 A CN200880106629 A CN 200880106629A CN 101965635 B CN101965635 B CN 101965635B
Authority
CN
China
Prior art keywords
precursor
gas
patterned substrate
metal
metal film
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN200880106629.7A
Other languages
English (en)
Chinese (zh)
Other versions
CN101965635A (zh
Inventor
铃木健二
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tokyo Electron Ltd
Original Assignee
Tokyo Electron Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tokyo Electron Ltd filed Critical Tokyo Electron Ltd
Publication of CN101965635A publication Critical patent/CN101965635A/zh
Application granted granted Critical
Publication of CN101965635B publication Critical patent/CN101965635B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10WGENERIC PACKAGES, INTERCONNECTIONS, CONNECTORS OR OTHER CONSTRUCTIONAL DETAILS OF DEVICES COVERED BY CLASS H10
    • H10W20/00Interconnections in chips, wafers or substrates
    • H10W20/40Interconnections external to wafers or substrates, e.g. back-end-of-line [BEOL] metallisations or vias connecting to gate electrodes
    • H10W20/41Interconnections external to wafers or substrates, e.g. back-end-of-line [BEOL] metallisations or vias connecting to gate electrodes characterised by their conductive parts
    • H10W20/425Barrier, adhesion or liner layers
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10PGENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
    • H10P14/00Formation of materials, e.g. in the shape of layers or pillars
    • H10P14/40Formation of materials, e.g. in the shape of layers or pillars of conductive or resistive materials
    • H10P14/42Formation of materials, e.g. in the shape of layers or pillars of conductive or resistive materials using a gas or vapour
    • H10P14/43Chemical deposition, e.g. chemical vapour deposition [CVD]
    • H10P14/432Chemical deposition, e.g. chemical vapour deposition [CVD] using selective deposition
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10WGENERIC PACKAGES, INTERCONNECTIONS, CONNECTORS OR OTHER CONSTRUCTIONAL DETAILS OF DEVICES COVERED BY CLASS H10
    • H10W20/00Interconnections in chips, wafers or substrates
    • H10W20/01Manufacture or treatment
    • H10W20/031Manufacture or treatment of conductive parts of the interconnections
    • H10W20/032Manufacture or treatment of conductive parts of the interconnections of conductive barrier, adhesion or liner layers
    • H10W20/033Manufacture or treatment of conductive parts of the interconnections of conductive barrier, adhesion or liner layers in openings in dielectrics
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10WGENERIC PACKAGES, INTERCONNECTIONS, CONNECTORS OR OTHER CONSTRUCTIONAL DETAILS OF DEVICES COVERED BY CLASS H10
    • H10W20/00Interconnections in chips, wafers or substrates
    • H10W20/01Manufacture or treatment
    • H10W20/031Manufacture or treatment of conductive parts of the interconnections
    • H10W20/032Manufacture or treatment of conductive parts of the interconnections of conductive barrier, adhesion or liner layers
    • H10W20/033Manufacture or treatment of conductive parts of the interconnections of conductive barrier, adhesion or liner layers in openings in dielectrics
    • H10W20/035Manufacture or treatment of conductive parts of the interconnections of conductive barrier, adhesion or liner layers in openings in dielectrics combinations of barrier, adhesion or liner layers, e.g. multi-layered barrier layers
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10WGENERIC PACKAGES, INTERCONNECTIONS, CONNECTORS OR OTHER CONSTRUCTIONAL DETAILS OF DEVICES COVERED BY CLASS H10
    • H10W20/00Interconnections in chips, wafers or substrates
    • H10W20/01Manufacture or treatment
    • H10W20/031Manufacture or treatment of conductive parts of the interconnections
    • H10W20/032Manufacture or treatment of conductive parts of the interconnections of conductive barrier, adhesion or liner layers
    • H10W20/033Manufacture or treatment of conductive parts of the interconnections of conductive barrier, adhesion or liner layers in openings in dielectrics
    • H10W20/037Manufacture or treatment of conductive parts of the interconnections of conductive barrier, adhesion or liner layers in openings in dielectrics the barrier, adhesion or liner layers being on top of a main fill metal

