CN102503700B - Titanium-containing trace element fertilizer - Google Patents
Titanium-containing trace element fertilizer Download PDFInfo
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- CN102503700B CN102503700B CN201110364273.0A CN201110364273A CN102503700B CN 102503700 B CN102503700 B CN 102503700B CN 201110364273 A CN201110364273 A CN 201110364273A CN 102503700 B CN102503700 B CN 102503700B
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Abstract
The invention provides a titanium-containing trace element fertilizer, which comprises, by optimal weight, 6.5% of zinc sulfate, 3.0% of manganese sulfate, 0.5% of ferrous sulfate, 0.25% of boric acid, 0.4% of organic chelated titanium, 2.0% of a neutralizing agent, 4.0% of a chelating agent, and the balance of high purity water. The production process is simple, and comprises: respectively dissolving the zinc sulfate, the manganese sulfate, the ferrous sulfate, the boric acid and the organic chelated titanium with the high purity water, uniformly mixing the resulting solutions, adding citric acid to carry out a chelating reaction, adding the neutralizing agent to carry out neutralization, and complementing the balance by using the high purity water, wherein the product is obtained after the balance is stabilized.
Description
Technical field
The present invention relates to a kind of trace element water-soluble fertilizer of titaniferous, be particularly useful for the plantation of potato.
Background technology
Fertilizer is the grain of crop, and in the agricultural modernization taking high yield, high quality, high benefit as target is produced, chemical fertilizer occupies critical positions, and effectively new variety chemical fertilizer and applying fertilizers scientifically is very remarkable to improving crop yield effect.
The chemical fertilizer of using at present mainly contains nitrogenous fertilizer, phosphate fertilizer and potash fertilizer, and peasant in use, is that single variety is used substantially.But facts have proved that single variety uses chemical fertilizer and can not give full play to the effect of used chemical fertilizer.There is in the market composite fertilizer, that nitrogen, phosphorus, potassium is reasonably combined, produce solid-state nitrogen phosphorus potassium Nitrogen, Phosphorus and Potassium and trace element compound fertilizer, but can not meet the plurality of raw materials of plant-growth.Therefore people are researching and producing one kind of multiple micro-fertilizer always, meet the growth requirement of plant, improve output.
In mid-term 1980's, the priorities such as Nankai University of China, Beijing Non-Ferrous Metal Research General Academy start to develop titanium fertilizer.Tai Feiyibei Patent Office of the People's Republic of China and the Ministry of Agriculture are decided to be the patented technology project for agriculture aspect in the first batch.To various crop tests and large-area applications, obtain obvious effect of increasing production and economic benefit through in the past few years.Applying so far area accumulative total reaches more than 100,000,000 mu.
Physiological effect and the increasing yield of titanium to crop, existing large quantity research abroad, is domesticly also carrying out the work.Titanium has following several respects to the effect of crop:
1, promote plant growth;
2, promote nutrition absorption and running;
3, improve chlorophyll content;
4, promote the activity of enzyme;
5, improve product quality;
Potato is called one of " world five generalized grain crops ", more has the good reputation of " underground ginseng " because it is nutritious.Every meal is only eaten whole milk and potato, can obtain all material elements that needed by human body is wanted.Potato property is flat, in having with stomach, adjusting, effect of invigorating the spleen, beneficial gas; Can improve stomach, the constipation that stomach ulcer, duodenal ulcer, chronic cholecystitis, hemorrhoid are caused all has certain curative effect.But because potato is to the having relatively high expectations of soil property, wants High Yield Potato amount also and be not easy, applying fertilizer and also have higher requirements.Titanium fertilizer formula for potato is not also studied at present.
The patent No. is in the patent of ZL96119416.2, has mentioned polynary composite titanium fertilizer, added vitamins C as sequestrant, but vitamins C is extremely unstable in formula, and the placement for some time color of making into fertilizer can become ink black.
Summary of the invention
The present invention is to provide one and contains zinc sulfate, manganous sulfate, and ferrous sulfate, boric acid, organic chelated titanium, neutralizing agent, the fertilizer of sequestrant and high purity water, this system component is simple, and technique is simple, can significantly improve the output of potato.
Each composition weight percent is as follows: a kind of titanium-containing trace element fertilizer, it is the fertilizer that comprises the raw material of following weight per-cent: zinc sulfate 5.0-7.5%, manganous sulfate 1.0-4.0%, ferrous sulfate 0.3-0.6%, boric acid 0.15-0.40%, organic chelated titanium 0.25-0.6%, neutralizing agent 1.0-3.0%, sequestrant 2.0-7.0%, surplus is high purity water.
Preferably formula consists of the fertilizer of the raw material that comprises following weight per-cent: zinc sulfate 6.0-7.0%, manganous sulfate 2.0-3.5%, ferrous sulfate 0.4-0.55%, boric acid 0.2-0.3%, organic chelated titanium 0.3-0.5%, neutralizing agent 1.5-2.5%, sequestrant 3.0-5.0%, surplus is high purity water.
