CN101953346B - Zinc thiazole-containing bactericidal composition - Google Patents
Zinc thiazole-containing bactericidal composition Download PDFInfo
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- CN101953346B CN101953346B CN2010102820929A CN201010282092A CN101953346B CN 101953346 B CN101953346 B CN 101953346B CN 2010102820929 A CN2010102820929 A CN 2010102820929A CN 201010282092 A CN201010282092 A CN 201010282092A CN 101953346 B CN101953346 B CN 101953346B
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Abstract
The present invention provides a zinc thiazole-containing bactericidal composition, which contains an active compound I and a bactericidally active compound II, wherein the active compound I is zinc thiazole; the bactericidally active compound II may be any one of a methoxyacrylate bactericide, a triazole bactericide, an amide bactericide, an iminazole bactericide, a dicarboxylic imide bactericide, a carbamic acid ester bactericide, an antibiotic bactericide, an oxazole bactericide, a morpholine bactericide, a pyrimidine bactericide, a quinazolone bactericide, a dithiocarbamate bactericide or other given bactericides.
Description
Technical field:
The present invention relates to the Fungicidal active compound composition, particularly be used for the composition that comprises thiazole zinc (Zinc thiazole) and other Fungicidal active compounds of the purposes of controlling plant diseases and promotion crop healthy growth.
Background technology:
Known plants suffers the infringement of microorganisms such as bacterium, fungi, virus and nematode, and wherein fungi, virus and bacteriosis are even more important, to plant growing, to breed, store and transport threat very big.Prevent and treat the reactive compound triazole type, methoxy acrylic, pyroles, miazines, amide-type of this class disease etc., but as a rule, the activity of their plant tolerance and opposing plant pathogen always can not satisfy the needs of agricultural production.Therefore only be difficult to reach the purpose that protective plant does not receive the harm of falling ill with a kind of reactive compound; in case the resistance generation can impel the user to increase dosage; thereby can accelerate generation, farming this increase, residue of pesticide and the crop safety problem of resistance more, these active high compounds are with safety is good, resistance produces slowly, the pharmacy mix of broad spectrum activity then becomes the problem that people receive much concern.
Thiazole zinc is the compound (ZL001321196) that the applicant succeeded in developing in 1999, and its single agent comes into the market in a large number, serves agricultural.
Thiazole zinc has sterilization idiocratic (WO2008/151513), outstanding to the bacterial diseases of plants control efficiency, the part fungal disease is also had good effect, and we find that the thiazole zinc of debita spissitudo has the growth that promotes root system and leaf to the part plant, improves effect degeneration-resistant, disease resistance simultaneously.It is good that thiazole zinc has crop safety, the characteristics strong with other bactericide miscibilty, thereby we think that this product is the good product that meets modern health protection cultivation, in order to enlarge its fungicidal spectrum, the generation of delaying drug resistance, be convenient to peasant's medication and product promotion, Zhejiang Xinnong Chemical Co.,Ltd has organized numerous scientific research institutions and the plant protection department of Zhejiang Province, Hubei Province, Jiangsu Province, Shandong Province to carry out mensuration and test indoor, outdoor activity, and its result is encouraging!
Although thiazole zinc is considered to effectively, it can not satisfy Fungicidal active compound fully to plant tolerance and highly active requirement.
Summary of the invention:
The present invention is in order to solve Fungicidal active compound to plant tolerance and the active problem that can not satisfy the demand, a kind of composition of Fungicidal active compound is proposed, contain thiazole zinc I and other any one known Fungicidal active compound II in this Fungicidal active compound composition, it is applied to prevent and treat plant epiphyte, bacterial disease.This Fungicidal active compound composition has the compatibility of Synergistic fungicidal active, improvement and plant, thereby satisfies the needs of agricultural production.
The Fungicidal active compound composition that the present invention relates to, it comprises reactive compound component I thiazole zinc:
Formula I thiazole zinc (CAS No:1202750-31-9), two (2-amino-5-sulfydryl-1,3,4-thiadiazoles) zinc
At least any one is selected from following II.1)-II.13) Fungicidal active compound component I I:
II.1) methoxy acrylic bactericide (strobilurin);
Fluoxastrobin (azoxystrobin) (being known in EP 0382375)
Kresoxim-methyl (kresoxim-methyl) (being known in EP 0253213)
Oxime bacterium ester (trifloxystrobin) (being known in EP 0460575)
Pyraclostrobin (pyraclostrobin) (being known in DE 4423612)
Enestroburin (enestroburin) (being known in EP 936213)
Azoles bacterium ester (Pyraoxystrobin) (being known in DE4423612)
II.2) triazole bactericidal agent (triazoles);
Difenoconazole (difenoconazole) (being known in EP 0112284)
Alkene azoles alcohol (diniconazole) (being known in EP 2838847)
Fluorine ring azoles (epoxiconazole) (being known in DE 3218130)
RH-7592 (fenbuconazole) (being known in DE 3721786)
Flusilazole (flusilazole) (being known in DP0068813)
Flutriafol (flutriafol) (being known in EP 0015756)
Tebuconazole (tebuconazole) (being known in DE 3018866)
Own azoles alcohol (hexaconazole) (being known in DE 3042303)
Nitrile bacterium azoles (myclobutanil) (being known in EP 0145294)
Penconazole (penconazole) (being known in DE 2735872)
Propiconazole (propiconazole) (being known in US 4079062)
Tetraconazole (tetraconazole) (being known in EP 0234242)
Triadimenol (triadimenol) (being known in DE 2324010)
Bitertanol (bitertanol) (being known in US 3952002)
Triazolone (triadimefon) (being known in US 3912752)
II.3) acid amide fungicides (amides);
Metalaxyl (metalaxyl) (being known in US 4151299)
Flutolanil (flutolanil) (being known in DE 2731522)
Mandipropamid amine (mandipropamid) (being known in EP 1282595)
Boscalid (boscalid) (being known in EPA545099)
Fluorine pyrrole bacterium acid amides (fluopicolide) (being known in CN1291187)
Carboxin (carboxin) (being known in US 3249499)
II.4) imidazoles bactericide (imidazoles);
Probenazole (thiabendazole) (being known in US 3017415)
Press down mould azoles (imazalil) (being known in US 6207695)
Prochloraz (prochloraz) (being known in AU 491880)
Cyanogen frost azoles (cyazofamid) (being known in EP 298196)
Fluorine bacterium azoles (triflumizole) (being known in US 4208411)
II.5) dicarboximide series bactericidal agent (dicarboximides);
Procymidone (procymidone) (being known in US 3903090)
Iprodione (iprodione) (being known in GB 1312536)
Vinclozolin (vinclozolin) (being known in DE 2207576)
Captan (captan) (being known in US 2553770)
Dimethachlon (dimethachlon) (being known in DE 1812206)
II.6) carbamate fungicide (carbamates);
Propamocarb (propamocard hydrochioride) (being known in DE1567169)
The mould prestige of second (diethofencarb) (being known in EP 78663)
Benomyl (benomyl) (being known in US 3631176)
Carbendazim (carbendazim) (being known in JP 906789)
Thiophanate-methyl (thiophanate-methyl) (being known in DE 1930540)
II.7) antibiotic series bactericidal agent (antibiotics);
Jinggangmeisu (jinggangmycin) (being known in GB/T 9553-1993)
Streptomycin sulphate (streptomycin) (being known in CB4290144)
Polyoxin (polyoxins) (being known in CB4383363)
Kasugarnycin (kasugamycin) (being known in GB 1094567)
Tetramycin (tetramycin) (being known in CN101633941)
II.8) oxazole series bactericidal agent (oxazoles);
Wakil (oxadixyl) (being known in GB 2058059)
Dislike mould spirit (hymexazol) (being known in JP 518249)
II.9) morpholine series bactericidal agent (morpholines);
Tridemorph (tridemorph) (being known in DE 1164152)
Dimethomorph (dimethomorph) (being known in EP 120321)
Flumorph (flumorph) (being known in EP 0860438)
II.10) miazines bactericide (pyrimidines);
Cyprodinil (cyprodinil) (being known in EP 310550)
Phonetic mould amine (pyrimethanil) (being known in EP 270111)
The phonetic phenol of second (ethirimol) (being known in GB 1182584)
II.11) quinoline (azoles) quinoline (ketone) series bactericidal agent (quinazolinones, quinolines, quinones, quinoxalines);
Dithianon (dithianon) (being known in GB 857383)
II.12) dithiocarbamate fungicide (dithiocarbamate antimicrobial, DTCs);
Carbatene (metiram) (being known in DE 1076434)
Tmtd (thiram) (being known in US 1972961)
Zineb (zineb) (being known in DE 1081446)
Mancozeb (mancozeb) (being known in US 3379610)
Propineb (propineb) (being known in BE 611960)
II.13) other series bactericidal agents (other);
Edifenphos (edifenphos) (being known in DE 1493736)
Phosethyl-Al (fosetyl-aluminium) (being known in FR 2254276)
Tpn (chlorothalonil) (being known in US 4931581)
Isoprothiolane (isoprothiolane) (being known in US 3856814)
Pcnb (quintozene) (being known in DE 682048)
Frost urea cyanogen (cymoxanil) (being known in US 3957847)
Fludioxonil (fludioxonil) (being known in EP 206999)
Fenaminosulf (fenaminosulf) (being known in HG 2317-1992)
Fluazinam (fluazinam) (being known in EP 31257)
Thiodiazole-copper (thiediazole copper) (being known in CN1227224)
Kocide SD (copper hydroxide) (being known in CA20427-59-2).
The bactericidal composition that contains thiazole zinc provided by the present invention can also contain conventional auxiliary agent and additive and/or thinner.
Bactericidal composition of the present invention preferably includes thiazole zinc and is selected from kresoxim-methyl, pyraclostrobin, Fluoxastrobin, oxime bacterium ester, Difenoconazole, fluorine ring azoles, Flusilazole, Tebuconazole, own azoles alcohol, nitrile bacterium azoles, propiconazole, triazolone, Boscalid, fluorine pyrrole bacterium acid amides, metalaxyl, Prochloraz, cyanogen frost azoles, procymidone, iprodione, propamocarb, thiophanate-methyl, streptomycin sulphate, jinggangmeisu, dislike mould spirit, dimethomorph, flumorph, phonetic mould amine, Carbatene, mancozeb, zineb, Propineb, tpn, any one Fungicidal active compound II of fenaminosulf or Kocide SD.
When reactive compound exists with the extra fine quality ratio in the bactericidal composition of the present invention, Synergistic effect highly significant.Generally speaking, the mass ratio of component I and component I I is 100: 1～1: 100, and according to the fact of component I+component I I bactericidal composition bactericidal action greater than component I and component I I bactericidal action summation, described bactericidal composition synergistic function of the present invention is tangible.
Component I I is formula II.1) during methoxy acrylic bactericide, I: the II mass ratio is 5: 50～80: 1, the preferred mass ratio is 20: 30～40: 5.
Component I I is formula II.2) during triazole bactericidal agent, I: the II mass ratio is 5: 50～80: 1, the preferred mass ratio is 20: 20～40: 5.
Component I I is formula II.3) during acid amide fungicides, I: the II mass ratio is 5: 40～80: 1, the preferred mass ratio is 20: 20～40: 5.
Component I I is formula II.4) during the imidazoles bactericide, I: the II mass ratio is 5: 60～80: 1, the preferred mass ratio is 20: 30～40: 10.
Component I I is formula II.5) during the dicarboximide series bactericidal agent, I: the II mass ratio is 5: 60～80: 1, the preferred mass ratio is 20: 50～40: 20.
Component I I is formula II.6) during carbamate fungicide, I: the II mass ratio is 5: 80～80: 5, the preferred mass ratio is 20: 60～40: 10.
Component I I is formula II.7) during the antibiotic series bactericidal agent, I: the II mass ratio is 5: 80～80: 1, the preferred mass ratio is 20: 70～40: 2.
When component I I was formula II.8) oxazole series bactericidal agent, I: the II mass ratio was 5: 60～80: 5, and the preferred mass ratio is 20: 50～40: 10.
Component I I is formula II.9) during the morpholine series bactericidal agent, I: the II mass ratio is 5: 80～80: 5, the preferred mass ratio is 20: 50～40: 20.
Component I I is formula II.10) during the miazines bactericide, I: the II mass ratio is 5: 60～80: 10, the preferred mass ratio is 20: 50～40: 20.
Component I I is formula II.11) during quinoline (azoles) quinoline (ketone) series bactericidal agent, I: the II mass ratio is 5: 60～80: 10, the preferred mass ratio is 20: 50～40: 20.
Component I I is formula II.12) during dithiocarbamate fungicide, I: the II mass ratio is 5: 80～80: 10, the preferred mass ratio is 20: 50～40: 20.
Component I I is formula II.13) during other series bactericidal agents, I: the II mass ratio is 5: 80～80: 1, the preferred mass ratio is 20: 50～40: 10.
Bactericidal composition of the present invention has extraordinary bactericidal activity, very effective to pathogenetic bacteria and fungi, for example be used for preventing and treating following germ: the Xanthomonas of pathogenetic bacteria (Xanthomonas), pseudomonas (Pseudomonas), erwinia belong to (Erwinia);
Ascomycetes in the disease fungus (Ascomycetes): Venturia (Venturia), Erysiphe (Erysiphe), Sclerotinia (Sclerotinia);
Basidiomycetes in the disease fungus (Basidiomycetes): Ustilago (Ustilago), Gibberella (Gibberella);
Oomycete in the disease fungus (Oomycota): Phytophthora (Phytophthora), Plasmopara (Plasmopara);
Fungi Imperfecti in the disease fungus (Deuteromyces): Rhizoctonia (Rhizoctonia), Botrytis (Botrytis), Pyricularia Sacc. (Pyricularia), Cercospora (Cercospora), bipolaris (Bipolaris), colletotrichum (Colletotrichum).
Bactericidal composition of the present invention has good compatibility with plant simultaneously, reduces the plant proof pressure, especially responsive especially to plant seedling, the young tip, flower, young fruit part.
The following kind of plant optimization of indication is disclosed within the scope of the present invention, here: cereal class wheat, barley, paddy rice, Chinese sorghum, sweet potato; Fruit tree kind apple, pears, peach, oranges and tangerines, grape, lichee, banana, longan, mango, loquat; Greengrocery cucumber, watermelon, hang melon, sponge gourd, muskmelon, spinach, celery, tomato, capsicum, eggplant, ginger, green onion, garlic, leek, wild cabbage, Chinese cabbage, strawberry, asparagus lettuce, Kidney bean, cowpea, broad bean, radish, carrot, potato, Chinese yam, taro, lotus rhizome, water chestnut, wild rice stem; Sugar plant class beet, sugarcane; Oil crop class soybean, peanut, rape, sesame, sunflower; Or such as tobacco, tea.This enumerating do not represent to have any restriction.
The present composition also can be used for the field that the safeguard industries material is not subjected to germ infringement, and these industrial circles comprise timber, paper, leather, building etc., the present composition can prevent such as rot, variable color or mouldy ill-effect.
The present composition is effective especially to the following plants disease:
The cucumber bacterial angular leaf spot that pseudomonas (Pseudomonas) bacterial classification causes, wildfire, Solanaceae bacterial wilt etc.
The bacillary leaf blight of cucumber that Xanthomonas (Xanthomonas) bacterial classification causes, cabbage black rot, citrus bacterial canker disease etc.
The soft rot of Chinese cabbage that erwinia genus (Erwinia) bacterial classification causes, fire blight of pear etc.
The potato that Phytophthora (Pyhtophthora) bacterial classification causes, the eqpidemic disease of tomato etc.
The downy mildew of garpe that Plasmopara (Plasmopara) bacterial classification causes etc.
The tobacco that Erysiphe (Erysiphe) bacterial classification causes, sesame, sunflower and powdery mildew such as melon etc.
Multiple gramineous plants head blight, bakanaes disease of rice such as large and small wheat that Gibberella (Gibberella) bacterial classification causes and corn
The scab of the apple that Venturia (Venturia) bacterial classification causes etc.
The various plants stalk break that Sclerotinia (Sclerotinia) bacterial classification causes
The wheat loose smut that Ustilago (Ustil-ago) bacterial classification causes etc.
The gray mold of the various plants that Botrytis (Botrytis) bacterial classification causes etc.
The rice blast that Pyricularia Sacc. (Pyricularia) bacterial classification causes
Cercospora leaf spot of sugar beet, the cercospora brown spot of peanut that Cercospora (Cercospora) bacterial classification causes
The corn southern leaf blight that bipolaris (Bipolaris) bacterial classification causes, paddy rice oriental sesame leaf pinta
Cotton seedling blight and rice sheath blight disease that Rhizoctonia (Rhi-zoctonia) bacterial classification causes
The anthracnose of multiple fruit trees such as the apple that colletotrichum (Colletotrichum) bacterial classification causes, pears, cotton, grape, wax gourd, cucumber, capsicum, eggplant and vegetables.
Making us interested especially in addition is, plant or seed are in disadvantageous growing environment or when coming to harm, using the present composition has the improvement of highly significant to plant or seed opposing adverse circumstance ability, for example recovery is grown, blade is light green, promote root growth etc., plant has the fact of good tolerability to active compound combinations when the needed concentration of controlling plant diseases, allow flower and the fruit and the seed of the acrial part of processing plant.Term " adverse circumstance " comprises unaccommodated humidity, hail, arid, low temperature, rainy, nutritional deficiency, element shortage etc.
The method that bactericidal composition of the present invention uses comprises plant to be processed or its growth place or seed or material, uses the formula I and the formula II reactive compound of total effective active bactericidal amount with mixing.Can before or after fungal infection material, plant or seed, use.
Described formula I is a thiazole zinc, and formula II is for being selected from aforementioned II.1)-II.13) in any one Fungicidal active compound.
Term used herein " growth place " comprises the field of growth process plant or sowing cultivated plant seed, or seed is embedded in the place in the soil.Term " seed " comprises the seed of plant propagation material such as skewer bar, seedling, seed, germination or immersion.
The present composition can be prepared into agricultural and go up acceptable solid, shaped or liquid preparation.This based composition can prepare with known method with suitable auxiliary element by mixed active composition I and II.But the solid, shaped form comprises wetting powder, pulvis, seed treatment dry powder doses, seed treatment dispersion powder, the granule of powdery, and liquid preparation comprises suspending agent, suspension emulsion, microcapsule suspending agent, seed treatment suspending agent, seed treatment microcapsule suspending agent, suspension seed-coating agent.
