CN101781151B - Amino acid chelated medium and trace element water-soluble fertilizer in and preparation method thereof - Google Patents
Amino acid chelated medium and trace element water-soluble fertilizer in and preparation method thereof Download PDFInfo
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- CN101781151B CN101781151B CN 201010124597 CN201010124597A CN101781151B CN 101781151 B CN101781151 B CN 101781151B CN 201010124597 CN201010124597 CN 201010124597 CN 201010124597 A CN201010124597 A CN 201010124597A CN 101781151 B CN101781151 B CN 101781151B
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- 150000001413 amino acids Chemical class 0.000 title claims abstract description 60
- 239000003337 fertilizer Substances 0.000 title claims abstract description 45
- 239000011573 trace mineral Substances 0.000 title claims abstract description 21
- 235000013619 trace mineral Nutrition 0.000 title claims abstract description 21
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 56
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 28
- 150000001875 compounds Chemical class 0.000 claims abstract description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 23
- -1 compound amino acid Chemical class 0.000 claims abstract description 16
- 239000005648 plant growth regulator Substances 0.000 claims abstract description 14
- 239000002994 raw material Substances 0.000 claims abstract description 8
- 235000001014 amino acid Nutrition 0.000 claims description 57
- 238000001914 filtration Methods 0.000 claims description 18
- 239000000243 solution Substances 0.000 claims description 17
- 229930191978 Gibberellin Natural products 0.000 claims description 16
- 238000006243 chemical reaction Methods 0.000 claims description 16
- 239000003448 gibberellin Substances 0.000 claims description 16
- 239000007864 aqueous solution Substances 0.000 claims description 15
- IXORZMNAPKEEDV-OBDJNFEBSA-N gibberellin A3 Chemical class C([C@@]1(O)C(=C)C[C@@]2(C1)[C@H]1C(O)=O)C[C@H]2[C@]2(C=C[C@@H]3O)[C@H]1[C@]3(C)C(=O)O2 IXORZMNAPKEEDV-OBDJNFEBSA-N 0.000 claims description 14
- 239000003375 plant hormone Substances 0.000 claims description 14
- 239000007921 spray Substances 0.000 claims description 14
- RNMDNPCBIKJCQP-UHFFFAOYSA-N 5-nonyl-7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-ol Chemical compound C(CCCCCCCC)C1=C2C(=C(C=C1)O)O2 RNMDNPCBIKJCQP-UHFFFAOYSA-N 0.000 claims description 13
- 239000004255 Butylated hydroxyanisole Substances 0.000 claims description 13
- 235000019282 butylated hydroxyanisole Nutrition 0.000 claims description 13
- CZBZUDVBLSSABA-UHFFFAOYSA-N butylated hydroxyanisole Chemical group COC1=CC=C(O)C(C(C)(C)C)=C1.COC1=CC=C(O)C=C1C(C)(C)C CZBZUDVBLSSABA-UHFFFAOYSA-N 0.000 claims description 13
- 229940043253 butylated hydroxyanisole Drugs 0.000 claims description 13
- 238000007689 inspection Methods 0.000 claims description 13
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 claims description 13
- 239000004299 sodium benzoate Substances 0.000 claims description 13
- 235000010234 sodium benzoate Nutrition 0.000 claims description 13
- 239000012752 auxiliary agent Substances 0.000 claims description 12
- 239000007790 solid phase Substances 0.000 claims description 12
- JEIPFZHSYJVQDO-UHFFFAOYSA-N ferric oxide Chemical compound O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 10
- 239000002245 particle Substances 0.000 claims description 8
- 239000000843 powder Substances 0.000 claims description 8
- 238000010438 heat treatment Methods 0.000 claims description 5
- 238000001694 spray drying Methods 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 2
- PRPINYUDVPFIRX-UHFFFAOYSA-N 1-naphthaleneacetic acid Chemical compound C1=CC=C2C(CC(=O)O)=CC=CC2=C1 PRPINYUDVPFIRX-UHFFFAOYSA-N 0.000 claims 2
- HCWYXKWQOMTBKY-UHFFFAOYSA-N calcium;dodecyl benzenesulfonate Chemical compound [Ca].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 HCWYXKWQOMTBKY-UHFFFAOYSA-N 0.000 claims 2
- 238000010521 absorption reaction Methods 0.000 abstract description 19
- 238000004519 manufacturing process Methods 0.000 abstract description 11
- 235000016709 nutrition Nutrition 0.000 abstract description 2
- 230000035764 nutrition Effects 0.000 abstract description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 49
- 239000011575 calcium Substances 0.000 description 49
- 239000011777 magnesium Substances 0.000 description 49
- 229910052791 calcium Inorganic materials 0.000 description 48
- 229910052749 magnesium Inorganic materials 0.000 description 46
- 239000005864 Sulphur Substances 0.000 description 45
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 44
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 44
- 241000196324 Embryophyta Species 0.000 description 20
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical group [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 19
- 229910052796 boron Inorganic materials 0.000 description 19
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 16
- 239000010949 copper Substances 0.000 description 16
- 239000011701 zinc Substances 0.000 description 16
- 229910052725 zinc Inorganic materials 0.000 description 16
- 235000013399 edible fruits Nutrition 0.000 description 15
- 239000011593 sulfur Substances 0.000 description 15
- 229910052717 sulfur Inorganic materials 0.000 description 15
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 14
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 14
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 14
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 14
- 239000000470 constituent Substances 0.000 description 14
- 229910052802 copper Inorganic materials 0.000 description 14
- 239000011734 sodium Substances 0.000 description 14
- 229910052708 sodium Inorganic materials 0.000 description 14
