CN101884608B - Mosquito repelling composition - Google Patents
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- CN101884608B CN101884608B CN2010102229337A CN201010222933A CN101884608B CN 101884608 B CN101884608 B CN 101884608B CN 2010102229337 A CN2010102229337 A CN 2010102229337A CN 201010222933 A CN201010222933 A CN 201010222933A CN 101884608 B CN101884608 B CN 101884608B
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Abstract
The invention provides a mosquito repelling composition which is prepared from grape seed extract, honeysuckle extract, wild chrysanthemum extract, licorice extract, wrinkled gianthyssop extract, atractylodes rhizome extract, clove extract, radix scutellariae extract and black tea extract. The invention also particularly provides toilet water containing the mosquito repelling composition. The mosquito repelling composition of the invention has the effects of repelling mosquitoes, sterilizing bacteria, preventing prickly heat, relieving itching and the like.
Description
Technical field
The invention relates to a kind of mosquito repellent composition, particularly about a kind of compositions that has anophelifuge, sterilization, anti-miliaria, effect such as antipruritic concurrently that is applied to cosmetics, and the cosmetics that comprise said composition floral water etc. for example.
Background technology
The broad definition of cosmetics is meant to smear, to spray or other similar approach, impose on human body surface (as epidermis, hair, fingernail, lip etc.), play clearly the product of buying, maintain, beautifying or eliminate the bad smell effect, this series products can have abirritation to using the position.In the cosmetics category, the product with repelling effect comprises some facial treatment milk, floral water etc.
Mainly be repellant for example diethyltoluamide (DEET), mosquitofugal oil (DMP) or the citronellal etc. that added chemosynthesis in traditional cosmetics, spread upon on the skin, form protecting film, make the mosquito dare not be close with repelling effect.The advantage of the repellant of this interpolation chemical constituent mainly is to use when being fit to go out outing or stroll, is the good recipe that realizes self-protection among a small circle; Yet the repellant of this interpolation chemical constituent may cause skin allergy.
Along with advocating of cosmetics bound pair natural plant product, also have in recent years plant extract as the research report of human body with mosquito-repellent, for example, utilize lemon scented gum extract, citronella oil, Oleum Pelargonii Graveolentis, Essential lavender oil, oil of rosemary, Oleum Caryophylli, Juniperus oxycedrus wet goods.But correlational study shows that utilizing these plant extracts merely is not very desirable as the mosquito-repellent effect, in actual product often is still to be added with a certain amount of synthetic repellant such as DMP etc. when adding plant extract.
In addition, existing cosmetics with repelling effect only have the single effect of the anophelifuge of being declared usually, do not have sterilization, anti-miliaria, function such as antipruritic.
Summary of the invention
One object of the present invention is to provide a kind of mosquito repellent composition, said composition is made up of the extract of various natural plants, can directly act on human body or be used to produce cosmetics and act on human body, reach the effect of mosquito repellent, and described compositions has sterilization, anti-miliaria, effect such as antipruritic concurrently.
Another object of the present invention is to provide a kind of cosmetics that comprise described mosquito repellent composition, particularly a kind of floral water, this floral water have sterilization, anti-miliaria, itching-relieving efficacies concurrently when having good repelling effect.
At first, the invention provides a kind of mosquito repellent composition, said composition is made up of Semen Vitis viniferae extract, Flos Lonicerae extract, Flos Chrysanthemi Indici extract, Radix Glycyrrhizae extract, Herba Pogostemonis extract, Rhizoma Atractylodis extract, Flos Caryophylli extract, Radix Scutellariae extract and black tea extract.
Among the present invention, the all commercially available acquisition of described Semen Vitis viniferae extract, Flos Lonicerae extract, Flos Chrysanthemi Indici extract, Radix Glycyrrhizae extract, Herba Pogostemonis extract, Rhizoma Atractylodis extract, Flos Caryophylli extract, Radix Scutellariae extract and black tea extract, also can prepare voluntarily according to the record of prior art, each extract should meet the correlated quality standard-required.
Among the present invention, studied the different characteristics character of Semen Vitis viniferae, Flos Lonicerae, Flos Chrysanthemi Indici, Radix Glycyrrhizae, Herba Pogostemonis, Rhizoma Atractylodis, Flos Caryophylli, Radix Scutellariae and black tea nine kind of plant, obtained a kind of mosquito repellent composition with the extract of this nine kind of plant is composite, can directly act on human body or be used to produce cosmetics and act on human body, do not need to add chemosynthesis repellant for example diethyltoluamide, mosquitofugal oil or citronellal etc., can reach the effect of mosquito repellent, and described compositions has sterilization, anti-miliaria, effect such as antipruritic concurrently.