Landscapes

  • Electrodes Of Semiconductors (AREA)
  • Chemical Vapour Deposition (AREA)
  • Internal Circuitry In Semiconductor Integrated Circuit Devices (AREA)
CN200880106629.7A 2007-09-11 2008-09-09 将选择性钌沉积集成到半导体器件的制造中的方法 Active CN101965635B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US11/853,393 US7829454B2 (en) 2007-09-11 2007-09-11 Method for integrating selective ruthenium deposition into manufacturing of a semiconductior device
US11/853,393 2007-09-11
PCT/IB2008/003805 WO2009060320A2 (en) 2007-09-11 2008-09-09 Method for integrating selective ruthenium deposition into manufacturing of a semiconductior device

Publications (2)

Publication Number Publication Date
CN101965635A CN101965635A (zh) 2011-02-02
CN101965635B true CN101965635B (zh) 2014-02-12

Family

ID=40430967

Family Applications (1)

Application Number Title Priority Date Filing Date
CN200880106629.7A Active CN101965635B (zh) 2007-09-11 2008-09-09 将选择性钌沉积集成到半导体器件的制造中的方法

Country Status (6)

Country Link
US (1) US7829454B2 (https=)
JP (1) JP5406191B2 (https=)
KR (1) KR101506755B1 (https=)
CN (1) CN101965635B (https=)
TW (1) TWI387051B (https=)
WO (1) WO2009060320A2 (https=)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106158723A (zh) * 2015-05-13 2016-11-23 格罗方德半导体公司 填充集成电路中的凹穴及其结果装置

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7737028B2 (en) * 2007-09-28 2010-06-15 Applied Materials, Inc. Selective ruthenium deposition on copper materials
US20100081274A1 (en) * 2008-09-29 2010-04-01 Tokyo Electron Limited Method for forming ruthenium metal cap layers
US7977235B2 (en) * 2009-02-02 2011-07-12 Tokyo Electron Limited Method for manufacturing a semiconductor device with metal-containing cap layers
US8716132B2 (en) * 2009-02-13 2014-05-06 Tokyo Electron Limited Radiation-assisted selective deposition of metal-containing cap layers
US8242019B2 (en) * 2009-03-31 2012-08-14 Tokyo Electron Limited Selective deposition of metal-containing cap layers for semiconductor devices
DE102009021488A1 (de) * 2009-05-15 2010-12-16 Globalfoundries Dresden Module One Llc & Co. Kg Verbessertes Elektromigrationsverhalten von Kupferleitungen in Metallisierungssystemen von Halbleiterbauelementen durch Legierung von Oberflächen
US8178439B2 (en) 2010-03-30 2012-05-15 Tokyo Electron Limited Surface cleaning and selective deposition of metal-containing cap layers for semiconductor devices
US8232200B1 (en) 2011-03-18 2012-07-31 International Business Machines Corporation Methods of forming integrated circuit devices having damascene interconnects therein with metal diffusion barrier layers and devices formed thereby
US8921228B2 (en) 2011-10-04 2014-12-30 Imec Method for selectively depositing noble metals on metal/metal nitride substrates
EP2584588B1 (en) * 2011-10-21 2017-10-04 Imec Method of forming MIM capacitor with Ru-comprising oxygen diffusion barrier
JP6257217B2 (ja) * 2013-08-22 2018-01-10 東京エレクトロン株式会社 Cu配線構造の形成方法
KR102321209B1 (ko) * 2014-11-03 2021-11-02 삼성전자주식회사 반도체 장치 및 이의 제조 방법
US10002834B2 (en) * 2015-03-11 2018-06-19 Applied Materials, Inc. Method and apparatus for protecting metal interconnect from halogen based precursors
US9576894B2 (en) * 2015-06-03 2017-02-21 GlobalFoundries, Inc. Integrated circuits including organic interlayer dielectric layers and methods for fabricating the same
JP7066929B2 (ja) 2015-06-05 2022-05-16 東京エレクトロン株式会社 インターコネクトのためのルテニウムメタルによるフィーチャ充填
US9768063B1 (en) * 2016-06-30 2017-09-19 Lam Research Corporation Dual damascene fill
US9947590B1 (en) * 2016-10-14 2018-04-17 Globalfoundries Inc. Method, apparatus, and system for using a cover mask for enabling metal line jumping over MOL features in a standard cell
WO2018125052A1 (en) * 2016-12-27 2018-07-05 Intel Corporation Selective area deposition of metal layers from hetero-pentadienyl metal complex precursors
TWI790320B (zh) * 2017-12-16 2023-01-21 美商應用材料股份有限公司 釕的選擇性原子層沉積
US10403564B2 (en) * 2017-12-30 2019-09-03 Intel Corporation Dual-damascene zero-misalignment-via process for semiconductor packaging
US10818557B2 (en) 2018-07-03 2020-10-27 Globalfoundries Inc. Integrated circuit structure to reduce soft-fail incidence and method of forming same
JP2020043139A (ja) * 2018-09-06 2020-03-19 東京エレクトロン株式会社 埋め込み方法及び処理システム
US11164780B2 (en) * 2019-06-07 2021-11-02 Applied Materials, Inc. Process integration approach for selective metal via fill
WO2020251696A1 (en) 2019-06-10 2020-12-17 Applied Materials, Inc. Processing system for forming layers
US20240412981A1 (en) * 2023-06-09 2024-12-12 Entegris, Inc. Selective ruthenium deposition and related systems and methods
US20250154643A1 (en) * 2023-11-14 2025-05-15 Tokyo Electron Limited Area selective deposition of metals for electronic devices