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 12
- 239000011733 molybdenum Substances 0.000 description 12
- 229910052750 molybdenum Inorganic materials 0.000 description 12
- 239000002253 acid Substances 0.000 description 11
- KWKXNDCHNDYVRT-UHFFFAOYSA-N dodecylbenzene Chemical compound CCCCCCCCCCCCC1=CC=CC=C1 KWKXNDCHNDYVRT-UHFFFAOYSA-N 0.000 description 11
- 239000010977 jade Substances 0.000 description 11
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 10
- 239000004327 boric acid Substances 0.000 description 10
- RNZCSKGULNFAMC-UHFFFAOYSA-L zinc;hydrogen sulfate;hydroxide Chemical compound O.[Zn+2].[O-]S([O-])(=O)=O RNZCSKGULNFAMC-UHFFFAOYSA-L 0.000 description 10
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 7
- 235000018660 ammonium molybdate Nutrition 0.000 description 7
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 7
- 229910000366 copper(II) sulfate Inorganic materials 0.000 description 7
- 229910001629 magnesium chloride Inorganic materials 0.000 description 7
- 239000011609 ammonium molybdate Substances 0.000 description 6
- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 description 6
- 229940010552 ammonium molybdate Drugs 0.000 description 6
- 239000011572 manganese Substances 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 235000015097 nutrients Nutrition 0.000 description 6
- 230000000050 nutritive effect Effects 0.000 description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 5
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 5
- 235000019341 magnesium sulphate Nutrition 0.000 description 5
- 229910052748 manganese Inorganic materials 0.000 description 5
- 239000011785 micronutrient Substances 0.000 description 5
- 235000013369 micronutrients Nutrition 0.000 description 5
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical group [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 4
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 4
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 4
- 235000011130 ammonium sulphate Nutrition 0.000 description 4
- 239000001110 calcium chloride Substances 0.000 description 4
- 229910001628 calcium chloride Inorganic materials 0.000 description 4
- ISPYRSDWRDQNSW-UHFFFAOYSA-L manganese(II) sulfate monohydrate Chemical compound O.[Mn+2].[O-]S([O-])(=O)=O ISPYRSDWRDQNSW-UHFFFAOYSA-L 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 230000009286 beneficial effect Effects 0.000 description 3
- 238000010790 dilution Methods 0.000 description 3
- 239000012895 dilution Substances 0.000 description 3
- 201000010099 disease Diseases 0.000 description 3
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 3
- 230000012010 growth Effects 0.000 description 3
- XBDUTCVQJHJTQZ-UHFFFAOYSA-L iron(2+) sulfate monohydrate Chemical compound O.[Fe+2].[O-]S([O-])(=O)=O XBDUTCVQJHJTQZ-UHFFFAOYSA-L 0.000 description 3
- 125000002924 primary amino group Chemical class [H]N([H])* 0.000 description 3
- JBQYATWDVHIOAR-UHFFFAOYSA-N tellanylidenegermanium Chemical compound [Te]=[Ge] JBQYATWDVHIOAR-UHFFFAOYSA-N 0.000 description 3
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 2
- 240000003768 Solanum lycopersicum Species 0.000 description 2
- 229930002875 chlorophyll Natural products 0.000 description 2
- 235000019804 chlorophyll Nutrition 0.000 description 2
- ATNHDLDRLWWWCB-AENOIHSZSA-M chlorophyll a Chemical compound C1([C@@H](C(=O)OC)C(=O)C2=C3C)=C2N2C3=CC(C(CC)=C3C)=[N+]4C3=CC3=C(C=C)C(C)=C5N3[Mg-2]42[N+]2=C1[C@@H](CCC(=O)OC\C=C(/C)CCC[C@H](C)CCC[C@H](C)CCCC(C)C)[C@H](C)C2=C5 ATNHDLDRLWWWCB-AENOIHSZSA-M 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- IXORZMNAPKEEDV-UHFFFAOYSA-N gibberellic acid GA3 Natural products OC(=O)C1C2(C3)CC(=C)C3(O)CCC2C2(C=CC3O)C1C3(C)C(=O)O2 IXORZMNAPKEEDV-UHFFFAOYSA-N 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 230000001737 promoting effect Effects 0.000 description 2
- 208000002874 Acne Vulgaris Diseases 0.000 description 1
- 244000291564 Allium cepa Species 0.000 description 1
- 235000002732 Allium cepa var. cepa Nutrition 0.000 description 1
- 240000002234 Allium sativum Species 0.000 description 1
- 235000017060 Arachis glabrata Nutrition 0.000 description 1
- 244000105624 Arachis hypogaea Species 0.000 description 1
- 235000010777 Arachis hypogaea Nutrition 0.000 description 1
- 235000018262 Arachis monticola Nutrition 0.000 description 1
- 244000178993 Brassica juncea Species 0.000 description 1
- 235000005855 Brassica juncea var. subintegrifolia Nutrition 0.000 description 1
- 235000010149 Brassica rapa subsp chinensis Nutrition 0.000 description 1
- 235000000536 Brassica rapa subsp pekinensis Nutrition 0.000 description 1
- 241000499436 Brassica rapa subsp. pekinensis Species 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- 241000220225 Malus Species 0.000 description 1
- 235000011430 Malus pumila Nutrition 0.000 description 1
- 235000015103 Malus silvestris Nutrition 0.000 description 1
- 241000220324 Pyrus Species 0.000 description 1
- 244000061458 Solanum melongena Species 0.000 description 1
- 235000002597 Solanum melongena Nutrition 0.000 description 1
- 244000061456 Solanum tuberosum Species 0.000 description 1
- 235000002595 Solanum tuberosum Nutrition 0.000 description 1
- 206010042496 Sunburn Diseases 0.000 description 1
- 235000009754 Vitis X bourquina Nutrition 0.000 description 1
- 235000012333 Vitis X labruscana Nutrition 0.000 description 1
- 240000006365 Vitis vinifera Species 0.000 description 1
- 235000014787 Vitis vinifera Nutrition 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 206010000496 acne Diseases 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- 230000006229 amino acid addition Effects 0.000 description 1
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Inorganic materials [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 239000011790 ferrous sulphate Substances 0.000 description 1