According to specific embodiments of the present invention, described Semen Vitis viniferae extract, Flos Lonicerae extract, Flos Chrysanthemi Indici extract, Radix Glycyrrhizae extract, Herba Pogostemonis extract, Rhizoma Atractylodis extract, Flos Caryophylli extract, Radix Scutellariae extract and black tea extract are respectively the extracts from Semen Vitis viniferae, Flos Lonicerae, Flos Chrysanthemi Indici, Radix Glycyrrhizae, Herba Pogostemonis, Rhizoma Atractylodis, Flos Caryophylli, Radix Scutellariae and black tea, can be respectively these plants to be extracted then extract is mixed; Also can be to extract again after earlier each kind of plant being mixed in proportion; Perhaps in these plants one or more are mixed, again all extract mixtures are lumped together after the extraction.
According to specific embodiments of the present invention, described Semen Vitis viniferae extract is business-like commodity raw material, from the extract of the seed of vitaceae Fructus Vitis viniferae (Vitis vinifera L.), rufous powder, feeble QI, puckery.Semen Vitis viniferae extract has the natural function composition of extremely strong non-oxidizability, as the raw material of health food directly makes dosage forms such as capsule usually, or extensively joined in various bread and cheeses such as beverage and wine, cake, the cheese.
According to specific embodiments of the present invention, be with Flos Lonicerae, Flos Chrysanthemi Indici, Radix Glycyrrhizae, Herba Pogostemonis, Rhizoma Atractylodis, Flos Caryophylli, plant material such as Radix Scutellariae and black tea is according to Flos Lonicerae 0.4～0.6 weight portion, Flos Chrysanthemi Indici 0.9～1.1 weight portion, Radix Glycyrrhizae 0.4～0.6 weight portion, Herba Pogostemonis 0.1～0.3 weight portion, Rhizoma Atractylodis 0.05～0.15 weight portion, Flos Caryophylli 0.02～0.08 weight portion, Radix Scutellariae 0.05～0.15 weight portion, the mixed of black tea 0.03～0.08 weight portion (with the dry weight basis of these Chinese medicinal plant), with water or alcohol leaching rule such as water or ethanol lixiviate, prepare water or the ethanol extract of these plants, and then the extracting solution that extraction obtains mixed with the Semen Vitis viniferae extract of 0.1～0.5 weight portion, obtain mosquito repellent composition of the present invention.Specifically, wherein, described water or alcoholic acid extraction temperature are preferably 18 ℃～35 ℃, extraction time was preferably more than 48 hours (does not have specific (special) requirements to the extraction time upper limit among the present invention, produce as not being badly in need of, extraction time can reach about half a year, and described lixiviating solution can't be putrid and deteriorated).
According to preferred specific embodiments of the present invention, mosquito repellent composition of the present invention prepares in accordance with the following methods:
With Flos Lonicerae, Flos Chrysanthemi Indici, Radix Glycyrrhizae, Herba Pogostemonis, Rhizoma Atractylodis, Flos Caryophylli, plant material such as Radix Scutellariae and black tea is according to Flos Lonicerae 0.4～0.6 weight portion, Flos Chrysanthemi Indici 0.9～1.1 weight portion, Radix Glycyrrhizae 0.4～0.6 weight portion, Herba Pogostemonis 0.1～0.3 weight portion, Rhizoma Atractylodis 0.05～0.15 weight portion, Flos Caryophylli 0.02～0.08 weight portion, Radix Scutellariae 0.05～0.15 weight portion, the mixed of black tea 0.03～0.07 weight portion (with the dry weight basis of these Chinese medicinal plant), can suitably pulverize, be dipped in the water or ethanol of 20～40 times of weight (preferably adopting the ethanol lixiviate among the present invention), soak at room temperature is more than 72 hours, with the medicinal residues filtering, obtain mixing Chinese medicine extraction liquid;
With above-mentioned mixing Chinese medicine extraction liquid 70～80 weight portions, mix with the Semen Vitis viniferae extract of 0.1～0.5 weight portion, obtain mosquito repellent composition of the present invention.