The described auxiliary element of the present composition comprises that wetting agent, dispersant, thickener, antifreezing agent, preservative, stabilizing agent, film forming agent, defoamer, colouring agent, filler etc. and other are of value to the known substance that active ingredient is stablized or reactive compound is brought into play in preparation, all be the various compositions that commonly used or agriculture upward permission is used in the preparation, be not particularly limited, concrete composition and consumption are determined by test as required.
Described wetting agent is selected from EO/PO block polyether, fatty alcohol-polyoxyethylene ether, fat alcohol ethoxyl compound, tallow ethyoxyl ammonium salt, alkylnaphthalene sulfonate, fatty alcohol polyoxyethylene ether sulfate, acyl group glutamate.
Described dispersant is selected from naphthalene sulfonic acid condensate sodium salt, phenolsulfonic acid condensation product sodium salt, methyl naphthalene sulfonate formaldehyde condensate, sodium lignin sulfonate, sodium metnylene bis-naphthalene sulfonate, acrylate homopolymer sodium salt, polymeric polycarboxylic acid salt, dioctyl sodium sulphosuccinate salt, EO/PO block polyether, maleic acid-acrylic acid copolymer sodium salt.
Described thickener is selected from xanthans, Magnesiumaluminumsilicate, sodium carboxymethylcellulose, starch phosphate sodium, starch Sodium Octenyl Succinate, polyvinyl alcohol.
Described solvent is selected from dimethylbenzene, trimethylbenzene
Described antifreezing agent is selected from ethylene glycol, propane diols, glycerine, isopropyl alcohol, urea.
Described film forming agent selects for use polyvinyl alcohol, polyvinyl acetate, polyethylene glycol polymethylacrylic acid glycol ester, carboxymethyl cellulose, gum Arabic, xanthans, starch etc. to have the high molecular polymer of cohesiveness and film forming.
Described disintegrant selects sodium chloride, ammonium sulfate, sodium sulphate, soluble starch.
Described preservative is selected from formaldehyde, phenyl salicytate, butyl p-hydroxybenzoate, potassium sorbate.
Described stabilizing agent is selected from epoxidized soybean oil, epoxychloropropane, triphenyl phosphite, glycidol ether or pentaerythrite.
Described defoamer is selected from silicone defoaming agent, polyether antifoam agent.
Described colouring agent is selected from iron oxide, titanium oxide, azo dyes.
Described filler is selected from kaolin, diatomite, talcum powder, precipitated calcium carbonate, white carbon.
Described water is deionized water or distilled water.
Active compound combinations described in the invention can prepare with universal method.Therefore, the present invention also comprises the preparation method of above-mentioned bactericidal composition.
The preparation that the present composition is used for controlling plant diseases generally comprises the reactive compound of 1～90 mass percent, preferred 20～60 mass percents.
Bactericidal composition of the present invention can use with itself concentrate form or with general conventional formulation form, different in kind according to the target disease adopts pouring, spraying, atomizing, dresses seed, spreads fertilizer over the fields or brushing method, changes with weather condition, crop state or application process total it uses the effective active bactericidal amount.
Fungicidal active compound composition of the present invention is compared with prior art also has very outstanding advantage:
1. bactericidal composition Synergistic of the present invention is obvious, and it is efficient to bacterial disease to give full play to thiazole zinc, to fungal disease general effectively characteristics and excellent protection performance thereof;
2. bactericidal composition composition of the present invention by different mechanism of action active ingredient form, the resistance that can effectively slow down disease produces, and greatly reduces thiazole zinc or other any known activity compound and uses the resistance risk that brings separately;
3. bactericidal composition of the present invention has not only improved antibiotic or antibacterial effect, also enlarged the diseases prevention spectrum, the bacterial disease and the part fungal disease that can take place crop simultaneously play excellent prevention or result of treatment, reduce the medication number of times, alleviate environmental pressure, thus play put prevention first, the effect of integrated control;
4. bactericidal composition of the present invention alleviates the pressure of agricultural chemicals to environment by the composite usage amount that reduces medicament, has reduced cost simultaneously;
5. bactericidal composition of the present invention can significantly improve the tolerance of crop, makes medicament higher to the safety of crop;
6. making us interested especially is that bactericidal composition of the present invention can lead to microelement-supplementing, thereby promotes plant growing, raising resistance and disease resistance.
Embodiment
In order to make purpose of the present invention, technical scheme and advantage clearer; the present invention describes with following specific embodiment and example; described embodiment is in order to explain the present invention better; rather than limiting the scope of the invention; all all belong to the scope that the present invention asks for protection based on any modification and the change made in basic thought of the present invention and the principle.Therefore, the protection domain of patent of the present invention should be as the criterion with claims.
Preparation embodiment:
In the following term explanation embodiments of the invention, reactive compound I (thiazole zinc) and the composition of Fungicidal active compound II with the specific blend composition of proportions.
One, the preparation of suspending agent
Embodiment 1:
With 40% reactive compound (35.0% thiazole zinc and 5.0% oxime bacterium ester composition), fatty alcohol-polyoxyethylene ether 2.0%, alkylnaphthalene sulfonate 3.0%, sodium metnylene bis-naphthalene sulfonate 1.0%, maleic acid-acrylate homopolymer sodium salt 3.0%, xanthans 0.05%, Magnesiumaluminumsilicate 0.6%, starch Sodium Octenyl Succinate 2.3%, glycerine 2.0%, Phenylsalicylate 0.4%, silicone defoaming agent 0.1%, deionized water is mended to 100%, putting into high shear homogeneous emulsifying machine high speed sheared 20 minutes, transport in the sand mill, the circulation sand milling promptly gets 40% content reactive compound for 1-3 time again.
Embodiment 2:
With 45% reactive compound (40.0% thiazole zinc and 5.0% Difenoconazole composition); alkylnaphthalene sulfonate 2.0%; acyl group glutamate 1.2%; fatty alcohol polyoxyethylene ether sulfate 1.3%; phenolsulfonic acid condensation product sodium salt 2.0%; methyl naphthalene sulfonate formaldehyde condensate 3.0%; starch Sodium Octenyl Succinate 2.0%; glycerine 2.0%; butyl p-hydroxybenzoate 0.2%; silicone defoaming agent 0.1%; deionized water is mended to 100%; putting into high shear homogeneous emulsifying machine high speed sheared 25 minutes; pump sand milling 90 minutes to the sand mill promptly gets 45% content reactive compound after the filtration again.
Embodiment 3:
30% reactive compound (20.0% thiazole zinc and 10.0% azoxystrobin composite), alkylnaphthalene sulfonate 2.0%, acyl group glutamate 2%, fatty alcohol polyoxyethylene ether sulfate 1%, phenolsulfonic acid condensation product sodium salt 1.0%, polymeric polycarboxylic acid salt 2.0%, starch Sodium Octenyl Succinate 2.0%, glycerine 2.0%, silicone defoaming agent 0.1%, deionized water are mended to 100%; putting into high shear homogeneous emulsifying machine high speed sheared 25 minutes; pump sand milling 90 minutes to the sand mill promptly gets 35% reactive compound after the filtration again.
Embodiment 4:
32% reactive compound (30.0% thiazole zinc and 2.0% alkene azoles alcohol composition), tallow ethyoxyl ammonium salt 2.0%, acyl group glutamate 1%, phenolsulfonic acid condensation product sodium salt 2.0%, methyl naphthalene sulfonate formaldehyde condensate 2.0%, starch Sodium Octenyl Succinate 2.0%, glycerine 2.0%, butyl p-hydroxybenzoate 0.2%, silicone defoaming agent 0.2%, deionized water are mended to 100%; putting into high shear homogeneous emulsifying machine high speed sheared 25 minutes; pump sand milling 90 minutes to the sand mill promptly gets 32% reactive compound after the filtration again.
Embodiment 5:
30% reactive compound (10.0% thiazole zinc and 20.0% epoxiconazole composition), alkylnaphthalene sulfonate 2.3%, acyl group glutamate 2%, fatty alcohol polyoxyethylene ether sulfate 1%, polymeric polycarboxylic acid salt 2.0%, sodium lignin sulfonate 2.0%, starch Sodium Octenyl Succinate 2.0%, triphenyl phosphite 0.5%, ethylene glycol 2.0%, silicone defoaming agent 0.1%, deionized water are mended to 100%; putting into high shear homogeneous emulsifying machine high speed sheared 25 minutes; pump sand milling 90 minutes to the sand mill promptly gets 30% reactive compound after the filtration again.
Embodiment 6:
50% reactive compound (10.0% thiazole zinc and 40.0% Flusilazole composition), fatty alcohol-polyoxyethylene ether 2.0%, tallow ethyoxyl amine salt 1.0%, acyl group glutamate 2.0%, polymeric polycarboxylic acid salt 3.0%, naphthalene sulfonic acid condensate sodium salt 1.0%, dioctyl sodium sulphosuccinate salt 1.0%, urea 3.0%, silicone defoaming agent 0.1%, deionized water are added to 100%; put into high shear homogeneous emulsifying machine high speed and shear 20min, again with promptly getting 50% reactive compound behind the high pressure homogenizer homogeneous.
Embodiment 7:
50% reactive compound (25.0% thiazole zinc and 25.0% Flutriafol composition), fatty alcohol ethyl oxide 2.0%, EO/PO block polyether 1.0%, alkylnaphthalene sulfonate 1.0%, polymeric polycarboxylic acid salt 4.0%, acrylate homopolymer sodium salt 1.5%, isopropyl alcohol 2.0%, silicone defoaming agent 0.1%, deionized water are mended to 100%, putting into high shear homogeneous emulsifying machine high speed sheared 30 minutes, transport in the sand mill, the circulation sand milling promptly gets 50% reactive compound 1-3 time again.
Embodiment 8:
40% reactive compound (30.0% thiazole zinc and 10.0% Tebuconazole composition), alkylnaphthalene sulfonate 2.0%, fatty alcohol-polyoxyethylene ether 3.0%, methyl naphthalene sulfonate formaldehyde condensate 2.0%, polymeric polycarboxylic acid salt 2.0%, epoxychloropropane 2.0%, glycerine 2.0%, xanthans 0.3%, silicone defoaming agent 0.1%, deionized water are supplied abundant mixing, put into high shear emulsifying agent high speed again and shear corase grind and homogeneous, pump sand milling to the sand mill again, sand milling promptly gets suspending agent to certain particle diameter after refiltering.Contain 40% content reactive compound in the suspending agent.
Embodiment 9:
With 35% reactive compound (30.0% thiazole zinc and 5.0% is the azoles alcohol composition); alkylnaphthalene sulfonate 2.3%; acyl group glutamate 2.0%; fatty alcohol polyoxyethylene ether sulfate 1%; phenolsulfonic acid condensation product sodium salt 1.0%; methyl naphthalene sulfonate formaldehyde condensate 2.0%; starch Sodium Octenyl Succinate 2.0%; epoxidized soybean oil 5.0%; glycerine 2.0%; silicone defoaming agent 0.1%; deionized water is mended to 100%; putting into high shear homogeneous emulsifying machine high speed sheared 25 minutes; pump sand milling 90 minutes to the sand mill promptly gets 35% reactive compound after the filtration again.
Embodiment 10:
35% reactive compound (30.0% thiazole zinc and 5.0% nitrile bacterium azoles composition), alkylnaphthalene sulfonate 2.0%, acyl group glutamate 2.0%, fatty alcohol-polyoxyethylene ether sulfuric acid 1.0%, phenolsulfonic acid condensation product sodium salt 2.0%, methyl naphthalene sulfonate formaldehyde condensate 2.0%, starch Sodium Octenyl Succinate 2.0%, propane diols 2.0%, silicone defoaming agent 0.1%, deionized water are mended to 100%; putting into high shear homogeneous emulsifying machine high speed sheared 25 minutes; pump sand milling 90 minutes to the sand mill promptly gets 35% reactive compound after the filtration again.
Embodiment 11:
30% reactive compound (10.0% thiazole zinc and 20.0% penconazole composition), fatty alcohol ethyl oxide 4.0%, EO/PO block polyether 1.0%, polymeric polycarboxylic acid salt 4.0%, Magnesiumaluminumsilicate 0.5%, isopropyl alcohol 2.0%, silicone defoaming agent 0.1%, deionized water are mended to 100%, putting into high shear homogeneous emulsifying machine high speed sheared 30 minutes, transport in the sand mill, the circulation sand milling promptly gets 30% reactive compound 1-3 time again.
Embodiment 12:
50% reactive compound (25.0% thiazole zinc and 25.0% propiconazole composition), fatty alcohol ethyl oxide 4.0%, EO/PO block polyether 1.0%, sodium metnylene bis-naphthalene sulfonate 2.0%, polymeric polycarboxylic acid salt 4.0%, xanthans 0.3%, urea 2.0%, silicone defoaming agent 0.1%, deionized water are mended to 100%, putting into high shear homogeneous emulsifying machine high speed sheared 30 minutes, transport in the sand mill, the circulation sand milling promptly gets 50% reactive compound 1-3 time again.
Embodiment 13:
35% reactive compound (30.0% thiazole zinc and 5.0% Triadimenol composition), alkylnaphthalene sulfonate 1.3%, acyl group glutamate 2.0%, fatty alcohol polyoxyethylene ether sulfate 1%, phenolsulfonic acid condensation product sodium salt 1.0%, methyl naphthalene sulfonate formaldehyde condensate 2.0%, starch Sodium Octenyl Succinate 2.0%, glycerine 2.0%, silicone defoaming agent 0.1%, deionized water are mended to 100%; putting into high shear homogeneous emulsifying machine high speed sheared 25 minutes; pump sand milling 90 minutes to the sand mill promptly gets 35% reactive compound after the filtration again.
Embodiment 14:
35% reactive compound (30.0% thiazole zinc and 5.0% bitertanol composition), alkylnaphthalene sulfonate 2.3%, acyl group glutamate 2%, fatty alcohol-polyoxyethylene ether 1.0%, phenolsulfonic acid condensation product sodium salt 1.0%, methyl naphthalene sulfonate formaldehyde condensate 2.0%, starch Sodium Octenyl Succinate 2.0%, urea 2.0%, silicone defoaming agent 0.1%, deionized water are mended to 100%; putting into high shear homogeneous emulsifying machine high speed sheared 25 minutes; pump sand milling 90 minutes to the sand mill promptly gets 35% reactive compound after the filtration again.
Embodiment 15:
40% reactive compound (20.0% thiazole zinc and 20.0% Thiodiazole-copper composition), alkylnaphthalene sulfonate 2.3%, acyl group glutamate 2.0%, fatty alcohol polyoxyethylene ether sulfate 1.0%, phenolsulfonic acid condensation product sodium salt 1.0%, methyl naphthalene sulfonate formaldehyde condensate 2.0%, sodium carboxymethylcellulose 1.0%, glycerine 2.0%, polyether antifoam agent 0.1%, deionized water are mended to 100%; putting into high shear homogeneous emulsifying machine high speed sheared 25 minutes; pump sand milling 90 minutes to the sand mill promptly gets 40% reactive compound after the filtration again.
Embodiment 16:
50% reactive compound (25.0% thiazole zinc and 25.0% metalaxyl composition), fatty alcohol ethyl oxide 4.0%, EO/PO block polyether 1.0%, naphthalene sulfonic acid condensate sodium salt 2.0%, polymeric polycarboxylic acid salt 4.0%, polyvinyl alcohol 0.5%, urea 2.0%, silicone defoaming agent 0.1%, deionized water are mended to 100%, putting into high shear homogeneous emulsifying machine high speed sheared 30 minutes, transport in the sand mill, the circulation sand milling promptly gets 50% reactive compound 1-3 time again.
Embodiment 17:
40% reactive compound (20.0% thiazole zinc and 20.0% flutolanil composition), fatty alcohol ethyl oxide 4.0%, EO/PO block polyether 1.0%, acrylate homopolymer sodium salt 1.0%, polymeric polycarboxylic acid salt 4.0%, polyvinyl alcohol 0.5%, epoxidized soybean oil 5.0%, urea 2.0%, silicone defoaming agent 0.1%, deionized water are mended to 100%, putting into high shear homogeneous emulsifying machine high speed sheared 30 minutes, transport in the sand mill, the circulation sand milling promptly gets 50% reactive compound 1-3 time again.
Embodiment 18:
40% reactive compound (20.0% thiazole zinc and 20.0% carboxin composition), fatty alcohol ethyl oxide 4.0%, EO/PO block polyether 1.0%, maleic acid-acrylic acid copolymer sodium salt 2.0%, polymeric polycarboxylic acid salt 3.0%, polyvinyl alcohol 0.5%, urea 2.0%, silicone defoaming agent 0.1%, deionized water are mended to 100%, putting into high shear homogeneous emulsifying machine high speed sheared 30 minutes, transport in the sand mill, the circulation sand milling promptly gets 40% reactive compound 1-3 time again.
Embodiment 19:
60% reactive compound (20.0% thiazole zinc and 40.0% probenazole composition), fat alcohol ethoxyl compound 3.0%, alkylnaphthalene sulfonate 1.0%, fatty alcohol polyoxyethylene ether sulfate 4.0%, phenolsulfonic acid condensation product sodium salt 3.0%, sodium metnylene bis-naphthalene sulfonate 1.5%, methyl naphthalene sulfonate formaldehyde condensate 0.5%, silicone defoaming agent 0.2%, distilled water are added to 100%, put into high shear homogeneous emulsifying machine high speed and shear 30min, again with promptly getting 60% reactive compound behind the high pressure homogenizer homogeneous.
Embodiment 20:
With 60% reactive compound (35.0% thiazole zinc and 25.0% Prochloraz composition), fatty alcohol-polyoxyethylene ether 3.0%, alkylnaphthalene sulfonate 1.0%, sodium metnylene bis-naphthalene sulfonate 2.0%, EO/PO block co-polyether 2.0%, maleic acid-acrylate homopolymer sodium salt 1.0%, xanthans 0.05%, Magnesiumaluminumsilicate 0.6%, pentaerythrite 1%, glycerine 2.0%, phenyl salicytate 0.4%, silicone defoaming agent 0.1%, deionized water is mended to 100%, putting into high shear homogeneous emulsifying machine high speed sheared 20 minutes, transport in the sand mill, the circulation sand milling promptly gets 60% content reactive compound for 1-3 time again.