- 235000003891 ferrous sulphate Nutrition 0.000 description 1
- 235000004611 garlic Nutrition 0.000 description 1
- 239000003630 growth substance Substances 0.000 description 1
- 208000021245 head disease Diseases 0.000 description 1
- 208000006278 hypochromic anemia Diseases 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000020232 peanut Nutrition 0.000 description 1
- 235000021017 pears Nutrition 0.000 description 1
- 230000029553 photosynthesis Effects 0.000 description 1
- 238000010672 photosynthesis Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 230000017423 tissue regeneration Effects 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
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- Fertilizers (AREA)
Abstract
The invention belongs to a water-soluble fertilizer in the field of agriculture production, in particular to an amino acid chelated medium and trace element water-soluble fertilizer and a preparation method thereof. The trace element water-soluble fertilizer is prepared by chelating raw materials, wherein the raw materials comprise the following components in part by weight: 45-55 parts of compound amino acid water solution, 39-43 parts of medium element compound, 8.5-10.8 parts of trace element compound, 1.2-2 parts of assistant and 0.6-0.8 part of plant growth regulator, wherein the compound amino acid water solution contains not less than 26 percent of free amino acid, not less than 12 percent of nitrogen and the balance of water solution. The preparation method is completed by four steps, can further improve the absorption utilization rate of plants, and has complete nutrition and high absorption and utilization rate.
Description
Technical field:
The invention belongs to trace element water-soluble fertilizer and preparation method thereof in the water-soluble fertilizer of agricultural production, particularly chelating amino acids.
Background technology
Through water dissolution or dilution, be used for fertigation, leaf dressing, soilless culture, seed soaking and dip in the liquid or solid fertilizer of the purposes such as root, be called water-soluble fertilizer (water-soluble fertilizer is defined as the NY1429-2007 of Ministry of Agriculture standard, and standard 3.1 water-soluble fertilizers define namely " to contain the amino acid water-soluble fertilizer ").All kinds of plant nutrients and the plant-growth regulator of general solubility all can be used as water-soluble fertilizer.Contain the amino acid water-soluble fertilizer, utilize the chelating amino acids plant nutrient, make inorganic elements become organic chelated attitude element, absorption rate further improves, and shows as with strong points, fertilizer efficiency is fast, fertilizer application amount is few, saves manpower, obvious effect of increasing production, and can avoid soil to the fixed action of its a little nutrients, economical and efficient.
Existing market provides contains the amino acid water-soluble fertilizer, be mainly according to the NY1429-2007 of Ministry of Agriculture standard, the standard production that namely " contains the amino acid water-soluble fertilizer " although also can play certain effect during use, but shortcoming is: nutritive element content is low, and use cost is high; The nutritive element composition is incomplete, do not promote other nutritive element that main nutrient elements absorbs, namely do not consider the absorption of mutually promoting of each nutritive element, synergy, so the plant absorbing utilization ratio is lower, therefore economic, efficient, the safe novel amino acid water-soluble fertilizer that contains of research and development, have positive realistic meaning to agriculture production.
Summary of the invention:
The purpose of this invention is to provide trace element water-soluble fertilizer and preparation method thereof in a kind of chelating amino acids, it can further improve the absorption rate of plant, and nutrition is higher than the hypersorption utilization ratio.
Technical scheme of the present invention is to provide trace element water-soluble fertilizer in a kind of chelating amino acids, it consists of water-soluble fertilizer after by raw material weight umber chelating, its material component is: complex amino acid aqueous solution 45-55 part, moderate-element compound 39-43 part, trace compound 8.5-10.8 part, auxiliary agent 1.2-2 part, plant-growth regulator 0.6-0.8 divide, complex amino acid aqueous solution is free aminoacid content 〉=26%, nitrogen content 〉=12%, all the other are the solution of water.
The combination of anhydrous magnesium sulfate, sulphur content 〉=24% and the nitrogen content of the four water-calcium nitrate that described moderate-element compound 39-43 part is calcium chloride, calcium content 〉=16% and nitrogen content 〉=11% of calcium content 〉=35%, magnesium chloride, magnesium content 〉=26% and sulphur content 〉=29% of magnesium content 〉=25% 〉=20% ammonium sulfate.
The cupric sulfate pentahydrate of Zinc Sulphate Monohydrate, copper content 〉=25% and sulphur content 〉=16% of boric acid, zinc content 〉=35% and sulphur content 〉=21% that described trace compound 8.5-10.8 part is boron-containing quantity 〉=17%, contain the combination of manganese sulfate monohydrate of ferrous sulfate monohydrate, manganese content 〉=30% and sulphur content 〉=15% of four water ammonium molybdates, iron-holder 〉=31% and sulphur content 〉=15% of molybdenum amount 〉=52%.
Described auxiliary agent 1.2-2 part is butylated hydroxy anisole 0.3-0.5 part, dodecylbenzene semi-annular jade pendant acid calcium 0.4-0.6 part, and polyoxyethylene nonylphenol ether E-13 is 0.2-0.4 part, Sodium Benzoate 0.3-0.5 part.