Among the present invention, can after making described mixing Chinese medicine extraction liquid, suitably replenish the water or the ethanol that lose in the immersion process as required.
In of the present invention one preferred specific embodiments, prepare in the raw material of mosquito repellent composition of the present invention, the weight ratio of described Flos Lonicerae, Flos Chrysanthemi Indici, Radix Glycyrrhizae, Herba Pogostemonis, Rhizoma Atractylodis, Flos Caryophylli, Radix Scutellariae and black tea is: Flos Lonicerae 0.5 weight portion, Flos Chrysanthemi Indici 1 weight portion, Radix Glycyrrhizae 0.5 weight portion, Herba Pogostemonis 0.2 weight portion, Rhizoma Atractylodis 0.1 weight portion, Flos Caryophylli 0.05 weight portion, Radix Scutellariae 0.1 weight portion, black tea 0.05 weight portion.
Mosquito repellent composition of the present invention is that utilization natural anophelifuge composition is driven away mosquito, to human body safety, is limpid amber, and fragrant, and abnormal smells from the patient is easy to accept, and does not have the offensive odour of conventional Chinese medicine extract.Mosquito repellent composition of the present invention has anophelifuge, sterilization, anti-miliaria, effect such as antipruritic concurrently, can directly use, and is applied in skin surface, also can be further used for preparing cosmetics, for example is prepared into floral water or body lotion etc., also can be used as after shave lotion and uses.
On the other hand, the present invention also provides the preparation method of described mosquito repellent composition, this method comprises: with Flos Lonicerae, Flos Chrysanthemi Indici, Radix Glycyrrhizae, Herba Pogostemonis, Rhizoma Atractylodis, Flos Caryophylli, Radix Scutellariae and black tea plant material according to described mixed, water or ethanol lixiviate, the mixing Chinese medicine extraction liquid that again extraction is obtained mixes with Semen Vitis viniferae extract, obtains described mosquito repellent composition.
On the other hand, the present invention also provides described mosquito repellent composition as the application in the cosmetics with anophelifuge, sterilization, anti-miliaria and/or antipruritic effect.
On the other hand, the present invention also provides a kind of cosmetics, wherein contains mosquito repellent composition of the present invention.Described cosmetics can be floral water for example, or are used for the after shave lotion of daily cosmetology usefulness.
According to specific embodiments of the present invention, described cosmetics are a kind of floral water, wherein except that containing mosquito repellent composition of the present invention, can also further contain adding ingredient conventional in the floral water, for example Mentholum, essence, deionized water etc.According to preferred specific embodiments of the present invention, comprise in the floral water of the present invention:
Mosquito repellent composition of the present invention, the amount of Semen Vitis viniferae extract wherein are 0.1%～0.5% of floral water gross weight:
Mentholum 0.1%～0.3%;
Essence 0.8%～1.2%;
The deionized water surplus.
In sum, the invention provides a kind of abnormal smells from the patient fragrance, have anophelifuge concurrently, the mosquito repellent composition of sterilization, anti-miliaria, effect such as antipruritic, and the floral water that utilizes said composition to prepare, mosquito repellent composition of the present invention and floral water have good repelling effect, bactericidal property is good, utilize the anti-miliaria antipruritic effect of compositions of the present invention remarkable, and use the skin sense good, make us being easy to accepting.
The specific embodiment
Below describe the beneficial effect of implementation process of the present invention and generation in detail by specific embodiment, be intended to help the reader to understand essence of the present invention and characteristics better, but not as qualification to this case practical range.
In following scheme description of the present invention and the prescription, used described Semen Vitis viniferae extract is for being purchased product, be extract from the seed of vitaceae Fructus Vitis viniferae (Vitis vinifera L.), the rufous powder, there is not the foreign odor flavor, absworption peak 280nm, 256nm, total number of bacteria≤1000/g, procyanidin content 〉=96%.
Embodiment 1
Chinese herbal medicine Flos Lonicerae, Flos Chrysanthemi Indici, Radix Glycyrrhizae, Herba Pogostemonis, Rhizoma Atractylodis, Flos Caryophylli, Radix Scutellariae and the black tea mixed according to Flos Lonicerae 0.5 weight portion, Flos Chrysanthemi Indici 1 weight portion, Radix Glycyrrhizae 0.5 weight portion, Herba Pogostemonis 0.2 weight portion, Rhizoma Atractylodis 0.1 weight portion, Flos Caryophylli 0.05 weight portion, Radix Scutellariae 0.1 weight portion, black tea 0.05 weight portion will be purchased, utilize pulverizer to grind, be dipped in then in the ethanol of 30 times of weight, room temperature (18 ℃～25 ℃) soaked 72 hours, with the medicinal residues filtering, obtain mixing Chinese medicine extraction liquid;
Get mixing Chinese medicine extraction liquid 75 weight portions that extract according to the method described above, mix, obtain the mosquito repellent composition of present embodiment with the Semen Vitis viniferae extract of 0.3 weight portion.