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004146516A (ja) * 2002-10-23 2004-05-20 Tokyo Electron Ltd 成膜方法
US20060121733A1 (en) * 2004-10-26 2006-06-08 Kilpela Olli V Selective formation of metal layers in an integrated circuit
US20060220248A1 (en) * 2005-03-31 2006-10-05 Tokyo Electron Limited Low-temperature chemical vapor deposition of low-resistivity ruthenium layers

Family Cites Families (45)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4851895A (en) * 1985-05-06 1989-07-25 American Telephone And Telegraph Company, At&T Bell Laboratories Metallization for integrated devices
US4929468A (en) * 1988-03-18 1990-05-29 The United States Of America As Represented By The United States Department Of Energy Formation of amorphous metal alloys by chemical vapor deposition
US4938999A (en) * 1988-07-11 1990-07-03 Jenkin William C Process for coating a metal substrate by chemical vapor deposition using a metal carbonyl
US5171610A (en) * 1990-08-28 1992-12-15 The Regents Of The University Of Calif. Low temperature photochemical vapor deposition of alloy and mixed metal oxide films
US5314727A (en) * 1992-07-28 1994-05-24 Minnesota Mining & Mfg. Co./Regents Of The University Of Minnesota Chemical vapor deposition of iron, ruthenium, and osmium
US5359787A (en) 1993-04-16 1994-11-01 Air Products And Chemicals, Inc. High purity bulk chemical delivery system
CA2206217C (en) 1997-05-27 2003-01-07 Miroslav Milinkovic Nickel carbonyl vapour deposition process
US6074945A (en) 1998-08-27 2000-06-13 Micron Technology, Inc. Methods for preparing ruthenium metal films
US6063705A (en) * 1998-08-27 2000-05-16 Micron Technology, Inc. Precursor chemistries for chemical vapor deposition of ruthenium and ruthenium oxide
EP1131475A1 (en) 1998-11-03 2001-09-12 Chemical Vapour Deposition Systems Inc. Nickel carbonyl vapour deposition apparatus and process
US6319832B1 (en) * 1999-02-19 2001-11-20 Micron Technology, Inc. Methods of making semiconductor devices
US6303809B1 (en) * 1999-12-10 2001-10-16 Yun Chi Organometallic ruthenium and osmium source reagents for chemical vapor deposition
US6440495B1 (en) * 2000-08-03 2002-08-27 Applied Materials, Inc. Chemical vapor deposition of ruthenium films for metal electrode applications
US6444263B1 (en) * 2000-09-15 2002-09-03 Cvc Products, Inc. Method of chemical-vapor deposition of a material
KR100366639B1 (ko) * 2001-03-23 2003-01-06 삼성전자 주식회사 다공성 산화막 플러그에 의한 저저항 컨택 형성방법 및이를 이용한 반도체 장치의 형성방법
JP4160277B2 (ja) * 2001-06-29 2008-10-01 株式会社東芝 半導体装置の製造方法
KR100727372B1 (ko) * 2001-09-12 2007-06-12 토소가부시키가이샤 루테늄착체, 그 제조방법 및 박막의 제조방법
US6420583B1 (en) * 2001-09-27 2002-07-16 Praxair Technology, Inc Methods of synthesizing ruthenium and osmium compounds
US6713373B1 (en) * 2002-02-05 2004-03-30 Novellus Systems, Inc. Method for obtaining adhesion for device manufacture
US7264846B2 (en) * 2002-06-04 2007-09-04 Applied Materials, Inc. Ruthenium layer formation for copper film deposition
US6989321B2 (en) * 2003-09-30 2006-01-24 Tokyo Electron Limited Low-pressure deposition of metal layers from metal-carbonyl precursors
US7078341B2 (en) 2003-09-30 2006-07-18 Tokyo Electron Limited Method of depositing metal layers from metal-carbonyl precursors