It is Plant hormones regulators,gibberellins 0.3-0.4 part that described plant-growth regulator 0.6-0.8 divides, naa sodium 0.3-0.4 part.
Trace element water-soluble fertilizer in chelating amino acids is pressed the product weight umber, and its component is:
1) complex amino acid aqueous solution is 50 parts, that is: free aminoacid content 〉=26%, and nitrogen content 〉=12%, all the other are water;
2) moderate-element compound: 21 parts, the calcium chloride of calcium content 〉=35 part, 10 parts of the four water-calcium nitrates of calcium content 〉=16% and nitrogen content 〉=11%, 11 parts, the magnesium chloride of magnesium content 〉=25%;
3) trace compound: 5.5 parts of the boric acid of boron-containing quantity 〉=17%, 2.7 parts of the Zinc Sulphate Monohydrates of zinc content 〉=35% and sulphur content 〉=21%; 2 parts of the cupric sulfate pentahydrates of copper content 〉=25% and sulphur content 〉=16% contain 0.6 part of the four water ammonium molybdate of molybdenum amount 〉=52%;
4) auxiliary agent: 0.3 part of butylated hydroxy anisole, 0.4 part of dodecylbenzene semi-annular jade pendant acid calcium, polyoxyethylene nonylphenol ether E-13,0.2 part, 0.5 part of Sodium Benzoate;
5) plant-growth regulator: 0.3 part of Plant hormones regulators,gibberellins, 0.3 part, naa sodium.
Trace element water-soluble fertilizer in chelating amino acids is pressed the product weight umber, and its component is:
1) complex amino acid aqueous solution is 45 parts, i.e. free aminoacid content 〉=26%, and nitrogen content 〉=12%, all the other are water;
2) moderate-element compound: 18 parts of the anhydrous magnesium sulfates of magnesium content 〉=26% and sulphur content 〉=29%, 25 parts, the magnesium chloride of magnesium content 〉=25%;
3) trace compound: 6 parts of the boric acid of boron-containing quantity 〉=17%, 4 parts of the Zinc Sulphate Monohydrates of zinc content 〉=35% and sulphur content 〉=21%;
4) auxiliary agent: 0.4 part of butylated hydroxy anisole, 0.5 part of dodecylbenzene semi-annular jade pendant acid calcium, polyoxyethylene nonylphenol ether E-13,0.3 part, 0.4 part of Sodium Benzoate;
5) plant-growth regulator: 0.3 part of Plant hormones regulators,gibberellins, 0.4 part, naa sodium.
Trace element water-soluble fertilizer in chelating amino acids is pressed the product weight umber, and its component is:
1) complex amino acid aqueous solution is 55 parts, that is: free aminoacid content 〉=26%, and nitrogen content 〉=12%, all the other are water;
2) moderate-element compound: 24 parts, the ammonium sulfate of sulphur content 〉=24% and nitrogen content 〉=20%, 15 parts of the anhydrous magnesium sulfates of magnesium content 〉=26% and sulphur content 〉=29%;
3) trace compound: 3 parts of the ferrous sulfate monohydrates of iron-holder 〉=31% and sulphur content 〉=15%, 2 parts of the manganese sulfate monohydrates of manganese content 〉=30% and sulphur content 〉=15%, 1 part of the Zinc Sulphate Monohydrate of zinc content 〉=35% and sulphur content 〉=21%, copper content 〉=25% and sulphur content 〉=1 part of 16% cupric sulfate pentahydrate, 1 part of the boric acid of boron-containing quantity 〉=17% contains 0.5 part of the four water ammonium molybdate of molybdenum amount 〉=52%;
4) auxiliary agent: 0.5 part of butylated hydroxy anisole, 0.6 part of dodecylbenzene semi-annular jade pendant acid calcium, polyoxyethylene nonylphenol ether E-13 is 0.4 part, 0.3 part of Sodium Benzoate;
5) plant-growth regulator: 0.4 part of Plant hormones regulators,gibberellins, 0.4 part, naa sodium.
The preparation method of trace element water-soluble fertilizer in chelating amino acids, by consisting of water-soluble fertilizer after raw material weight umber chelating, its preparation process is as follows:
A, chelatropic reaction one: complex amino acid aqueous solution 45-55 part is added the reactor of heating, be warmed to 60 ℃, then add successively butylated hydroxy anisole 0.3-0.5 part, moderate-element compound 39-43 part, heat and keep between temperature 60 C-70 ℃, and constantly stirring, reacting 1-1.5 hour;
B, chelatropic reaction two: in gained solution of upper step, add successively trace compound 8.5-10.8 part, dodecylbenzene semi-annular jade pendant acid calcium 0.4-0.6 part, polyoxyethylene nonylphenol ether E-13 is 0.2-0.4 part, Sodium Benzoate 0.3-0.5 part, Plant hormones regulators,gibberellins 0.3-0.4 part, naa sodium 0.3-0.4 part, heat and keep between temperature 60 C-70 ℃, and constantly stirring, reacting 1.5-2 hour;
C, smart filtering are mixed: with gained solution suction of upper step secondary filter, smart filtering is assorted;
D, the smart filtering of upper step is assorted after gained solution be spray dried to pressed powder or small-particle by spray-drying tower, carry out quality inspection; Quality inspection is qualified, is solid phase prod.
Characteristics of the present invention are:
A kind of chelating amino acids Meso-and micro-nutrients water-soluble fertilizer-high calcium microelement type, high magnesium microelement type, high-sulfur microelement type are provided, make constituent content higher, cost is lower, and absorption rate further improves.
