CN101935241A - Potassium-calcium biological composite foliar fertilizer and preparation method and application thereof - Google Patents

Potassium-calcium biological composite foliar fertilizer and preparation method and application thereof Download PDF

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CN101935241A
CN101935241A CN2009101959857A CN200910195985A CN101935241A CN 101935241 A CN101935241 A CN 101935241A CN 2009101959857 A CN2009101959857 A CN 2009101959857A CN 200910195985 A CN200910195985 A CN 200910195985A CN 101935241 A CN101935241 A CN 101935241A
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calcium
potassium
raw material
foliage fertilizer
fertilizer
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CN101935241B (en
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闫龙翔
曹良元
史学军
史静
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LULE BIOLOGICAL SCIENCE AND TECHNOLOGY Co Ltd SHANGHAI
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    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A40/00Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
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    • Y02A40/20Fertilizers of biological origin, e.g. guano or fertilizers made from animal corpses

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Abstract

The invention relates to a potassium-calcium biological composite foliar fertilizer. The potassium-calcium biological composite foliar fertilizer consists of the following components in percentage by weight: 20 to 40 percent of bacteria-containing yeast organic raw material, 24.5 to 39.5 percent of potassium nitrate, 35 to 45 percent of calcium ammonium nitrate and the balance of azone. The invention also provides a preparation method and application of the potassium-calcium biological composite foliar fertilizer. The invention provides a new raw material for the production of the foliar fertilizer, so that the conventional mode of preparing potassium and calcium foliar fertilizers from inorganic raw materials is broken and the new raw material is found for technically improving a composite microorganism fertilizer to the foliar fertilizer. The foliar fertilizer has the characteristics of making waste profitable, lowering the production cost of the foliar fertilizer and improving product quality, along with low cost, high water solubility, high utilization ratio and the like.

Description

Biological composite foliage fertilizer of a kind of potassium calcium and its production and application
[technical field]
The present invention relates to a kind of foliage fertilizer, specifically, is about biological composite foliage fertilizer of a kind of potassium calcium and its production and application.
[background technology]
The exploitation of microbial fertilizer and research be enter 21 century since a hot issue of international agricultural; the excessive chemical fertilizer of using; to keeping the eubiosis and protecting environment unfavorable; characteristics such as that microbial fertilizer has is long-acting, nontoxic, pollution-free, save energy, cost are low; be an importance of modern agriculture Sustainable development, be subjected to common concern both domestic and external.Leaf dressing claims foliage top dressing or foliage application again, be that fertilizer is directly sprayed blade surface crop, absorb by blade, rest branch and be transported to each position in the body, its outstanding feature is with strong points, the nutrition absorption running is fast, can avoid the fixed action of soil to some nutrient, improve plant recovery of nutrient, and rate of fertilizer application is few, obvious effect of increasing production, especially edatope is bad, excess moisture or arid low humidity condition, the soil peracid is crossed factor such as alkali and is caused the root system sorption to be obstructed or the crop nutritional deficiency, is badly in need of supplementing the nutrients and during plant growth later stage root system receptivity decline, adopts foliage spray can remedy root system and inhale fertile not enough, can obtain effect of increasing production preferably, expert both domestic and external in recent years, scholar and colleague more and more pay attention to the exploitation of foliage fertilizer, produce and use.Data shows that abroad, fertilizer surpasses 40% by the foliage applying proportion, and effect of increasing production can reach more than 10%, has the effect of " art is good for strength ".
In growing process, potassium, calcium all are the essential a kind of nutritive elements of plant, play and keep the normal vital movement effect of vegetable cell, and important effect is played in the growth of plant and the raising of crop yield.Can form calcium pectinate with pectic acid such as calcium, the structure of stabilized cell wall; Calcium can be tied phospholipid molecule, stabilizing cell membrane; The major part of calcium is present in the intracellular vacuole, and the balance of zwitterion in the vacuole is had significant contribution, has the osmoregulation effect; The calcium element can also the intravital signal transduction of involved in plant etc. a series of effects.The main effect of potassium comprises promotion photosynthesis, helps protein synthesis, carbohydrate metabolism, symbiotic nitrogen fixation etc.; Can quicken synthetic product flows, accumulates; Can also activate plurality of enzymes, make the plant growth stalwartness, improve that crop is freeze proof, drought resisting, disease resistance and lodging tolerance.Owing to the reasons such as a large amount of long-term application of chemical fertilizer, make soil acid, basicity excessive, cause drenching of potassium in the soil, calcium serious, and, cause plant potassium deficiency and calcium because anoxic in the soil is unfavorable for the absorption of plant to potassium, calcium.In recent years, the report of relevant plant potassium deficiency, calcium phenomenon is successive, has brought great financial loss to agriculture production.
The potassium that provides in the market, calcium foliage fertilizer mainly are single-element fertilizer, and substantially all are inorganic types, wherein have only calcium or have only potassium.By use potassium, though the calcium single fertilizer also can play certain effect, the specific absorption of potassium, calcium is not high, again the lost labor.
[summary of the invention]
The objective of the invention is at deficiency of the prior art, provide a kind of efficiently, cheap, the biological composite foliage fertilizer of potassium calcium that quality meets " composite microbiological fertilizer " agriculture standard (NY/T 798-2004).
One purpose more of the present invention is that the preparation method of the biological composite foliage fertilizer of a kind of potassium calcium is provided.
Another purpose of the present invention is that the application of the biological composite foliage fertilizer of a kind of potassium calcium is provided.
For achieving the above object, the technical scheme taked of the present invention is:
The biological composite foliage fertilizer of a kind of potassium calcium, the biological composite foliage fertilizer of described potassium calcium by weight percentage, this foliage fertilizer is composed of the following components:
Contain bacterium yeast organic raw material 20-40%
Saltpetre 24.5-39.5%
Calcium ammonium nitrate 35-45%
The azone surplus.
Be preferably, the described bacterium yeast organic raw material that contains comprises bacterium liquid and yeast organic raw material, and wherein the absorption ratio of bacterium liquid and yeast organic raw material is 1: 20-1: 40.
Be preferably, described bacterium liquid be subtilis liquid and bacillusmusilaginosiengineering liquid by 2: 1-3: 1 mixed forms.
For realizing above-mentioned second purpose, the technical scheme that the present invention takes is:
The preparation method of the biological composite foliage fertilizer of a kind of potassium calcium, this method may further comprise the steps:
A, the preparation of yeast organic raw material: will extract the later yeast fermentation broth waste liquid magma of yeast fermentation and concentrate, and obtain the yeast organic raw material through spray dry process then;
B, complex micro organism fungicide preparation: with subtilis and the independent fermentative production of bacillusmusilaginosiengineering, two bacterial classifications press 2 with two kinds of bacterium liquid after the fermentation: 1-3: 1 mixed respectively separately through slant culture, shaking table enlarged culturing, seeding tank fermentation and ferment tank; Adsorb with above-mentioned powder yeast organic raw material then;
C, in the above-mentioned yeast organic raw material that is adsorbed with strain fermentating liquid, add saltpetre, nitric acid ammonia calcium, azone (permeate agent) etc., after the mixing the biological composite foliage fertilizer of potassium calcium.
Preparation method of the present invention produces the potassium calcium biological compound foliage fertilizer that obtains, and the technical indicator of described product is as follows:
(1), living bacteria count 〉=2 * 10 7Individual/gram (2), N+P 2O 5+ K 2O 〉=25%
(3)、K 2O≥15% (4)、CaO≥10%
(5), organic 〉=15% (6), humic acid 〉=10%
For realizing above-mentioned the 3rd purpose, the technical scheme that the present invention takes is:
The biological composite foliage fertilizer of a kind of potassium calcium, the application of as fertilizer sources in the agricultural crops growth, described foliage fertilizer by weight percentage, this foliage fertilizer is composed of the following components:
Contain bacterium yeast organic raw material 20-40%
Saltpetre 24.5-39.5%
Calcium ammonium nitrate 35-45%
The azone surplus
Be preferably the application of the biological composite foliage fertilizer as fertilizer sources of described potassium calcium in agricultural crops potassium deficiency, calcium deficiency growth.
Know-why of the present invention is, beneficial microorganism can improve the micro-ecological environment of plant, and the regulation ecological balance can suppress the intrusion of pathogenic bacteria, has sterilizing disease-preventing, improves effects such as crop nutrition content supply.On the other hand, the yeast fermentation broth waste liquid that produces when producing yeast is through containing great number of organic matters, amino acid, humic acids, protein and multiple middle trace element in the organic raw material after the spraying drying, most of nutritive substance is the required nutrient of crop and microorganism growth in these materials, particularly small molecules organic matter wherein can directly be absorbed, utilize by crop, can replenish crop alimentary and promote that beneficial microorganism is bred fast in the fertilizer, have stimulating plant growth, enhancing body vigor and metabolic capacity, improve disease resistance and the anti-adversity ability of plant.Simultaneously, plant is replenished the potassium calcium constituent when lacking potassium, calcium constituent, has the plant of mutually promoting to each other absorption, and calcium helps keeping the integrity of cell quality, keeps the aperture and the permeability of film, can prevent intracellular K +Exosmose, help the absorption of potassium element.Witz test also proves Ca 2+Ion not only can promote K +Absorption, and can also reduce cationic exosmosing in the plant.
Compared with prior art, the present invention has following beneficial effect:
1, a kind of new starting material are provided for foliage fertilizer production: broken single traditional mode of producing potassium, calcium foliage fertilizer with inorganic raw material, for being that foliage fertilizer has been found a kind of new starting material with the composite microbiological fertilizer technological improvement, it has with low cost, turn waste into wealth, good water solubility, characteristics such as utilization ratio height, when reducing the foliage fertilizer production cost, quality product also is improved.
2, fertilizer efficiency improves: the biological composite foliage fertilizer of potassium calcium can efficiently replenish middle potassium, the calcium constituent of crop, fine growing of guaranteeing crop, and potassium calcium interacts, and absorbs soon, and plant recovery of nutrient improves.Simultaneously, include beneficial microbe colony, can improve the micro-ecological environment of plant, improve the crop nutrition content supply, and beneficial microorganism is attached to and forms dominant microflora on the plant, can suppress the intrusion of pathogenic bacteria.In addition, the yeast organic raw material strengthens the crop anti-adversity ability except can directly being participated in can also activating the crop cell tissue, improving the plant organ function the plant growth metabolism by plant absorbing.
3, nutrient is comprehensive: the breakthrough of the biological composite foliage fertilizer of potassium calcium is not only to supply with inorganic nutrients such as crop potassium, calcium, and provide effective viable bacteria, organic matter, amino acid, humic acids, protein and microbiotic etc., not only, also can play the effect of drought resisting, disease-resistant, short life, conditioning and sterilizing disease-preventing for crop provides more fully nutritive substance.
4, utilization of waste material: not only for the fermented liquid waste liquid that produces in the yeast production process provides a brand-new disposal of resources approach, and can obtain the higher foliage fertilizer product of added value, thereby reduce the treatment and disposal cost of fermented liquid waste liquid.
5, safety, environmental protection: the present invention has nontoxic, tasteless, and is safe and reliable, has no side effect, and utilization ratio height, fertilizer loss be few, agricultural-food, surrounding environment are not polluted, and has characteristics such as safety and environmental protection.Simultaneously, the present invention adopts scientific formula and vanguard technology to make with extra care and forms, and the crop blade face is increased, and chlorophyll content improves, photosynthesis strengthens; Well developed root system, sugar and dry-matter accumulation increase, and strengthen the drought resisting of crop, waterlogging-resistant and resistance against diseases etc.
[description of drawings]
Accompanying drawing 1 is a waste liquid output process flow sheet in the yeast production process.
Accompanying drawing 2 is yeast fermentation broth waste liquid drying process with atomizing schema of the present invention.
Accompanying drawing 3 is the biological composite foliage fertilizer production scheme of potassium calcium of the present invention.
[embodiment]
Below in conjunction with accompanying drawing embodiment provided by the invention is elaborated.
Embodiment 1
1, powder yeast organic raw material produces
Concentrate extracting the later fermented liquid waste liquid magma of yeast, waste liquid magma concentration is about 7%, makes concentration reach 50% after concentrating, and produces fineness greater than 80 orders through spray dry process then, and moisture is less than 3% tawny powder yeast organic raw material.(in the yeast production process waste liquid output process flow sheet can referring to Fig. 1).
The basic proterties of the powdery yeast organic raw material after the spraying drying sees Table 1. (yeast fermentation broth waste liquid drying process with atomizing flow process is seen Fig. 2).
The basic proterties of table 1 powdery yeast organic raw material
Figure B2009101959857D0000051
2, strain fermentation
Subtilis (Bacillus subtilis) and bacillusmusilaginosiengineering (Bacillus mucilaginosus) are utilized the independent fermentative production of fermentation equipment, two bacterial classifications are respectively separately through slant culture, shaking table enlarged culturing, seeding tank fermentation and ferment tank, with the mixed of two kinds of bacterium liquid, make the number of viable of zymocyte liquid reach 5,000,000,000/ml after the fermentation by 2: 1.
3, batching
(1), accurately takes by weighing yeast organic materials 300Kg in stirrer, according to bacterium liquid: the ratio of yeast powder=1: 30 (L/kg) adds the mixed fermentation liquid 10L of 5,000,000,000/ml of living bacteria count, fully stirs the back for containing the yeast organic matter of hundred million of number of viable 1.3-1.6/gram;
(2), in being 500 kilograms stirrer, capacity carries out accurate feed proportioning: the above-mentioned yeast organic raw material 30% that contains viable bacteria that makes, saltpetre 29.5%, calcium ammonium nitrate 40% according to the proportioning raw materials of table 2.(Fig. 3 is seen in the biological composite foliage fertilizer Production Flow Chart of potassium calcium).
The production formula of the biological composite foliage fertilizer of table 2 potassium calcium
Figure B2009101959857D0000052
Annotate: the content of each raw material is as follows:
1., contain bacterium yeast organic raw material: N 〉=4%, K 2O 〉=11%, organic 〉=60%, humic acid 〉=41, amino acid 〉=12%, living bacteria count 〉=1.3 hundred million/gram;
2., saltpetre: N 〉=13%, K 2O 〉=46%;
3., calcium ammonium nitrate: N 〉=15%, CaO 〉=25%;
Stirrer stirred 10-15 minute, allowed the material thorough mixing, was crushed to the 60-80 order after the mixing.
4, quality examination
The examination and test of products is carried out according to the method for the agriculture standard of Ministry of Agriculture's industry standard " composite microbiological fertilizer " (NY/T798-2004), and the basic proterties of the biological composite foliage fertilizer finished product of potassium calcium sees Table 3.
The detected result of the biological composite foliage fertilizer of table 3 potassium calcium
Figure B2009101959857D0000061
Embodiment 2
In the complex micro organism fungicide preparation, the blending ratio after subtilis (Bacillus subtilis) and bacillusmusilaginosiengineering (Bacillus mucilaginosus) fermentation is 3: 1, and the absorption ratio of bacterium liquid and yeast organic raw material is 1: 20.
The additional proportion of yeast organic raw material is 40%, saltpetre 24.5%, calcium ammonium nitrate 35%; Other are with embodiment 1.
Embodiment 3
In the complex micro organism fungicide preparation, the blending ratio after subtilis (Bacillus subtilis) and bacillusmusilaginosiengineering (Bacillus mucilaginosus) fermentation is 2: 1, and the absorption ratio of bacterium liquid and yeast organic raw material is 1: 40.
The additional proportion of yeast organic raw material is 20%, saltpetre 39.5%, calcium ammonium nitrate 45%.Other are with embodiment 1.
The test example
The pear tree field test effect
Test is handled:
A: spray compound bio potassium calcium foliage fertilizer (adopting the biological composite foliage fertilizer of potassium calcium of embodiment 1) by 1: 600 extent of dilution, hereinafter to be referred as handling A;
B: spray biological foliage fertilizer (adopt the pure bacterium yeast organic raw material foliage fertilizer that contains, other are with embodiment 1) by 1: 600 extent of dilution, hereinafter to be referred as treatments B;
C: spray saltpetre foliage fertilizer (adopt pure saltpetre foliage fertilizer, other are with embodiment 1) by 1: 600 extent of dilution, hereinafter to be referred as handling C;
D: spray calcium ammonium nitrate foliage fertilizer (adopt pure calcium ammonium nitrate foliage fertilizer, other are with example 1) by 1: 600 extent of dilution, hereinafter to be referred as handling D;
E: compare with clear water and to carry out foliage-spray, hereinafter to be referred as handling E.
Sub-district area 80m 2, establish 3 repetitions, district's group is arranged at random.All tests are handled base manure and press habits fertilization and handle, and manuring late is handled by test and carried out, and the foliage fertilizer time that sprays is spent back 20 days thanking for the first time, sprays once in later per 20 days, sprays altogether 4 times, and other management is identical with habits fertilization.Testing data is carried out variance analysis and test of significance thereof with SPSS13.0 software, and Excel adds up, analyzes.
(1) different treatment is to the influence of pears quality
Table 5 different treatment is to the influence of pears quality and storage tolerance
Figure B2009101959857D0000071
Annotate: numeral is the mean value of 3 mensuration in the table; Numeral same column right side lowercase is identical, does not have significant difference between the expression, indicates different lowercases and represents to reach 95% significant difference; Indicate different capitalizations and represent to reach 99% significant difference; Down together.
Data as can be seen from table 5, in the influence of different treatment to crop quality, each index of handling A, treatments B, processing C and processing D pears is better than each index of handling among the E, fruit soluble solid as pears has increased by 4.0%, 1.7%, 1.1% and 0.9% than handling E respectively, soluble sugar increases by 2.10%, 1.20%, 0.41% and 0.20%, and mashed loss rate improves 1.4%, 0.5%, 0.6% and 0.2%.Handling A can increase fruit soluble solid, hardness and vitamin contents preferably, strengthens the fruit storage tolerance then, and is better than the spraying effect of treatments B, C and D.ANOVA showed significant, the spraying effect of the biological composite foliage fertilizer of potassium calcium is significantly higher than the processing that compares with clear water, and with single with inorganic or singly also reached the significant difference level with the spraying effect of organic foliar fertilizer.Illustrate that the biological composite foliage fertilizer of potassium calcium is than single quality that can effectively improve pears with inorganic or list with organic foliar fertilizer.
(2) different treatment is to the influence of pears output
Table 6 different treatment is to the effect of increasing production of pears
Figure B2009101959857D0000072
Different treatment can get single plant yield and the single fruit weight measurement result (table 6) of pear tree, and the pear tree single plant yield that the biological composite foliage fertilizer of potassium calcium sprays is higher than other, and each is handled, and effect of increasing production reaches utmost point conspicuous level.Simultaneously, the single fruit weight of handling A also is higher than treatments B, handles C and handles D, is higher than more greatly and handles E, and ANOVA showed significant reaches significant difference between them, and the single fruit weight of handling A is significantly higher than treatments B, handles C and handles D.
From above test-results as can be seen: when the biological composite foliage fertilizer of potassium calcium can obviously increase crop yield, the effect that can play utilization of waste material, reduces the wasting of resources, protects environment, reduces fertilizer amount, improves quality of agricultural product.
The above only is a preferred implementation of the present invention; should be pointed out that for those skilled in the art, under the prerequisite that does not break away from the inventive method; can also make some improvement and replenish, these improvement and replenish and also should be considered as protection scope of the present invention.