Embodiment 21:
65 parts of reactive compounds (60.0% thiazole zinc and 5.0% tetramycin composition) fatty alcohol ethyl oxide 4.0%, EO/PO block polyether 1.0%, naphthalene sulfonic acid condensate sodium salt 2.0%, polymeric polycarboxylic acid salt 4.0%, polyvinyl alcohol 0.5%, urea 2.0%, silicone defoaming agent 0.1%, deionized water are mended to 100%, putting into high shear homogeneous emulsifying machine high speed sheared 30 minutes, transport in the sand mill, the circulation sand milling promptly gets 65% reactive compound 1-3 time again.
Embodiment 22:
40% reactive compound (20.0% thiazole zinc and 20.0% iprodione composition), fatty alcohol ethyl oxide 2.0%, EO/PO block polyether 1.0%, sulfomethylated lignin ester sodium 1.0%, polymeric polycarboxylic acid salt 4.0%, polyvinyl alcohol 0.5%, epoxidized soybean oil 5%, urea 2.0%, silicone defoaming agent 0.1%, deionized water are mended to 100%, putting into high shear homogeneous emulsifying machine high speed sheared 30 minutes, transport in the sand mill, the circulation sand milling promptly gets 40% reactive compound 1-3 time again.
Embodiment 23:
50% reactive compound (15.0% thiazole zinc and 35.0% propamocarb composition), fatty alcohol-polyoxyethylene ether 3.0%, EO/PO block polyether 1.0%, polymeric polycarboxylic acid salt 4.0%, starch phosphate sodium 0.5%, pentaerythrite 1.0%, urea 2.0%, silicone defoaming agent 0.1%, deionized water are mended to 100%, putting into high shear homogeneous emulsifying machine high speed sheared 30 minutes, transport in the sand mill, the circulation sand milling promptly gets 50% reactive compound 1-3 time again.
Embodiment 24:
65% reactive compound (50.0% thiazole zinc and 15.0% jinggangmeisu composition) fatty alcohol ethyl oxide 4.0%, EO/PO block polyether 1.0%, methyl naphthalene sulfonate formaldehyde condensate 2.0%, polymeric polycarboxylic acid salt 4.0%, polyvinyl alcohol 0.5%, urea 2.0%, silicone defoaming agent 0.1%, deionized water are mended to 100%, putting into high shear homogeneous emulsifying machine high speed sheared 30 minutes, transport in the sand mill, the circulation sand milling promptly gets 65% reactive compound 1-3 time again.
Embodiment 25:
65% reactive compound (60.0% thiazole zinc and 5.0% kasugarnycin composition) fatty alcohol-polyoxyethylene ether 4.0%, EO/PO block polyether 2.0%, naphthalene sulfonic acid condensate sodium salt 2.0%, polymeric polycarboxylic acid salt 4.0%, polyvinyl alcohol 0.5%, urea 2.0%, silicone defoaming agent 0.1%, deionized water are mended to 100%, putting into high shear homogeneous emulsifying machine high speed sheared 30 minutes, transport in the sand mill, the circulation sand milling promptly gets 65% reactive compound 1-3 time again.
Embodiment 26:
With 35% reactive compound (20.0% thiazole zinc and 15.0% Wakil composition); alkylnaphthalene sulfonate 2.3%; acyl group glutamate 2.0%; fatty alcohol polyoxyethylene ether sulfate 1.0%; phenolsulfonic acid condensation product sodium salt 1.0%; methyl naphthalene sulfonate formaldehyde condensate 2.0%; starch Sodium Octenyl Succinate 2.0%; pentaerythrite 1%; glycerine 2.0%; silicone defoaming agent 0.1%; deionized water is mended to 100%; putting into high shear homogeneous emulsifying machine high speed sheared 25 minutes; pump sand milling 90 minutes to the sand mill promptly gets 35% reactive compound after the filtration again.
Embodiment 27:
50% reactive compound (25.0% thiazole zinc and 25.0% is disliked mould clever composition), alkylnaphthalene sulfonate 4.0%, EO/PO block polyether 1.0%, sodium metnylene bis-naphthalene sulfonate 1.0%, polymeric polycarboxylic acid salt 4.0%, polyvinyl alcohol 0.5%, epoxidized soybean oil 5.0%, urea 2.0%, silicone defoaming agent 0.1%, deionized water are mended to 100%, putting into high shear homogeneous emulsifying machine high speed sheared 30 minutes, transport in the sand mill, the circulation sand milling promptly gets 50% reactive compound 1-3 time again.
Embodiment 28:
With 50% reactive compound (35.0% thiazole zinc and 15.0% dimethomorph composition); alkylnaphthalene sulfonate 2.0%; acyl group glutamate 1.2%; fatty alcohol polyoxyethylene ether sulfate 1.3%; phenolsulfonic acid condensation product sodium salt 2.0%; methyl naphthalene sulfonate formaldehyde condensate 2.0%; starch Sodium Octenyl Succinate 2.0%; glycerine 2.0%; butyl p-hydroxybenzoate 0.2%; silicone defoaming agent 0.1%; deionized water is mended to 100%; putting into high shear homogeneous emulsifying machine high speed sheared 25 minutes; pump sand milling 90 minutes to the sand mill promptly gets 50% content reactive compound after the filtration again.
Embodiment 29:
40% reactive compound (20.0% thiazole zinc and 20.0% phonetic mould amine composition), fatty alcohol ethyl oxide 4.0%, EO/PO block polyether 1.0%, sulfomethylated lignin ester sodium 1.0%, polymeric polycarboxylic acid salt 4.0%, polyvinyl alcohol 0.5%, triphenyl phosphite 1%, urea 2.0%, silicone defoaming agent 0.1%, deionized water are mended to 100%, putting into high shear homogeneous emulsifying machine high speed sheared 30 minutes, transport in the sand mill, the circulation sand milling promptly gets 40% reactive compound 1-3 time again.
Embodiment 30:
40% reactive compound (the phonetic phenol composition of 20.0% thiazole zinc and 20.0% second), fatty alcohol ethyl oxide 2.0%, EO/PO block polyether 2.0%, dioctyl sodium sulphosuccinate salt 2.0%, polymeric polycarboxylic acid salt 3.0%, polyvinyl alcohol 0.5%, urea 2.0%, silicone defoaming agent 0.1%, deionized water are mended to 100%, putting into high shear homogeneous emulsifying machine high speed sheared 30 minutes, transport in the sand mill, the circulation sand milling promptly gets 40% reactive compound 1-3 time again.
Embodiment 31:
40% reactive compound (20.0% thiazole zinc and 20.0% dithianon composition), alkylnaphthalene sulfonate 2.0%, fatty alcohol-polyoxyethylene ether 3.0%, sodium lignin sulfonate 2.0%, methyl naphthalene sulfonate formaldehyde condensate 2.0%, glycerine 2%, xanthans 0.3%, silicone defoaming agent 0.1%, deionized water are supplied abundant mixing, put into high shear emulsifying agent high speed again and shear corase grind and homogeneous, pump sand milling to the sand mill again, sand milling promptly gets suspending agent to certain particle diameter after refiltering.Contain 40% content reactive compound in the suspending agent.
Embodiment 32:
65% reactive compound (30.0% thiazole zinc and 35.0% tpn composition) fatty alcohol ethyl oxide 4.0%, EO/PO block polyether 1.0%, naphthalene sulfonic acid condensate sodium salt 2.0%, polymeric polycarboxylic acid salt 4.0%, polyvinyl alcohol 0.5%, glycidol ether 1%, urea 2.0%, silicone defoaming agent 0.1%, deionized water are mended to 100%, putting into high shear homogeneous emulsifying machine high speed sheared 30 minutes, transport in the sand mill, the circulation sand milling promptly gets 65% reactive compound 1-3 time again.
Two, microcapsule suspending agent
Embodiment 33:
With 25% reactive compound (10.0% thiazole zinc and 15.0% fluazinam composition): thiazole zinc 50.0%, silicone defoaming agent 0.1%, deionized water 49.9% are fully mixed, put into sand milling in the sand mill again, sand milling promptly gets suspending agent to certain particle diameter after refiltering.Contain 50.0% thiazole zinc in the suspending agent, the D90 particle diameter is the 3-5 micron.Again 20.0% 50.0% thiazole zincium suspension agent, fluazinam 15.0%, alkylnaphthalene sulfonate 1.0%, acyl group glutamate 2.0%, fatty alcohol polyoxyethylene ether sulfate 1.0%, phenolsulfonic acid condensation product sodium salt 1.0%, methyl naphthalene sulfonate formaldehyde condensate 1.0%, urea 2.0%, glycerine 2.0%, deionized water are mended to 100%; put into and be warming up to 80 ℃ in the high shear homogeneous emulsifying machine; emulsifying rate is 1200 rev/mins; high speed shear 25 minutes; temperature was bathed 120 minutes, promptly got 25% reactive compound after the filtration.
Three, the preparation of water dispersible granules
Method one: after agricultural chemicals, dispersant, disintegrant, wetting agent, binding agent etc. are mixed, by comminution by gas stream, granulating and forming.
Embodiment 34:
60% reactive compound (20.0% thiazole zinc and 40.0% procymidone composition), fatty alcohol-polyoxyethylene ether 4.0%, lignosulfonates 3.0%, sodium chloride 15.0%, polyvinyl alcohol 2.0%, kaolin 16.0% fully mix, by comminution by gas stream, granulating and forming gets water dispersible granules again.Contain 60% content reactive compound in the water dispersible granules, product cut size is the 80-120 order.
Embodiment 35:
60% reactive compound (20.0% thiazole zinc and 40.0% cyprodinil composition), lignosulfonates 3.0%, naphthalene sulfonate 3.0%, ammonium sulfate 15.0%, xanthans 1.0%, talcum powder 1.0%, kaolin 17.0% fully mix, by comminution by gas stream, granulating and forming gets water dispersible granules again.Contain 60% content reactive compound in the water dispersible granules, product cut size is the 80-120 order.
Embodiment 36:
60% reactive compound (40.0% thiazole zinc and 20.0% captan composition), EO/PO block polyether 4.0%, lignosulfonates 3.0%, soluble starch 5.0%, polyvinyl alcohol 2.0%, precipitated calcium carbonate 3.0%, diatomite 23.0% fully mix, by comminution by gas stream, granulating and forming gets water dispersible granules again.Contain 60% content reactive compound in the water dispersible granules, product cut size is the 80-120 order.
Embodiment 37:
60% reactive compound (20.0% thiazole zinc and 40.0% dimethachlon composition), fatty alcohol-polyoxyethylene ether 4.0%, lignosulfonates 3.0%, sodium sulphate 15.0%, polyvinyl alcohol 2.0%, white carbon black 2.0%, kaolin 16.0% fully mix, by comminution by gas stream, granulating and forming gets water dispersible granules again.Contain 60% content reactive compound in the water dispersible granules, product cut size is the 80-120 order.
Method two: agricultural chemicals and various auxiliary agent are ground in water, be deployed into slurry after granulating and drying obtain.
Embodiment 38:
50% reactive compound (20.0% thiazole zinc and 30.0% benomyl composition), EO/PO block polyether 7.0%, fatty alcohol-polyoxyethylene ether 5.0%, sodium sulphate 6.0%, xanthans 1.0%, kaolin 31.0% are fully mixed, put into high shear emulsifying agent high speed again and shear corase grind and homogeneous, pump sand milling to the sand mill again, sand milling is to certain particle diameter, and granulating and forming gets water dispersible granules again.Contain 50% content reactive compound in the water dispersible granules, product cut size is the 80-120 order.
Embodiment 39:
55% reactive compound (the mould prestige composition of 40.0% thiazole zinc and 15.0% second), EO/PO block polyether 4.0%, naphthalene sulfonate 3.0%, soluble starch 5.0%, xanthans 1.0%, diatomite 32.0% are fully mixed, put into high shear emulsifying agent high speed again and shear corase grind and homogeneous, pump sand milling to the sand mill again, sand milling is to certain particle diameter, and granulating and forming gets water dispersible granules again.Contain 55% content reactive compound in the water dispersible granules, product cut size is the 80-120 order.
Embodiment 40:
60% reactive compound (35.0% thiazole zinc and 25.0% carbendazim composition), EO/PO block polyether 4.0%, fatty alcohol-polyoxyethylene ether 6.0%, sodium chloride 11.0%, xanthans 2.0%, kaolin 17.0% are fully mixed, put into high shear emulsifying agent high speed again and shear corase grind and homogeneous, pump sand milling to the sand mill again, sand milling is to certain particle diameter, and granulating and forming gets water dispersible granules again.Contain 60% content reactive compound in the water dispersible granules, product cut size is the 80-120 order.
Embodiment 41:
60% reactive compound (35.0% thiazole zinc and 25.0% thiophanate-methyl composition), EO/PO block polyether 4.0%, fatty alcohol-polyoxyethylene ether 6.0%, ammonium sulfate 11.0%, xanthans 2.0%, kaolin 17.0% are fully mixed, put into high shear emulsifying agent high speed again and shear corase grind and homogeneous, pump sand milling to the sand mill again, sand milling is to certain particle diameter, and granulating and forming gets water dispersible granules again.Contain 60% content reactive compound in the water dispersible granules, product cut size is the 80-120 order.
Embodiment 42:
65% reactive compound (60.0% thiazole zinc and 5.0% streptomycin sulphate composition), lignosulfonates 6.0%, naphthalene sulfonate 3.0%, sodium sulphate 10.0%, xanthans 1.0%, kaolin 15.0% are fully mixed, put into high shear emulsifying agent high speed again and shear corase grind and homogeneous, pump sand milling to the sand mill again, sand milling is to certain particle diameter, fully mediate with 15% kaolin again, get water dispersible granules through granulating and forming.Contain 65% content reactive compound in the water dispersible granules, product cut size is the 80-120 order.
Four, the preparation of wetting powder
By the prescription requirement, former medicine, various auxiliary agent and filler etc. are fully mixed in the ratio of prescription, after pulverizing, ultrafine crusher can obtain.
Embodiment 43:
35% reactive compound (20.0% thiazole zinc and 15.0% tridemorph composition), lauryl sodium sulfate 4.0%, sodium lignin sulfonate 5.0%, white carbon 2.0%, kaolin 56.0% are fully mixed, by the extremely certain particle diameter of ultra-fine grinding, get wetting powder again.Contain 35% content reactive compound in the wetting powder.
Embodiment 44:
50% reactive compound (35.0% thiazole zinc and 15.0% dimethomorph composition), polymeric polycarboxylic acid salt 3%, talcum powder 1.0%, precipitated calcium carbonate 5.0%, kaolin 46.0% are fully mixed, by the extremely certain particle diameter of ultra-fine grinding, get wetting powder again.Contain 50% content reactive compound in the wetting powder.
Embodiment 45:
60% reactive compound (10.0% thiazole zinc and 50.0% tmtd composition), naphthalene sulfonic acid condensate sodium salt 1.0%, polymeric polycarboxylic acid salt 2.0%, talcum powder 2.0%, precipitated calcium carbonate 5.0%, kaolin 30.0% are fully mixed, by the extremely certain particle diameter of ultra-fine grinding, get wetting powder again.Contain 60% content reactive compound in the wetting powder.
Embodiment 46:
70% reactive compound (20.0% thiazole zinc and 50.0% mancozeb composition), naphthalene sulfonic acid condensate sodium salt 1.0%, polymeric polycarboxylic acid salt 2.0%, white carbon 2.0%, precipitated calcium carbonate 3.0%, diatomite 22.0% are fully mixed, by the extremely certain particle diameter of ultra-fine grinding, get wetting powder again.Contain 70% content reactive compound in the wetting powder.
Embodiment 47:
70% reactive compound (20.0% thiazole zinc and 50.0% zineb composition), phenolsulfonic acid condensation product sodium salt 1.0%, polymeric polycarboxylic acid salt 2.0%, white carbon 3.0%, precipitated calcium carbonate 2.0%, kaolin 22.0% are fully mixed, by the extremely certain particle diameter of ultra-fine grinding, get wetting powder again.Contain 70% content reactive compound in the wetting powder.
Embodiment 48:
70% reactive compound (20.0% thiazole zinc and 50.0% Propineb composition), methyl naphthalene sulfonate formaldehyde condensate 1.0%, polymeric polycarboxylic acid salt 2.0%, white carbon 2.0%, precipitated calcium carbonate 3.0%, diatomite 22.0% are fully mixed, by the extremely certain particle diameter of ultra-fine grinding, get wetting powder again.Contain 70% content reactive compound in the wetting powder.
Five, plant the preparation of clothing agent
The preparation of suspension seed-coating agent
By the prescription requirement, former medicine, auxiliary agent and inserts, film forming agent etc. are fully mixed, put into high shear emulsifying agent high speed and shear, pump sand milling to the sand mill promptly gets the agent of floating type kind clothing after the filtration again.
Embodiment 49:
16% reactive compound (15.0% thiazole zinc and 1.0% fludioxonil composition), alkylnaphthalene sulfonate 1.0%, fatty alcohol-polyoxyethylene ether 3.0%, acrylate homopolymer sodium salt 1.0%, carboxymethyl cellulose 1.0%, glycerine 3.0%, xanthans 0.2%, silicone defoaming agent 0.1%, azo dyes 0.2%, deionized water 74.5% are fully mixed, put into high shear emulsifying agent high speed again and shear corase grind and homogeneous, pump sand milling to the sand mill again, sand milling promptly gets the agent of floating type kind clothing to certain particle diameter after refiltering.Contain 16% content reactive compound, D in the agent of floating type kind clothing
90Particle diameter is the 3-5 micron.
Embodiment 50:
30% reactive compound (18.0% thiazole zinc and 12.0% Prochloraz composition), alkylnaphthalene sulfonate 2.0%, fatty alcohol-polyoxyethylene ether 3.0%, methyl naphthalene sulfonate formaldehyde condensate 2.0%, gum Arabic 2.0%, glycerine 3.0%, xanthans 0.2%, iron oxide 0.2%, silicone defoaming agent 0.1%, deionized water 57.5% are fully mixed, put into high shear emulsifying agent high speed again and shear corase grind and homogeneous, pump sand milling to the sand mill again, sand milling promptly gets the agent of floating type kind clothing to certain particle diameter after refiltering.Contain 30% content reactive compound, D in the agent of floating type kind clothing
90Particle diameter is the 3-5 micron.
Embodiment 51:
45% reactive compound (20.0% thiazole zinc and 25.0% pcnb composition), naphthalene sulfonate 2.0%, polymeric polycarboxylic acid salt 3.0%, methyl naphthalene sulfonate formaldehyde condensate 2.0%, polyvinyl acetate 2.0%, ethylene glycol 3.0%, carboxymethyl cellulose 0.2%, polyether antifoam agent 0.1%, titanium oxide 0.2%, deionized water 42.5% are fully mixed, put into high shear emulsifying agent high speed again and shear corase grind and homogeneous, pump sand milling to the sand mill again, sand milling promptly gets the agent of floating type kind clothing to certain particle diameter after refiltering.Contain 45% content reactive compound, D in the agent of floating type kind clothing
90Particle diameter is the 3-5 micron.
Six, seed treatment dry powder doses
Embodiment 52:
40% reactive compound (20.0% thiazole zinc and 20.0% carbendazim composition), naphthalene sulfonic acid condensate sodium salt 2.0%, talcum powder 2.0%, precipitated calcium carbonate 5.0%, diatomite 51.0% are fully mixed, by the extremely certain particle diameter of ultra-fine grinding, get dry powder doses again.Contain 40% content reactive compound in the dry powder doses.
But seven, seed treatment dispersible granule
Embodiment 53:
50% reactive compound (20.0% thiazole zinc and 30.0% Prochloraz composition), EO/PO block polyether 7.0%, fatty alcohol-polyoxyethylene ether 5.0%, sodium sulphate 6.0%, xanthans 1.0%, kaolin 31.0% are fully mixed, put into high shear emulsifying agent high speed again and shear corase grind and homogeneous, pump sand milling to the sand mill again, sand milling is to certain particle diameter, and granulating and forming gets water dispersible granules again.Contain 50% content reactive compound in the water dispersible granules, product cut size is the 80-120 order.
Eight, seed treatment suspending agent
Embodiment 54:
With 35% reactive compound (20.0% thiazole zinc and 15.0% Wakil composition); alkylnaphthalene sulfonate 2.0%; acyl group glutamate 1.0%; fatty alcohol polyoxyethylene ether sulfate 1.0%; phenolsulfonic acid condensation product sodium salt 1.0%; methyl naphthalene sulfonate formaldehyde condensate 1.0%; starch Sodium Octenyl Succinate 2.0%; polyethylene glycol polymethylacrylic acid glycol ester 2.0%; pentaerythrite 1.0%; glycerine 2.0%; silicone defoaming agent 0.1%; deionized water is mended to 100%; putting into high shear homogeneous emulsifying machine high speed sheared 25 minutes; pump sand milling 60 minutes to the sand mill promptly gets 35% reactive compound after the filtration again.
Nine, seed treatment microcapsule suspending agent
Embodiment 55:
With 35% reactive compound (30.0% thiazole zinc and 5.0% triazolone composition): thiazole zinc 50.0%, polyether antifoam agent 0.5%, deionized water 49.5% are fully mixed, drop into sand milling in the sand mill again, sand milling promptly gets suspending agent to certain particle diameter after refiltering.Contain 50.0% thiazole zinc in the suspending agent, the D90 particle diameter is the 3-5 micron.Again 60.0% 50.0% thiazole zincium suspension agent, triazolone 5.0%, alkylnaphthalene sulfonate 1.0%, acyl group glutamate 2.0%, fatty alcohol polyoxyethylene ether sulfate 1.0%, phenolsulfonic acid condensation product sodium salt 1.0%, methyl naphthalene sulfonate formaldehyde condensate 1.0%, starch Sodium Octenyl Succinate 1.0%, glycerine 2.0%, deionized water are mended to 100%; put into and be warming up to 70 ℃ in the high shear homogeneous emulsifying machine; emulsifying rate is 1200 rev/mins; high speed shear 25 minutes; temperature was bathed 120 minutes, promptly got 35% reactive compound after the filtration.
Ten, the preparation of suspension emulsion
Embodiment 56:
With 25% reactive compound (20.0% thiazole zinc and 5.0% is the azoles alcohol composition): 40.0% thiazole zinc, EO/PO block polyether 1%, phenolsulfonic acid condensation product sodium salt 2%, acrylate homopolymer sodium salt 1.0%, ethylene glycol 2.0%, xanthans 0.3%, polyether antifoam agent 0.1%, deionized water 54.6% are fully mixed, put into high shear emulsifying agent high speed again and shear corase grind and homogeneous, pump sand milling to the sand mill again, sand milling promptly gets suspending agent to certain particle diameter after refiltering.Contain 40.0% thiazole zinc in the suspending agent, the D90 particle diameter is the 3-5 micron.Again with 50.0% 40.0% thiazole zincium suspension agent, azoles alcohol 5.0%, dimethylbenzene 10.0%, acrylate homopolymer sodium salt 3.0%, fatty alcohol-polyoxyethylene ether 3.0%, ethylene glycol 3.0%, xanthans 0.1%, polyether antifoam agent 0.1%, deionized water 25.8% fully mix, high speed shear, emulsifying, filtration promptly make suspension emulsion, and suspension emulsion contains the reactive compound of 25% content.
Embodiment 57:
With 30% reactive compound (20.0% thiazole zinc and 10.0% Tebuconazole composition): 40.0% thiazole zinc, EO/PO block polyether 1.0%, phenolsulfonic acid condensation product sodium salt 2.0%, acrylate homopolymer sodium salt 1.0%, ethylene glycol 2.0%, xanthans 0.3%, polyether antifoam agent 0.1%, deionized water 54.6% are fully mixed, put into high shear emulsifying agent high speed again and shear corase grind and homogeneous, pump sand milling to the sand mill again, sand milling promptly gets suspending agent to certain particle diameter after refiltering.Contain 40.0% thiazole zinc in the suspending agent, the D90 particle diameter is the 3-5 micron.Again 50.0% 40.0% thiazole zincium suspension agent, Tebuconazole 10.0%, dimethylbenzene 15.0%, naphthalene sulfonic acid condensate sodium salt 3%, fat alcohol ethoxyl compound 5.0%, ethylene glycol 4.0%, sodium carboxymethylcellulose 0.3%, polyether antifoam agent 0.1%, deionized water 12.6% are fully mixed, high speed shear, emulsifying, filtration promptly make suspension emulsion, and suspension emulsion contains the reactive compound of 30% content.
Embodiment 58:
With 35% reactive compound (25.0% thiazole zinc and 10.0% carboxin composition): thiazole zinc 50.0%, EO/PO block polyether 2.0%, methyl naphthalene sulfonate formaldehyde condensate 3.0%, acrylate homopolymer sodium salt 1.0%, glycerine 2.0%, xanthans 0.3%, potassium sorbate 0.1%, polyether antifoam agent 0.1%, deionized water 41.5% are fully mixed, put into high shear emulsifying agent high speed again and shear corase grind and homogeneous, pump sand milling to the sand mill again, sand milling promptly gets suspending agent to certain particle diameter after refiltering.Contain 50% thiazole zinc in the suspending agent, the D90 particle diameter is the 3-5 micron.Again 50.0% 50.0% thiazole zincium suspension agent, carboxin 10.0%, trimethylbenzene 15.0%, tallow ethyoxyl ammonium salt 3.0%, fat alcohol ethoxyl compound 4.0%, glycerine 2.0%, sodium carboxymethylcellulose 0.3%, polyether antifoam agent 0.1%, deionized water 15.6% are fully mixed, high speed shear, emulsifying, filtration promptly make suspension emulsion, and suspension emulsion contains the reactive compound of 35% content.
Embodiment 59:
With 40% reactive compound (25.0% thiazole zinc and 15.0% dimethomorph composition): thiazole zinc 50.0%, EO/PO block polyether 2.0%, methyl naphthalene sulfonate formaldehyde condensate 3.0%, acrylate homopolymer sodium salt 1.0%, glycerine 2.0%, xanthans 0.3%, potassium sorbate 0.1%, polyether antifoam agent 0.1%, deionized water 41.5% are fully mixed, put into high shear emulsifying agent high speed again and shear corase grind and homogeneous, pump sand milling to the sand mill again, sand milling promptly gets suspending agent to certain particle diameter after refiltering.Contain 50.0.% thiazole zinc in the suspending agent, the D90 particle diameter is the 3-5 micron.Again 50.0% 50.0% thiazole zincium suspension agent, dimethomorph 15.0%, trimethylbenzene 15.0%, fatty alcohol-polyoxyethylene ether 3.0%, fat alcohol ethoxyl compound 4.0%, glycerine 3.0%, sodium carboxymethylcellulose 0.3%, polyether antifoam agent 0.1%, deionized water 9.6% are fully mixed, high speed shear, emulsifying, filtration promptly make suspension emulsion, and suspension emulsion contains the reactive compound of 40% content.
Biologicall test example 1:
Citrus ulcer bacteria (Xanthomonas campestris) activity test
Test method: with reference to " the agricultural industry criteria NY/T 1156.16-2008 of the People's Republic of China (PRC) ", nephelometry.Adopt the DPS data handling system to calculate EC
50, calculate synergy ratio SR according to the Wadley method, estimate synergy.SR is greater than 1.5 for synergistic effect, and SR is between 0.5～1.5 being summation action, and SR is an antagonism less than 0.5.
Theoretical (mixing)
(all adopt the DPS in this example to calculate EC in the following example
50The evaluation synergy that is mixed with the Wadley method)
The result shows: thiazole zinc and Kocide SD are mixed all had summation action to the active proportioning of citrus ulcer bacteria between 30: 1～1: 30, and can improve the safety of reactive compound to plant.(seeing Table 1)
Table 1, thiazole zinc and Kocide SD are mixed to the citrus ulcer bacteria virulence
| Handle | Proportioning | Actual measurement EC 50(mg/L) | Theoretical EC 50(mg/L) | Synergy ratio (SR) |
| I thiazole zinc | 1∶0 | 19.14 | 19.14 | 1.00 |
| The II Kocide SD | 0∶1 | 83.63 | 83.63 | 1.00 |
| I∶II | 30∶1 | 21.52 | 19.63 | 0.91 |
| I∶II | 10∶1 | 15.65 | 20.58 | 1.32 |
| I∶II | 1∶1 | 26.51 | 31.15 | 1.18 |
| I∶II | 1∶15 | 59.23 | 69.08 | 1.17 |
| I∶II | 1∶30 | 72.89 | 75.43 | 1.03 |
Biologicall test example 2:
Soft rot of cabbage bacterium (Erwinia carotovora) activity test
Test method: with reference to " the agricultural industry criteria NY/T 1156.16-2008 of the People's Republic of China (PRC) ", nephelometry.
Result of the test shows: thiazole zinc and kasugarnycin proportioning had synergistic effect at 30: 1 and 10: 1, and proportioning can reduce use cost, delaying drug resistance between 50: 1～1: 5.(seeing Table 2)
Table 2, thiazole zinc and kasugarnycin are mixed to Chinese cabbage Bacteria erwinia virulence
| Handle | Proportioning | Actual measurement EC 50(mg/L) | Theoretical EC 50(mg/L) | Synergy ratio (SR) |
| I thiazole zinc | 1∶0 | 15.26 | 15.26 | 1.00 |
| The II kasugarnycin | 0∶1 | 29.57 | 29.57 | 1.00 |
| I∶II | 50∶1 | 13.01 | 15.41 | 1.18 |
| I∶II | 30∶1 | 9.11 | 15.50 | 1.70 |
| I∶II | 10∶1 | 10.28 | 15.96 | 1.55 |
| I∶II | 1∶1 | 17.76 | 20.13 | 1.13 |
| I∶II | 1∶5 | 25.44 | 25.57 | 1.01 |
Biologicall test example 3:
Cucumber bacterial angular leaf spot bacterium (Pseudomonas syringae) activity test
Test method: with reference to " the agricultural industry criteria NY/T 1156.16-2008 of the People's Republic of China (PRC) ", nephelometry.
Result of the test shows: thiazole zinc and the streptomycin sulphate proportioning that is mixed all had summation action between 30: 1～1: 50, and proportioning is that the be mixed generation of effective delaying drug resistance of synergistic effect, thiazole zinc and streptomycin sulphate was arranged in 1: 1 o'clock.(seeing Table 3)
Table 3, thiazole zinc and streptomycin sulphate are mixed to cucumber bacterial angular leaf spot bacterium power
| Handle | Proportioning | Actual measurement EC 50(mg/L) | Theoretical EC 50(mg/L) | Synergy ratio (SR) |
| I thiazole zinc | 1∶0 | 12.09 | 12.09 | 1.00 |
| The II streptomycin sulphate | 0∶1 | 57.25 | 57.25 | 1.00 |
| I∶II | 30∶1 | 9.82 | 12.41 | 1.26 |
| I∶II | 15∶1 | 9.17 | 12.72 | 1.39 |
| I∶II | 1∶1 | 10.55 | 19.96 | 1.89 |
| I∶II | 1∶10 | 31.76 | 42.74 | 1.35 |
| I∶II | 1∶30 | 47.91 | 51.09 | 1.07 |
| I∶II | 1∶50 | 58.00 | 53.34 | 0.92 |
Biologicall test example 4:
Peach bacterial shot hole bacterium (Xanthomonas campestris) activity test
Test method: with reference to " the agricultural industry criteria NY/T 1156.16-2008 of the People's Republic of China (PRC) ", nephelometry.
Result of the test shows: thiazole zinc and mancozeb are mixed to the active synergy of peach bacterial shot hole bacterium obviously, proportioning is higher than using the activity of sum in proportion down separately between 20: 1～1: 50, especially at 1: 1 obvious synergistic effect is arranged, be mixed to use and also can reduce both usage amounts.(seeing Table 4)
Table 4, thiazole zinc and mancozeb are mixed to peach bacterial shot hole bacterium power
| Handle | Proportioning | Actual measurement EC 50(mg/L) | Theoretical EC 50(mg/L) | Synergy ratio (SR) |
| I thiazole zinc | 1∶0 | 10.87 | 10.87 | 1.00 |
| The II mancozeb | 0∶1 | 139.04 | 139.04 | 1.00 |
| I∶II | 20∶1 | 10.32 | 11.37 | 1.10 |
| I∶II | 10∶1 | 10.01 | 11.86 | 1.19 |
| I∶II | 1∶1 | 11.69 | 20.16 | 1.72 |
| I∶II | 1∶15 | 52.58 | 80.05 | 1.52 |
| I∶II | 1∶30 | 95.31 | 100.73 | 1.06 |
| I∶II | 1∶50 | 111.70 | 112.93 | 1.01 |
Biologicall test example 5:
Ginger plague germ (Pseudomonas solanacearum) activity test
Test method: with reference to " the agricultural industry criteria NY/T 1156.16-2008 of the People's Republic of China (PRC) ", nephelometry.
Result of the test shows: thiazole zinc and zineb are mixed ginger plague germ activity are better than independent activity, and proportioning all had active preferably between 30: 1～1: 40, and especially proportioning synergy in 3: 1 is obvious.(seeing Table 5)
Table 5, thiazole zinc and zineb are mixed to bacterial wilt of ginger bacterium power
| Handle | Proportioning | Actual measurement EC 50(mg/L) | Theoretical EC 50(mg/L) | Synergy ratio (SR) |
| I thiazole zinc | 1∶0 | 149.77 | 149.77 | 1.00 |
| The II zineb | 0∶1 | 539.29 | 539.29 | 1.00 |
| I∶II | 30∶1 | 140.70 | 153.34 | 1.09 |
| I∶II | 15∶1 | 119.44 | 156.85 | 1.31 |
| I∶II | 3∶1 | 108.50 | 182.77 | 1.68 |
| I∶II | 1∶10 | 317.25 | 436.17 | 1.37 |
| I∶II | 1∶20 | 473.07 | 479.86 | 1.01 |
| I∶II | 1∶40 | 528.96 | 507.12 | 0.96 |
Biologicall test example 6:
Bacterial canker of tomato (Clavivbacter michiganense) activity test
Test method: with reference to " the agricultural industry criteria NY/T 1156.16-2008 of the People's Republic of China (PRC) ", nephelometry.
Result of the test shows: thiazole zinc and tmtd are mixed the bacterial canker of tomato activity all are higher than in proportion the activity of addition separately, and especially proportioning is that 15: 1 and synergy in 1: 1 are obvious, the generation of effective delaying drug resistance that is mixed simultaneously.(seeing Table 6)
Table 6, thiazole zinc and tmtd are mixed to the bacterial canker of tomato virulence
| Handle | Proportioning | Actual measurement EC 50(mg/L) | Theoretical EC 50(mg/L) | Synergy ratio (SR) |
| I thiazole zinc | 1∶0 | 11.29 | 11.29 | 1.00 |
| The II tmtd | 0∶1 | 351.03 | 351.03 | 1.00 |
| I∶II | 30∶1 | 9.20 | 11.65 | 1.27 |
| I∶II | 15∶1 | 6.19 | 12.02 | 1.94 |
| I∶II | 1∶1 | 11.65 | 21.88 | 1.88 |
| I∶II | 1∶15 | 117.60 | 121.85 | 1.04 |
| I∶II | 1∶30 | 177.03 | 178.12 | 1.01 |
Biologicall test example 7:
Ring rot of apple bacterium (Physalospora piricola) activity test
Test method: with reference to " the agricultural industry criteria NY/T 1156.2-2006 of the People's Republic of China (PRC) " mycelial growth rate method.
Result of the test shows: thiazole zinc and Propineb or iprodione or tridemorph are mixed synergy obviously, especially thiazole zinc and Propineb, thiazole zinc and iprodione, thiazole zinc and tridemorph proportioning are 1: 5,1: 2 and 1: 1, the synergy ratio is respectively 1.76,1.63 and 1.63, synergy is obvious, can effectively reduce using dosage.(seeing Table 7,8,9)
Table 7, thiazole zinc and Propineb are to ring rot of apple bacterium power
| Handle | Proportioning | Actual measurement EC 50(mg/L) | Theoretical EC 50(mg/L) | Synergy ratio (SR) |
| I thiazole zinc | 1∶0 | 203.82 | 203.82 | 1.00 |
| The II Propineb | 0∶1 | 87.58 | 87.58 | 1.00 |
| I∶II | 25∶1 | 188.89 | 193.92 | 1.03 |
| I∶II | 10∶1 | 164.50 | 181.88 | 1.11 |
| I∶II | 1∶5 | 55.06 | 96.78 | 1.76 |
| I∶II | 1∶20 | 68.33 | 90.02 | 1.32 |
| I∶II | 1∶50 | 80.53 | 88.57 | 1.10 |
Table 8, thiazole zinc and iprodione are mixed to ring rot of apple bacterium power
| Handle | Proportioning | Actual measurement EC 50(mg/L) | Theoretical EC 50(mg/L) | Synergy ratio (SR) |
| I thiazole zinc | 1∶0 | 195.11 | 195.11 | 1.00 |
| The II iprodione | 0∶1 | 0.37 | 0.37 | 1.00 |
| I∶II | 25∶1 | 9.46 | 9.18 | 0.97 |
| I∶II | 10∶1 | 2.51 | 3.99 | 1.59 |
| I∶II | 1∶2 | 0.34 | 0.55 | 1.63 |
| I∶II | 1∶20 | 0.32 | 0.39 | 1.21 |
| I∶II | 1∶50 | 0.39 | 0.38 | 0.97 |
Table 9, thiazole zinc and tridemorph are to ring rot of apple bacterium power
| Handle | Proportioning | Actual measurement EC 50(mg/L) | Theoretical EC 50(mg/L) | Synergy ratio (SR) |
| I thiazole zinc | 1∶0 | 195.11 | 195.11 | 1.00 |
| The II tridemorph | 0∶1 | 1.79 | 1.79 | 1.00 |
| I∶II | 25∶1 | 36.22 | 37.86 | 1.05 |
| I∶II | 10∶1 | 16.90 | 18.04 | 1.07 |
| I∶II | 1∶1 | 2.18 | 3.55 | 1.63 |
| I∶II | 1∶20 | 1.32 | 1.88 | 1.42 |
| I∶II | 1∶50 | 1.80 | 1.83 | 1.01 |
Biologicall test example 8:
Alternaria leaf spot of apple bacterium (Alternaria mali) activity test
Test method: with reference to " the agricultural industry criteria NY/T 1156.2-2006 of the People's Republic of China (PRC) " mycelial growth rate method.
The result of the test explanation: any one is mixed in thiazole zinc and thiophanate-methyl, alkene azoles alcohol or the nitrile bacterium azoles, its activity all is higher than both sums, thiazole zinc and thiophanate-methyl, alkene azoles alcohol, nitrile bacterium azoles mixed ratio are that 1: 2,1: 1,1: 5 synergy ratio is 1.88,1.90 and 1.60, all greater than 1.5, synergy is obvious, is mixed to enlarge fungi-proofing spectrum simultaneously.(seeing Table 10,11,12)
Table 10, thiazole zinc and thiophanate-methyl are mixed to alternaria leaf spot of apple bacterium power
| Handle | Proportioning | Actual measurement EC 50(mg/L) | Theoretical EC 50(mg/L) | Synergy ratio (SR) |
| I thiazole zinc | 1∶0 | 195.23 | 195.23 | 1.00 |
| The II thiophanate-methyl | 0∶1 | 121.06 | 121.06 | 1.00 |
| I∶II | 25∶1 | 176.00 | 190.74 | 1.08 |
| I∶II | 10∶1 | 146.03 | 184.93 | 1.27 |
| I∶II | 1∶2 | 73.55 | 138.61 | 1.88 |
| I∶II | 1∶20 | 87.32 | 123.29 | 1.41 |
| I∶II | 1∶50 | 110.66 | 121.97 | 1.10 |
Table 11, thiazole zinc and alkene azoles alcohol are mixed to alternaria leaf spot of apple bacterium power
| Handle | Proportioning | Actual measurement EC 50(mg/L) | Theoretical EC 50(mg/L) | Synergy ratio (SR) |
| I thiazole zinc | 1∶0 | 208.11 | 208.11 | 1.00 |
| II alkene azoles alcohol | 0∶1 | 0.19 | 0.19 | 1.00 |
| I∶II | 50∶1 | 8.43 | 9.27 | 1.10 |
| I∶II | 25∶1 | 4.20 | 4.83 | 1.15 |
| I∶II | 1∶1 | 0.20 | 0.38 | 1.90 |
| I∶II | 1∶8 | 0.12 | 0.21 | 1.78 |
| I∶II | 1∶15 | 0.18 | 0.20 | 1.13 |
Table 12, thiazole zinc and nitrile bacterium azoles are mixed to alternaria leaf spot of apple bacterium power
| Handle | Proportioning | EC 50(mg/L) | Theoretical EC 50(mg/L) | Synergy ratio (SR) |
| I thiazole zinc | 1∶0 | 179.6 | 179.60 | 1.00 |
| II nitrile bacterium azoles | 0∶1 | 0.28 | 0.28 | 1.00 |
| I∶II | 50∶1 | 13.07 | 13.25 | 1.01 |
| I∶II | 25∶1 | 6.09 | 7.01 | 1.15 |
| I∶II | 1∶1 | 0.45 | 0.56 | 1.55 |
| I∶II | 1∶5 | 0.21 | 0.34 | 1.60 |
| I∶II | 1∶10 | 0.26 | 0.31 | 1.18 |
Biologicall test example 9:
Apricot alternaria (Alternaria tenuisnees) activity test
Test method: with reference to " the agricultural industry criteria NY/T 1156.2-2006 of the People's Republic of China (PRC) " mycelial growth rate method.
Result of the test shows: thiazole zinc and fluorine ring azoles are mixed apricot alternaria activity is higher than and descend proportioning active in both sums between 20: 1～1: 50 in proportion, and especially proportioning had synergistic effect between 10: 1～1: 3.Thiazole zinc and fluorine ring azoles are mixed diseases such as bacterium and apricot black spot are all had activity, enlarge the diseases prevention spectrum.(seeing Table 13)
Table 13, thiazole zinc and fluorine ring azoles are mixed to apricot alternaria virulence
| Handle | Proportioning | Actual measurement EC 50(mg/L) | Theoretical EC 50(mg/L) | Synergy ratio (SR) |
| I thiazole zinc | 1∶0 | 362.75 | 362.75 | 1.00 |
| II fluorine ring azoles | 0∶1 | 7.07 | 7.07 | 1.00 |
| I∶II | 20∶1 | 98.27 | 106.83 | 1.09 |
| I∶II | 10∶1 | 41.73 | 65.08 | 1.56 |
| I∶II | 1∶3 | 5.48 | 9.37 | 1.71 |
| I∶II | 1∶15 | 5.04 | 7.53 | 1.49 |
| I∶II | 1∶30 | 6.80 | 7.30 | 1.07 |
| I∶II | 1∶50 | 7.11 | 7.21 | 1.01 |
Biologicall test example 10:
Botrytis cinerea pers (Botrytis cinerea) activity test
Test method: with reference to " the agricultural industry criteria NY/T 1156.9-2008 of the People's Republic of China (PRC) " blade method;
Or " the agricultural industry criteria NY/T 1156.10-2008 of the People's Republic of China (PRC) " pot-culture method.
Result of the test shows: thiazole zinc and Difenoconazole or carbendazim are mixed and active all are higher than in proportion to botrytis cinerea pers down single with active, thiazole zinc and the Difenoconazole proportioning that is mixed had synergistic effect between 5: 1～1: 5, proportioning all had summation action between 20: 1～1: 50.Thiazole zinc and carbendazim proportioning are that greater activity is all arranged between 40: 1～1: 50, and especially proportioning is that synergy in 1: 1 o'clock is more obvious.Thiazole zinc and Difenoconazole are mixed and promote plant growing and improve quality, and thiazole zinc and carbendazim are mixed not only synergistic effect, can also obviously reduce the consumption of carbendazim and thiazole zinc.(seeing Table 14,15)
Table 14, thiazole zinc and Difenoconazole are mixed to botrytis cinerea pers virulence (blade method)
Table 15, thiazole zinc and carbendazim are mixed to botrytis cinerea pers virulence (pot-culture method)
| Handle | Proportioning | Actual measurement EC 50(mg/L) | Theoretical EC 50(mg/L) | Synergy ratio (SR) |
| I thiazole zinc | 1∶0 | 1303.05 | 1303.05 | 1.00 |
| The II carbendazim | 0∶1 | 95.02 | 95.02 | 1.00 |
| I∶II | 40∶1 | 905.09 | 994.63 | 1.10 |
| I∶II | 20∶1 | 622.50 | 811.67 | 1.30 |
| I∶II | 1∶1 | 101.90 | 177.12 | 1.74 |
| I∶II | 1∶20 | 71.43 | 99.41 | 1.39 |
| I∶II | 1∶50 | 79.80 | 96.78 | 1.21 |
Biologicall test example 11:
Bacterium of downy mildew of cucumber (Pseudoperonospora cubensis) determination of activity
Test method: show with reference to " the agricultural industry criteria NY/T 1156.3-2006 of the People's Republic of China (PRC) " plate blade method or " the agricultural industry criteria NY/T 1156.7-2006 of the People's Republic of China (PRC) " pot-culture method result of the test: thiazole zinc and metalaxyl, dimethomorph or propamocarb are mixed and use sum to want high in proportion down separately to the bacterium of downy mildew of cucumber specific activity, good synergy and synergistic effect are arranged, and wherein thiazole zinc and metalaxyl or the dimethomorph proportioning that is mixed is respectively 1.74 and 1.80 at 1: 1,5: 1 o'clock synergy ratios.Metalaxyl, dimethomorph or propamocarb all are easy to generate pesticide resistance, remarkable delaying drug resistance after using with.(seeing Table 16,17,18)
Table 16, thiazole zinc and metalaxyl are mixed to bacterium of downy mildew of cucumber virulence (pot-culture method)
| Handle | Proportioning | Actual measurement EC 50(mg/L) | Theoretical EC 50(mg/L) | Synergy ratio (SR) |
| I thiazole zinc | 1∶0 | 130.30 | 130.30 | 1.00 |
| The II metalaxyl | 0∶1 | 73.61 | 73.61 | 1.00 |
| I∶II | 30∶1 | 143.71 | 127.14 | 0.88 |
| I∶II | 15∶1 | 96.37 | 124.32 | 1.29 |
| I∶II | 1∶1 | 54.05 | 94.07 | 1.74 |
| I∶II | 1∶20 | 59.93 | 75.17 | 1.25 |
| I∶II | 1∶40 | 71.6 | 74.40 | 1.04 |
Table 17, thiazole zinc and dimethomorph are mixed to cucumber downy mildew virulence (plate blade method)
| Handle | Proportioning | Actual measurement EC 50(mg/L) | Theoretical EC 50(mg/L) | Synergy ratio (SR) |
| I thiazole zinc | 1∶0 | 130.30 | 130.30 | 1.00 |
| The II dimethomorph | 0∶1 | 17.91 | 17.91 | 1.00 |
| I∶II | 40∶1 | 100.45 | 113.00 | 1.12 |
| I∶II | 20∶1 | 60.67 | 100.32 | 1.65 |
| I∶II | 5∶1 | 35.40 | 63.69 | 1.80 |
| I∶II | 1∶10 | 16.66 | 19.43 | 1.17 |
| I∶II | 1∶20 | 19.20 | 18.68 | 0.97 |
Table 18, thiazole zinc and propamocarb are mixed to cucumber downy mildew virulence (pot-culture method)
Biologicall test example 12:
Rhizoctonia solani Kuhn (Rhizoctonia solani) activity test
Test method: with reference to " the agricultural industry criteria NY/T1156.2-2006 of the People's Republic of China (PRC) " mycelial growth rate method.
Result of the test shows: thiazole zinc and Tebuconazole, flutolanil or jinggangmeisu are mixed all has synergistic function to the rice sheath blight disease pathogen, the proportioning of thiazole zinc and Tebuconazole, flutolanil, jinggangmeisu is in 30: 1～1: 30 scope, the effect of using with is better than single effect of using, especially be respectively 2.47,1.85,1.94 at thiazole zinc and Tebuconazole, flutolanil, jinggangmeisu proportioning at 3: 1,3: 1,1: 5 o'clock synergy ratio, synergy is remarkable.One of thiazole zinc and Tebuconazole, flutolanil, jinggangmeisu are mixed and can effectively reduce consumption and improve the resistance against diseases of plant.(seeing Table 19,20,21)
Table 19, thiazole zinc and Tebuconazole are mixed to the rice sheath blight disease Toxicity Determination
| Handle | Proportioning | Actual measurement EC 50(mg/L) | Theoretical EC 50(mg/L) | Synergy ratio (SR) |
| I thiazole zinc | 1∶0 | 263.50 | 263.50 | 1.00 |
| The II Tebuconazole | 0∶1 | 1.31 | 1.31 | 1.00 |
| I∶II | 20∶1 | 37.53 | 25.02 | 0.67 |
| I∶II | 10∶1 | 11.95 | 13.73 | 1.15 |
| I∶II | 5∶1 | 6.20 | 7.67 | 1.24 |
| I∶II | 3∶1 | 2.09 | 5.16 | 2.47 |
| I∶II | 1∶3 | 1.83 | 1.74 | 0.95 |
Table 20, thiazole zinc and flutolanil are mixed to the rice sheath blight disease Toxicity Determination
| Handle | Proportioning | Actual measurement EC 50(mg/L) | Theoretical EC 50(mg/L) | Synergy ratio (SR) |
| I thiazole zinc | 1∶0 | 247.21 | 247.21 | 1.00 |
| The II flutolanil | 0∶1 | 8.05 | 8.05 | 1.00 |
| I∶II | 20∶1 | 123.15 | 102.38 | 0.83 |
| I∶II | 10∶1 | 94.08 | 66.80 | 0.71 |
| I∶II | 3∶1 | 15.84 | 29.33 | 1.85 |
| I∶II | 1∶3 | 5.95 | 10.62 | 1.78 |
| I∶II | 1∶15 | 7.70 | 8.57 | 1.11 |
| I∶II | 1∶30 | 12.12 | 8.31 | 0.69 |
Table 21, thiazole zinc and jinggangmeisu are mixed to the rice sheath blight disease Toxicity Determination
| Handle | Proportioning | Actual measurement EC 50(mg/L) | Theoretical EC 50(mg/L) | Synergy ratio (SR) |
| I thiazole zinc | 1∶0 | 249.27 | 249.27 | 1.00 |
| The II jinggangmeisu | 0∶1 | 1.99 | 1.99 | 1.00 |
| I∶II | 30∶1 | 82.15 | 49.77 | 0.61 |
| I∶II | 10∶1 | 18.5 | 20.27 | 1.10 |
| I∶II | 1∶1 | 2.16 | 3.95 | 1.83 |
| I∶II | 1∶5 | 1.23 | 2.38 | 1.94 |
| I∶II | 1∶30 | 2.15 | 2.06 | 0.96 |
| I∶II | 1∶50 | 3.07 | 2.03 | 0.66 |
Biologicall test example 13:
Tomato early blight bacterium (Alternaria solani) activity test
Test method: with reference to " the agricultural industry criteria NY/T 1156.1-2006 of the People's Republic of China (PRC) " spore germination method
Result of the test shows: thiazole zinc and tpn, Fluoxastrobin, phonetic mould amine, the activity that any one reactive compound of cyprodinil is mixed to tomato early blight bacterium all is better than both independent virulence sums, have addition or synergistic effect, proportioning between 30: 1～1: 40 the synergy ratio greater than 0.5, there is not antagonism, especially thiazole zinc and tpn, Fluoxastrobin, phonetic mould amine, the cyprodinil proportioning was respectively 1: 20,2: 1,1: 1, the synergy ratio was respectively 1.85 in 5: 1 o'clock, 1.97,1.50,1.94, thiazole zinc and tpn, Fluoxastrobin, phonetic mould amine, the any reactive compound of cyprodinil is mixed, can reduce the consumption of phonetic mould amine and tpn, the resistance that delays Fluoxastrobin produces, and improves the result of use of cyprodinil.(seeing Table 22,23,24,25)
Table 22, thiazole zinc and tpn are mixed to the tomato early blight bacterium virulence
| Handle | Proportioning | Actual measurement EC 50(mg/L) | Theoretical EC 50(mg/L) | Synergy ratio (SR) |
| I thiazole zinc | 1∶0 | 142.27 | 142.27 | 1.00 |
| The II tpn | 0∶1 | 13.90 | 13.90 | 1.00 |
| I∶II | 20∶1 | 95.71 | 98.81 | 1.03 |
| I∶II | 10∶1 | 68.09 | 77.34 | 1.14 |
| I∶II | 1∶5 | 18.56 | 25.33 | 1.36 |
| I∶II | 1∶20 | 8.82 | 16.36 | 1.85 |
| I∶II | 1∶40 | 11.04 | 14.52 | 1.32 |
Table 23, thiazole zinc and Fluoxastrobin are mixed to the tomato early blight bacterium virulence
| Handle | Proportioning | Actual measurement EC 50(mg/L) | Theoretical EC 50(mg/L) | Synergy ratio (SR) |
| I thiazole zinc | 1∶0 | 142.27 | 142.27 | 1.00 |
| The II Fluoxastrobin | 0∶1 | 0.73 | 0.73 | 1.00 |
| I∶II | 30∶1 | 20.53 | 19.61 | 0.96 |
| I∶II | 15∶1 | 8.76 | 10.85 | 1.24 |
| I∶II | 2∶1 | 1.10 | 2.17 | 1.97 |
| I∶II | 1∶5 | 0.52 | 0.88 | 1.68 |
| I∶II | 1∶10 | 0.77 | 0.80 | 1.04 |
Table 24, thiazole zinc and phonetic mould amine are mixed to the tomato early blight bacterium virulence
| Handle | Proportioning | Actual measurement EC 50(mg/L) | Theoretical EC 50(mg/L) | Synergy ratio (SR) |
| I thiazole zinc | 1∶0 | 142.27 | 142.27 | 1.00 |
| The phonetic mould amine of II | 0∶1 | 55.06 | 55.06 | 1.00 |
| I∶II | 30∶1 | 133.09 | 135.35 | 1.02 |
| I∶II | 10∶1 | 104.87 | 124.36 | 1.19 |
| I∶II | 1∶1 | 52.9 | 79.39 | 1.50 |
| I∶II | 1∶10 | 49.66 | 58.31 | 1.17 |
| I∶II | 1∶30 | 55.54 | 56.17 | 1.01 |
Table 25, thiazole zinc and cyprodinil are mixed to the tomato early blight bacterium virulence
| Handle | Proportioning | Actual measurement EC 50(mg/L) | Theoretical EC 50(mg/L) | Synergy ratio (SR) |
| I thiazole zinc | 1∶0 | 142.27 | 142.27 | 1.00 |
| The II cyprodinil | 0∶1 | 3.58 | 3.58 | 1.00 |
| I∶II | 30∶1 | 64.1 | 63.24 | 0.99 |
| I∶II | 15∶1 | 27.56 | 41.58 | 1.51 |
| I∶II | 5∶1 | 9.82 | 19.08 | 1.94 |
| I∶II | 1∶1 | 4.17 | 6.98 | 1.67 |
| I∶II | 1∶10 | 3.07 | 3.93 | 1.28 |
| I∶II | 1∶20 | 3.66 | 3.75 | 1.03 |
Biologicall test example 14:
Phytophthora capsici (Phytophthora capsic) activity test
Test method: with reference to " the agricultural industry criteria NY/T 1156.1-2006 of the People's Republic of China (PRC) " spore germination method
Result of the test shows: thiazole zinc and Wakil are mixed and improve capsicum epidemic disease is active, have summation action, and especially proportioning is that synergistic effect is obvious between 5: 1～1: 10, can effectively delay the generation of Wakil resistance.(seeing Table 26)
Table 26, thiazole zinc and Wakil are mixed to the phytophthora capsici virulence
| Handle | Proportioning | Actual measurement EC 50(mg/L) | Theoretical EC 50(mg/L) | Synergy ratio (SR) |
| I thiazole zinc | 1∶0 | 651.77 | 651.77 | 1.00 |
| The II Wakil | 0∶1 | 36.80 | 36.80 | 1.00 |
| I∶II | 30∶1 | 405.23 | 423.48 | 1.05 |
| I∶II | 15∶1 | 300.28 | 318.80 | 1.06 |
| I∶II | 5∶1 | 101.55 | 172.19 | 1.70 |
| I∶II | 1∶10 | 20.07 | 40.25 | 2.01 |
| I∶II | 1∶20 | 31.36 | 38.53 | 1.23 |
| I∶II | 1∶50 | 35.29 | 37.49 | 1.06 |
Biologicall test example 15:
Rhizoctonia cerealis (Rhizoctonia cerealis) activity test
Test method: with reference to " the agricultural industry criteria NY/T1156.2-2006 of the People's Republic of China (PRC) " mycelial growth rate method.
Result of the test shows: thiazole zinc and the propiconazole activity that is mixed is higher than in proportion both independent virulence sums down, and especially proportioning all had synergistic effect at 1: 1 and 1: 10 o'clock, can reduce the consumption of propiconazole after being mixed.(seeing Table 27)
Table 27, thiazole zinc and propiconazole are mixed to the rhizoctonia cerealis virulence
| Handle | Proportioning | Actual measurement EC 50(mg/L) | Theoretical EC 50(mg/L) | Synergy ratio (SR) |
| I thiazole zinc | 1∶0 | 178.23 | 178.23 | 1.00 |
| The II propiconazole | 0∶1 | 3.81 | 3.81 | 1.00 |
| I∶II | 30∶1 | 65.63 | 71.96 | 1.10 |
| I∶II | 10∶1 | 26.24 | 34.53 | 1.32 |
| I∶II | 1∶1 | 3.95 | 7.46 | 1.89 |
| I∶II | 1∶10 | 2.60 | 4.18 | 1.61 |
| I∶II | 1∶30 | 3.01 | 3.93 | 1.31 |
| I∶II | 1∶50 | 3.69 | 3.88 | 1.05 |
Biologicall test example 16:
Cucumber alternaria (Alternaria cucumerina) activity test
Test method: with reference to " the agricultural industry criteria NY/T 1156.1-2006 of the People's Republic of China (PRC) " spore germination method
Result of the test shows: thiazole zinc and the bitertanol activity that is mixed is higher than the both activities sum, and especially proportioning synergy ratio between 5: 1～1: 5 is 2.63 and 2.07, and synergy is obvious.(seeing Table 28)
Table 28, thiazole zinc and bitertanol are to cucumber alternaria virulence.
| Handle | Proportioning | Actual measurement EC 50(mg/L) | Theoretical EC 50(mg/L) | Synergy ratio (SR) |
| I thiazole zinc | 1∶0 | 178.23 | 178.23 | 1.00 |
| The II bitertanol | 0∶1 | 1.94 | 1.94 | 1.00 |
| I∶II | 30∶1 | 52.67 | 45.34 | 0.86 |
| I∶II | 15∶1 | 21.13 | 26.68 | 1.26 |
| I∶II | 5∶1 | 4.20 | 11.04 | 2.63 |
| I∶II | 1∶5 | 1.12 | 2.32 | 2.07 |
| I∶II | 1∶10 | 1.49 | 2.13 | 1.43 |
| I∶II | 1∶15 | 2.48 | 2.07 | 0.83 |
Biologicall test example 17:
Sporisorium reilianum (Sphacelotheca reiliana) activity test
Test method: with reference to " the agricultural industry criteria NY/T 1156.1-2006 of the People's Republic of China (PRC) " spore germination method
Result of the test shows: it is to be higher than thiazole zinc and the active sum of Triadimenol in 40: 1～1: 20 in proportioning that thiazole zinc and Triadimenol are mixed to the Sporisorium reilianum activity, and especially proportioning is that remarkable synergistic effect is arranged between 1: 5～15.(seeing Table 29)
Table 29, thiazole zinc and Triadimenol are mixed to the Sporisorium reilianum virulence
| Handle | Proportioning | Actual measurement EC 50(mg/L) | Theoretical EC 50(mg/L) | Synergy ratio (SR) |
| I thiazole zinc | 1∶0 | 352.81 | 352.81 | 1.00 |
| The II Triadimenol | 0∶1 | 2.83 | 2.83 | 1.00 |
| I∶II | 40∶1 | 79.25 | 87.84 | 1.11 |
| I∶II | 20∶1 | 41.80 | 51.21 | 1.23 |
| I∶II | 1∶5 | 1.74 | 3.39 | 1.95 |
| I∶II | 1∶15 | 1.99 | 3.02 | 1.52 |
| I∶II | 1∶20 | 2.06 | 2.97 | 1.44 |
Biologicall test example 18:
Sclerotinia sclerotiorum (Sclerotinia sclerotiorum) activity test
Test method: with reference to " the agricultural industry criteria NY/T1156.2-2006 of the People's Republic of China (PRC) " mycelial growth rate method
Result of the test shows: thiazole zinc and dimethachlon or procymidone are mixed the Sclerotinia sclerotiorum virulence are improved, proportioning is that synergy is all arranged between 20: 1～1: 50, especially thiazole zinc and dimethachlon proportioning are 4: 1,1: 4,1: 20 o'clock, the synergy ratio is 1.86,1.63 and 1.95, thiazole zinc and procymidone proportioning are 1: 9 o'clock, the synergy ratio is 2.08, and synergy is obvious.Dimethachlon and procymidone applying unit consumption for many years are very big, can reduce the unit consumption after being mixed with thiazole zinc.(seeing Table 30,31)
Table 30, thiazole zinc and dimethachlon are mixed to the Sclerotinia sclerotiorum virulence
| Handle | Proportioning | Actual measurement EC 50(mg/L) | Theoretical EC 50(mg/L) | Synergy ratio (SR) |
| I thiazole zinc | 1∶0 | 1229.05 | 1229.05 | 1.00 |
| The II dimethachlon | 0∶1 | 1.76 | 1.76 | 1.00 |
| I?∶II | 20∶1 | 33.68 | 35.93 | 1.07 |
| I∶II | 4∶1 | 4.71 | 8.75 | 1.86 |
| I∶II | 1∶4 | 2.16 | 3.51 | 1.63 |
| I∶II | 1∶20 | 1.13 | 2.20 | 1.95 |
| I∶II | 1∶50 | 1.44 | 1.85 | 1.28 |
Table 31, thiazole zinc and procymidone are mixed to the Sclerotinia sclerotiorum virulence
| Handle | Proportioning | Actual measurement EC 50(mg/L) | Theoretical EC 50(mg/L) | Synergy ratio (SR) |
| I thiazole zinc | 1∶0 | 1229.05 | 1229.05 | 1.00 |
| The II procymidone | 0∶1 | 0.58 | 0.58 | 1.00 |
| I∶II | 20∶1 | 11.67 | 12.07 | 1.03 |
| I∶II | 10∶1 | 4.58 | 6.35 | 1.39 |
| I∶II | 1∶9 | 0.31 | 0.64 | 2.08 |
| I∶II | 1∶20 | 0.42 | 0.61 | 1.45 |
| I∶II | 1∶40 | 0.50 | 0.59 | 1.19 |
Biologicall test example 19:
Citrus scab bacterium (Sphaceloma fawcettii) activity test
Test method: with reference to " the agricultural industry criteria NY/T1156.2-2006 of the People's Republic of China (PRC) " mycelial growth rate method
Result of the test shows: thiazole zinc and benomyl are mixed to citrus scab bacterium activity greater than the both activities addition, and proportioning is synergy all to be arranged in 20: 1～1: 40, and especially proportioning is that 4: 1 o'clock synergy ratios are 2.36, and obvious synergistic effect is arranged.(seeing Table 32)
Table 32, thiazole zinc and benomyl are mixed to citrus scab bacterium power
| Handle | Proportioning | Actual measurement EC 50(mg/L) | Theoretical EC 50(mg/L) | Synergy ratio (SR) |
| I thiazole zinc | 1∶0 | 11.46 | 11.46 | 1.00 |
| The II benomyl | 0∶1 | 18.79 | 18.79 | 1.00 |
| I∶II | 20∶1 | 10.8 | 11.68 | 1.08 |
| I∶II | 10∶1 | 8.23 | 11.88 | 1.44 |
| I∶II | 4∶1 | 5.27 | 12.43 | 2.36 |
| I∶II | 1∶8 | 12.40 | 17.54 | 1.41 |
| I∶II | 1∶20 | 14.49 | 18.23 | 1.26 |
| I∶II | 1∶40 | 15.96 | 18.50 | 1.16 |
Biologicall test example 20:
Withered germ of water-melon (Fusarium oxysporum) activity test
Test method: with reference to " the agricultural industry criteria NY/T 1156.1-2006 of the People's Republic of China (PRC) " spore germination method
Result of the test shows: thiazole zinc is mixed with the mould spirit of evil the withered germ of water-melon virulence is had synergy, is that 1: 1 o'clock synergy ratio is 1.72 in proportioning especially, and synergistic effect is arranged, and both are mixed and delay the generation of this soil-borne disease resistance.(seeing Table 33)
Table 33, thiazole zinc are mixed to the withered germ of water-melon virulence with the mould spirit of evil
| Handle | Proportioning | Actual measurement EC 50(mg/L) | Theoretical EC 50(mg/L) | Synergy ratio (SR) |
| I thiazole zinc | 1∶0 | 809.85 | 809.85 | 1.00 |
| II dislikes mould spirit | 0∶1 | 379.26 | 379.26 | 1.00 |
| I∶II | 30∶1 | 658.33 | 781.24 | 1.19 |
| I∶II | 10∶1 | 521.75 | 734.08 | 1.41 |
| I∶II | 1∶1 | 299.54 | 516.59 | 1.72 |
| I∶II | 1∶10 | 298.77 | 398.52 | 1.33 |
| I∶II | 1∶30 | 295.56 | 385.88 | 1.31 |
Biologicall test example 21:
Watermelon anthrax bacteria (Colletotrichum orbiculare) activity test
Test method: with reference to " the agricultural industry criteria NY/T 1156.11-2008 of the People's Republic of China (PRC) " pot-culture method
Result of the test shows: the virulence that thiazole zinc and dithianon are mixed to watermelon anthrax bacteria is higher than the virulence that both use separately in proportion, and proportioning is that synergistic effect, especially proportioning all to be arranged in 1: 1 and 1: 3 be that 1: 3 synergy ratio reaches 1.94.(seeing Table 34)
Table 34, thiazole zinc and dithianon are mixed to powdery mildew of cucumber bacterium power
| Handle | Proportioning | Actual measurement EC 50(mg/L) | Theoretical EC 50(mg/L) | Synergy ratio (SR) |
| I thiazole zinc | 1∶0 | 667.31 | 667.31 | 1.00 |
| The II dithianon | 0∶1 | 18.30 | 18.30 | 1.00 |
| I∶II | 30∶1 | 293.72 | 311.24 | 1.06 |
| I∶II | 10∶1 | 127.80 | 157.98 | 1.24 |
| I∶II | 1∶1 | 22.35 | 35.62 | 1.59 |
| I∶II | 1∶3 | 12.47 | 24.18 | 1.94 |
| I∶II | 1∶10 | 13.85 | 20.07 | 1.45 |
| I∶II | 1∶20 | 15.06 | 19.19 | 1.27 |
Biologicall test example 22:
Tobacco black shank bacterium (Phytophthora parasitica) activity test
Test method: with reference to " the agricultural industry criteria NY/T1156.2-2006 of the People's Republic of China (PRC) " mycelial growth rate method
Result of the test shows: thiazole zinc and the phosethyl-Al activity that is mixed is higher than both sums, addition or synergistic effect are arranged, especially proportioning is that 5: 1 and 1: 3 o'clock synergy ratio are 1.53 and 1.94, and obvious synergistic effect is arranged, and both use with and improve the safety of reactive compound to crop.(seeing Table 35)
Table 35, thiazole zinc and phosethyl-Al are mixed to the tobacco black shank bacterium virulence
| Handle | Proportioning | Actual measurement EC 50(mg/L) | Theoretical EC 50(mg/L) | Synergy ratio (SR) |
| I thiazole zinc | 1∶0 | 154.78 | 154.78 | 1.00 |
| The II phosethyl-Al | 0∶1 | 5.16 | 5.16 | 1.00 |
| I∶II | 10∶1 | 31.26 | 42.57 | 1.36 |
| I∶II | 5∶1 | 17.33 | 26.54 | 1.53 |
| I∶II | 1∶3 | 3.51 | 6.80 | 1.94 |
| I∶II | 1∶10 | 4.48 | 5.66 | 1.26 |
| I∶II | 1∶20 | 4.90 | 5.41 | 1.10 |
| I∶II | 1∶50 | 5.04 | 5.26 | 1.04 |
Biologicall test example 23:
Rice blast fungus (Pyricularia oryzae Cav.) activity test
Test method: with reference to " the agricultural industry criteria NY/T1156.8-2007 of the People's Republic of China (PRC) " pot-culture method
Result of the test shows: thiazole zinc and tricyclazole or the iprobenfos activity that is mixed is starkly lower than both sums, antagonism is arranged, especially proportioning is that 5: 1 and 1: 1 o'clock synergy ratio are 0.16 and 0.21, and tangible antagonism is arranged, and both use all the safety (seeing Table 36-37) to crop with
Table 36, thiazole zinc and tricyclazole are mixed to the Pyricularia oryzae virulence
| Handle | Proportioning | Actual measurement EC 50(mg/L) | Theoretical EC 50(mg/L) | Synergy ratio (SR) |
| I thiazole zinc | 1∶0 | 372.92 | 372.92 | 1.00 |
| The II tricyclazole | 0∶1 | 34.28 | 34.28 | 1.00 |
| I∶II | 10∶1 | 899.37 | 196.47 | 0.22 |
| I∶II | 5∶1 | 783.09 | 140.91 | 0.18 |
| I∶II | 1∶3 | 281.41 | 44.35 | 0.16 |
| I∶II | 1∶10 | 86.05 | 37.36 | 0.43 |
| I∶II | 1∶20 | 79.42 | 35.83 | 0.45 |
| I∶II | 1∶50 | 75.09 | 34.90 | 0.46 |
Table 37, thiazole zinc and iprobenfos are mixed to the Pyricularia oryzae virulence
| Handle | Proportioning | Actual measurement EC 50(mg/L) | Theoretical EC 50(mg/L) | Synergy ratio (SR) |
| I thiazole zinc | 1∶0 | 372.92 | 372.92 | 1.00 |
| The II iprobenfos | 0∶1 | 9.54 | 34.28 | 3.59 |
| I∶II | 30∶1 | 483.3 | 167.33 | 0.35 |
| I∶II | 10∶1 | 281.09 | 83.56 | 0.30 |
| I∶II | 1∶1 | 87.45 | 18.60 | 0.21 |
| I∶II | 1∶10 | 43.03 | 10.47 | 0.24 |
| I∶II | 1∶20 | 30.24 | 10.00 | 0.33 |
| I∶II | 1∶40 | 21.88 | 9.77 | 0.45 |
Biologicall test example 24:
Powdery mildew of cucumber bacterium (Sphaerotheca fuliginea) activity test
Test method: with reference to " the agricultural industry criteria NY/T1156.11-2008 of the People's Republic of China (PRC) " pot-culture method
Result of the test shows: thiazole zinc and the sulphur activity that is mixed is starkly lower than both sums, and antagonism is arranged, and especially proportioning is that 1: 5 o'clock synergy ratio is 0.27, and tangible antagonism is arranged, and both use all the safety (seeing Table 38) to crop with
Table 38, thiazole zinc and sulphur are mixed to powdery mildew of cucumber bacterium power
| Handle | Proportioning | Actual measurement EC 50(mg/L) | Theoretical EC 50(mg/L) | Synergy ratio (SR) |
| I thiazole zinc | 1∶0 | 2674.57 | 372.92 | 1.00 |
| II sulphur | 0∶1 | 24.76 | 34.28 | 1.00 |
| I∶II | 30∶1 | 1483.3 | 600.72 | 0.40 |
| I∶II | 10∶1 | 672.18 | 249.28 | 0.37 |
| I∶II | 1∶5 | 107.89 | 29.66 | 0.27 |
| I∶II | 1∶15 | 68.03 | 26.39 | 0.39 |
| I∶II | 1∶30 | 63.95 | 25.58 | 0.40 |
| I∶II | 1∶50 | 61.07 | 25.25 | 0.41 |
Biologicall test example 25:
Bacterium of downy mildew of cucumber (Pseudoperonopora cubensis) activity test
Test method: with reference to " the agricultural industry criteria NY/T1156.7-2006 of the People's Republic of China (PRC) " pot-culture method
Result of the test shows: thiazole zinc and the copper 8-hydroxyquinolinate activity that is mixed is starkly lower than both sums, and antagonism is arranged, and especially proportioning is that 1: 3 o'clock synergy ratio is 0.24, and tangible antagonism is arranged, and both use all the safety (seeing Table 39) to crop with
Table 39, thiazole zinc and copper 8-hydroxyquinolinate are mixed to the bacterium of downy mildew of cucumber virulence
| Handle | Proportioning | Actual measurement EC 50(mg/L) | Theoretical EC 50(mg/L) | Synergy ratio (SR) |
| I thiazole zinc | 1∶0 | 128.71 | 372.92 | 1.00 |
| The II copper 8-hydroxyquinolinate | 0∶1 | 14.46 | 34.28 | 1.00 |
| I∶II | 30∶1 | 283.28 | 102.57 | 0.36 |
| I∶II | 15∶1 | 272.17 | 86.16 | 0.32 |
| I∶II | 1∶3 | 77.80 | 18.58 | 0.24 |
| I∶II | 1∶10 | 73.15 | 15.73 | 0.22 |
| I∶II | 1∶30 | 69.44 | 14.89 | 0.21 |
Field trial embodiment
20% thiazole zinc SC is that Zhejiang Xinnong Chemical Co.,Ltd produces in the test specimen
1,25% Fluoxastrobin SC+20% thiazole zinc SC: the control cucumber downy mildew, 25% Fluoxastrobin SC sample is commercial, for Syngenta Co.,Ltd produces.Test method: carry out field control effectiveness test with reference to " State Standard of the People's Republic of China GB/T 17980.26-2000 ", tested in April, 2009 and carry out in Xiaoshan, Zhejiang.
| Active substance | Effective concentration of treatment | Disease index | Control efficiency (%) |
| A:20% thiazole zinc SC | 356 mg/kg | 24.26 | 72.61 |
| B:25% Fluoxastrobin SC | 150 mg/kg | 15.95 | 80.24 |
| A+B | 600 mg/kg+100 mg/kg | 13.24 | 81.65 |
| A+B | 300 mg/kg+200 mg/kg | 10.56 | 84.17 |
| A+B | 100 mg/kg+400 mg/kg | 8.56 | 86.21 |
| Blank | Clear water | 46.99 | /. |
2,50% water dispersion granules agent of Kresoxim+20% thiazole zinc SC: the control cucumber downy mildew, 50% water dispersion granules agent of Kresoxim sample is commercial, for Syngenta Co.,Ltd produces.Test method: carry out field control effectiveness test with reference to " State Standard of the People's Republic of China GB/T 17980.26-2000 ", tested in April, 2008 and carry out in Xiaoshan, Zhejiang.
3,25% pyraclostrobin missible oil+20% thiazole zinc SC: the control cucumber downy mildew, 25% pyraclostrobin missible oil sample is commercial, for BASF European Co.,Ltd produces.Test method: carry out field control effectiveness test with reference to " State Standard of the People's Republic of China GB/T 17980.26-2000 ", tested in April, 2010 and carry out in Xiaoshan, Zhejiang.
| Active substance | Effective concentration of treatment | Disease index | Control efficiency (%) |
| A:20% thiazole zinc SC | 360 mg/kg | 17.60 | 71.00 |
| B:25% pyraclostrobin EC | 110 mg/kg | 16.40 | 74.10 |
| A+B | 450 milligrams/thousand+80 milligrams/thousand | 16.20 | 73.26 |
| A+B | 300 milligrams/thousand+100 mg/kg | 10.59 | 80.52 |
| A+B | 250 milligrams/thousand+150 milligrams/thousand | 9.25 | 82.65 |
| Blank | Clear water | 32.64 | /. |
4,25% Enestroburin missible oil+20% thiazole zinc SC: the control cucumber downy mildew, 25% Enestroburin missible oil sample is commercial, for Shenyang Kechuang chemicals Co., Ltd produces.Test method: carry out field control effectiveness test with reference to " State Standard of the People's Republic of China GB/T 17980.26-2000 ", tested in April, 2010 and carry out in Xiaoshan, Zhejiang.
5,20% azoles bacterium ester SC+20% thiazole zinc SC: the control cucumber downy mildew, 20% azoles bacterium ester SC sample is commercial, for Shenyang Kechuang chemicals Co., Ltd produces.Test method: carry out field control effectiveness test with reference to " State Standard of the People's Republic of China GB/T 17980.26-2000 ", tested in April, 2010 and carry out at Xiaoshan, Zhejiang.
6,24% RH-7592 SC+20% thiazole zinc SC: control peach brown spot, 24% RH-7592 SC sample is commercial, for The Dow Agrosciences, LLC. produces.Tested in May, 2009 and carry out in Ningbo of Zhejiang.
| Active substance | Effective concentration of treatment | Disease index | Control efficiency (%) |
| A:20% thiazole zinc SC | 450 mg/kg | 17.80 | 65.20 |
| B:24% RH-7592 SC | 100 mg/kg | 12.54 | 74.00 |
| A+B | 550 mg/kg+60 mg/kg | 10.35 | 80.07 |
| A+B | 410 mg/kg+80 mg/kg | 9.67 | 81.20 |
| A+B | 350 mg/kg+150 mg/kg | 7.36 | 85.3 |
| Blank | Clear water | 29.33 | /. |
7,40% Flusilazole missible oil+20% thiazole zinc SC: control mandarin tree scab, 40% Flusilazole missible oil sample is commercial, is du pont company production.Tested in April, 2006 and carry out in the Quzhou, Zhejiang.
| Active substance | Effective concentration of treatment | Disease index | Control efficiency (%) |
| A:20% thiazole zinc SC | 450 mg/kg | 19.75 | 67.72 |
| B:40% Flusilazole EC | 40 mg/kg | 9.96 | 80.32 |
| A+B | 540 mg/kg+100 mg/kg | 15.22 | 75.10 |
| A+B | 440 mg/kg+140 mg/kg | 7.52 | 82.11 |
| A+B | 350 mg/kg+200 mg/kg | 6.30 | 84.35 |
| Blank | Clear water | 29.61 | /. |
8,25% Flutriafol SC+20% thiazole zinc SC: wheat powdery mildew, 25% Flutriafol SC sample is commercial, for Fengdeng Pesticide Co., Ltd., Jiangsu produces.Tested in April, 2007 and carry out at Jinhua, Zhejiang.Test method: carry out field control effectiveness test with reference to " State Standard of the People's Republic of China GB/T17980.22-2000 ".
| Active substance | Effective concentration of treatment | Disease index | Control efficiency (%) |
| A:20% thiazole zinc SC | 444 mg/kg | 15.20 | 61.20 |
| B:25% Flutriafol SC | 111 mg/kg | 12.46 | 78.60 |
| A+B | 600 mg/kg+100 mg/kg | 11.23 | 75.62 |
| A+B | The 450+150 mg/kg | 8.67 | 82.34 |
| A+B | 400 mg/kg+180 mg/kg | 9.65 | 82.69 |
| Blank | Clear water | 34.59 | /. |
9,10% penconazole missible oil+20% thiazole zinc SC: the control grape powdery mildew, 10% penconazole missible oil sample is commercial, and Co., Ltd produces for Hangzhou, Zhejiang province space dragon chemical industry.Tested in April, 2010 and carry out at Jinhua, Zhejiang.Test method: carry out field control effectiveness test with reference to " pesticide field efficacy medicine test criterion NY/T1464.12-2007 ".
| Active substance | Effective concentration of treatment | Disease index | Control efficiency (%) |
| A:20% thiazole zinc SC | 450 mg/kg | 21.54 | 61.21 |
| B:10% penconazole EC | 30 mg/kg | 16.20 | 78.20 |
| A+B | 600 mg/kg+20 mg/kg | 14.52 | 81.35 |
| A+B | 400 mg/kg+40 mg/kg | 10.36 | 86.72 |
| A+B | 350 mg/kg+40 mg/kg | 9.88 | 87.50 |
| Blank | Clear water | 39.52 | /. |
10,25% propiconazole emulsifiable concentrate+20% thiazole zinc SC: prevent and treat rice sheath blight disease, 25% propiconazole emulsifiable concentrate sample is commercial, and Co., Ltd produces for Hangzhou, Zhejiang province space dragon chemical industry.Tested in August, 2007 and carry out at Xiaoshan, Zhejiang.Test method: carry out field control effectiveness test with reference to " pesticide field efficacy medicine test criterion GB/T17980.20-2000 ".
| Active substance | Effective concentration of treatment | Disease index | Control efficiency (%) |
| A:20% thiazole zinc SC | 450 mg/kg | 19.21 | 71.32 |
| B:25% propiconazole EC | 110 mg/kg | 15.38 | 82.67 |
| A+B | 600 mg/kg+90 mg/kg | 16.89 | 80.00 |
| A+B | 500 mg/kg+120 mg/kg | 11.15 | 85.00 |
| A+B | 400 mg/kg+150 mg/kg | 17.23 | 85.21 |
| Blank | Clear water | 42.17 | /. |
11,4% tetraconazole aqueous emulsion+20% thiazole zinc SC: prevent and treat powdery mildew of cucumber, 4% tetraconazole aqueous emulsion sample is commercial, for Shanghai Taihe (Group) Co., Ltd. produces.Tested in April, 2010 and carry out at Xiaoshan, Zhejiang.Test method: carry out field control effectiveness test with reference to " pesticide field efficacy medicine test criterion NY/T1464.12-2007 ".
| Active substance | Effective concentration of treatment | Disease index | Control efficiency (%) |
| A:20% thiazole zinc SC | 440 mg/kg | 26.22 | 46.20 |
| B:4% tetraconazole EW | 50 mg/kg | 20.65 | 72.96 |
| A+B | 550 mg/kg+40 mg/kg | 22.33 | 60.32 |
| A+B | 450 mg/kg+60 mg/kg | 18.68 | 79.50 |
| A+B | 400 mg/kg+60 mg/kg | 12.58 | 83.56 |
| Blank | Clear water | 41.50 | /. |
12,20% flumorph wetting powder+20% thiazole zinc SC: the control cucumber downy mildew, 20% flumorph wetting powder is commercial, for Shenyang Kechuang chemicals Co., Ltd produces.Tested in April, 2009 and carry out at Xiaoshan, Zhejiang.Test method: carry out field control effectiveness test with reference to " State Standard of the People's Republic of China GB/T17980.26-2000 ".
| Active substance | Effective concentration of treatment | Disease index | Control efficiency (%) |
| A:20% thiazole zinc SC | 4504 mg/kg | 22.40 | 60.38 |
| B:20% flumorph WP | 180 mg/kg | 13.67 | 84.56 |
| A+B | 600 mg/kg+140 mg/kg | 16.86 | 75.36 |
| A+B | 500 mg/kg+180 mg/kg | 9.79 | 86.72 |
| A+B | 400 mg/kg+220 mg/kg | 7.25 | 89.35 |
| Blank | Clear water | 45.2 | /. |
13,25% mandipropamid amine SC+20% thiazole zinc SC: prevent and treat downy mildew of garpe, 25% mandipropamid amine SC sample is commercial, produces for Switzerland is just reaching earlier crop protection Co., Ltd.Tested in April, 2010 and carry out in Jinhua.Test method: carry out field control effectiveness test with reference to " State Standard of the People's Republic of China GB/T 17980.122-2004 ".
14,50% Boscalid water dispersible granules+20% thiazole zinc SC: the control gray mold of cucumber, 50% Boscalid water dispersible granules sample is commercial, for BASF European Co.,Ltd produces.Tested in October, 2009 and carry out at Xiaoshan, Zhejiang.Test method: carry out field control effectiveness test with reference to " State Standard of the People's Republic of China GB/T 17980.28-2000 ".
15,41.7% fluorine pyrrole bacterium acid amides SC+20% thiazole zinc SC: control grape grey mould, 41.7% fluorine pyrrole bacterium acid amides SC sample are from test unit, for Bayer crop science company produces.Tested in April, 2010 and carry out at Xiaoshan, Zhejiang.
16,450 grams per liter prochloraz aqueous emulsions+20% thiazole zinc SC: prevent and treat rice sheath blight disease, 450g/L prochloraz aqueous emulsion sample is commercial, and for Israel Maxime chemical company produces, Bayer crop science company produces.Tested in August, 2008 and carry out at Xiaoshan, Zhejiang.Test method: carry out field control effectiveness test with reference to " pesticide field efficacy medicine test criterion GB/T 17980.20-2000 ".
| Active substance | Effective concentration of treatment | Disease index | Control efficiency (%) |
| A:20% thiazole zinc SC | 450 mg/kg | 21.30 | 55.42 |
| B:450 grams per liter Prochloraz AS | 500 mg/kg | 18.52 | 72.20 |
| A+B | 600 mg/kg+350 mg/kg | 19.68 | 70.00 |
| A+B | The 500+450 mg/kg | 15.43 | 78.20 |
| A+B | 400 mg/kg+550 mg/kg | 13.24 | 80.21 |
| Blank | Clear water | 41.67 | /. |
17,100 grams per liter cyanogen frost azoles SC+20% thiazole zinc SC: prevent and treat downy mildew of garpe, 10% cyanogen frost azoles SC sample is commercial, produces for Japanese stone originates in Co., Ltd..Tested in April, 2008 and carry out test method: carry out field control effectiveness test with reference to " State Standard of the People's Republic of China GB/T 17980.122-2004 ".
| Active substance | Effective concentration of treatment | Disease index | Control efficiency (%) |
| A:20% thiazole zinc SC | 440 mg/kg | 26.62 | 64.67 |
| B:10 grams per liter cyanogen frost azoles SC | 70 mg/kg | 15.12 | 83.33 |
| A+B | 600 mg/kg+50 mg/kg | 17.85 | 78.88 |
| A+B | 500 mg/kg+60 mg/kg | 12.23 | 85.62 |
| A+B | 400 mg/kg+70 mg/kg | 11.58 | 86.53 |
| Blank | Clear water | 38.89 | / |
18,30% triflumizole wettable powder+20% thiazole zinc SC: control mandarin tree scab, 30% triflumizole wettable powder sample is commercial, for Zhejiang Prov HeBen pesticide Chemical Co., Ltd produces.Tested in April, 2009 and carry out in the Quzhou, Zhejiang.
| Active substance | Effective concentration of treatment | Disease index | Control efficiency (%) |
| A:20% thiazole zinc SC | 440 mg/kg | 22.22 | 51.24 |
| B:30% fluorine bacterium azoles WP | 270 mg/kg | 14.15 | 81.25 |
| A+B | 600 mg/kg+200 mg/kg | 16.58 | 75.62 |
| A+B | 500 mg/kg+260 mg/kg | 12.17 | 79.24 |
| A+B | 400 mg/kg+320 mg/kg | 9.35 | 82.25 |
| Blank | Clear water | 27.69 | /. |
19,50% vinclozolin water dispersible granules+20% thiazole zinc SC: the control gray mold of cucumber, 50% vinclozolin water dispersible granules sample is commercial, for BASF European Co.,Ltd produces.Tested in October, 2008 and carry out test method at Xiaoshan, Zhejiang: carry out field control effectiveness test with reference to " State Standard of the People's Republic of China GB/T 17980.28-2000 ".
| Active substance | Effective concentration of treatment | Disease index | Control efficiency (%) |
| A:20% thiazole zinc SC | 440 mg/kg | 16.17 | 70.67 |
| The rare sclex WDG of B:50% second | 1000 mg/kg | 11.18 | 78.52 |
| A+B | 600 mg/kg+800 mg/kg | 13.63 | 75.26 |
| A+B | 500 mg/kg+1000 mg/kg | 9.54 | 83.33 |
| A+B | 400 mg/kg+1100 mg/kg | 10.21 | 82.62 |
| Blank | Clear water | 33.33 | /. |
20,50% captan wetting powder+20% thiazole zinc SC: prevent and treat downy mildew of garpe, 50% captan wetting powder sample is commercial, for Longdeng Chemical Co Ltd, Jiangsu produces.Tested in 2008 10 and carry out at Jinhua, Zhejiang.Test method: carry out field control effectiveness test with reference to " State Standard of the People's Republic of China GB/T17980.122-2004 ".
| Active substance | Effective concentration of treatment | Disease index | Control efficiency (%) |
| A:20% thiazole zinc SC | 440 mg/kg | 17.13 | 66.67 |
| B:50% captan WP | 440 mg/kg | 15.23 | 74.33 |
| A+B | 600 mg/kg+400 mg/kg | 15.75 | 74.00 |
| A+B | 460 mg/kg+440 mg/kg | 11.18 | 78.61 |
| A+B | 360 mg/kg+500 mg/kg | 9.28 | 80.21 |
| Blank | Clear water | 35.62 | /. |
21,722 grams per liter propamocarb aquas+20% thiazole zinc SC: the control cucumber downy mildew, 72.2% propamocarb sample is commercial, for Bayer Cropscience (China) Co., Ltd produces.Tested in October, 2007 and carry out at Xiaoshan, Zhejiang.Test method: carry out field control effectiveness test with reference to " State Standard of the People's Republic of China GB/T 17980.26-2000 ".
22,50% dimethomorph wetting powder+20% thiazole zinc SC: downy mildew of garpe, 50% dimethomorph WP sample is commercial, for BASF European Co.,Ltd produces.Test in Jinhua, Zhejiang and carry out.Test method: carry out field control effectiveness test with reference to " State Standard of the People's Republic of China GB/T 17980.122-2004 ".
| Active substance | Effective concentration of treatment | Disease index | Control efficiency (%) |
| A:20% thiazole zinc SC | 440 mg/kg | 21.20 | 61.12 |
| B:50% dimethomorph WP | 220 mg/kg | 15.57 | 78.81 |
| A+B | 600 mg/kg+140 mg/kg | 19.25 | 72.56 |
| A+B | 500 mg/kg+180 mg/kg | 10.68 | 83.35 |
| A+B | 400 mg/kg+220 mg/kg | 8.54 | 85.25 |
| Blank | Clear water | 35.55 | /. |
23,70% Carbatene water dispersible granules+20% thiazole zinc SC: prevent and treat canker of tomato, 70% Carbatene water dispersible granules sample is commercial, for BASF European Co.,Ltd produces.Tested in May, 2008 and carry out at Xiaoshan, Zhejiang.
| Active substance | Effective concentration of treatment | Disease index | Control efficiency (%) |
| A:20% thiazole zinc SC | 444 mg/kg | 12.38 | 81.81 |
| B:70% Carbatene WDG | 1500 mg/kg | 18.27 | 75.56 |
| A+B | 600 mg/kg+1200 mg/kg | 14.28 | 78.25 |
| A+B | 500 mg/kg+1400 mg/kg | 9.62 | 85.62 |
| A+B | 400 mg/kg+1600 mg/kg | 8.25 | 86.58 |
| Blank | Clear water | 30.52 | /. |
24,45% edifenphos pulvis+20% thiazole zinc SC: the control rice blast, 45% rice blast phosphorus powder agent sample is commercial, for Zhejiang Province Yifan Chemical Co., Ltd produces.Tested in June, 2008 and carry out at Xiaoshan, Zhejiang.
| Active substance | Effective concentration of treatment | Disease index | Control efficiency (%) |
| A:20% thiazole zinc SC | 500 mg/kg | 21.15 | 57.52 |
| B:45% edifenphos DP | 1000 mg/kg | 12.23 | 82.24 |
| A+B | 650 mg/kg+800 mg/kg | 16.24 | 79.25 |
| A+B | 500 mg/kg+1000 mg/kg | 15.61 | 80.02 |
| A+B | 400 mg/kg+1100 mg/kg | 16.38 | 79.65 |
| Blank | Clear water | 36.64 | /. |
25,25 grams per liter fludioxonil suspension seed-coating agents+100 kilograms of seed rice of 20% thiazole zinc SC seed dressing are prevented and treated bakanae disease of rice, and 25 grams per liter fludioxonil suspension seed-coating agent samples are commercial, produce for Switzerland is just reaching earlier crop protection Co., Ltd.Tested in April, 2008 and carry out at Jinhua, Zhejiang.Test method: carry out field control effectiveness test with reference to " State Standard of the People's Republic of China GB/T 17980.104-2004 ".
| Active substance | Effective concentration of treatment | Disease index | Control efficiency (%) |
| A:20% thiazole zinc | 220 mg/kg | 22.38 | 56.60 |
| B:25 grams per liter fludioxonil FSB | 30 mg/kg | 9.08 | 85.51 |
| A+B | 300 mg/kg+20 mg/kg | 17.25 | 80.35 |
| A+B | 240 mg/kg+25 mg/kg | 14.15 | 83.22 |
| A+B | 200 mg/kg+30 mg/kg | 13.16 | 84.21 |
| Blank | Clear water | 34.25 | /. |
26,20% mebenil missible oil+20% thiazole zinc SC: prevent and treat rice sheath blight disease, 25% mebenil missible oil is that Zhejiang Xinnong Chemical Co.,Ltd produces.Tested in August, 2007 and carry out at Xiaoshan, Zhejiang.Test method: carry out field control effectiveness test with reference to " pesticide field efficacy medicine test criterion GB/T 17980.20-2000 ".
| Active substance | Effective concentration of treatment | Disease index | Control efficiency (%) |
| A:20% thiazole zinc SC | 450 mg/kg | 19.21 | 71.32 |
| B:20% mebenil EC | 600 mg/kg | 15.38 | 82.67 |
| A+B | 400 mg/kg+200 mg/kg | 20.89 | 67.64 |
| A+B | 300 mg/kg+300 mg/kg | 19.20 | 70.20 |
| A+B | 200 mg/kg+400 mg/kg | 19.30 | 71.80 |
| Blank | Clear water | 42.17 | /. |
27,40% thiazole zinc Tebuconazole suspends, and (thiazole zinc: Tebuconazole=30: 10) the rice seedling growth test is regulated in agent, is tested in May, 2010 and carries out in Jiangxi Province's Zhangshu City plant protection unit.Test shows: use reagent agent and can effectively regulate the rice seedling growth, strengthen resistance, improve growth rate, accretion is obvious, and its effect is along with the increase or the medication number of times of dosage increase and improve.
40% thiazole zinc Tebuconazole SC regulates rice seedling growth test result
28,40% thiazole zinc Tebuconazole (the thiazole zinc: Tebuconazole=30: 10), tested in July, 2010 and carry out that suspends in Tongcheng City, Anhui Province plant protection unit to the rice seedling test of keeping a full stand of seedings.Test shows: uses reagent agent and can effectively regulate rice seedling plant height, false stem and slightly reach and increase white root and length all has obvious effect, thus easier turning green after rice seedling is transplanted.
40% thiazole zinc Tebuconazole SC is to the rice seedling result of the test of keeping a full stand of seedings
The applicant adopts in the above-mentioned field trial is that the mode of two kinds of components " bucket mixes " is carried out, why adopt this mode, reason is that these test objectives are to find and can have the component of cooperative synergism effect with thiazole zinc in the magnanimity Fungicidal active compound, and finished before the application's complex composition prepares embodiment, those skilled in the art all understand the clear and definite technology guide that " bucket mixes " is the preparation complex composition, the applicant has realized technical scheme of the present invention just under such technology is guided, reached desired technique effect, the complex composition of final preparation not only have the stability of unitary agent, and have the shown outstanding bactericidal property of above-mentioned data.
Though reactive compound I thiazole zinc and elite Fungicidal active compound II are known compound among the present invention, and the bactericidal property of each component and fungicidal spectrum are still composite to realize that the desired more outstanding bactericidal effect of the present invention then is non-obvious for those skilled in the art with above-mentioned reactive compound by those skilled in the art's basic understanding.Known Fungicidal active compound enormous amount, can be with thiazole zinc composite and can reach the component of cooperative synergism effect in order in the reactive compound of magnanimity, to find on a small quantity, the applicant has paid a large amount of creative works, through the biology test and the test of pesticide effectiveness many times.Though the result of the test of the bactericidal composition that the application limited is encouraging, but the applicant is in the process of the test of looking for suitable composite component, find that also more known Fungicidal active compound is can not realize the object of the invention when thiazole zinc is composite, can not produce cooperative synergism effect when for example thiazole zinc and tricyclazole, iprobenfos, copper 8-hydroxyquinolinate, sulphur or mebenil are composite, even can produce serious antagonism, be not suitable in production practices, using.
Claims (41)
1. bactericidal composition that contains thiazole zinc, it is characterized in that containing Fungicidal active compound I and Fungicidal active compound II, wherein said Fungicidal active compound I is a thiazole zinc, and described Fungicidal active compound II is selected from II.1 for any one)-II.13) compound
II.1) methoxy acrylic bactericide is selected from a kind of in Fluoxastrobin, kresoxim-methyl, oxime bacterium ester, pyraclostrobin, Enestroburin, the azoles bacterium ester;
II.2) triazole bactericidal agent is selected from a kind of in Difenoconazole, alkene azoles alcohol, fluorine ring azoles, RH-7592, Flusilazole, Flutriafol, Tebuconazole, own azoles alcohol, nitrile bacterium azoles, penconazole, propiconazole, tetraconazole, Triadimenol, bitertanol, the triazolone;
II.3) acid amide fungicides is selected from a kind of in metalaxyl, flutolanil, mandipropamid amine, Boscalid, fluorine pyrrole bacterium acid amides, the carboxin;
II.4) a kind of in the imidazoles bactericide is selected from a kind of in cyanogen frost azoles, the fluorine bacterium azoles;
II.5) dicarboximide series bactericidal agent is selected from a kind of in procymidone, iprodione, vinclozolin, captan, the dimethachlon;
II.6) carbamate fungicide is selected from a kind of in propamocarb, the mould prestige of second, benomyl, carbendazim, the thiophanate-methyl;
II.7) antibiotic series bactericidal agent is selected from a kind of in jinggangmeisu, streptomycin sulphate, kasugarnycin, the tetramycin;
II.8) oxazole series bactericidal agent is selected from Wakil, dislikes a kind of in the mould spirit;
II.9) morpholine series bactericidal agent is selected from a kind of in tridemorph, dimethomorph, the flumorph;
II.10) miazines bactericide is selected from a kind of in cyprodinil, phonetic mould amine, the phonetic phenol of second;
II.11) the quinolines bactericide is selected from dithianon;
II.12) dithiocarbamate fungicide is selected from a kind of in Carbatene, tmtd, zineb, mancozeb, the Propineb; Perhaps
II.13) other bactericide are selected from a kind of in edifenphos, phosethyl-Al, tpn, Isoprothiolane, fludioxonil or the Kocide SD.
2. bactericidal composition as claimed in claim 1 is characterized in that: it contains thiazole zinc and any one is selected from Fluoxastrobin, kresoxim-methyl, pyraclostrobin, Enestroburin, azoles bacterium ester, Difenoconazole, alkene azoles alcohol, fluorine ring azoles, RH-7592, Flusilazole, Flutriafol, Tebuconazole, nitrile bacterium azoles, penconazole, propiconazole, tetraconazole, Triadimenol, bitertanol, triazolone, metalaxyl, flutolanil, mandipropamid amine, Boscalid, fluorine pyrrole bacterium acid amides, cyanogen frost azoles, fluorine bacterium azoles, procymidone, iprodione, vinclozolin, captan, dimethachlon, propamocarb, benomyl, carbendazim, thiophanate-methyl, jinggangmeisu, streptomycin sulphate, kasugarnycin, Wakil, dislike mould spirit, tridemorph, dimethomorph, flumorph, cyprodinil, phonetic mould amine, the phonetic phenol of second, dithianon, Carbatene, tmtd, zineb, mancozeb, Propineb, edifenphos, phosethyl-Al, tpn, Isoprothiolane, the Fungicidal active compound II of fludioxonil or Kocide SD.
3. bactericidal composition as claimed in claim 1, it is characterized in that comprising with mass ratio is 5: 50～80: 1 thiazole zinc and methoxy acrylic bactericide reactive compound II.1.
4. bactericidal composition as claimed in claim 3 is characterized in that thiazole zinc and methoxy acrylic Fungicidal active compound II.1 mass ratio are 20: 30～40: 5.
5. bactericidal composition as claimed in claim 1, it is characterized in that comprising with mass ratio is 5: 50～80: 1 thiazole zinc and triazole type Fungicidal active compound II.2.
6. bactericidal composition as claimed in claim 5 is characterized in that thiazole zinc and triazole type Fungicidal active compound II.2 mass ratio are 20: 20～40: 5.
7. bactericidal composition as claimed in claim 1 is characterized in that comprising that mass ratio is 5: 40～80: 1 thiazole zinc and amide-type Fungicidal active compound II.3.
8. bactericidal composition as claimed in claim 7 is characterized in that thiazole zinc and amide-type Fungicidal active compound II.3 mass ratio are 20: 20～40: 5.
9. bactericidal composition as claimed in claim 1 is characterized in that comprising that mass ratio is 5: 60～80: 1 thiazole zinc and imidazoles Fungicidal active compound II.4.
10. bactericidal composition as claimed in claim 10 is characterized in that thiazole zinc and imidazoles Fungicidal active compound II.4 mass ratio are 20: 30～40: 10.
11. bactericidal composition as claimed in claim 1 is characterized in that comprising that mass ratio is 5: 60～80: 1 thiazole zinc and dicarboximide class Fungicidal active compound II.5.
12. bactericidal composition as claimed in claim 11 is characterized in that thiazole zinc and dicarboximide class Fungicidal active compound II.5 mass ratio are 20: 50～40: 20.
13. bactericidal composition as claimed in claim 1 is characterized in that comprising that mass ratio is 5: 80～80: 5 thiazole zinc and carbamate sterilization reactive compound II.6.
14. bactericidal composition as claimed in claim 13 is characterized in that thiazole zinc and carbamate sterilization reactive compound II.6 mass ratio are 20: 60～40: 10.
15. bactericidal composition as claimed in claim 1 is characterized in that comprising that mass ratio is 5: 80～80: 1 thiazole zinc and antibiotic class Fungicidal active compound II.7.
16. bactericidal composition as claimed in claim 15 is characterized in that thiazole zinc and antibiotic class Fungicidal active compound II.7 mass ratio are 20: 70～40: 2.
17. bactericidal composition as claimed in claim 1 is characterized in that comprising that mass ratio is that 5: 60～80: 5 thiazole Xin is with oxazole class reactive compound II.8.
18. bactericidal composition as claimed in claim 17 is characterized in that comprising that mass ratio is that 5: 60～80: 5 thiazole Xin is with oxazole class reactive compound II.8 mass ratio is 20: 50～40: 10.
19. bactericidal composition as claimed in claim 1 is characterized in that comprising that mass ratio is 5: 80～80: 5 thiazole zinc and morpholine class reactive compound II.9.
20. bactericidal composition as claimed in claim 19 is characterized in that thiazole zinc and morpholine class reactive compound II.9 mass ratio are 20: 50～40: 20.
21. bactericidal composition as claimed in claim 1 is characterized in that comprising that mass ratio is 5: 60～80: 10 thiazole zinc and miazines reactive compound II.10.
22. bactericidal composition as claimed in claim 1 is characterized in that thiazole zinc and miazines reactive compound II.10 mass ratio are 20: 50～40: 20.
23. bactericidal composition as claimed in claim 1 is characterized in that comprising that mass ratio is 5: 60～80: 10 thiazole zinc and quinolines reactive compound II.11.
24. bactericidal composition as claimed in claim 23 is characterized in that thiazole zinc and quinolines reactive compound II.11 mass ratio are 20: 50～40: 20.
25. bactericidal composition as claimed in claim 1 is characterized in that comprising that mass ratio is 5: 80～80: 10 thiazole zinc and dithiocarbamates reactive compound II.12.
26. bactericidal composition as claimed in claim 25 is characterized in that thiazole zinc and dithiocarbamates reactive compound II.12 mass ratio are 20: 50～40: 20.
27. bactericidal composition as claimed in claim 1 is characterized in that comprising that mass ratio is 5: 80～80: 1 thiazole zinc and Fungicidal active compound II.13.
28. bactericidal composition as claimed in claim 27 is characterized in that thiazole zinc and Fungicidal active compound II.13 mass ratio are 20: 50～40: 10.
29. bactericidal composition as claimed in claim 1 is characterized in that the reactive compound sum accounts for 1～90% of total amount in the described by percentage to the quality composition.
30. bactericidal composition as claimed in claim 29 is characterized in that in the described by percentage to the quality composition that the reactive compound sum accounts for 20～60% of total amount in the composition.
31. bactericidal composition according to claim 29 is characterized in that it further includes wetting agent, dispersant, thickener, antifreezing agent, preservative, disintegrant, stabilizing agent, film forming agent, defoamer, colouring agent, filler and/or water.
32. bactericidal composition as claimed in claim 31 is characterized in that described wetting agent is selected from EO/PO block polyether, fatty alcohol-polyoxyethylene ether, fat alcohol ethoxyl compound, tallow ethyoxyl ammonium salt, alkylnaphthalene sulfonate, fatty alcohol polyoxyethylene ether sulfate and/or acyl group glutamate.
33. bactericidal composition as claimed in claim 31 is characterized in that described dispersant is selected from naphthalene sulfonic acid condensate sodium salt, phenolsulfonic acid condensation product sodium salt, methyl naphthalene sulfonate formaldehyde condensate, sodium lignin sulfonate, sodium metnylene bis-naphthalene sulfonate, acrylate homopolymer sodium salt, polymeric polycarboxylic acid salt, dioctyl sodium sulphosuccinate salt, EO/PO block polyether and/or maleic acid-acrylic acid copolymer sodium salt.
34. bactericidal composition as claimed in claim 31 is characterized in that described thickener is selected from xanthans, Magnesiumaluminumsilicate, sodium carboxymethylcellulose, starch phosphate sodium, starch Sodium Octenyl Succinate and/or polyvinyl alcohol.
35. bactericidal composition as claimed in claim 31 is characterized in that described solvent is selected from dimethylbenzene and/or trimethylbenzene, described antifreezing agent is selected from ethylene glycol, propane diols, glycerine, isopropyl alcohol and/or urea.
36. bactericidal composition as claimed in claim 31 is characterized in that described film forming agent selects the high molecular polymer with cohesiveness and film forming of polyvinyl alcohol, polyvinyl acetate, polyethylene glycol polymethylacrylic acid glycol ester, carboxymethyl cellulose, gum Arabic, xanthans and/or starch for use.
37. bactericidal composition as claimed in claim 31 is characterized in that described disintegrant is selected from sodium chloride, ammonium sulfate, sodium sulphate and/or soluble starch, described preservative is selected from formaldehyde, phenyl salicytate, butyl p-hydroxybenzoate and/or potassium sorbate.
38. bactericidal composition as claimed in claim 31, it is characterized in that described stabilizing agent is selected from epoxidized soybean oil, epoxychloropropane, triphenyl phosphite, glycidol ether and/or pentaerythrite, described defoamer is selected from silicone defoaming agent and/or polyether antifoam agent, and described colouring agent is selected from iron oxide, titanium oxide and/or azo dyes.
39. bactericidal composition as claimed in claim 31 is characterized in that described filler is selected from kaolin, diatomite, talcum powder, precipitated calcium carbonate and/or white carbon, described water is deionized water or distilled water.
40., but it is characterized in that described bactericidal composition is wetting powder, pulvis, seed treatment dry powder doses, seed treatment dispersion powder, granule, suspending agent, suspension emulsion, microcapsule suspending agent, seed treatment suspending agent, seed treatment microcapsule suspending agent or suspension seed-coating agent as arbitrary described bactericidal composition among the claim 1-31.
41. the purposes of bactericidal composition as claimed in claim 1 in controlling plant diseases and promotion crop healthy growth.
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| CN102379293B (en) * | 2011-10-26 | 2013-05-08 | 广东中迅农科股份有限公司 | Bactericidal composition |
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