US7107998B2 (en) * 2003-10-16 2006-09-19 Novellus Systems, Inc. Method for preventing and cleaning ruthenium-containing deposits in a CVD apparatus
US8158532B2 (en) * 2003-10-20 2012-04-17 Novellus Systems, Inc. Topography reduction and control by selective accelerator removal
US20050110142A1 (en) * 2003-11-26 2005-05-26 Lane Michael W. Diffusion barriers formed by low temperature deposition
US7285308B2 (en) * 2004-02-23 2007-10-23 Advanced Technology Materials, Inc. Chemical vapor deposition of high conductivity, adherent thin films of ruthenium
US7279421B2 (en) * 2004-11-23 2007-10-09 Tokyo Electron Limited Method and deposition system for increasing deposition rates of metal layers from metal-carbonyl precursors
US7270848B2 (en) * 2004-11-23 2007-09-18 Tokyo Electron Limited Method for increasing deposition rates of metal layers from metal-carbonyl precursors
US7638002B2 (en) * 2004-11-29 2009-12-29 Tokyo Electron Limited Multi-tray film precursor evaporation system and thin film deposition system incorporating same
US20060113675A1 (en) * 2004-12-01 2006-06-01 Chung-Liang Chang Barrier material and process for Cu interconnect
JP2006179599A (ja) * 2004-12-21 2006-07-06 Toshiba Corp 半導体装置およびその製造方法
KR100613388B1 (ko) * 2004-12-23 2006-08-17 동부일렉트로닉스 주식회사 다마신법을 이용한 구리 배선층을 갖는 반도체 소자 및 그형성 방법
US7265048B2 (en) * 2005-03-01 2007-09-04 Applied Materials, Inc. Reduction of copper dewetting by transition metal deposition
US7288479B2 (en) * 2005-03-31 2007-10-30 Tokyo Electron Limited Method for forming a barrier/seed layer for copper metallization
US20070059502A1 (en) * 2005-05-05 2007-03-15 Applied Materials, Inc. Integrated process for sputter deposition of a conductive barrier layer, especially an alloy of ruthenium and tantalum, underlying copper or copper alloy seed layer
US7402519B2 (en) * 2005-06-03 2008-07-22 Intel Corporation Interconnects having sealing structures to enable selective metal capping layers
JP2007043018A (ja) * 2005-08-05 2007-02-15 Toshiba Corp 半導体装置
US7713876B2 (en) * 2005-09-28 2010-05-11 Tokyo Electron Limited Method for integrating a ruthenium layer with bulk copper in copper metallization
US7215006B2 (en) * 2005-10-07 2007-05-08 International Business Machines Corporation Plating seed layer including an oxygen/nitrogen transition region for barrier enhancement
US7785658B2 (en) * 2005-10-07 2010-08-31 Asm Japan K.K. Method for forming metal wiring structure
US7439624B2 (en) * 2006-05-18 2008-10-21 International Business Machines Corporation Enhanced mechanical strength via contacts
US8034406B2 (en) * 2006-09-26 2011-10-11 Tokyo Electron Limited Integrated substrate processing in a vacuum processing tool
US20080081464A1 (en) * 2006-09-29 2008-04-03 Tokyo Electron Limited Method of integrated substrated processing using a hot filament hydrogen radical souce
US7592257B2 (en) * 2007-05-14 2009-09-22 Tokyo Electron Limited Semiconductor contact structure containing an oxidation-resistant diffusion barrier and method of forming
US7884018B2 (en) * 2007-06-21 2011-02-08 International Business Machines Corporation Method for improving the selectivity of a CVD process