Chelating amino acids Meso-and micro-nutrients water-soluble fertilizer product of the present invention is pressed aminoacid addition nutritive element type, and product is divided into: high calcium microelement type, high magnesium microelement type, high-sulfur microelement type.Every kind of product is all solid phase prod.
Embodiment:
Embodiment 1: trace element water-soluble fertilizer in chelating amino acids-high calcium microelement type
1, technical target of the product (solid phase prod)
Trace element water-soluble fertilizer in chelating amino acids (high calcium microelement type) technical target of the product
| Project | Index |
| Free aminoacid content, % 〉= | 15.5 |
| Calcium (Ca) content, % 〉= | 10.5 |
| Nitrogen (N) content, % 〉= | 8.0 |
| Magnesium (Mg) content, % 〉= | 3.0 |
| Boron (B) content, % 〉= | 1.0 |
| Zinc (Zn) content, % 〉= | 1.0 |
| Copper (Cu) content, % 〉= | 0.55 |
| Molybdenum (Mo) content, % 〉= | 0.3 |
| Water insoluble matter content, %≤ | 5.0 |
| PH value (1+250 doubly dilutes) | 5.0-6.0 |
| Moisture (H 2O)，％≤ | 4.0 |
2, product moiety (following component is the product weight umber, and every part of unit is kilogram)
(1) 50 parts of complex amino acid aqueous solution (all the other are water for free aminoacid content 〉=26%, nitrogen content 〉=12%);
(2) moderate-element compound: 21 parts, calcium chloride (calcium content 〉=35 part), 10 parts of four water-calcium nitrates (calcium content 〉=16%, nitrogen content 〉=11%), 11 parts, magnesium chloride (magnesium content 〉=25%);
(3) trace compound: 5.5 parts of boric acid (boron-containing quantity 〉=17%), 2.7 parts of Zinc Sulphate Monohydrates (zinc content 〉=35%, sulphur content 〉=21%); 2 parts of cupric sulfate pentahydrates (copper content 〉=25%, sulphur content 〉=16%), 0.6 part of four water ammonium molybdate (containing molybdenum amount 〉=52%).
(4) auxiliary agent: 0.3 part of butylated hydroxy anisole, 0.4 part of dodecylbenzene semi-annular jade pendant acid calcium, 0.2 part, alkylphenol-polyethenoxy (13) ether (being polyoxyethylene nonylphenol ether E-13), 0.5 part of Sodium Benzoate;
(5) plant-growth regulator: 0.3 part of Plant hormones regulators,gibberellins, 0.3 part, naa sodium.
3, production technique sketch
A (chelatropic reaction one) → B (chelatropic reaction two) → C (smart filtering is assorted) → D (be spray dried to pressed powder or small-particle, quality inspection is qualified) → solid phase prod
4, production technique is described:
A, chelatropic reaction one: 50 parts of complex amino acid aqueous solution are added the reactor of heating, be warmed to 60 ℃, add successively again 0.3 part of butylated hydroxy anisole, 21 parts, calcium chloride (calcium content 〉=35%), 10 parts of four water-calcium nitrates (calcium content 〉=16%, nitrogen content 〉=11%), 11 parts, magnesium chloride (magnesium content 〉=25%), heat and keep between temperature 60 C-70 ℃, and constantly stirring, reacting 1 hour.
B, chelatropic reaction two: in gained solution of upper step, add successively 5.5 parts of boric acid (boron-containing quantity 〉=17%), Zinc Sulphate Monohydrate (zinc content 〉=35%, sulphur content 〉=21%) 2.7 parts, cupric sulfate pentahydrate (copper content 〉=25%, sulphur content 〉=16%) 2 parts, 0.6 part of four water ammonium molybdate (containing molybdenum amount 〉=52%), 0.4 part of dodecylbenzene semi-annular jade pendant acid calcium, 0.2 part, alkylphenol-polyethenoxy (13) ether (being polyoxyethylene nonylphenol ether E-13), 0.5 part of Sodium Benzoate, 0.3 part of Plant hormones regulators,gibberellins, 0.3 part, naa sodium, heat and keep between temperature 60 C-70 ℃, and constantly stir, reacted 1.5 hours.
C, smart filtering are mixed: with gained solution suction of upper step secondary filter, smart filtering is assorted.
D, the smart filtering of upper step is assorted after gained solution be spray dried to pressed powder or small-particle by spray-drying tower, carry out quality inspection; Quality inspection is qualified, is solid phase prod.
5, the beneficial effect of chelating amino acids Meso-and micro-nutrients water-soluble fertilizer-high calcium microelement type:
(1), this high calcium microelement type product contains nitrogen, magnesium, boron, zinc, copper, the molybdenum element that promotes that calcium constituent absorbs, and the absorption rate of calcium is further improved.
This high calcium microelement type product and the NY1429-2007 of Ministry of Agriculture standard (namely " contain the amino acid water-soluble fertilizer " standard)---the calcium constituent type is compared, and has added in addition nitrogen, magnesium, boron, zinc, copper, molybdenum element.Wherein the nitrogen element promotes the absorption ratio of calcium constituent on blade and fruit; Magnesium elements promotes movement and the exchange of calcium constituent on blade and fruit; Boron promotes the absorption and accumulation of calcium constituent; Zinc element promotes growing and tissue regeneration of plant; Copper promotes the eubolism of plant; The nitrogen fixation of molybdenum involved in plant.Nitrogen, magnesium, boron, zinc, copper, molybdenum are also the essential nutritive elements of plant simultaneously.
(2), this high calcium microelement type product contains gibberellin of plant growth regulator and the naa sodium that promotes that calcium constituent absorbs, and the absorption rate of calcium constituent is further improved.Calcium constituent is difficult to absorb, and must multi-prongedly could promote absorbing of calcium constituent.The formulated receptivity that not only can improve calcium constituent of calcium and Plant hormones regulators,gibberellins also can improve plant drought, the resistance against disadvantage such as disease-resistant; Naa sodium also can promote plant leaf and fruit to the absorbing of calcium constituent, and especially has outstanding performance on fruit tree, vegetables.
Usage and dosage: 1500 times of product dilutions of the present invention, young fruit period, fruit expanding period at apple, grape, pears spray on blade, fruit, be used in conjunction 2-3 time, the water core of effective control fruit, acne pinta, bitter pit, iron head disease, cracked fruit etc., and fruit is large evenly, the hardness of fruit is good, anti-storage, commercial grade obviously improves, volume increase 10-20%; Spray on blade, fruit in the young fruit period on tomato, Chinese cabbage, on eggplant, fruit expanding period, be used in conjunction 2-3 time, effectively prevent and treat the malacopathia, sun burn, canker, fruit-shrink disease of fruit etc., volume increase 10-25%.
(3), this high calcium microelement type product calcium constituent, free aminoacid content improve, particularly calcium element content increases substantially; Can also reach simultaneously the benefit of replenishing simultaneously various nutrient elements, saving of work and time when using, the unit use cost reduces.
This high calcium microelement type product and the NY1429-2007 of Ministry of Agriculture standard (namely " containing the amino acid water-soluble fertilizer ") standard---calcium constituent type product is compared, all meet on this standard base in other technical indicator, calcium element content 〉=10.5%, than standard index 〉=3.0%, be 3.5 times of standard index; Free aminoacid content 〉=15.5%, than standard index 〉=10%, be 1.55 times of standard index.Because product of the present invention meets the NY1429-2007 of Ministry of Agriculture standard fully, so the technology of the present invention suitability for industrialized is produced and spread use on agricultural.
Embodiment 2: trace element water-soluble fertilizer in chelating amino acids---high magnesium microelement type
1, technical target of the product (solid phase prod)
Trace element water-soluble fertilizer in chelating amino acids (high magnesium microelement type) technical target of the product
| Project | Index |
| Free aminoacid content, % 〉= | 13.0 |
| Magnesium (Mg) content, % 〉= | 12.0 |
| Sulphur (S) content, % 〉= | 5.5 |
| Nitrogen (N) content, % 〉= | 5.5 |
| Boron (B) content, % 〉= | 1.1 |
| Zinc (Zn) content, % 〉= | 1.55 |
| Water insoluble matter content, %≤ | 5.0 |
| PH value (1+250 doubly dilutes) | 5.0-6.0 |
| Moisture (H 2O)，％≤ | 4.0 |
2, product moiety (following component is the product weight umber, and every part of unit is kilogram)
(1) 45 parts of complex amino acid aqueous solution (all the other are water for free aminoacid content 〉=26%, nitrogen content 〉=12%);
(2) moderate-element compound: 18 parts of anhydrous magnesium sulfates (magnesium content 〉=26%, sulphur content 〉=29%), 25 parts, magnesium chloride (magnesium content 〉=25%);
(3) trace compound: 6 parts of boric acid (boron-containing quantity 〉=17%), 4 parts of Zinc Sulphate Monohydrates (zinc content 〉=35%, sulphur content 〉=21%);
(4) auxiliary agent: 0.4 part of butylated hydroxy anisole, 0.5 part of dodecylbenzene semi-annular jade pendant acid calcium, 0.3 part, alkylphenol-polyethenoxy (13) ether (being polyoxyethylene nonylphenol ether E-13), 0.4 part of Sodium Benzoate;
(5) plant-growth regulator: 0.3 part of Plant hormones regulators,gibberellins, 0.4 part, naa sodium.
3, production technique sketch
A (chelatropic reaction one) → B (chelatropic reaction two) → C (smart filtering is assorted) → D (be spray dried to pressed powder or small-particle, quality inspection is qualified) → solid phase prod
4, production technique is described:
A, chelatropic reaction one: 45 parts of complex amino acid aqueous solution are added the reactor of heating, be warmed to 60 ℃, then add successively 0.4 part of butylated hydroxy anisole, anhydrous magnesium sulfate (magnesium content 〉=26%, sulphur content 〉=29%) 18 parts, 25 parts, magnesium chloride (magnesium content 〉=25%); Heat and keep between temperature 60 C-70 ℃, and constantly stirring, reacting 1.5 hours.
B, chelatropic reaction two: in gained solution of upper step, add successively 6 parts of boric acid (boron-containing quantity 〉=17%), 4 parts of Zinc Sulphate Monohydrates (zinc content 〉=35%, sulphur content 〉=21%), 0.5 part of dodecylbenzene semi-annular jade pendant acid calcium, 0.3 part, alkylphenol-polyethenoxy (13) ether (being polyoxyethylene nonylphenol ether E-13), 0.4 part of Sodium Benzoate, 0.3 part of Plant hormones regulators,gibberellins, 0.4 part, naa sodium, heat and keep between temperature 60 C-70 ℃, and constantly stirring, reacting 1.5 hours.
C, smart filtering are mixed: with gained solution suction of upper step secondary filter, smart filtering is assorted.
D, the smart filtering of upper step is assorted after gained solution be spray dried to pressed powder or small-particle by spray-drying tower, carry out quality inspection; Quality inspection is qualified, is solid phase prod.
5, chelating amino acids Meso-and micro-nutrients water-soluble fertilizer---the beneficial effect of high magnesium microelement type:
(1), this high magnesium microelement type product is by amino acid whose chelating, makes inorganic magnesium become organic-magnesium, and the absorption rate of magnesium is further improved.