Best formula consists of the fertilizer of the raw material that comprises following weight per-cent: zinc sulfate 6.5%, and manganous sulfate 3.0%, ferrous sulfate 0.5%, boric acid 0.25%, organic chelated titanium 0.4%, neutralizing agent 2.0%, sequestrant 4.0%, surplus is high purity water.
Described neutralizing agent is sodium hydroxide or potassium hydroxide.
Described sequestrant is citric acid or oxysuccinic acid.
The manufacture craft of titanium-containing trace element fertilizer:
First zinc sulfate, manganous sulfate, ferrous sulfate, boric acid, organic chelated titanium are dissolved with high purity water respectively, solution is mixed, add citric acid to carry out chelatropic reaction, then add neutralizing agent to neutralize, surplus is supplied with high purity water, after stable equilibrium and obtain product.
Organic chelated titanium is the former powder of organic chelated titanium of the Yang Ling Ao Bang Biology Science Co., Ltd of purchase, all can be used for the present invention as long as meet the organic chelated titanium of this standard.Organic chelated titanium contains high organic matter and ammonium nitrogen, again due to special role and the effect of titanium, so its symptom showing is: can supplement plant nutrition, can greatly promote again absorption and the utilization of Plant To Nutrient composition.
In this formula, the content of zinc sulfate, manganous sulfate, ferrous sulfate, boric acid, organic chelated titanium is reasonable, give full play to feature separately, for potato provides zinc, manganese, iron, boron, titanium trace element, and each component content is applicable, has brought into play to greatest extent effect.Output and the resistance against diseases of potato are obviously improved.And select citric acid or oxysuccinic acid not only trace element to be effectively combined together as sequestrant, and stable, be difficult for destroyed.
In order to show all effects of potato planting of the present invention, can obviously improve output, prepare titanium-containing trace element fertilizer according to embodiment 3 and compare with the polynary composite titanium fertilizer of using clear water and use ZL96119416.2.
Test site: the former Institute of agricultural sciences of Daxing'an Mountainrange agricultural and forest science institute experimental field
Test design:
Contrast 1 (spray clear water), contrast 2 (1000 times of polynary composite titanium solutions), process titanium-containing trace element fertilizer (1000 times of liquid).On July 3rd, 2010, potato was sprayed for the first time seedling stage, and potato tiller phase July 18 sprays for the second time, and potato florescence July 31 sprays for the third time.Experiment is processed and is established three repetitions, every community 200m
2, potato is two generations of original seed, adopts mechanical planting, row spacing 67cm, spacing in the rows 20cm, mu 4500 strains of keeping a full stand of seedings.
Field management adopts ordinary method, and late blight of potato control adopts professor Zhu Jiehua of Agricultural University Of Hebei to prevent and treat scheme, and in finding to record weekly late blight of potato field incidence after primary infection focus, calculates disease index.
Potato yield result is that product is surveyed in field sampling, each community sampling 2m
2survey product, repeat for three times.
Experimental result:
Potato yield result
Table 1 potato yield result
Table 2 potato sick epidemic disease result in evening
See according to potato yield result, spray titanium-containing trace element fertilizer and contrast with two to compare potato number of blocks and belong to eventually output and all increase to some extent, and the quantity of sick bad potato and bad potato rate are all lower than control group.Therefore spray titanium-containing trace element fertilizer the yield and quality that improves seed potato is had to active effect.
This Recipe is simple, uses organic huge legendary turtle to close titanium and can supplement plant nutrition, can greatly promote again absorption and the utilization of Plant To Nutrient composition, and uses oxysuccinic acid or citric acid to make product more stable as sequestrant.
Embodiment
Below in conjunction with embodiment, to according to embodiment provided by the invention, details are as follows: (to produce 1000g titanium-containing trace element fertilizer as standard)
Embodiment 1:
Zinc sulfate 50g, manganous sulfate 20g, ferrous sulfate 3g, boric acid 1.5g, organic chelated titanium 2.6g, potassium hydroxide 10g, citric acid 2g, surplus is high purity water.
Embodiment 2:
Zinc sulfate 75g, manganous sulfate 40g, ferrous sulfate 6g, boric acid 4g, organic chelated titanium 6g, sodium hydroxide 30g, oxysuccinic acid 7g, surplus is high purity water.
Embodiment 3:
Zinc sulfate 65g, manganous sulfate 30g, ferrous sulfate 5g, boric acid 2.5g, organic chelated titanium 4g, sodium hydroxide 20g, oxysuccinic acid 4g, surplus is high purity water.
Production method is as follows:
First zinc sulfate, manganous sulfate, ferrous sulfate, boric acid, organic chelated titanium are dissolved with high purity water respectively, solution is mixed, add citric acid to carry out chelatropic reaction, then add neutralizing agent to neutralize, surplus is supplied with high purity water, obtains product after stable equilibrium.
Claims (3)
1. a titanium-containing trace element fertilizer, is characterized in that, is made up of following material: zinc sulfate 50g, and manganous sulfate 20g, ferrous sulfate 3g, boric acid 1.5g, organic chelated titanium 2.6g, potassium hydroxide 10g, citric acid 2g, surplus is high purity water.