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004146516A (ja) * 2002-10-23 2004-05-20 Tokyo Electron Ltd 成膜方法
US20060121733A1 (en) * 2004-10-26 2006-06-08 Kilpela Olli V Selective formation of metal layers in an integrated circuit
US20060220248A1 (en) * 2005-03-31 2006-10-05 Tokyo Electron Limited Low-temperature chemical vapor deposition of low-resistivity ruthenium layers

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
Low-tempreture chemical vapor deposition and scaling limitofultrathin Ru film;Q.Wang, J.G.Ekerdt, D.Gay, Y.-M.Sun, J.M.White;《App.Phy.Lett.》;20040223;正文第1页左栏第1行至第3页左栏第26行 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106158723A (zh) * 2015-05-13 2016-11-23 格罗方德半导体公司 填充集成电路中的凹穴及其结果装置

Also Published As

Publication number Publication date
WO2009060320A3 (en) 2009-08-06
WO2009060320A2 (en) 2009-05-14
CN101965635A (zh) 2011-02-02
KR101506755B1 (ko) 2015-03-27
US7829454B2 (en) 2010-11-09
TW200913146A (en) 2009-03-16
JP2010539698A (ja) 2010-12-16
KR20100113475A (ko) 2010-10-21
US20090065939A1 (en) 2009-03-12
JP5406191B2 (ja) 2014-02-05
TWI387051B (zh) 2013-02-21

Similar Documents

Publication Publication Date Title
CN101965635B (zh) 将选择性钌沉积集成到半导体器件的制造中的方法
CN101981686B (zh) 用于将选择性的低温钌沉积集成到半导体器件的铜金属化中的方法
CN102165573B (zh) 用于形成钌金属覆盖层的方法
US20120252210A1 (en) Method for modifying metal cap layers in semiconductor devices
TWI382496B (zh) 將保形釕層整合至具高縱橫比特徵之銅金屬化結構的方法
CN100572591C (zh) 用于增大由羰基金属前驱体沉积金属层的速率的方法
US8242019B2 (en) Selective deposition of metal-containing cap layers for semiconductor devices
US7473634B2 (en) Method for integrated substrate processing in copper metallization
CN102859035A (zh) 用于在凹陷特征中的连续钌膜上多步骤镀铜的方法
US7718527B2 (en) Method for forming cobalt tungsten cap layers
JP4787073B2 (ja) 処理方法および処理装置

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant