CN101935241B - Potassium-calcium biological composite foliar fertilizer and preparation method and application thereof - Google Patents
Potassium-calcium biological composite foliar fertilizer and preparation method and application thereof Download PDFInfo
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- CN101935241B CN101935241B CN2009101959857A CN200910195985A CN101935241B CN 101935241 B CN101935241 B CN 101935241B CN 2009101959857 A CN2009101959857 A CN 2009101959857A CN 200910195985 A CN200910195985 A CN 200910195985A CN 101935241 B CN101935241 B CN 101935241B
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- 239000002131 composite material Substances 0.000 title claims abstract description 35
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- 240000004808 Saccharomyces cerevisiae Species 0.000 claims abstract description 46
- 239000002994 raw material Substances 0.000 claims abstract description 37
- 241000894006 Bacteria Species 0.000 claims abstract description 24
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000002699 waste material Substances 0.000 claims abstract description 13
- 235000010333 potassium nitrate Nutrition 0.000 claims abstract description 11
- 239000004323 potassium nitrate Substances 0.000 claims abstract description 11
- 244000005700 microbiome Species 0.000 claims abstract description 7
- AXTGDCSMTYGJND-UHFFFAOYSA-N 1-dodecylazepan-2-one Chemical compound CCCCCCCCCCCCN1CCCCCC1=O AXTGDCSMTYGJND-UHFFFAOYSA-N 0.000 claims abstract description 5
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- 239000000284 extract Substances 0.000 claims description 2
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- 238000004519 manufacturing process Methods 0.000 abstract description 16
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- 239000011591 potassium Substances 0.000 abstract description 14
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- QJZYHAIUNVAGQP-UHFFFAOYSA-N 3-nitrobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical compound C1C2C=CC1C(C(=O)O)C2(C(O)=O)[N+]([O-])=O QJZYHAIUNVAGQP-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
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- PYMYPHUHKUWMLA-UHFFFAOYSA-N 2,3,4,5-tetrahydroxypentanal Chemical compound OCC(O)C(O)C(O)C=O PYMYPHUHKUWMLA-UHFFFAOYSA-N 0.000 description 1
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
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Images
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
- Y02A40/10—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
- Y02A40/20—Fertilizers of biological origin, e.g. guano or fertilizers made from animal corpses
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- Fertilizers (AREA)
Abstract
The invention relates to a potassium-calcium biological composite foliar fertilizer. The potassium-calcium biological composite foliar fertilizer consists of the following components in percentage by weight: 20 to 40 percent of bacteria-containing yeast organic raw material, 24.5 to 39.5 percent of potassium nitrate, 35 to 45 percent of calcium ammonium nitrate and the balance of azone. The invention also provides a preparation method and application of the potassium-calcium biological composite foliar fertilizer. The invention provides a new raw material for the production of the foliar fertilizer, so that the conventional mode of preparing potassium and calcium foliar fertilizers from inorganic raw materials is broken and the new raw material is found for technically improving a composite microorganism fertilizer to the foliar fertilizer. The foliar fertilizer has the characteristics of making waste profitable, lowering the production cost of the foliar fertilizer and improving product quality, along with low cost, high water solubility, high utilization ratio and the like.
Description
[technical field]
The present invention relates to a kind of foliage fertilizer, specifically, is about the biological composite foliage fertilizer of a kind of potassium calcium.
[background technology]
The exploitation of microbial fertilizer and research be get into 21 century since a hot issue of international agricultural; The excessive chemical fertilizer of using; Unfavorable to keeping the eubiosis with the protection environment; Characteristics such as that microbial fertilizer has is long-acting, nontoxic, pollution-free, save energy, cost are low are importances of modern agriculture Sustainable development, receive common concern both domestic and external.Foliage top dressing or foliage application are claimed in leaf dressing again, are fertilizer is directly sprayed the blade surface crop, absorb through blade; Rest branch and be transported to each position in the body, its outstanding feature is with strong points, and the nutrition absorption running is fast; Can avoid the fixed action of soil, improve plant recovery of nutrient, and dose be few some nutrient; Obvious effect of increasing production; Especially bad, excess moisture of edatope or arid low humidity condition, soil peracid are crossed factor such as alkali and are caused the root system sorption to be obstructed or the crop nutritional deficiency, are badly in need of supplementing the nutrients and during plant growth later stage root system receptivity decline, adopt foliage spray can remedy root system and inhale fertile not enough; Can obtain effect of increasing production preferably, expert both domestic and external in recent years, scholar and colleague more and more pay attention to exploitation, production and the application of foliage fertilizer.Data shows that abroad, fertilizer surpasses 40% through the foliage applying proportion, and effect of increasing production can reach more than 10%, has the effect of " art is good for strength ".
In growing process, potassium, calcium all are the essential a kind of nutritive elements of plant, play and keep the normal vital movement effect of vegetable cell, and important effect is played in the growth of plant and the raising of crop yield.Can form calcium pectinate with pectic acid such as calcium, the structure of stabilized cell wall; Calcium can connect phospholipid molecule, stabilizing cell membrane; The major part of calcium is present in the intracellular vacuole, and the balance of zwitterion in the vacuole is had significant contribution, has the osmoregulation effect; The calcium element can also the intravital signal transduction of involved in plant etc. a series of effects.The main effect of potassium comprises promotion photosynthesis, helps protein synthesis, carbohydrate metabolism, symbiotic nitrogen fixation etc.; Can quicken synthetic product flows, accumulates; Can also the activation plurality of enzymes, make plant growth healthy and strong, improve that crop is freeze proof, drought resisting, disease resistance and lodging tolerance.Owing to the reasons such as a large amount of long-term application of chemical fertilizer, make that soil is sour, basicity is excessive, cause drenching of potassium in the soil, calcium serious, and, be unfavorable for the absorption of plant potassium, calcium owing to anoxic in the soil, cause plant potassium deficiency and calcium.In recent years, the report of relevant plant potassium deficiency, calcium phenomenon is successive, has brought great financial loss to agriculture prodn.
The potassium that provides in the market, calcium foliage fertilizer mainly are single-element fertilizer, and basically all are inorganic types, wherein have only calcium or have only potassium.Through use potassium, though the calcium single fertilizer also can play certain effect, the specific absorption of potassium, calcium is not high, again the lost labor.
[summary of the invention]
The objective of the invention is to deficiency of the prior art, provide a kind of efficiently, cheap, the biological composite foliage fertilizer of potassium calcium that quality meets " composite microbiological fertilizer " agriculture standard (NY/T 798-2004).
One purpose more of the present invention is that the preparation method of the biological composite foliage fertilizer of a kind of potassium calcium is provided.
Another purpose of the present invention is that the application of the biological composite foliage fertilizer of a kind of potassium calcium is provided.
For realizing above-mentioned purpose, the technical scheme that the present invention takes is:
The biological composite foliage fertilizer of a kind of potassium calcium, the biological composite foliage fertilizer of described potassium calcium by weight percentage, this foliage fertilizer is composed of the following components:
Contain bacterium yeast organic raw material 20-40%
Saltpetre 24.5-39.5%
Calcium ammonium nitrate 35-45%
The azone surplus.
Be preferably, the described bacterium yeast organic raw material that contains comprises bacterium liquid and yeast organic raw material, and wherein the absorption ratio of bacterium liquid and yeast organic raw material is 1: 20-1: 40.
Be preferably, described bacterium liquid be subtilis liquid and bacillusmusilaginosiengineering liquid by 2: 1-3: 1 mixed forms.
For realizing above-mentioned second purpose, the technical scheme that the present invention takes is:
The preparation method of the biological composite foliage fertilizer of a kind of potassium calcium, this method may further comprise the steps:
A, the preparation of yeast organic raw material: will extract the later yeast fermentation broth waste liquid magma of yeast fermentation and concentrate, and obtain the yeast organic raw material through spray dry process then;
B, complex micro organism fungicide preparation: with subtilis and the independent fermentative prodn of bacillusmusilaginosiengineering; Two bacterial classifications press 2 with two kinds of bacterium liquid after the fermentation: 1-3: 1 mixed respectively separately through slant culture, shaking table enlarged culturing, seeding tank fermentation and ferment tank; Adsorb with above-mentioned powder yeast organic raw material then;
C, in the above-mentioned yeast organic raw material that is adsorbed with strain fermentating liquid, add saltpetre, nitric acid ammonia calcium, azone (permeate agent) etc., after the mixing the biological composite foliage fertilizer of potassium calcium.
Preparing method of the present invention produces the potassium calcium biological compound foliage fertilizer that obtains, and the technical indicator of said product is following:
(1), living bacteria count>=2 * 10
7Individual/gram (2), N+P
2O
5+ K
2O>=25%
(3)、K
2O≥15% (4)、CaO≥10%
(5), organic >=15% (6), humic acid >=10%
For realizing above-mentioned the 3rd purpose, the technical scheme that the present invention takes is:
The biological composite foliage fertilizer of a kind of potassium calcium, the application of as fertilizer sources in the agricultural crops growth, described foliage fertilizer by weight percentage, this foliage fertilizer is composed of the following components:
Contain bacterium yeast organic raw material 20-40%
Saltpetre 24.5-39.5%
Calcium ammonium nitrate 35-45%
The azone surplus
Be preferably the application of the biological composite foliage fertilizer as fertilizer sources of described potassium calcium in agricultural crops potassium deficiency, calcium deficiency growth.
Know-why of the present invention is, useful microbe can improve the micro-ecological environment of plant, and the regulation ecological balance can suppress the intrusion of pathogenic bacteria, has sterilizing disease-preventing, improves effects such as crop nutrition content supply.On the other hand; The yeast fermentation broth waste liquid that produces when producing yeast is through containing great number of organic matters, amino acid, humic acids, protein and multiple middle trace element in the organic raw material after the spraying drying; Most of nutritive substance is the required nutrient of crop and microorganism growth in these materials; Particularly wherein small molecules organic matter can be directly absorbed, utilizes by crop; Can replenish crop alimentary and promote that beneficial microorganism is bred fast in the fertilizer, have stimulating plant growth, enhancing body vigor and metabolic capacity, improve disease resistance and the anti-adversity ability of plant.Simultaneously, plant is replenished the potassium calcium constituent when lacking potassium, calcium constituent, has the plant of mutually promoting to each other absorption, and calcium helps keeping the integrity of cell quality, keeps the aperture and the permeability of film, can prevent intracellular K
+Exosmose, help the plain absorption of potassium.Witz test also proves Ca
2+Ion not only can promote K
+Absorption, and can also reduce cationic exosmosing in the plant.
Compared with prior art, the present invention has following beneficial effect:
1, for foliage fertilizer production a kind of new starting material is provided: broken single traditional mode of producing potassium, calcium foliage fertilizer with inorganic raw material; For being that foliage fertilizer has been found a kind of new starting material with the composite microbiological fertilizer technological improvement, it has with low cost, turns waste into wealth; Good water solubility; Characteristics such as utilization ratio height, when reducing the foliage fertilizer production cost, quality product also is improved.
2, fertilizer efficiency improves: the biological composite foliage fertilizer of potassium calcium can efficiently replenish middle potassium, the calcium constituent of crop, fine growing of guaranteeing crop, and potassium calcium interacts, and absorbs soon, and plant recovery of nutrient improves.Simultaneously, include beneficial microbe colony, can improve the micro-ecological environment of plant, improve the crop nutrition content supply, and useful microbe is attached to and forms dominant microflora on the plant, can suppress the intrusion of pathogenic bacteria.In addition, the yeast organic raw material is except can directly being participated in can also activating the crop cell tissue, improving the plant organ function, the enhancing crop anti-adversity ability the plant growth metabolism by plant absorbing.
3, nutrient is comprehensive: the breakthrough of the biological composite foliage fertilizer of potassium calcium is not only to supply with inorganic nutrients such as crop potassium, calcium; And effective viable bacteria, organic matter, amino acid, humic acids, protein and microbiotic etc. are provided; Be not merely crop more comprehensive nutritive materials is provided, also can play the effect of drought resisting, disease-resistant, short life, conditioning and sterilizing disease-preventing.
4, utilization of waste material: be not merely the fermented liquid waste liquid that produces in the yeast production process a brand-new disposal of resources approach is provided, and can obtain the higher foliage fertilizer product of added value, thereby reduced the treatment and disposal cost of fermented liquid waste liquid.
5, safety, environmental protection: the present invention has nontoxic, tasteless, and is safe and reliable, has no side effect, and utilization ratio is high, fertilizer loss is few, agricultural-food, surrounding environment are not had pollution, has characteristics such as safety and environmental protection.Simultaneously, the present invention adopts scientific formula and vanguard technology to make with extra care and forms, and the crop blade face is increased, and chlorophyll content improves, photosynthesis strengthens; Well developed root system, sugar and dry-matter accumulation increase, the drought resisting of enhancing crop, waterlogging-resistant and resistance against diseases etc.
[description of drawings]
Accompanying drawing 1 is a waste liquid output process flow sheet in the yeast production process.
Accompanying drawing 2 is yeast fermentation broth waste liquid drying process with atomizing schema of the present invention.
Accompanying drawing 3 is the biological composite foliage fertilizer production scheme of potassium calcium of the present invention.
[embodiment]
Below in conjunction with accompanying drawing embodiment provided by the invention is elaborated.
Embodiment 1
1, powder yeast organic raw material produces
Concentrate extracting the later fermented liquid waste liquid magma of yeast, waste liquid magma concentration is about 7%, makes concentration reach 50% after concentrating, and produces fineness greater than 80 orders through spray dry process then, and moisture is less than 3% tawny powder yeast organic raw material.(in the yeast production process waste liquid output process flow sheet can referring to Fig. 1).
The basic proterties of the powdery yeast organic raw material after the spraying drying is seen table 1. (yeast fermentation broth waste liquid drying process with atomizing flow process is seen Fig. 2).
The basic proterties of table 1 powdery yeast organic raw material
2, strain fermentation
Subtilis (Bacillus subtilis) and bacillusmusilaginosiengineering (Bacillusmucilaginosus) are utilized the independent fermentative prodn of fermentation equipment; Two bacterial classifications are respectively separately through slant culture, shaking table enlarged culturing, seeding tank fermentation and ferment tank; With the mixed of two kinds of bacterium liquid, make the number of viable of zymocyte liquid reach 5,000,000,000/ml after the fermentation by 2: 1.
3, batching
(1), accurately takes by weighing yeast organic materials 300Kg in stirrer; According to bacterium liquid: the ratio of yeast powder=1: 30 (L/kg) adds the mixed fermentation liquid 10L of 5,000,000,000/ml of living bacteria count, fully stirs the back for containing the yeast organic matter of hundred million of number of viable 1.3-1.6/gram;
(2),, capacity carries out accurate feed proportioning in being 500 kilograms stirrer: the above-mentioned yeast organic raw material 30% that contains viable bacteria that makes, saltpetre 29.5%, calcium ammonium nitrate 40% according to the proportioning raw materials of table 2.(Fig. 3 is seen in the biological composite foliage fertilizer Production Flow Chart of potassium calcium).
The production formula of the biological composite foliage fertilizer of table 2 potassium calcium
Annotate: the content of each raw material is following:
1., contain bacterium yeast organic raw material: N>=4%, K
2O>=11%, organic>=60%, humic acid>=41, amino acid>=12%, living bacteria count>=1.3 hundred million/gram;
2., saltpetre: N>=13%, K
2O>=46%;
3., calcium ammonium nitrate: N >=15%, CaO >=25%;
Stirrer stirred 10-15 minute, let the material thorough mixing, was crushed to the 60-80 order after the mixing.
4, quality examination
The examination and test of products is carried out according to the method for the agriculture standard of Ministry of Agriculture's industry standard " composite microbiological fertilizer " (NY/T798-2004), and the basic proterties of the biological composite foliage fertilizer finished product of potassium calcium is seen table 3.
The detected result of the biological composite foliage fertilizer of table 3 potassium calcium
Embodiment 2
In the complex micro organism fungicide preparation, the blending ratio after subtilis (Bacillus subtilis) and bacillusmusilaginosiengineering (Bacillus mucilaginosus) fermentation is 3: 1, and the absorption ratio of bacterium liquid and yeast organic raw material is 1: 20.
The additional proportion of yeast organic raw material is 40%, saltpetre 24.5%, calcium ammonium nitrate 35%; Other are with embodiment 1.
Embodiment 3
In the complex micro organism fungicide preparation, the blending ratio after subtilis (Bacillus subtilis) and bacillusmusilaginosiengineering (Bacillus mucilaginosus) fermentation is 2: 1, and the absorption ratio of bacterium liquid and yeast organic raw material is 1: 40.
The additional proportion of yeast organic raw material is 20%, saltpetre 39.5%, calcium ammonium nitrate 45%.Other are with embodiment 1.
Test Example
The pear tree field test effect
Test is handled:
A: spray compound bio potassium calcium foliage fertilizer (adopting the biological composite foliage fertilizer of potassium calcium of embodiment 1) by 1: 600 extent of dilution, hereinafter to be referred as handling A;
B: spray biological foliage fertilizer (adopt the pure bacterium yeast organic raw material foliage fertilizer that contains, other are with embodiment 1) by 1: 600 extent of dilution, hereinafter to be referred as treatments B;
C: spray saltpetre foliage fertilizer (adopt pure saltpetre foliage fertilizer, other are with embodiment 1) by 1: 600 extent of dilution, hereinafter to be referred as handling C;
D: spray calcium ammonium nitrate foliage fertilizer (adopt pure calcium ammonium nitrate foliage fertilizer, other are with instance 1) by 1: 600 extent of dilution, hereinafter to be referred as handling D;
E: compare with clear water and to carry out foliage-spray, hereinafter to be referred as handling E.
Sub-district area 80m
2, establish 3 repetitions, district's group is arranged at random.All tests are handled base manure and press habits fertilization and handle, and manuring late is handled by test and carried out, and the foliage fertilizer time that sprays is spent back 20 days thanking for the first time, sprays once in later per 20 days, sprays altogether 4 times, and other management is identical with habits fertilization.Testing data is carried out variance analysis and test of significance thereof with SPSS13.0 software, and Excel adds up, analyzes.
(1) different treatment is to the influence of pears quality
Table 5 different treatment is to the influence of pears quality and storage tolerance
Annotate: numeral is the MV of 3 mensuration in the table; Numeral same column right side lowercase is identical, does not have significant difference between the expression, indicates different lowercases and representes to reach 95% significant difference; Indicate different capitalizations and represent to reach 99% significant difference; Down together.
Data can be found out from table 5; In the influence of different treatment to crop quality; Each index of handling A, treatments B, processing C and processing D pears is better than each index of handling among the E; Fruit soluble solid like pears has increased by 4.0%, 1.7%, 1.1% and 0.9% than handling E respectively, and soluble sugar increases by 2.10%, 1.20%, 0.41% and 0.20%, and mashed loss rate improves 1.4%, 0.5%, 0.6% and 0.2%.Handling A can increase fruit soluble solid, hardness and vitamin contents preferably, strengthens the fruit storage tolerance then, and is superior to the spraying effect of treatments B, C and D.ANOVA showed significant, the spraying effect of the biological composite foliage fertilizer of potassium calcium is significantly higher than the processing that compares with clear water, and with single with inorganic or singly also reached the significant difference level with the spraying effect of organic foliar fertilizer.Explain that the biological composite foliage fertilizer of potassium calcium is than single quality that can effectively improve pears with inorganic or list with organic foliar fertilizer.
(2) different treatment is to the influence of pears output
Table 6 different treatment is to the effect of increasing production of pears
Different treatment can get single plant yield and the single fruit weight mensuration result (table 6) of pear tree, and the pear tree single plant yield that the biological composite foliage fertilizer of potassium calcium sprays is higher than other, and each is handled, and effect of increasing production reaches utmost point level of signification.Simultaneously, the single fruit weight of handling A also is higher than treatments B, handles C and handles D, is higher than more greatly and handles E, and ANOVA showed significant reaches significant difference between them, and the single fruit weight of handling A is significantly higher than treatments B, handles C and handles D.
Can find out from above test-results: when the biological composite foliage fertilizer of potassium calcium can obviously increase crop yield, the effect that can play utilization of waste material, reduces the wasting of resources, protects environment, reduces fertilizer amount, improves quality of agricultural product.
The above only is a preferred implementation of the present invention; Should be pointed out that for those skilled in the art, under the prerequisite that does not break away from the inventive method; Can also make some improvement and replenish, these improvement and replenish and also should be regarded as protection scope of the present invention.
Claims (3)
1. the biological composite foliage fertilizer of a potassium calcium, the application of as fertilizer sources in the agricultural crops growth, described foliage fertilizer by weight percentage, this foliage fertilizer is composed of the following components:
The described bacterium yeast organic raw material that contains comprises bacterium liquid and yeast organic raw material; Wherein the absorption ratio of bacterium liquid and yeast organic raw material is 1: 20-1: 40; The unit of described absorption ratio is L/kg; Described yeast organic raw material is that yeast fermentation broth waste liquid magma concentrate drying makes, and described bacterium liquid is subtilis liquid and bacillusmusilaginosiengineering liquid by volume 2: 1-3: 1 mixed forms.
2. application according to claim 1 is characterized in that, the application of the biological composite foliage fertilizer as fertilizer sources of described potassium calcium in agricultural crops potassium deficiency, calcium deficiency growth.
3. the preparation method of the biological composite foliage fertilizer of the said potassium calcium of claim 1 is characterized in that this method may further comprise the steps:
A, the preparation of yeast organic raw material: will extract the later yeast fermentation broth waste liquid magma of yeast fermentation and concentrate, and obtain the yeast organic raw material through spray dry process then;
B, complex micro organism fungicide preparation: with subtilis and the independent fermentative prodn of bacillusmusilaginosiengineering; Two bacterial classifications are respectively separately through slant culture, shaking table enlarged culturing, seeding tanks fermentation and ferment tanks, after the fermentation with two kinds of bacterium liquid by volume 2: 1-3: 1 mixed; Adsorb with above-mentioned powder yeast organic raw material then;
C, in the above-mentioned yeast organic raw material that is adsorbed with strain fermentating liquid, add saltpetre, nitric acid ammonia calcium, azone, after the mixing the biological composite foliage fertilizer of potassium calcium.
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CN103710281B (en) * | 2013-11-12 | 2015-11-04 | 青岛明月蓝海生物科技有限公司 | Bacillus mucilaginosus strain and application thereof in seaweed biofertilizer |
CN105175049B (en) * | 2015-07-13 | 2019-02-19 | 青岛阿道姆农业科技有限公司 | Foliar fertilizer and preparation method thereof containing calcium ammonium nitrate |
CN106431629A (en) * | 2016-08-31 | 2017-02-22 | 广德明凯蔬果种植家庭农场 | Adjusting foliar fertilizer |
CN106242864A (en) * | 2016-08-31 | 2016-12-21 | 广德明凯蔬果种植家庭农场 | A kind of composite foliage fertilizer material |
CN107935747A (en) * | 2017-11-30 | 2018-04-20 | 孙铭岐 | A kind of high-efficiency compound foliar fertilizer |
CN111732471A (en) * | 2020-04-17 | 2020-10-02 | 广西宇花灵科技发展有限公司 | Foliar fertilizer with function of improving crop resistance and preparation method thereof |
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CN1197780A (en) * | 1998-04-03 | 1998-11-04 | 北京宝贝科技开发有限责任公司 | Complete nutritive special fertilizer |
CN1229776A (en) * | 1999-01-16 | 1999-09-29 | 邬纯忠 | Vigourous liquid fertilizer for plant |
CN101318857A (en) * | 2007-06-07 | 2008-12-10 | 华丰源生物科技(深圳)有限公司 | Liquid fertilizer special for alkali soil |
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CN1197780A (en) * | 1998-04-03 | 1998-11-04 | 北京宝贝科技开发有限责任公司 | Complete nutritive special fertilizer |
CN1229776A (en) * | 1999-01-16 | 1999-09-29 | 邬纯忠 | Vigourous liquid fertilizer for plant |
CN101318857A (en) * | 2007-06-07 | 2008-12-10 | 华丰源生物科技(深圳)有限公司 | Liquid fertilizer special for alkali soil |
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