Claims (6)

1. the biological composite foliage fertilizer of a potassium calcium, the application of as fertilizer sources in the agricultural crops growth, described foliage fertilizer by weight percentage, this foliage fertilizer is composed of the following components:
Contain bacterium yeast organic raw material 20-40%
Saltpetre 24.5-39.5%
Calcium ammonium nitrate 35-45%
The azone surplus.
2. application according to claim 1 is characterized in that, the application of the biological composite foliage fertilizer as fertilizer sources of described potassium calcium in agricultural crops potassium deficiency, calcium deficiency growth.
3. the biological composite foliage fertilizer of a potassium calcium is characterized in that, the biological composite foliage fertilizer of described potassium calcium by weight percentage, this foliage fertilizer is composed of the following components:
Contain bacterium yeast organic raw material 20-40%
Saltpetre 24.5-39.5%
Calcium ammonium nitrate 35-45%
The azone surplus.
4. the biological composite foliage fertilizer of potassium calcium according to claim 3 is characterized in that the described bacterium yeast organic raw material that contains comprises bacterium liquid and yeast organic raw material, and wherein the absorption ratio of bacterium liquid and yeast organic raw material is 1: 20-1: 40.
5. the biological composite foliage fertilizer of potassium calcium according to claim 3 is characterized in that, described bacterium liquid be subtilis liquid and bacillusmusilaginosiengineering liquid by 2: 1-3: 1 mixed forms.
6. the preparation method of the biological composite foliage fertilizer of the arbitrary described potassium calcium of claim 3-5 is characterized in that this method may further comprise the steps:
A, the preparation of yeast organic raw material: will extract the later yeast fermentation broth waste liquid magma of yeast fermentation and concentrate, and obtain the yeast organic raw material through spray dry process then;
B, complex micro organism fungicide preparation: with subtilis and the independent fermentative production of bacillusmusilaginosiengineering, two bacterial classifications press 2 with two kinds of bacterium liquid after the fermentation: 1-3: 1 mixed respectively separately through slant culture, shaking table enlarged culturing, seeding tank fermentation and ferment tank; Adsorb with above-mentioned powder yeast organic raw material then;
C, in the above-mentioned yeast organic raw material that is adsorbed with strain fermentating liquid, add saltpetre, nitric acid ammonia calcium, azone (permeate agent) etc., after the mixing the biological composite foliage fertilizer of potassium calcium.
CN2009101959857A 2009-09-21 2009-09-21 Potassium-calcium biological composite foliar fertilizer and preparation method and application thereof Expired - Fee Related CN101935241B (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103710281A (en) * 2013-11-12 2014-04-09 青岛明月蓝海生物科技有限公司 Bacillus mucilaginosus strain and application thereof in seaweed biofertilizer
CN105175049A (en) * 2015-07-13 2015-12-23 青岛苏贝尔作物营养有限公司 Leaf fertilizer containing calcium ammonium nitrate, and preparation method thereof
CN106242864A (en) * 2016-08-31 2016-12-21 广德明凯蔬果种植家庭农场 A kind of composite foliage fertilizer material
CN106431629A (en) * 2016-08-31 2017-02-22 广德明凯蔬果种植家庭农场 Adjusting foliar fertilizer
CN107935747A (en) * 2017-11-30 2018-04-20 孙铭岐 A kind of high-efficiency compound foliar fertilizer
CN111732471A (en) * 2020-04-17 2020-10-02 广西宇花灵科技发展有限公司 Foliar fertilizer with function of improving crop resistance and preparation method thereof

Family Cites Families (3)

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CN1197780A (en) * 1998-04-03 1998-11-04 北京宝贝科技开发有限责任公司 Complete nutritive special fertilizer
CN1083816C (en) * 1999-01-16 2002-05-01 邬纯忠 Vigourous liquid fertilizer for plant
CN101318857A (en) * 2007-06-07 2008-12-10 华丰源生物科技(深圳)有限公司 Liquid fertilizer special for alkali soil

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103710281A (en) * 2013-11-12 2014-04-09 青岛明月蓝海生物科技有限公司 Bacillus mucilaginosus strain and application thereof in seaweed biofertilizer
CN103710281B (en) * 2013-11-12 2015-11-04 青岛明月蓝海生物科技有限公司 Bacillus mucilaginosus strain and application thereof in seaweed biofertilizer
CN105175049A (en) * 2015-07-13 2015-12-23 青岛苏贝尔作物营养有限公司 Leaf fertilizer containing calcium ammonium nitrate, and preparation method thereof
CN105175049B (en) * 2015-07-13 2019-02-19 青岛阿道姆农业科技有限公司 Foliar fertilizer and preparation method thereof containing calcium ammonium nitrate
CN106242864A (en) * 2016-08-31 2016-12-21 广德明凯蔬果种植家庭农场 A kind of composite foliage fertilizer material
CN106431629A (en) * 2016-08-31 2017-02-22 广德明凯蔬果种植家庭农场 Adjusting foliar fertilizer
CN107935747A (en) * 2017-11-30 2018-04-20 孙铭岐 A kind of high-efficiency compound foliar fertilizer
CN111732471A (en) * 2020-04-17 2020-10-02 广西宇花灵科技发展有限公司 Foliar fertilizer with function of improving crop resistance and preparation method thereof

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