In above-mentioned mosquito repellent composition of the present invention, further add the Mentholum of 0.2 weight portion, the essence of 1 weight portion replenishes deionized water to 100 weight portion then, obtains the floral water of present embodiment, and called after Chinese grass reveals.
Embodiment 2
Chinese herbal medicine Flos Lonicerae, Flos Chrysanthemi Indici, Radix Glycyrrhizae, Herba Pogostemonis, Rhizoma Atractylodis, Flos Caryophylli, Radix Scutellariae and the black tea mixed according to Flos Lonicerae 0.55 weight portion, Flos Chrysanthemi Indici 0.9 weight portion, Radix Glycyrrhizae 0.4 weight portion, Herba Pogostemonis 0.2 weight portion, Rhizoma Atractylodis 0.08 weight portion, Flos Caryophylli 0.04 weight portion, Radix Scutellariae 0.08 weight portion, black tea 0.04 weight portion will be purchased, utilize pulverizer to grind, be dipped in then in the ethanol of about 33 times of weight, room temperature (18 ℃～25 ℃) soaked about 78 hours, with the medicinal residues filtering, obtain mixing Chinese medicine extraction liquid;
Get mixing Chinese medicine extraction liquid 75 weight portions that extract according to the method described above, mix, obtain the mosquito repellent composition of present embodiment with the Semen Vitis viniferae extract of 0.25 weight portion.
In above-mentioned mosquito repellent composition of the present invention, further add the Mentholum of 0.15 weight portion, the essence of 1 weight portion replenishes deionized water to 100 weight portion then, obtains the floral water of present embodiment.
Embodiment 3
Chinese herbal medicine Flos Lonicerae, Flos Chrysanthemi Indici, Radix Glycyrrhizae, Herba Pogostemonis, Rhizoma Atractylodis, Flos Caryophylli, Radix Scutellariae and the black tea mixed according to Flos Lonicerae 0.45 weight portion, Flos Chrysanthemi Indici 1.1 weight portions, Radix Glycyrrhizae 0.6 weight portion, Herba Pogostemonis 0.15 weight portion, Rhizoma Atractylodis 0.13 weight portion, Flos Caryophylli 0.06 weight portion, Radix Scutellariae 0.12 weight portion, black tea 0.06 weight portion will be purchased, utilize pulverizer to grind, be dipped in then in the water of about 30 times of weight, room temperature (18 ℃～25 ℃) soaked about 78 hours, with the medicinal residues filtering, obtain mixing Chinese medicine extraction liquid;
Get mixing Chinese medicine extraction liquid 80 weight portions that extract according to the method described above, mix, obtain the mosquito repellent composition of present embodiment with the Semen Vitis viniferae extract of 0.4 weight portion.
In above-mentioned mosquito repellent composition of the present invention, further add the Mentholum of 0.2 weight portion, the essence of 1 weight portion replenishes deionized water to 100 weight portion then, obtains the floral water of present embodiment.
After testing, the floral water of the embodiment of the invention 1,2,3, abnormal smells from the patient fragrance is pleasant, reach heat-resisting repeatedly (40 ± 1 ℃ through long-term shelf storage test (following 3 years of room temperature), recovered not muddy after the room temperatures in 24 hours), cold-resistant (15 ± 1 ℃, recovered room temperatures in 24 hours after, system is normal, no turbid phenomenon) destructive testing, the every sense index of product, physical and chemical index, sanitary index all meet corresponding national standards.
The result of use experiment:
Among the present invention, carried out bactericidal effect test experiments, repelling effect test experiments and anti-miliaria antipruritic effect test experiments with the floral water of embodiment 1,2,3, specifically experiment and test result are as follows:
1) bactericidal assay: detect according to GB15979-2002 " disposable use hygienic article sanitary standard ", experimental result is as shown in the table:
Result from above form as can be known, floral water bactericidal property of the present invention is good.