Magnesium is the component of plant chlorophyll, is the promoting agent of plurality of enzymes, is the necessary moderate-element of plant.In agriculture production, traditional fertiliser containing magnesium kind is mainly applied fertilizer by root, and traditional fertiliser containing magnesium kind is because be all mineral compound, and the absorption rate of plant is not high.This high magnesium microelement type product makes inorganic magnesium become organic-magnesium by amino acid whose chelating, and the absorption rate of magnesium is further improved.
(2) this high magnesium microelement type product contains nitrogen, sulphur, boron, the zinc that promotes that magnesium elements absorbs, and promotes photosynthesis of plant, impels chlorophyll to increase, and the absorption rate of magnesium is further improved.
(3) this high magnesium microelement type product contains gibberellin of plant growth regulator and the naa sodium that promotes that magnesium elements absorbs, and also comprises the auxiliary agent that multiple promotion magnesium elements absorbs, and makes the absorption rate of magnesium elements faster.When chlorosis appears in plant, improve very soon after spraying this product.
Usage and dosage: 1000 times of this high magnesium microelement type product thin ups, in earlier stage spray 1-2 time at tomato, potato growth, can prevent and improve the blade yellow, make plant strain growth vigorous, volume increase 8-15%; In earlier stage spray 1-2 time at cotton, peanut growth, make the dark leaf of plant root green, resistance strengthens, volume increase 10-15%.
Embodiment 3: trace element water-soluble fertilizer in chelating amino acids---the high-sulfur microelement type
1, technical target of the product (solid phase prod)
Trace element water-soluble fertilizer in chelating amino acids (high-sulfur microelement type) technical target of the product
| Project | Index |
| Free aminoacid content, % 〉= | 17.5 |
| Sulphur (S) content, % 〉= | 13.8 |
| Magnesium (Mg) content, % 〉= | 4.5 |
| Nitrogen (N) content, % 〉= | 13.5 |
| Iron (Fe) content, % 〉= | 1.1 |
| Manganese (Mn) content, % 〉= | 0.7 |
| Zinc (Zn) content, % 〉= | 0.4 |
| Copper (Cu) content, % 〉= | 0.30 |
| Boron (B) content, % 〉= | 0.19 |
| Molybdenum (Mo) content, % 〉= | 0.25 |
| Water insoluble matter content, %≤ | 5.0 |
| PH value (1+250 doubly dilutes) | 5.0-6.0 |
| Moisture (H 2O)，％≤ | 4.0 |
2, product moiety (following component is the product weight umber, and every part of unit is kilogram)
(1) 55 parts of complex amino acid aqueous solution (all the other are water for free aminoacid content 〉=26%, nitrogen content 〉=12%);
(2) moderate-element compound: 24 parts, ammonium sulfate (sulphur content 〉=24%, nitrogen content 〉=20%), 15 parts of anhydrous magnesium sulfates (magnesium content 〉=26%, sulphur content 〉=29%);
(3) trace compound: ferrous sulfate monohydrate (iron-holder 〉=31%, sulphur content 〉=15%) 3 parts, manganese sulfate monohydrate (manganese content 〉=30%, sulphur content 〉=15%) 2 parts, 1 part of Zinc Sulphate Monohydrate (zinc content 〉=35%, sulphur content 〉=21%), cupric sulfate pentahydrate (copper content 〉=25%, sulphur content 〉=16%) 1 part, 1 part of boric acid (boron-containing quantity 〉=17%), 0.5 part of four water ammonium molybdate (containing molybdenum amount 〉=52%);
(4) auxiliary agent: 0.5 part of butylated hydroxy anisole, 0.6 part of dodecylbenzene semi-annular jade pendant acid calcium, 0.4 part, alkylphenol-polyethenoxy (13) ether (being polyoxyethylene nonylphenol ether E-13), 0.3 part of Sodium Benzoate;
(5) plant-growth regulator: 0.4 part of Plant hormones regulators,gibberellins, 0.4 part, naa sodium.
3, production technique sketch
A (chelatropic reaction one) → B (chelatropic reaction two) → C (smart filtering is assorted) → D (be spray dried to pressed powder or small-particle, quality inspection is qualified) → solid phase prod
4, production technique is described:
A, chelatropic reaction one: 55 parts of complex amino acid aqueous solution are added the reactor of heating, be warmed to 60 ℃, add successively again 0.5 part of butylated hydroxy anisole, ammonium sulfate (sulphur content 〉=24%, nitrogen content 〉=20%) 24 parts, 15 parts of anhydrous magnesium sulfates (magnesium content 〉=26%, sulphur content 〉=29%); Heat and keep between temperature 60 C-70 ℃, and constantly stirring, reacting 1.5 hours.
B, chelatropic reaction two: in gained solution of upper step, add successively ferrous sulfate monohydrate (iron-holder 〉=31%, sulphur content 〉=15%) 3 parts, 2 parts of manganese sulfate monohydrates (manganese content 〉=30%, sulphur content 〉=15%), Zinc Sulphate Monohydrate (zinc content 〉=35%, sulphur content 〉=21%) 1 part, 1 part of cupric sulfate pentahydrate (copper content 〉=25%, sulphur content 〉=16%), 1 part of boric acid (boron-containing quantity 〉=17%), 0.5 part of four water ammonium molybdate (containing molybdenum amount 〉=52%); Add again 0.6 part of dodecylbenzene semi-annular jade pendant acid calcium, 0.4 part, alkylphenol-polyethenoxy (13) ether (being polyoxyethylene nonylphenol ether E-13), 0.3 part of Sodium Benzoate, 0.4 part of Plant hormones regulators,gibberellins, 0.4 part, naa sodium is heated and keeps between temperature 60 C-70 ℃, and constantly stir, reacted 2 hours.