2. a titanium-containing trace element fertilizer, is characterized in that, is made up of following material: zinc sulfate 75g, and manganous sulfate 40g, ferrous sulfate 6g, boric acid 4g, organic chelated titanium 6g, sodium hydroxide 30g, oxysuccinic acid 7g, surplus is high purity water.
3. a titanium-containing trace element fertilizer, is characterized in that, is made up of following material: zinc sulfate 65g, and manganous sulfate 30g, ferrous sulfate 5g, boric acid 2.5g, organic chelated titanium 4g, sodium hydroxide 20g, oxysuccinic acid 4g, surplus is high purity water.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201110364273.0A CN102503700B (en) | 2011-11-17 | 2011-11-17 | Titanium-containing trace element fertilizer |
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| CN201110364273.0A CN102503700B (en) | 2011-11-17 | 2011-11-17 | Titanium-containing trace element fertilizer |
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| CN102503700A CN102503700A (en) | 2012-06-20 |
| CN102503700B true CN102503700B (en) | 2014-12-03 |
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Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9334200B2 (en) * | 2013-01-28 | 2016-05-10 | Bfp Management, Llc | Fertilizer composition and method for suspending fertilizer in an aqueous solution |
| CN103254016A (en) * | 2013-06-01 | 2013-08-21 | 陈静静 | Production process of hydrolysis-resistant stable titanium ions |
| CN104230452A (en) * | 2013-06-07 | 2014-12-24 | 钛谷（天津）科技有限公司 | Hydrolysis-resistant stable ionic titanium ASIT |
| CN104341234A (en) * | 2013-08-01 | 2015-02-11 | 刘舰艇 | Multi-element compound titanium micro fertilizer |
| CN105254436A (en) * | 2015-11-13 | 2016-01-20 | 钛谷（天津）科技有限公司 | Light energy variable valency ion titanium complex liquid and preparation method thereof |
| CN106431679A (en) * | 2016-10-08 | 2017-02-22 | 东莞市农立农业科技有限公司 | Preparation method of titanium citrate liquid |
| CN106673868A (en) * | 2017-02-28 | 2017-05-17 | 洛阳启禾生态农业科技有限责任公司 | Titanium containing water-soluble fertilizer |
| CN107793262A (en) * | 2017-10-20 | 2018-03-13 | 日正九安科技（北京）有限公司 | A kind of water soluble fertilizer and preparation method thereof |
| CN110511090A (en) * | 2019-09-26 | 2019-11-29 | 稻叶裕治 | A kind of preparation method of the dedicated organic acid chelated microelement liquid of CAM plants |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1063860A (en) * | 1991-02-08 | 1992-08-26 | 天津师范大学 | Plant organic nutrient |
| CN1096506A (en) * | 1993-06-18 | 1994-12-21 | 崔世林 | Organic complex compound trace element fertilizer and production method thereof |
| CN1105009A (en) * | 1994-11-04 | 1995-07-12 | 白云涛 | Chelating micro fertilizer |
| CN1176954A (en) * | 1996-09-17 | 1998-03-25 | 裴圣镐 | Multi-element and composite tiltanium trace element fertilizer |
| CN101575230A (en) * | 2009-06-12 | 2009-11-11 | 陕西惠蕊德农业科技有限公司 | Organic titanium-boron fertilizer and preparation method thereof |
| CN101781151A (en) * | 2010-03-16 | 2010-07-21 | 北京中研美华生化研究所 | Amino acid chelated medium and trace element water-soluble fertilizer in and preparation method thereof |
| CN102153418A (en) * | 2011-05-19 | 2011-08-17 | 湖南省中科农业有限公司 | Efficient amino acid chelated leaf fertilizer containing trace elements |
-
2011
- 2011-11-17 CN CN201110364273.0A patent/CN102503700B/en not_active Expired - Fee Related
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1063860A (en) * | 1991-02-08 | 1992-08-26 | 天津师范大学 | Plant organic nutrient |
| CN1096506A (en) * | 1993-06-18 | 1994-12-21 | 崔世林 | Organic complex compound trace element fertilizer and production method thereof |
| CN1105009A (en) * | 1994-11-04 | 1995-07-12 | 白云涛 | Chelating micro fertilizer |
| CN1176954A (en) * | 1996-09-17 | 1998-03-25 | 裴圣镐 | Multi-element and composite tiltanium trace element fertilizer |
| CN101575230A (en) * | 2009-06-12 | 2009-11-11 | 陕西惠蕊德农业科技有限公司 | Organic titanium-boron fertilizer and preparation method thereof |
| CN101781151A (en) * | 2010-03-16 | 2010-07-21 | 北京中研美华生化研究所 | Amino acid chelated medium and trace element water-soluble fertilizer in and preparation method thereof |
| CN102153418A (en) * | 2011-05-19 | 2011-08-17 | 湖南省中科农业有限公司 | Efficient amino acid chelated leaf fertilizer containing trace elements |
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