2) anophelifuge test: carry out according to GB/T17322.10-1998.The experimenter is 45 people, is divided into three groups, and every group 15 people tests the floral water of the embodiment of the invention 1,2,3 respectively.Everyone is blank on the other hand, and another hands is by 1.5 μ l/cm
2Dosage evenly smear 5cm * 5cm the back of the hand zone, expose wherein 4cm * 4cm position, remainder tightly covers.Spread product 2 hours begins to test.Experimental result shows that the floral water of the embodiment of the invention 1,2,3 is to all compound B level of Aedes albopictus repellent effect.
3) the anti-antipruritic test of miliaria: select 450 volunteers to participate in free trial activity in summer, be divided into three carefully, every group 150 people tests the floral water of the embodiment of the invention 1,2,3 respectively.The using method of floral water of the present invention: (1) splashes in the bathtub in right amount with this product, stirs evenly the back bathing and gets final product; (2) adopt spray bottle directly to spray and the skin desired area behind the mosquito bite.Test after 60 days, to the evaluation result of result of use record as following table:
As can be seen from the above table, consumer prevents miliaria itching relieving situation to using floral water of the present invention, and satisfaction rate can reach more than 90%, and effect is remarkable.And in using, consumer reflects that generally floral water of the present invention is easy to use, health, and the skin sense is better, and abnormal smells from the patient fragrance makes us taking like a shot.
Claims (9)
1. mosquito repellent composition, said composition is made up of Semen Vitis viniferae extract, Flos Lonicerae extract, Flos Chrysanthemi Indici extract, Radix Glycyrrhizae extract, Herba Pogostemonis extract, Rhizoma Atractylodis extract, Flos Caryophylli extract, Radix Scutellariae extract and black tea extract; It prepares in accordance with the following methods:
With Flos Lonicerae, Flos Chrysanthemi Indici, Radix Glycyrrhizae, Herba Pogostemonis, Rhizoma Atractylodis, Flos Caryophylli, Radix Scutellariae and black tea plant material mixed according to Flos Lonicerae 0.4～0.6 weight portion, Flos Chrysanthemi Indici 0.9～1.1 weight portion, Radix Glycyrrhizae 0.4～0.6 weight portion, Herba Pogostemonis 0.1～0.3 weight portion, Rhizoma Atractylodis 0.05～0.15 weight portion, Flos Caryophylli 0.02～0.08 weight portion, Radix Scutellariae 0.05～0.15 weight portion, black tea 0.03～0.08 weight portion, water or ethanol lixiviate, and the mixing Chinese medicine extraction liquid that extraction obtains mixed with the Semen Vitis viniferae extract of 0.1～0.5 weight portion, obtain described mosquito repellent composition.
2. mosquito repellent composition according to claim 1, wherein, described water or alcoholic acid extraction temperature are 18 ℃～35 ℃, extraction time is more than 48 hours.
3. mosquito repellent composition according to claim 1, it prepares in accordance with the following methods:
With Flos Lonicerae, Flos Chrysanthemi Indici, Radix Glycyrrhizae, Herba Pogostemonis, Rhizoma Atractylodis, Flos Caryophylli, Radix Scutellariae and black tea plant material mixed according to Flos Lonicerae 0.4～0.6 weight portion, Flos Chrysanthemi Indici 0.9～1.1 weight portion, Radix Glycyrrhizae 0.4～0.6 weight portion, Herba Pogostemonis 0.1～0.3 weight portion, Rhizoma Atractylodis 0.05～0.15 weight portion, Flos Caryophylli 0.02～0.08 weight portion, Radix Scutellariae 0.05～0.15 weight portion, black tea 0.03～0.08 weight portion, be dipped in the water or ethanol of 20～40 times of weight, soak at room temperature is more than 72 hours, with the medicinal residues filtering, obtain mixing Chinese medicine extraction liquid;
With above-mentioned mixing Chinese medicine extraction liquid 70～80 weight portions, mix with the Semen Vitis viniferae extract of 0.1～0.5 weight portion, obtain described mosquito repellent composition.
4. according to claim 1 or 3 described mosquito repellent compositions, wherein, the weight ratio of described Flos Lonicerae, Flos Chrysanthemi Indici, Radix Glycyrrhizae, Herba Pogostemonis, Rhizoma Atractylodis, Flos Caryophylli, Radix Scutellariae and black tea is: Flos Lonicerae 0.5 weight portion, Flos Chrysanthemi Indici 1 weight portion, Radix Glycyrrhizae 0.5 weight portion, Herba Pogostemonis 0.2 weight portion, Rhizoma Atractylodis 0.1 weight portion, Flos Caryophylli 0.05 weight portion, Radix Scutellariae 0.1 weight portion, black tea 0.05 weight portion.