C, smart filtering are mixed: with gained solution suction of upper step secondary filter, smart filtering is assorted.
D, the smart filtering of upper step is assorted after gained solution be spray dried to pressed powder or small-particle by spray-drying tower, carry out quality inspection; Quality inspection is qualified, is solid phase prod.
5, chelating amino acids Meso-and micro-nutrients water-soluble fertilizer---the beneficial effect of high-sulfur microelement type:
(1), this high-sulfur microelement type product contains and promotes the growth regulator that sulphur absorbs and promote the multiple auxiliary agent that sulphur absorbs, and makes the absorption rate of sulphur faster.Sulfur fertilizer is generally executed by root and is carried out, and when plant a lack of sulfur disease occurred, absorption rate sulfur fertilizer faster can comparatively fast be improved Reducing sugar.
(2) this high-sulfur microelement type product makes inorganic sulfur become organosulfur by amino acid whose chelating, and the absorption rate of sulphur is further improved.This high-sulfur microelement type product also contains nitrogen, magnesium, iron, manganese, zinc, copper, boron, molybdenum, can replenish simultaneously the multiple nutrients composition when using, and saves manually, and use cost is lower.
(3) this high-sulfur microelement type product contains nitrogen and the trace element that promotes that element sulphur absorbs, and is more conducive to the absorption of element sulphur.
Usage and dosage: when cotton, soybean plant strain slight of stature, when plant becomes pale green or yellow-green colour, spray with 1000 times of this high-sulfur microelement type product thin ups, can comparatively fast impel plant to recover green, enhancing development.When green onion, garlic, leaf mustard the brown spot occurs when blade, spray or fill with root with this high-sulfur microelement type product dilution 1000, can comparatively fast impel blade to recover green, produce vigorous.
Above embodiment Raw composition is than being raw material composition ratio after preferred, and the present invention is not limited only to this proportioning raw materials.
Claims (1)
1. trace element water-soluble fertilizer in chelating amino acids, it consists of water-soluble fertilizer after by raw material weight umber chelating, its material component is: complex amino acid aqueous solution 45-55 part, moderate-element compound 39-43 part, trace compound 8.5-10.8 part, auxiliary agent 1.2-2 part, plant-growth regulator 0.6-0.8 part, complex amino acid aqueous solution is free aminoacid content 〉=26%, nitrogen content 〉=12%, all the other are the solution of water; Described auxiliary agent 1.2-2 part is butylated hydroxy anisole 0.3-0.5 part, calcium dodecylbenzene sulphonate 0.4-0.6 part, and polyoxyethylene nonylphenol ether E-13 is 0.2-0.4 part, Sodium Benzoate 0.3-0.5 part; Described plant-growth regulator 0.6-0.8 part is Plant hormones regulators,gibberellins 0.3-0.4 part, Nafusaku 0.3-0.4 part;
The preparation method of trace element water-soluble fertilizer in described chelating amino acids, by consisting of water-soluble fertilizer after raw material weight umber chelating, its preparation process is as follows:
A, chelatropic reaction one: complex amino acid aqueous solution 45-55 part is added the reactor of heating, be warmed to 60 ℃, then add successively butylated hydroxy anisole 0.3-0.5 part, moderate-element compound 39-43 part, heat and keep between temperature 60 C-70 ℃, and constantly stirring, reacting 1-1.5 hour;
B, chelatropic reaction two: in gained solution of upper step, add successively trace compound 8.5-10.8 part, calcium dodecylbenzene sulphonate 0.4-0.6 part, polyoxyethylene nonylphenol ether E-13 is 0.2-0.4 part, Sodium Benzoate 0.3-0.5 part, Plant hormones regulators,gibberellins 0.3-0.4 part, Nafusaku 0.3-0.4 part, heat and keep between temperature 60 C-70 ℃, and constantly stirring, reacting 1.5-2 hour;
C, smart filtering are mixed: with gained solution suction of upper step secondary filter, smart filtering is assorted;
D, the smart filtering of upper step is assorted after gained solution be spray dried to pressed powder or small-particle by spray-drying tower, carry out quality inspection; Quality inspection is qualified, is solid phase prod.
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| CN115594545A (en) * | 2022-11-15 | 2023-01-13 | 石家庄上争信息科技有限公司（Cn） | Method for producing Gly-containing water-soluble fertilizer |
| CN116391549A (en) * | 2023-06-09 | 2023-07-07 | 海南省丹若农业有限责任公司 | Method for preventing and treating solar disease of tropical soft-seed pomegranates |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1052107A (en) * | 1990-07-10 | 1991-06-12 | 刘长久 | The prescription of plant nutrition liquid and production technique |
| CN1152565A (en) * | 1995-12-20 | 1997-06-25 | 郑州大学 | Mixed amino-acid complex state multielement micro-fertilizer and making method |
| CN1279229A (en) * | 1999-06-25 | 2001-01-10 | 石丽华 | Nutritive liquid of plant and its preparing process |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1025957C (en) * | 1990-08-30 | 1994-09-21 | 王贞良 | Nutritious type leaf fertilizer |
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1052107A (en) * | 1990-07-10 | 1991-06-12 | 刘长久 | The prescription of plant nutrition liquid and production technique |
| CN1152565A (en) * | 1995-12-20 | 1997-06-25 | 郑州大学 | Mixed amino-acid complex state multielement micro-fertilizer and making method |
| CN1279229A (en) * | 1999-06-25 | 2001-01-10 | 石丽华 | Nutritive liquid of plant and its preparing process |
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