CN101829589B - 用于制备甲基丙烯酸的催化剂及其制备方法 - Google Patents

用于制备甲基丙烯酸的催化剂及其制备方法 Download PDF

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Publication number
CN101829589B
CN101829589B CN201010143947XA CN201010143947A CN101829589B CN 101829589 B CN101829589 B CN 101829589B CN 201010143947X A CN201010143947X A CN 201010143947XA CN 201010143947 A CN201010143947 A CN 201010143947A CN 101829589 B CN101829589 B CN 101829589B
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CN
China
Prior art keywords
catalyst
antimony
slurry
methacrolein
methacrylic acid
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Expired - Fee Related
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CN201010143947XA
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English (en)
Chinese (zh)
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CN101829589A (zh
Inventor
須藤渥
倉上竜彦
小島利丈
林本成生
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Nippon Kayaku Co Ltd
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Nippon Kayaku Co Ltd
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/0221—Coating of particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/24—Nitrogen compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
    • B01J27/198—Vanadium
    • B01J27/199—Vanadium with chromium, molybdenum, tungsten or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/0219—Coating the coating containing organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B61/00—Other general methods
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
    • C07C51/235—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of —CHO groups or primary alcohol groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
    • C07C57/02—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
    • C07C57/03—Monocarboxylic acids
    • C07C57/04—Acrylic acid; Methacrylic acid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/51—Spheres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027—Powdering
    • B01J37/0045—Drying a slurry, e.g. spray drying

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN201010143947XA 2005-03-29 2006-03-28 用于制备甲基丙烯酸的催化剂及其制备方法 Expired - Fee Related CN101829589B (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2005-094734 2005-03-29
JP2005094734A JP4756890B2 (ja) 2005-03-29 2005-03-29 メタクリル酸製造用触媒及びその製造方法

Related Parent Applications (1)

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CN101829589A CN101829589A (zh) 2010-09-15
CN101829589B true CN101829589B (zh) 2013-08-21

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CN2006800093175A Expired - Fee Related CN101175568B (zh) 2005-03-29 2006-03-28 用于制备甲基丙烯酸的催化剂及其制备方法

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Country Link
US (1) US8716523B2 (cg-RX-API-DMAC7.html)
EP (2) EP1867387B1 (cg-RX-API-DMAC7.html)
JP (1) JP4756890B2 (cg-RX-API-DMAC7.html)
KR (2) KR101223590B1 (cg-RX-API-DMAC7.html)
CN (2) CN101829589B (cg-RX-API-DMAC7.html)
BR (1) BRPI0608759A2 (cg-RX-API-DMAC7.html)
CA (1) CA2603005A1 (cg-RX-API-DMAC7.html)
MY (1) MY143359A (cg-RX-API-DMAC7.html)
TW (1) TW200642757A (cg-RX-API-DMAC7.html)
WO (1) WO2006104155A1 (cg-RX-API-DMAC7.html)

Families Citing this family (14)

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JP2006314923A (ja) * 2005-05-12 2006-11-24 Nippon Kayaku Co Ltd メタクリル酸製造用触媒の製造方法
US8178718B2 (en) * 2007-02-05 2012-05-15 Saudi Basic Industries Corporation Catalyst for oxidation of saturated and unsaturated aldehydes to unsaturated carboxylic acid, method of making and method of using thereof
CN102203040B (zh) * 2008-11-06 2014-04-16 日本化药株式会社 甲基丙烯酸的制造方法及甲基丙烯酸制造用催化剂
JP5261231B2 (ja) * 2009-03-04 2013-08-14 三菱レイヨン株式会社 不飽和カルボン酸合成用触媒の製造方法
JP5570142B2 (ja) * 2009-05-26 2014-08-13 日本化薬株式会社 メタクリル酸製造触媒の製造方法およびメタクリル酸の製造方法
JP5387297B2 (ja) * 2009-09-30 2014-01-15 住友化学株式会社 複合酸化物触媒の製造方法
CN105665020B (zh) * 2009-11-30 2019-09-06 日本化药株式会社 异丁烯酸制造催化剂的制造方法及异丁烯酸的制造方法
JP2012110806A (ja) * 2010-11-22 2012-06-14 Nippon Kayaku Co Ltd メタクリル酸製造触媒の製造方法およびメタクリル酸の製造方法
US20140316160A1 (en) * 2011-11-17 2014-10-23 Nipponkayaku Kabushikikaisha Catalyst For Methacrylic Acid Production And Process For Producing Methacrylic Acid
JP6077533B2 (ja) * 2012-05-18 2017-02-08 日本化薬株式会社 メタクリル酸製造用触媒、その製造方法及び該触媒を用いるメタクリル酸の製造方法
EP3056482B1 (en) 2013-10-10 2020-06-17 Nippon Kayaku Kabushiki Kaisha Method for producing a supported catalyst
CN106140239A (zh) * 2015-04-23 2016-11-23 北京化工大学 一种用于油品脱硫的多酸基负载型催化剂及其制备方法
MX2019013522A (es) 2017-05-25 2020-02-13 Rohm & Haas Proceso para preparar metacroleina.
CN115888779B (zh) * 2022-10-31 2024-05-28 鞍山七彩化学股份有限公司 一种丁二酸制备丁二腈的催化剂及丁二腈的制备方法

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Also Published As

Publication number Publication date
KR101223590B1 (ko) 2013-01-17
MY143359A (en) 2011-04-29
CA2603005A1 (en) 2006-10-05
CN101175568B (zh) 2011-05-25
EP1867387A4 (en) 2009-09-02
KR20070114362A (ko) 2007-12-03
US8716523B2 (en) 2014-05-06
US20090234158A1 (en) 2009-09-17
TWI374056B (cg-RX-API-DMAC7.html) 2012-10-11
EP2204234A1 (en) 2010-07-07
EP1867387B1 (en) 2013-12-04
BRPI0608759A2 (pt) 2010-01-26
KR101208433B1 (ko) 2012-12-05
WO2006104155A1 (ja) 2006-10-05
CN101175568A (zh) 2008-05-07
JP4756890B2 (ja) 2011-08-24
CN101829589A (zh) 2010-09-15
TW200642757A (en) 2006-12-16
KR20120043152A (ko) 2012-05-03
JP2006272151A (ja) 2006-10-12
EP1867387A1 (en) 2007-12-19

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