5. the preparation method of each described mosquito repellent composition of claim 1～4, this method comprises:
Flos Lonicerae, Flos Chrysanthemi Indici, Radix Glycyrrhizae, Herba Pogostemonis, Rhizoma Atractylodis, Flos Caryophylli, Radix Scutellariae and black tea plant material are mixed, water or ethanol lixiviate, the mixing Chinese medicine extraction liquid that again extraction is obtained mixes with Semen Vitis viniferae extract, obtains described mosquito repellent composition.
6. each described mosquito repellent composition of claim 1～4 is as the application in the cosmetics with anophelifuge, sterilization, anti-miliaria and/or antipruritic effect.
7. cosmetics wherein contain each described mosquito repellent composition of claim 1～4.
8. cosmetics according to claim 7, it is floral water or after shave lotion.
9. cosmetics according to claim 8, comprising:
Each described mosquito repellent composition of claim 1～4, the amount of Semen Vitis viniferae extract wherein is 0.1%～0.5% of a floral water gross weight;
Mentholum 0.1%～0.3%;
Essence 0.8%～1.2%;
The deionized water surplus.
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| CN2010102229337A CN101884608B (en) | 2010-07-09 | 2010-07-09 | Mosquito repelling composition |
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| CN2010102229337A CN101884608B (en) | 2010-07-09 | 2010-07-09 | Mosquito repelling composition |
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| CN101884608B true CN101884608B (en) | 2011-12-21 |
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Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103655245B (en) * | 2012-08-31 | 2015-03-11 | 郭心仪 | Mosquito repelling flora water |
| CN102846517B (en) * | 2012-09-26 | 2013-09-11 | 王强 | Traditional Chinese medicine composition capable of removing miliaria and relieving itching as well as cosmetic containing traditional Chinese medicine composition |
| CN103520005B (en) * | 2013-10-17 | 2015-09-02 | 天津郁美净集团有限公司 | A kind of mosquito repellent composition microcapsule and preparation method thereof and application |
| CN103735485A (en) * | 2014-01-15 | 2014-04-23 | 张一文 | Mosquito-repellent floral water and preparation method thereof |
| CN103735468B (en) * | 2014-01-22 | 2015-10-14 | 天津郁美净集团有限公司 | A kind of cosmetics containing mosquito repellent composition microcapsule |
| CN105310911A (en) * | 2014-06-20 | 2016-02-10 | 徐萍 | Children anti-mosquito and skin-protective oil |
| CN104146014A (en) * | 2014-07-18 | 2014-11-19 | 李克锋 | Preparation method for mosquito-expelling traditional Chinese medicine sachet |
| CN105232415A (en) * | 2015-11-23 | 2016-01-13 | 梁秀萍 | Geranium essential oil floral water and preparation method thereof |
| CN105232416A (en) * | 2015-11-23 | 2016-01-13 | 梁秀萍 | Rose essential oil floral water and preparation method thereof |
| CN107136133B (en) * | 2017-04-25 | 2019-02-19 | 黄山力神日用品有限公司 | A kind of preparation method of aqua type plant electric mosquito repellent liquid |
| CN108272696A (en) * | 2018-04-15 | 2018-07-13 | 啵噜噜（广州）婴儿用品科技有限公司 | A kind of external preparation with mosquito-expelling and antipruritic |
| CN108721478A (en) * | 2018-09-11 | 2018-11-02 | 广州旭升化工科技有限公司 | A kind of plant multi-effect compound agent of mosquito-proof sting |
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| CN1126586A (en) * | 1993-11-19 | 1996-07-17 | 姜少华 | Mosquito repelling bath lotion of natural plant material |
| CN1165012A (en) * | 1997-01-21 | 1997-11-19 | 石小雷 | Instant stop itching spray agent for mosquito and insect bite and its preparation method |
| CN1310634C (en) * | 2005-03-16 | 2007-04-18 | 周娉 | Perfume extracted from Chinese medicine and its preparing method |
| CN101695469A (en) * | 2009-10-26 | 2010-04-21 | 张发明 | Mosquito dispelling liquid |
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